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2023

Articles 31 - 60 of 66

Full-Text Articles in Physical Sciences and Mathematics

Pro-Environmental Diversification Of Pasture-Based Dairy And Beef Production In Ireland, The United Kingdom And New Zealand: A Scoping Review Of Impacts And Challenges, Maria Markiewicz-Keszycka, Aileen Carter, Donal O'Brien, Maeve Henchion, Simon Mooney, Paul Hynds Jan 2023

Pro-Environmental Diversification Of Pasture-Based Dairy And Beef Production In Ireland, The United Kingdom And New Zealand: A Scoping Review Of Impacts And Challenges, Maria Markiewicz-Keszycka, Aileen Carter, Donal O'Brien, Maeve Henchion, Simon Mooney, Paul Hynds

Articles

Grass-fed dairy and beef products are valued by consumers for their unique nutrient profile, enhanced animal welfare and lower environmental footprint compared to conventional produce derived from animals reared indoors on higher volumes of concentrate feeds (O'Callaghan et al., Reference O'Callaghan, Vázquez-Fresno, Serra-Cayuela, Dong, Mandal, Hennessy, McAuliffe, Dillon, Wishart, Stanton and Ross2018; Moscovici Joubran et al., Reference Moscovici Joubran, Pierce, Garvey, Shalloo and O'Callaghan2021). For the current study, pasture-based production of dairy and beef is defined as a system within which cattle graze freely outdoors on green pasture for ≥6 months per year, using grazed grass as the primary feed …

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Enzymatic Electrochemical Biosensors For Neurotransmitters Detection: Recent Achievements And Trends, Zina Fredj, Baljit Singh Dr., Mohamed Bahri, Peiwu Qin, Mohamad Sawan Jan 2023

Enzymatic Electrochemical Biosensors For Neurotransmitters Detection: Recent Achievements And Trends, Zina Fredj, Baljit Singh Dr., Mohamed Bahri, Peiwu Qin, Mohamad Sawan

Articles

Neurotransmitters (NTs) play a crucial role in regulating the behavioral and physiological functions of the nervous system. Imbalances in the concentrations of NT have been directly linked to various neurological diseases (e.g., Parkinson’s, Huntington’s, and Alzheimer’s disease), in addition to multiple psychotic disorders such as schizophrenia, depression, dementia, and other neurodegenerative disorders. Hence, the rapid and real-time monitoring of the NTs is of utmost importance in comprehending neurological functions and identifying disorders. Among different sensing techniques, electrochemical biosensors have garnered significant interest due to their ability to deliver fast results, compatibility for miniaturization and portability, high sensitivity, and good controllability. …

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Color-Changing Reflection Hologram For Quality Assurance Of Therapeutic Ultrasound Systems, Tatsiana Mikulchyk, John Walsh, Jacinta Browne, Izabela Naydenova, Dervil Cody Jan 2023

Color-Changing Reflection Hologram For Quality Assurance Of Therapeutic Ultrasound Systems, Tatsiana Mikulchyk, John Walsh, Jacinta Browne, Izabela Naydenova, Dervil Cody

Articles

The acoustic output of clinical therapeutic ultrasound equipment requires regular quality assurance (QA) testing to ensure the safety and efficacy of the treatment and that any potentially harmful deviations from the expected output power density are detected as soon as possible. A hologram, consisting of a reflection grating fabricated in an acrylate photopolymer film, has been developed to produce an immediate, visible, and permanent change in the color of the reconstructed hologram from red to green in response to incident ultrasound energy. The influence of the therapeutic ultrasound insonation parameters (exposure time, ultrasound power density, and proximity to the point …

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Review-Electrode Kinetics And Electrolyte Stability In Vanadium Flow Batteries, Andrea Bourke, Daniela Oboroceanu, Nathan Quill, Catherine Lenihan, Maria Alhajji Safi Maria Alhajji Safi, Mallory A. Miller, Robert F. Savinell, Jesse S. Wainright, Varsha Sasikumarsp, Maria Rybalchenko, Pupak Amini, Niall Dalton, Robert P. Lynch, D. Noel Buckley Jan 2023

