Physical Sciences and Mathematics Commons^™

Socially Responsible Investment In A Changing World, Desheng Wu

Electronic Thesis and Dissertation Repository

Socially responsible investment funds make up a growing segment of the investment world. This work considers the impact of including SRI in an investor portfolio both normally and during crisis times. Regimes are identified using Markov switching models. This study is based on return data of four indices, namely, the MSCI World Index, S&P 500, Eurostoxx 50, and the socially responsible index - Advanced Sustainable Performance Index (ASPI). The approaches used are portfolio optimization, GARCH and Markov switching models. Our work shows that a socially responsible index is a good asset to keep in a portfolio. Our simulation results suggest …

Molecular Dynamics Studies Of Interactions Of Phospholipid Membranes With Dehydroergosterol And Penetrating Peptides, Amir Mohsen Pourmousa Abkenar

Electronic Thesis and Dissertation Repository

We have performed molecular modeling of membrane and peptide systems by employing the classical molecular dynamics method and force field parameterizations. In this thesis, our main interest is the interaction of sterols as well as peptides with membranes. The thesis consists of three related projects. The first project focuses on cholesterol (CHOL) and dehydroergosterol (DHE) interacting with palmitoyl-oleoyl phosphatidylcholine (POPC) lipid bilayers. We study the effects of both sterols on the bilayer and compare them with each other. We first study the condensing and ordering effect of these sterols. Then, we study their orientations within the bilayer and relate them …

Study Of Malaria Transmission Dynamics By Mathematical Models, Yanyu Xiao

Electronic Thesis and Dissertation Repository

This Ph.D thesis focuses on modeling transmission and dispersal of one of the most common infectious disease, Malaria. Firstly, an integro-differential equation system is derived, based on the classical Ross-Macdonald model, toemphasize the impacts of latencies on disease dynamics. The novelty lies in the fact that different distributionfunctions are used to describe the variance of individual latencies. The theoretical results of this projectindicate that latencies reduce the basic reproduction number. Secondly, a patch model is derived to examine how travels of human beings affects the transmission and spread of Malaria. Due to coexistence of latency and dispersal, the model turns …

Thermal Plume Transport From Sand And Gravel Pits Potential Thermal Impacts On Cool-Water Streams, Jeffrey M. Markle

Electronic Thesis and Dissertation Repository

Potential thermal impacts from below-water-table aggregate extraction on a cool-water stream were investigated by monitoring thermal plumes, moving through an unconfined glacial-outwash aquifer, and assessing their subsurface persistence. The growing demand for aggregate and increased pressure to pursue extraction in ecologically sensitive areas has driven the need for this work. During a 10-year period, ground and surface water temperatures were measured monthly, including two periods of intensive monitoring (22 months and 2.5 years). The aquifer hydraulic conductivity (K) is quantified at the laboratory and field scale. The mean K’s from the multi-scale tests depend on test-support volume and …

Transition Metal Complexes With Reactive Trimethylsilylchalcogenolate Ligands: Precursors For The Preparation Of Ternary Nanoclusters, Chhatra Bahadur Khadka

Electronic Thesis and Dissertation Repository

The Co²⁺ and Mn²⁺ complexes (N,N´-tmeda)Co(ESiMe₃)₂ (E = S, 1a; E = Se, 1b), (3,5-Me₂C₅H₃N)₂Co(ESiMe₃)₂ (E = S, 2a; E = Se, 2b), [Li(N,N´-tmeda)]₂[(N,N´-tmeda)Mn₅(μ-ESiMe₃)₂(ESiMe₃)₄(μ₄-E)(μ₃-E)₂] (E = S, 3a; E = Se, 3b), [Li(N,N´-tmeda)]₂[Mn(SSiMe₃)₄] (4), [Li(N,N´-tmeda)]4[Mn₄(SeSiMe₃)₄(μ_{3 …}

Quantum Coherence And Interference In Metallic Photonic Crystals And Hybrid Systems, Ali Hatef

Electronic Thesis and Dissertation Repository

In the first part of the thesis, we study the absorption coefficient of quantum dots doped in metallic photonic crystals under different circumferences. We study numerically the temporal evolution of the absorption coefficient profile where a probe field is applied to monitor the absorption process in two cases, when quantum dots are embedded lightly and densely. We also studied the effect of a changing plasma frequency on the absorption profile of quantum dots two possible field configurations. We show that the changes in plasma energy can take the system from the absorption region to the transparent and gain region.