Review-Electrode Kinetics And Electrolyte Stability In Vanadium Flow Batteries, Andrea Bourke, Daniela Oboroceanu, Nathan Quill, Catherine Lenihan, Maria Alhajji Safi Maria Alhajji Safi, Mallory A. Miller, Robert F. Savinell, Jesse S. Wainright, Varsha Sasikumarsp, Maria Rybalchenko, Pupak Amini, Niall Dalton, Robert P. Lynch, D. Noel Buckley

Articles

Two aspects of vanadium flow batteries are reviewed: electrochemical kinetics on carbon electrodes and positive electrolyte stability. There is poor agreement between reported values of kinetic parameters; however, most authors report that kinetic rates are faster for VIV/VV than for VII/VIII. Cycling the electrode potential increases the rates of both reactions initially due to roughening but when no further roughening is observed, the VII/VIII and VIV/VV reactions are affected oppositely by the pretreatment potential. Anodic pretreatment activates the electrode for the VII/VIII reaction, and deactivates it for VIV/VV. Three states of the carbon surface are suggested: reduced and oxidized states …

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Effects Of Flexibility In Coarse-Grained Models For Bovine Serum Albumin And Immunoglobulin G, Frank Hirschmann, Hender Lopez, Felix Roosen-Runge, Tilo Seydel, Frank Schreiber, Martin Oettel Jan 2023

Effects Of Flexibility In Coarse-Grained Models For Bovine Serum Albumin And Immunoglobulin G, Frank Hirschmann, Hender Lopez, Felix Roosen-Runge, Tilo Seydel, Frank Schreiber, Martin Oettel

Articles

We construct a coarse-grained, structure-based, low-resolution, 6-bead flexible model of bovine serum albumin (BSA, PDB: 4F5S), which is a popular example of a globular protein in biophysical research. The model is obtained via direct Boltzmann inversion using all-atom simulations of a single molecule, and its particular form is selected from a large pool of 6-bead coarse-grained models using two suitable metrics that quantify the agreement in the distribution of collective coordinates between all-atom and coarse-grained Brownian dynamics simulations of solutions in the dilute limit. For immunoglobulin G (IgG), a similar structure-based 12-bead model has been introduced in the literature [Chaudhri …

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Soil Organic Matter Carbon Chemistry Signatures, Hydrophobicity And Humification Index Following Land Use Change In Temperate Peat Soils, Samuel Obeng Apori, Julie Dunne, Michelle Giltrap, Furong Tian Jan 2023

Soil Organic Matter Carbon Chemistry Signatures, Hydrophobicity And Humification Index Following Land Use Change In Temperate Peat Soils, Samuel Obeng Apori, Julie Dunne, Michelle Giltrap, Furong Tian

Articles

Peatlands play a critical role in the global carbon cycle, storing large amounts of carbon because of a net imbalance between primary production and the microbial decomposition of the organic matter. Nevertheless, peatlands have historically been drained for energy sources (e.g. peat briquettes), forestry, or agriculture - practices that could affect the quality of the soil organic matter (SOM) composition, hydrophobicity and humification index. This study compared the effect of land use change on the quality and composition of peatland organic material in Co-Offaly, Ireland. Specifically, drained and grazing peat (grassland), drained and forest plantation peat (forest plantation), drained and …

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Structural, Thermal, Optical, And Mechanical Properties Of Composite Films Developed From The Button Mushroom (Agaricus Bisporus)-Sourced High Molecular Weight Chitosan And Potato Starch, Bullyamini Alimi, Monjural Hoque, Shivani Pathania, Jude Wilson, Brendan Duffy, Jesus Maria Frias Jan 2023

Structural, Thermal, Optical, And Mechanical Properties Of Composite Films Developed From The Button Mushroom (Agaricus Bisporus)-Sourced High Molecular Weight Chitosan And Potato Starch, Bullyamini Alimi, Monjural Hoque, Shivani Pathania, Jude Wilson, Brendan Duffy, Jesus Maria Frias

Articles

Films were fabricated using the button mushroom (Agaricus bisporus) sourced high molecular weight chitosan with or without potato starch using the casting method. Glycerol was used as the plasticizer. Chitosan content in the film-forming solution (FFS) was varied (0.5, 0.75 and 1.0% w/v of FFS) while potato starch (1.0% of FFS) and glycerol (25% of the total solid content in the solution) contents were not varied. The control sample contained only chitosan (1.0% of the FFS) and glycerol. The effect of increasing the content of chitosan on the rheological properties of FFS and the properties of the films were investigated. …

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A Mathematical Model Of Juvenile Delinquency In The New York State, Oluwasegun Micheal Ibrahim Jan 2023

A Mathematical Model Of Juvenile Delinquency In The New York State, Oluwasegun Micheal Ibrahim

Articles

This report presents a mathematical model of juvenile delinquency in the New York State. In particular, we develop a juvenile delinquency system of non-linear differential equations using the mathematical epidemiology framework. In constructing this model, we assume that juvenile delinquency can be studied as a socially infectious disease. The stability of the juvenile delinquency-free equilibrium of the model is examined using the standard non-linear dynamical systems theory technique. We carried out a data fitting based on real-life data from the New York State Criminal Justice Services. The research result reveals that the formulated model conforms with the available data and …

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Nonlinear Two-Dimensional Water Waves With Arbitrary Vorticity, Delia Ionescu-Kruse, Rossen Ivanov Jan 2023

Nonlinear Two-Dimensional Water Waves With Arbitrary Vorticity, Delia Ionescu-Kruse, Rossen Ivanov

Articles

We consider the two-dimensional water-wave problem with a general non-zero vorticity field in a fluid volume with a flat bed and a free surface. The nonlinear equations of motion for the chosen surface and volume variables are expressed with the aid of the Dirichlet-Neumann operator and the Green function of the Laplace operator in the fluid domain. Moreover, we provide new explicit expressions for both objects. The field of a point vortex and its interaction with the free surface is studied as an example. In the small-amplitude long-wave Boussinesq and KdV regimes, we obtain appropriate systems of coupled equations for …

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The Lagrangian Formulation For Wave Motion With A Shear Current And Surface Tension, Conor Curtin, Rossen Ivanov Jan 2023

The Lagrangian Formulation For Wave Motion With A Shear Current And Surface Tension, Conor Curtin, Rossen Ivanov

Articles

The Lagrangian formulation for the irrotational wave motion is straightforward and follows from a Lagrangian functional which is the difference between the kinetic and the potential energy of the system. In the case of fluid with constant vorticity, which arises for example when a shear current is present, the separation of the energy into kinetic and potential is not at all obvious and neither is the Lagrangian formulation of the problem. Nevertheless, we use the known Hamiltonian formulation of the problem in this case to obtain the Lagrangian density function, and utilising the Euler-Lagrange equations we proceed to derive some …

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Sustainable Utilisation And Management Of Food Waste For High-Value Products, Amit Jaiswal Jan 2023

Sustainable Utilisation And Management Of Food Waste For High-Value Products, Amit Jaiswal

Articles

Welcome to the Special Issue on “Sustainable Utilisation and Management of Food Waste for High-Value Products”. This Special Issue focuses on one of the most critical challenges facing our world today—the efficient management and utilisation of food waste. It presents a variety of scientific investigations from renowned scholars and researchers worldwide to address this challenge, covering an array of topics ranging from fundamental research to real-world applications. Food waste is a global dilemma that requires urgent attention. According to the Food and Agriculture Organization (FAO), approximately one-third of food produced for human consumption worldwide, or around 1.3 billion tons, is …

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Global Short-Term Mortality Risk And Burden Associated With Tropical Cyclones From 1980 To 2019: A Multi-Country Time-Series Study, Wenzhong Huang, Shansan Li, Thomas Vogt, Rongbin Xu, Shilu Tong, Tomas Molina, Pierre Masselot, Antonio Gasparrini, Ben Armstrong, Mathilde Pascal, Dominic Roye, Chris Fook Sheng Ng, Ana Maria Vicedo-Cabrera, Joel Schwartz, Eric Lavigne, Haidong Kan, Patrick J. Goodman, Ariana Zeka, Masahiro Hashizume, Magali Hurtado Dias, Cesar De La Cruz Valencia, Xerxes Seposo, Baltazar Nunes, Joana Madureira, Ho Kim, Whanhee Lee, Aurelio Tobias, Carmen Iniguez, Yue Leon Guo, Shih-Chun Pan, Antonella Zanobetti, Tran Ngoc Dang, Do Van Dung, Tobias Geiger, Christian Otto, Amanda Johnson, Simon Hales, Pei Yu, Zhengyu Yang, Elizabeth A. Ritchie, Yuming Guo Jan 2023