As …

Bifurcations And Stability In Models Of Infectious Diseases, Bernard S. Chan

Electronic Thesis and Dissertation Repository

This work is concerned with bifurcation and stability in models related to various aspects of infections diseases.

First, we study the dynamics of a mathematical model on primary and secondary cytotoxic T-lymphocyte responses to viral infections by Wodarz et al. This model has three equilibria and the stability criteria of them are discussed. We analytically show that periodic solutions may arise from the third equilibrium via Hopf bifurcation. Numerical simulations of the model agree with the theoretical results. These dynamical behaviours occur within biologically realistic parameter range.

After studying the single-strain model, we analyze the bifurcation dynamics of an …

Investigating Interfacial Reactions Of Silver-Containing Films Using Novel Methods, Sarah Danielle Pretty

Electronic Thesis and Dissertation Repository

This thesis presents work on the mechanism and kinetics of the surface film reactions involving the conversion of aqueous species on solid surfaces, and specifically, the reactions of iodide and bromide on silver oxide on silver substrate. These reactions provide a method of immobilizing unwanted halides and are particularly suited to control of hazardous radioactive iodine. Potential applications of this research include nuclear reactor safety and post-accident radioiodine management, and the safe production and use of the medical isotope ¹³¹I.

The aqueous-solid conversion of reaction Ag₂O with X^-(aq) to form AgX on a Ag substrate …

Reactivity Of Dimethylplatinum (Ii) Complexes, Muhieddine A. Safa

Electronic Thesis and Dissertation Repository

This thesis describes a study of dimethylplatinum(II) and dimethylplatinum(IV) complexes containing bidentate nitrogen donor ligands. This work deals with oxidative addition, and reductive elimination chemistry, and it focuses on synthesis, characterization, and reaction mechanisms in studies of these complexes.

The compound [PtMe₂(bpe)], bpe = 1,2-bis(2-pyridyl)ethane, is easily oxidized to give octahedral organoplatinum(IV) complexes and the subsequent chemistry is profoundly influenced by the accompanying strain induced in the 7-membered Pt(bpe) chelate ring. On reaction of [PtMe₂(bpe)] with HCl, the initial product [PtHClMe₂(bpe)] undergoes reductive elimination of methane to form [PtClMe(bpe)]. In contrast, methyl …

Trust-Based Service Selection, Zainab Aljazzaf

Electronic Thesis and Dissertation Repository

Service Oriented Architecture (SOA) is an architectural style that builds enterprise solutions based on services. In SOA, the lack of trust between different parties affects the adoption of such architecture. Trust is as significant a factor for successful online interactions as it is in real life communities, and consequently, it is an important factor that is used as a criterion for service selection. In the context of online services and SOA, the literature shows that the field of trust is not mature. Trust definition and the consideration of the essentials of trust aspects do not reflect the true nature of …

High Power Systems For Dynamic Field Control And Shielding In The Mr Environment, Dustin W. Haw

Electronic Thesis and Dissertation Repository

This thesis addresses several aspects of gradient and shim coil design and fabrication. New design techniques are coupled with experimental construction methods to expand small animal insert gradient and shim technology. The design techniques are also applied to other areas of magnetic resonance hardware.

A custom 2-axis gradient insert coil is designed and fabricated for the purpose of eddy current characterization. The construction tolerances were examined via bench top inductance measurements and eddy currents measurement inside a 7.0 T head-only MR system. A great deal of freedom is available when positioning shielding coils with respect to their corresponding primary coils …

Real Options Models In Real Estate, Jin Won Choi

Electronic Thesis and Dissertation Repository

Our aim in this thesis is to investigate the usefulness of real options analysis, taking case studies of problems in real estate. In the realm of real estate, we consider the following three problems. First, we consider the valuation and usefulness of presale contracts of condominiums, which can be viewed as similar to call options on condominiums. Secondly, we consider the valuation of farm land from the perspective of land developers, who may think of farm land as being similar to call options on subdivision lots. Third, we consider the valuation of opportunities to install solar panels on properties, in …

Generalized Exponential Models With Applications, Iman Mabrouk

Electronic Thesis and Dissertation Repository

We introduce a generalized exponential model whose exact moments and normalizing constant are obtained in terms of Meijer’s generalized hypergeometric G-function. Actually, several widely utilized statistical distributions such as the gamma, Weibull and half-normal constitute particular cases thereof. The generalized inverse Gaussian distribution, which was popularized in the late seventies by Ole Barndor_Neilsen, is also extended by incorporating an additional parameter in its density function, the moments of the resulting distribution being expressed in terms of Bessel functions. A number of data sets were then fitted with diverse exponential-type models for comparison purposes. Additionally, it is shown that the …

Convection Due To Spatially Distributed Heating, Mohammad Zakir Hossain

Electronic Thesis and Dissertation Repository

Convection in an infinite horizontal slot subject to spatially distributed heating has been investigated for a wide range of Prandtl numbers. The primary flow response consists of convection in the form of rolls. When heating wave number alpha is sufficiently large the convection is found to be limited to a layer adjacent to lower wall and a uniform conductive layer emerges at upper section of the slot.

Conditions leading to the emergence of secondary convection have been identified using linear stability of the above primary convection. The secondary convection gives rise to longitudinal, or transverse, or oblique rolls; or to …

Seismic Microzonation Of Great Toronto Area And Influence Of Building Resonances On Measured Soil Responses, Dimitar Genchev Mihaylov

Electronic Thesis and Dissertation Repository

A pilot seismic microzonation of the Greater Toronto Area (GTA) is used to establish the conditions and limitations of geophysical methods for site response investigations in city conditions. Maps of fundamental soil resonant frequencies, amplifications at these frequencies and interpolated average shear wave velocity of top 30 m of soil profile (VS- 30) used in soil classification were compared to the maps of drift thickness and surficial geology for the GTA. The non-applicability of the interpolated VS-30 map for site classification between measured test points is indicated. It is also shown that the soil response cannot be estimated properly using …

Structure And Dynamics Of The Membrane Protein Bacteriorhodopsin Studied By Mass Spectrometry, Yan Pan

Electronic Thesis and Dissertation Repository

Membrane proteins continue to represent a major challenge for most analytical techniques. Using bacteriorhodopsin (BR) as model system, this work aims to develop mass spectrometry (MS)-based approaches for exploring the structure, dynamics and folding of membrane proteins.

As the first step, BR in its native lipid environment was exposed to hydroxyl radicals, which were produced by laser photolysis of hydrogen peroxide. It was found that the resulting methionine (Met) labeling pattern was consistent with the known BR structure. This finding demonstrates that laser-induced oxidative Met labeling can provide structural information on membrane proteins. In subsequent experiments, the effects of different …

Classic Mosaics And Visual Correspondence Via Graph-Cut Based Energy Optimization, Yu Liu

Electronic Thesis and Dissertation Repository

Computer graphics and computer vision were traditionally two distinct research fields focusing on opposite topics. Lately, they have been increasingly borrowing ideas and tools from each other. In this thesis, we investigate two problems in computer vision and graphics that rely on the same tool, namely energy optimization with graph cuts.

In the area of computer graphics, we address the problem of generating artificial classic mosaics, still and animated. The main purpose of artificial mosaics is to help a user to create digital art. First we reformulate our previous static mosaic work in a more principled global optimization framework. Then, …

Three-Dimensional Modeling Of Electrostatic Precipitator Using Hybrid Finite Element - Flux Corrected Transport Technique, Niloofar Farnoosh

Electronic Thesis and Dissertation Repository

This thesis presents the results of a three-dimensional simulation of the entire precipitation process inside a single-electrode one-stage electrostatic precipitator (ESP). The model was designed to predict the motion of ions, gas and solid particles. The precipitator consists of two parallel grounded collecting plates with a corona electrode mounted at the center, parallel to the plates and excited with a high dc voltage. The complex mutual interaction between the three coexisting phenomena of electrostatic field, fluid dynamics and the particulate transport, which affect the ESP process, were taken into account in all the simulations. The electrostatic field and ionic space …