Global Short-Term Mortality Risk And Burden Associated With Tropical Cyclones From 1980 To 2019: A Multi-Country Time-Series Study, Wenzhong Huang, Shansan Li, Thomas Vogt, Rongbin Xu, Shilu Tong, Tomas Molina, Pierre Masselot, Antonio Gasparrini, Ben Armstrong, Mathilde Pascal, Dominic Roye, Chris Fook Sheng Ng, Ana Maria Vicedo-Cabrera, Joel Schwartz, Eric Lavigne, Haidong Kan, Patrick J. Goodman, Ariana Zeka, Masahiro Hashizume, Magali Hurtado Dias, Cesar De La Cruz Valencia, Xerxes Seposo, Baltazar Nunes, Joana Madureira, Ho Kim, Whanhee Lee, Aurelio Tobias, Carmen Iniguez, Yue Leon Guo, Shih-Chun Pan, Antonella Zanobetti, Tran Ngoc Dang, Do Van Dung, Tobias Geiger, Christian Otto, Amanda Johnson, Simon Hales, Pei Yu, Zhengyu Yang, Elizabeth A. Ritchie, Yuming Guo

Articles

The global spatiotemporal pattern of mortality risk and burden attributable to tropical cyclones is unclear. We aimed to evaluate the global short-term mortality risk and burden associated with tropical cyclones from 1980 to 2019.

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Selection And Characterization Of Bacteriocinogenic Lactic Acid Bacteria From The Intestine Of Gilthead Seabream (Sparus Aurata) And Whiting Fish (Merlangius Merlangus): Promising Strains For Aquaculture Probiotic And Food Bio-Preservation, Sarah Cheriet, Sana Lenglitz, Amel Romdhani, Paul Hynds, Mohamed Salah Abbassi, Taofik Ghrairi Jan 2023

Selection And Characterization Of Bacteriocinogenic Lactic Acid Bacteria From The Intestine Of Gilthead Seabream (Sparus Aurata) And Whiting Fish (Merlangius Merlangus): Promising Strains For Aquaculture Probiotic And Food Bio-Preservation, Sarah Cheriet, Sana Lenglitz, Amel Romdhani, Paul Hynds, Mohamed Salah Abbassi, Taofik Ghrairi

Articles

This study sought to evaluate the probiotic properties and the food preservation ability of lactic acid bacteria isolates collected from the intestines of wild marine fishes (gilthead seabream (Sparus aurata) (n = 60) and whiting fish (Merlangius merlangus) (n = 40)) from the Mediterranean sea in the area of Mostaganem city, Algeria. Forty-two isolates were identified as: Enterococcus durans (n = 19), Enterococcus faecium (n = 15), Enterococcus faecalis (n = 4), Lactococcus lactis subp. lactis (n = 3), and Lactobacillus plantarum (n = 1). All isolates showed inhibition to at least one indicator strain, especially against Listeria monocytogenes, Staphylococcus …

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Isolation And Identification Of Chlorate-Reducing Hafnia Sp. From Milk, William P. Mccarthy, Meghana Srinivas, Martin Danaher, Christine O'Connor, Tom F. O'Callaghan, Douwe Van Sinderen, John Kenny, John T. Tobin Jan 2023

Isolation And Identification Of Chlorate-Reducing Hafnia Sp. From Milk, William P. Mccarthy, Meghana Srinivas, Martin Danaher, Christine O'Connor, Tom F. O'Callaghan, Douwe Van Sinderen, John Kenny, John T. Tobin

Articles

Chlorate has become a concern in the food and beverage sector, related to chlorine sanitizers in industrial food production and water treatment. It is of particular concern to regulatory bodies due to the negative health effects of chlorate exposure. This study investigated the fate of chlorate in raw milk and isolated bacterial strains of interest responsible for chlorate breakdown. Unpasteurized milk was demonstrated to have a chlorate-reducing capacity, breaking down enriched chlorate to undetectable levels in 11 days. Further enrichment and isolation using conditions specific to chlorate-reducing bacteria successfully isolated three distinct strains of Hafnia paralvei . Chlorate-reducing bacteria were …

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A Simple Microcalorimetry System To Determine The Adsorption Behaviour Of Acids In Large Adhesive Bond Gaps Using Base-Initiated Solution Polymerisation Of Ethyl-2-Cyanoacrylate, Kevin Raheem, John Cassidy, Tony Betts, Bernard Ryan Jan 2023

A Simple Microcalorimetry System To Determine The Adsorption Behaviour Of Acids In Large Adhesive Bond Gaps Using Base-Initiated Solution Polymerisation Of Ethyl-2-Cyanoacrylate, Kevin Raheem, John Cassidy, Tony Betts, Bernard Ryan

Articles

This work presents the use of a simple microcalorimetry cyanoacrylate (CA) polymerisation system for investigating aspects of CA adhesive cure through gap and adsorption of adhesive acid stabiliser by a range of metal and glass substrates. It is well established that strong acid induced inhibition periods (IPs) are almost directly proportional to the acid concentration in weak base initiated polymerisations of alkyl CAs in tetrahydrofuran (THF). Ethyl cyanoacrylate (ECA) polymerisation IP measurements were used to determine the adsorption of methanesulfonic acid (MSA) in THF or ECA solutions by a range of metal, glass and polypropylene (PP) lap shears surfaces. The …

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Use Of Inner/Outer Sphere Terminology In Electrochemistry—A Hexacyanoferrate Ii/Iii Case Study, John Cassidy, Rafaela Cristina De Carvalho, Tony Betts Jan 2023

Use Of Inner/Outer Sphere Terminology In Electrochemistry—A Hexacyanoferrate Ii/Iii Case Study, John Cassidy, Rafaela Cristina De Carvalho, Tony Betts

Articles

Salts of hexacyanoferrate II/III anions have been widely used as redox couple probe molecules to determine the characteristics of electrode surfaces. Examples include the assessment of electrocatalysts for energy applications and electrocatalysts for the detection of biological or chemical species, as well as the determination of electrochemically active surface areas. An examination of the electrochemical literature, based largely on cyclic voltammetric investigations, reveals a wide range of peak separation and/or heterogeneous electron transfer rate constants, classified sometimes as inner or outer sphere electron transfer processes. Originally developed for the mechanistic interpretation of inorganic transition metal compounds in solution, this terminology …

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Switch-On Luminescent Sensing Of Unlabelled Bacterial Lectin By Terbium(Iii) Glycoconjugate Systems, Karolina Wojtczak, Eva Zahorska, Ian J. Murphy, Finnja Koppel, Gordon Cooke, Alexander Titz, Joseph P. Byrne Jan 2023

Switch-On Luminescent Sensing Of Unlabelled Bacterial Lectin By Terbium(Iii) Glycoconjugate Systems, Karolina Wojtczak, Eva Zahorska, Ian J. Murphy, Finnja Koppel, Gordon Cooke, Alexander Titz, Joseph P. Byrne

Articles

Interactions of lectins with glycoconjugate-terbium(III) self-assembly complexes lead to sensing through enhanced lanthanide luminescence. This glycan-directed sensing paradigm detects an unlabelled lectin (LecA) associated with pathogen P. aeruginosa in solution, without any bactericidal activity. Further development of these probes could have potential as a diagnostic tool.

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On The Modelling Of Short And Intermediate Water Waves, Rossen Ivanov Jan 2023