Electronic And Magnetic Excitations In Graphene And Magnetic Nano-Ribbons, Maher Zakaria Ahmed Selim

Electronic Thesis and Dissertation Repository

The discovery of graphene - a 2D material with superior physical properties - in 2004 was important for the intensive global research to find alternatives to three-dimensional (3D) semiconductor materials in industry. At the same time there have been exciting advances for 2D magnetic materials on the nanometer scale. The superior properties of graphene are mainly attributed to its crystal structure and its relatively short-range interactions. These properties show that natural and artificial 2D materials are promising for new applications.

In this thesis we have carried out a comprehensive investigation of the effects of the 2D lattice structures, the roles …

Development Of Single And Multimodality Imaging Probes For Pet, Spect And Fluorescence Imaging, Babak Behnam Azad

Electronic Thesis and Dissertation Repository

This dissertation is in an integrated format discussing three major projects centered around probe development. In the first project, novel metal-chelated and fluorinated GLP-1 derivatives were prepared all containing D-Ala-8, a modification known to improve resistance towards degradation by dipeptidyl-peptidase IV. The effect of increased distance between DOTA and the peptide chain was investigated using a spacer, in order to reduce steric effects imposed by DOTA. Placement of linker and DOTA moieties were varied within the GLP-1 sequence to test for optimal metal-complex location. Binding affinity of peptide derivatives was determined in vitro with CHO/GLP-1R cell line and shown to …

Hyperthermal H2 Induced C–H Bond Cleavage: A Novel Approach To Cross-Linking Of Organic Molecules, Tomas Trebicky

Electronic Thesis and Dissertation Repository

The development of simple and effective methods of incorporating molecular moieties with desirable properties into new functional materials is one of the ultimate goals of material scientists. The work presented in this thesis demonstrates an easy way to accomplish this using a beam of gaseous H₂, which we call hyperthermal hydrogen induced cross-linking (HHIC). We prove theoretically and experimentally that when the kinetic energy of H₂ is raised to ~20 eV, it becomes a light-mass projectile which is energetic enough to knock hydrogen atoms off of organic molecules, but not other heavier atoms. By developing a reactor …

Addressing Computational Complexity Of High Speed Distributed Circuits Using Model Order Reduction, Ehsan Rasekh

Electronic Thesis and Dissertation Repository

Advanced in the fabrication technology of integrated circuits (ICs) over the last couple of years has resulted in an unparalleled expansion of the functionality of microelectronic systems. Today’s ICs feature complex deep-submicron mixed-signal designs and have found numerous applications in industry due to their lower manufacturing costs and higher performance levels. The tendency towards smaller feature sizes and increasing clock rates is placing higher demands on signal integrity design by highlighting previously negligible interconnect effects such as distortion, reflection, ringing, delay, and crosstalk. These effects if not predicted in the early stages of the design cycle can severely degrade circuit …

Improving Search Engine Results By Query Extension And Categorization, Guo Mei

Electronic Thesis and Dissertation Repository

Since its emergence, the Internet has changed the way in which information is distributed and it has strongly influenced how people communicate. Nowadays, Web search engines are widely used to locate information on the Web, and online social networks have become pervasive platforms of communication.

Retrieving relevant Web pages in response to a query is not an easy task for Web search engines due to the enormous corpus of data that the Web stores and the inherent ambiguity of search queries. We present two approaches to improve the effectiveness of Web search engines. The first approach allows us to retrieve …

Uncovering New Bonding Motifs: The Synthesis Of Chalcogen And Phosphorus Complexes Supported By Nitrogen Based Ligands, Caleb D. Martin

Electronic Thesis and Dissertation Repository

The chemistry of the main group elements with nitrogen based ligands has been an area that has received little attention in comparison to transition metals. The preliminary investigations have focused on groups 13 and 14 revealing new bonding motifs and interesting reactivity. This has motivated us to synthesize group 15 and 16 derivatives in new bonding arrangements capable of activating small molecules.