On The Modelling Of Short And Intermediate Water Waves, Rossen Ivanov

Articles

Most of the model equations for water waves are approximations for the long-wave propagation regimes, since most of the energy of the wave motion is concentrated in these waves. Long waves (or shallow-water waves) are defined usually as the depth to wavelength ratio δ = h/λ < 0.05. Several famous integrable nonlinear equations, like the K d V equation [1,2], are models for long waves of small amplitude. The short waves (or waves over deep water) are usually defined with δ > 0.5, and the intermediate waves (or transitional waves) - with 0.05 < δ < 0.5. The intermediate and short waves received a lot less attention, and one reason is perhaps the fact that the corresponding approximations lead to more complicated, nonlinear and nonlocal equations. In [3] an integral equation for surface waves has been proposed for arbitrary wavelengths and finite depth. The problem has been studied in [4] and model equations both for long and short waves are derived from the governing equations as well. The short-wave effects usually compete with the capillarity effects and then resonances can be observed — these have been studied quite a lot, see for example [5–12]. For the intermediate long waves or for waves on deep water the so-called Benjamin–Ono (BO) [13–15] and the Intermediate Long Wave Equation (ILWE) [16–18] are derived for the internal waves below a flat surface, which leads to some simplifications and these models are in fact integrable.

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The Pierce Decomposition And Pierce Embedding Of Endomorphism Rings Of Abelian P-Groups, Brendan Goldsmith, Luigi Salce Jan 2023

The Pierce Decomposition And Pierce Embedding Of Endomorphism Rings Of Abelian P-Groups, Brendan Goldsmith, Luigi Salce

Articles

We prove that more classes of groups than those described by Pierce have the property that the map Ψ is surjective, and we furnish examples of groups which do not have this property. Several results connecting the Pierce decomposition and the Pierce embedding of End(G) are obtained that allow one to derive general conditions on a group G which ensure that the Pierce embedding of End(G) is not surjective.

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On The Cubic Equation With Its Siebeck–Marden–Northshield Triangle And The Quartic Equation With Its Tetrahedron, Emil Prodanov Jan 2023

On The Cubic Equation With Its Siebeck–Marden–Northshield Triangle And The Quartic Equation With Its Tetrahedron, Emil Prodanov

Articles

The real roots of the cubic and quartic polynomials are studied geometrically with the help of their respective Siebeck–Marden–Northshield equilateral triangle and regular tetrahedron. The Viète trigonometric formulæ for the roots of the cubic are established through the rotation of the triangle by variation of the free term of the cubic. A very detailed complete root classification for the quartic 𝑥4 + 𝑎𝑥3 + 𝑏𝑥2 + 𝑐𝑥 + 𝑑 is proposed for which the conditions are imposed on the individual coefficients 𝑎, 𝑏, 𝑐, and 𝑑. The maximum and minimum lengths of the interval containing the four real roots of …

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Probabilistic Network Analysis Of Social-Ecological Relationships Emerging From Eu Life Projects For Nature And Biodiversity: An Application Of Ergm Models In The Case Study Of The Veneto Region (Italy), Elena Andriollo, Laura Secco, Alberto Caimo, Elena Pisani Jan 2023

Probabilistic Network Analysis Of Social-Ecological Relationships Emerging From Eu Life Projects For Nature And Biodiversity: An Application Of Ergm Models In The Case Study Of The Veneto Region (Italy), Elena Andriollo, Laura Secco, Alberto Caimo, Elena Pisani

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Considering social-ecological relationships in managing protected areas is fundamental to ensuring effective biodiversity conservation and restoration governance. Network analysis offers valuable methods to disentangle intangible relations between and within the social and ecological systems. In this way, it could be possible to identify and integrate multiple social and ecological variables that inevitably affect collaborative environmental governance's effectiveness. Nevertheless, this research area is still nascent, with few methodologies and concrete applications reported in the scientific literature. With this study, we aim to propose a robust novel application of a network methodology to enrich the evaluation of the effectiveness of collaborative environmental …

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Turbulence Phenomena In Magnetohydrodynamic Phase Transitions, Giovambattista Amendola, Mauro Fabrizio, John Murrough Golden Jan 2023

Turbulence Phenomena In Magnetohydrodynamic Phase Transitions, Giovambattista Amendola, Mauro Fabrizio, John Murrough Golden

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The model developed in (Fabrizio in J. Eng. Math., 2023) and (Fabrizio in Int. J. Eng. Sci. 44:529–539, 2006), involving the use of a local Reynolds number, is applied to describe phase transitions in a fluid. Specifically, it is applied in a magnetohydrodynamics context to study the evolution of turbulence in certain phenomena. The relevant equations describing the system are those of Navier-Stokes, Ginzburg-Landau and the magnetohydrodynamic equations, all suitably interconnected.