In pursuit of isolating such species, the reactivity of sulfur dichloride and “S(OTf)2” with a series of diazabutadiene (DAB) ligands was explored. The substitution on the ligand was extremely influential on the outcome of the reaction. Alkyl groups …

Advances In Graph-Cut Optimization: Multi-Surface Models, Label Costs, And Hierarchical Costs, Andrew T. Delong

Electronic Thesis and Dissertation Repository

Computer vision is full of problems that are elegantly expressed in terms of mathematical optimization, or energy minimization. This is particularly true of "low-level" inference problems such as cleaning up noisy signals, clustering and classifying data, or estimating 3D points from images. Energies let us state each problem as a clear, precise objective function. Minimizing the correct energy would, hypothetically, yield a good solution to the corresponding problem. Unfortunately, even for low-level problems we are confronted by energies that are computationally hard—often NP-hard—to minimize. As a consequence, a rather large portion of computer vision research is dedicated to proposing …

Active Learning With Generalized Queries, Jun Du

Electronic Thesis and Dissertation Repository

We study active learning with generalized queries in the thesis.

In contrast to supervised learning, active learning can usually achieve the same predictive accuracy with much fewer labeled training examples, thus significantly reducing the labeling cost. However, previous studies of active learning mostly assume that the learner can only ask specific queries (i.e., require labels for specific examples by providing all feature values). For instance, if the task is to predict osteoarthritis based on a patient data set with 30 features, the previous active learners could only ask the specific queries as: does this patient have osteoarthritis, if ID is …

Molecular Dynamics Simulations Of Charged Nanodroplets, Elias Ahadi

Electronic Thesis and Dissertation Repository

Charged nanodroplets represent a fascinating research area due to their unique dynamics and physical properties. These nanodroplets play a key role in electrospray mass spectrometry (ESI-MS), which is a method for analyzing organic/inorganic molecules as well as proteins and other biomolecular species. The mechanism whereby these analytes are transferred into the gas phase as intact ions remains incompletely understood. Two competing models have been proposed to explain the process, the charged residue model (CRM) and the ion evaporation model (IEM). Under the CRM, evaporation of the droplet proceeds until dryness, at which point the analyte ion is left behind. Under …

The Analysis Of Extreme Synoptic Winds, David A. Gatey

Electronic Thesis and Dissertation Repository

Time histories of wind speed and direction from 394 surface observation stations were obtained to calculate synoptic 50-year return period wind speeds for 11 countries in Europe. Preliminary investigation indicated wind speed differences along national borders were successfully reduced by application of a simple consistent methodology to wind speed data. This study considers the ideal methodology for calculating synoptic 50-year return period wind speeds.

Wind speed data requires standardisation through quality control measures, exposure correction and adjustment for disjunct sampling. A quality control algorithm was successfully applied to identify shifts of monthly mean wind speeds and data conversion issues. Three …

Solving Polynomial Systems Via Triangular Decomposition, Changbo Chen

Electronic Thesis and Dissertation Repository

Finding the solutions of a polynomial system is a fundamental problem with numerous applications in both the academic and industrial world. In this thesis, we target on computing symbolically both the real and the complex solutions of nonlinear polynomial systems with or without parameters. To this end, we improve existing algorithms for computing triangular decompositions. Based on that, we develop various new tools for solving polynomial systems and illustrate their effectiveness by applications.

We propose new algorithms for computing triangular decompositions of polynomial systems incrementally. With respect to previous works, our improvements are based on a weakened notion of a …

Asymptotic Theory Of General Multivariate Garch Models, Weibin Jiang

Electronic Thesis and Dissertation Repository

Generalized autoregressive conditional heteroscedasticity (GARCH) models are widely used in financial markets. Parameters of GARCH models are usually estimated by the quasi-maximum likelihood estimator (QMLE). In recent years, economic theory often implies equilibrium between the levels of time series, which makes the application of multivariate models a necessity. Unfortunately the asymptotic theory of the multivariate GARCH models is far from coherent since many algorithms on the univariate case do not extend to multivariate models naturally. This thesis studies the asymptotic theory of the QMLE under mild conditions. We give some counterexamples for the parameter identifiability result in Jeantheau [1998] and …