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Analog Holographic Wavefront Sensor For Defocus And Spherical Aberration Measurement Recorded In A Photopolymer, Emma Branigan, Suzanne Martin, Matthew Sheehan, Kevin Murphy Jan 2023

Analog Holographic Wavefront Sensor For Defocus And Spherical Aberration Measurement Recorded In A Photopolymer, Emma Branigan, Suzanne Martin, Matthew Sheehan, Kevin Murphy

Articles

An analog holographic wavefront sensor (AHWFS), for measurement of low and high order (defocus and spherical aberration) aberration modes has been developed as volume phase holograms in a photopolymer recording medium. This is the first time that high order aberrations such as spherical aberration can be sensed using a volume hologram in a photosensitive medium. Both defocus and spherical aberration were recorded in a multi-mode version of this AHWFS. Refractive elements were used to generate a maximum and minimum phase delay of each aberration which were multiplexed as a set of volume phase holograms in an acrylamide based-photopolymer layer. The …

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Improving The Angular Visibility Of Photopolymer-Based Reflection Holograms For Sensing Applications, Tatsiana Mikulchyk, Kevin Murphy, John Walsh, Suzanne Martin, Dervil Cody, Izabela Naydenova Jan 2023

Improving The Angular Visibility Of Photopolymer-Based Reflection Holograms For Sensing Applications, Tatsiana Mikulchyk, Kevin Murphy, John Walsh, Suzanne Martin, Dervil Cody, Izabela Naydenova

Articles

Volume reflection hologram-based sensors are designed to visibly change colour in response to a target stressor or analyte. However, reflection holograms fabricated in thick photopolymer films are highly angularly selective, making these sensors challenging to view and interpret by non-experts. Here, the use of speckle holography to improve the visibility of reflection holograms is presented. A novel recording approach combining speckle recording techniques with Denisyuk reflection recording geometry is described. The recorded speckle reflection grating operates as a series of multiplexed reflection gratings with a range of spatial frequencies, capable of reflecting light at a wider range of angles. A …

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Triplet Sensitization Enables Bidirectional Isomerization Of Diazocine With 130 Nm Redshift In Excitation Wavelengths, Jussi Isokuortti, Thomas Griebenow, Jan-Simon Von Glasenapp, Tim Raeker, Timo Laaksonen, Rainer Herges, Nikita A. Durandin Jan 2023

Triplet Sensitization Enables Bidirectional Isomerization Of Diazocine With 130 Nm Redshift In Excitation Wavelengths, Jussi Isokuortti, Thomas Griebenow, Jan-Simon Von Glasenapp, Tim Raeker, Timo Laaksonen, Rainer Herges, Nikita A. Durandin

Articles

Diazocines are bridged azobenzenes with phenyl rings connected by a CH2–CH2 group. Despite this rather small structural difference, diazocine exhibits improved properties over azobenzene as a photoswitch and most importantly, its Z configuration is more stable than the E isomer. Herein, we reveal yet another unique feature of this emerging class of photoswitches. In striking contrast to azobenzenes and other photochromes, diazocine can be selectively switched in E / Z direction and most intriguingly from its thermodynamically stable Z to metastable E isomer upon successive excitation of two different triplet sensitizers present in solution at the same time. This approach …

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Modification Of Hyaluronic Acid To Enable Click Chemistry Photo-Crosslinking Of Hydrogels With Tailorable Degradation Profiles, Ciara Buckley Jan 2023

Modification Of Hyaluronic Acid To Enable Click Chemistry Photo-Crosslinking Of Hydrogels With Tailorable Degradation Profiles, Ciara Buckley

Articles

Hyaluronic acid (HA) is a naturally occurring mucopolysaccharide that, due to its inherent bioactivity and extracellular matrix-like structure, has the potential to be utilised extensively in tissue engineering. However, this glycosaminoglycan lacks the properties required for cellular adhesion and photo-crosslinking by UV light, which significantly hinders this polymers applicability. This research presents a method for modifying hyaluronic acid via thiolation and methacrylation to generate a novel photo-crosslinkable polymer with improved physicochemical properties, biocompatibility and the potential to customize biodegradability according to the ratio of monomers used. A decrease in stiffness proportional to increasing thiol concentration was observed when testing the …

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Finally, It Seems To Be Working – The Evolving Valuation Effect Of The European Union’S Emissions Trading System, Benjamin Lynch Jan 2023

Finally, It Seems To Be Working – The Evolving Valuation Effect Of The European Union’S Emissions Trading System, Benjamin Lynch

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This research examines the market reaction to the publication of firm-specific environmental news for participating firms in the European Union’s Emissions Trading System (EU ETS) during its third phase. Our sample of 123 publicly listed participating firms, located in 21 European countries, accounted for 45.43% of emissions in the EU ETS in 2020. Using an event study methodology during the period 2014–2021, we find that positive news was rewarded with increased returns for publication events related to the latter years of the phase (2017–2020) while it had an insignificant impact for earlier year (2013–2016). This indicates that the EU ETS …

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The Potential And Limitations Of Conversational Agents For Chronic Conditions And Well-Being, Ekaterina Uetova, Lucy Hederman, Robert J. Ross, Dympna O'Sullivan Jan 2023

The Potential And Limitations Of Conversational Agents For Chronic Conditions And Well-Being, Ekaterina Uetova, Lucy Hederman, Robert J. Ross, Dympna O'Sullivan

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Conversational agents are becoming more common in the health and wellness domains in part due to assumptions regarding potential improvements in individuals’ outcomes. This paper presents initial findings from a review of conversational agent use in healthcare for chronic conditions and well-being. A search of the literature was performed on electronic databases PubMed, ACM Digital Library, Scopus and IEEE Xplore. Studies were included if they were focused on chronic disorder management, disease prevention or lifestyle change and if systems were tested on target user groups. This paper investigates the health domains, the user profiles and reasons why conversational agents may …

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Towards Sweetness Classification Of Orange Cultivars Using Short‑Wave Nir Spectroscopy, Ayesha Zeb, Waqar Shahid Qureshi, Abdul Ghafoor, Amanullah Malik, Muhammad Imran, Alina Mirza, Mohsin Islam Tiwana, Eisa Alanazi Jan 2023

Towards Sweetness Classification Of Orange Cultivars Using Short‑Wave Nir Spectroscopy, Ayesha Zeb, Waqar Shahid Qureshi, Abdul Ghafoor, Amanullah Malik, Muhammad Imran, Alina Mirza, Mohsin Islam Tiwana, Eisa Alanazi

Articles

The global orange industry constantly faces new technical challenges to meet consumer demands for quality fruits. Instead of traditional subjective fruit quality assessment methods, the interest in the horticulture industry has increased in objective, quantitative, and non-destructive assessment methods. Oranges have a thick peel which makes their non-destructive quality assessment challenging. This paper evaluates the potential of short-wave NIR spectroscopy and direct sweetness classification approach for Pakistani cultivars of orange, i.e., Red-Blood, Mosambi, and Succari. The correlation between quality indices, i.e., Brix, titratable acidity (TA), Brix: TA and BrimA (Brix minus acids), sensory assessment of the fruit, and short-wave NIR …

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The Use Of Transport Time Scales As Indicators Of Pollution Persistence In A Macro-Tidal Setting, Guanghai Gao, John J. O'Sullivan, Aisling Corkery, Zeinab Bedri, Gregory M.P. O'Hare, Wim G. Meijer Jan 2023

The Use Of Transport Time Scales As Indicators Of Pollution Persistence In A Macro-Tidal Setting, Guanghai Gao, John J. O'Sullivan, Aisling Corkery, Zeinab Bedri, Gregory M.P. O'Hare, Wim G. Meijer

Articles

An understanding of water exchange processes is essential for assessing water quality management issues in coastal bays. This paper evaluates the impact of water exchange processes on pollution persistence in a macro-tidal semi-closed coastal bay through two transport time scales (TTS), namely residence time and exposure time. The numerical model was calibrated against field-measured data for various tidal conditions. Simulated current speeds and directions were shown to agree well with the field data. By considering different release scenarios of a conservative tracer by the refinement of an integrated hydrodynamic and solute transport model (the EFDC), the two TTS were used …

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