Physical Sciences and Mathematics Commons^™

Hyperspectral Infrared Imaging Of Surface Phonon-Polaritons In Srtio3, D. J. Lahneman, M. M. Qazilbash

Arts & Sciences Articles

Polaritons have a demonstrated impact on nanophotonic applications in the midinfrared through visible spectral range. Surface phonon-polaritons (SPhPs) offer a way to bring the potential of polaritons to the longer infrared wavelengths. Strontium titanate (STO) is a perovskite polar dielectric with diverse technologically advantageous properties and it can support SPhPs in a uniquely broad spectral range of the far infrared. Despite these advantages, STO has mostly been overlooked as a nanophotonic material. In this work we investigate SPhP propagation in STO in the far-infrared through midinfrared spectral range using broadband, near-field nanospectroscopy. We developed a tabletop, laser sustained plasma light …

Ware River Intensive Watershed Study Data Files - Part 2. Estuarine Receiving Water Quality, Gary F. Anderson

Data

The Ware River is a small coastal estuary draining into the Chesapeake Bay estuary. VIMS monitored the Ware watershed for rain events, runoff, and impacts to the estuary from April 1979 through July 1981. This entry contains the estuarine receiving water quality monitoring data files for the portion of the study known as Part 2 – Estuarine Receiving Water Quality. A set of stations on the tidal estuarine portion of the river were sampled by-monthly during high slack tide events. The stations were also sampled during 24-hour ‘intensive surveys’ and immediately following storm events to document impacts. Methods and results …

Nonlocal Lorentz-Violating Modifications Of Qed, Qian Niu

Undergraduate Honors Theses

We consider nonlocal Lorentz-violating theories, with infinite-derivative quadratic terms. The nonlocal modifications in the form of exponential damping in the propagator lead to a better convergence of amplitudes than in the local theories. Moreover, the nonlocal Lorentz-violating theories are ghost-free and unitary when formulated in Minkowski space. We compute the loop effects assuming one-parameter and two-parameter nonlocal functions. By comparing the lower bound of the nonlocality scale with the Planck scale, we rule out these theories. We then review a more general argument, developed by Collins et al. (2004), that a microscopic theory with Lorentz violation around the Planck scale …

Developing Iron Complexes For Electrocatalytic Hydrogen Generation, Benjamin Travis

Undergraduate Honors Theses

Artificial photosynthesis systems convert solar energy into chemical fuels such as hydrogen gas. Photocatalytic hydrogen generation systems have previously been developed, but reliance on expensive metal catalysts limits the viability of these systems. In order for artificial photosynthesis to be used as a large-scale clean energy solution, it is crucial to discover more active and cost-efficient catalysts.

To this end, several novel iron polypyridyl complexes were synthesized using relatively inexpensive reactants. Electrochemical testing revealed that these complexes are active electrocatalysts for the reduction of protons to generate hydrogen gas. Furthermore, a naphthalene-terminated iron polypyridyl complex was found to be an …

Static And Dynamic Analysis In Cryptographic-Api Misuse Detection Of Mobile Application, Kunyang Li

Undergraduate Honors Theses

With Android devices becoming more advanced and gaining more popularity, the number of cryptographic-API misuses in mobile applications is escalating. Numerous snippets of code in Android are from Stack Overflow and over 90% of them contain several crypto-issues. Various crypto-misuse detectors come out aiming to report vulnerabilities of apps and better secure users’ privacy. These detectors can be broadly classified into two categories based on the analysis strategies employed to catch misuses – static analysis (i.e., by scanning the code base) and dynamic analysis (i.e., by executing the code). However, there are not enough research on comparing their underlying differences, …

Toponym-Assisted Map Georeferencing: Evaluating The Use Of Toponyms For The Digitization Of Map Collections, Karim Bahgat, Daniel Runfola

Arts & Sciences Articles

A great deal of information is contained within archival maps—ranging from historic political boundaries, to mineral resources, to the locations of cultural landmarks. There are many ongoing efforts to preserve and digitize historic maps so that the information contained within them can be stored and analyzed efficiently. A major barrier to such map digitizing efforts is that the geographic location of each map is typically unknown and must be determined through an often slow and manual process known as georeferencing. To mitigate the time costs associated with the georeferencing process, this paper introduces a fully automated method based on map …

Influence Of Salinity On Sav Distribution In A Series Of Intermittently Connected Coastal Lakes, A. Challen Hyman, Rom Lipcius, R. Gray, D. B. Stephens

VIMS Articles

Intermittently closed and open lakes and lagoons (ICOLLs) are coastal lakes that intermittently exchange water with the sea and experience saline intrusions. Understanding effects of seawater exchange on local biota is important to preserve ecosystem functioning and ecological integrity. Coastal dune lakes of northwest Florida are an understudied group of ICOLLs in close geographic proximity and with entrance regimes operating along a frequency continuum. We exploited this natural continuum and corresponding water chemistry gradient to determine effects of water chemistry on resident submersed aquatic vegetation (SAV) distributions in these ecosystems. SAV distribution decreased with increases in salinity, but was unaffected …

Virginia Seafood Sustainability, Samantha E. Askin, Robert A. Fisher

Reports

Virginia’s commercial fisheries operate sustainability under a suite of management tools based upon information received from marine scientists and fishery managers who regularly conduct biological sampling of fish while tracking commercial landings and other gathering of required information. Analyses of fishing effort and overall stock conditions, as well as formulas designed to calculate threshold limits for maintaining sustainable stocks are regularly performed. Restrictions on seasons, size, days at sea, and gear are imposed as needed to achieve management supporting long-term biological sustainability.

Winter Harbor Dredge Channel Data Report, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox, Cameron Green

Reports

Winter Harbor is a tidal creek that flows between a sandy barrier system and an eroding marsh shoreline. It is an important waterway that provides access to the Chesapeake Bay from the Winter Harbor watershed. In the past, Winter Harbor Inlet was the only hydraulic connection from the Winter Harbor watershed and Chesapeake Bay. The two open water areas of Winter Harbor were separated by marsh channels that hydraulically connected to the mouth at the present-day Winter Harbor Inlet. The federally-defined channel at Winter Harbor was authorized by Congress in 1950. It was authorized as a 12 feet (ft) deep, …

Leveraging The Interdependencies Between Barrier Islands And Backbarrier Saltmarshes To Enhance Resilience To Sea-Level Rise, Christopher J. Hein, Michael S. Fenster, Keryn B. Gedan, Jeff R. Tabar, Emily A. Hein, Todd Demunda

VIMS Articles

Barrier islands and their backbarrier saltmarshes have a reciprocal relationship: aeolian and storm processes transport sediment from the beaches and dunes to create and build marshes along the landward fringe of the island. In turn, these marshes exert a stabilizing influence on the barrier by widening the barrier system and forming a platform onto which the island migrates, consequently slowing landward barrier migration and inhibiting storm breaching. Here, we present a novel framework for applying these natural interdependencies to managing coastal systems and enhancing barrier-island resilience. Further, we detail application of these principles through a case study of the design …

Living Shoreline Design Guidelines For Shore Protection In Virginia’S Estuarine Environment, C. Scott Hardaway Jr., Donna A. Milligan, Karen Duhring

Reports

The Chesapeake Bay has about 6.5 million people living in its coastal counties and much of the shoreline is privately-owned. For communities along the shore, the continual shore retreat may be a problem. When land along the shore show signs of erosion, property owners tend to address it.

These guidelines are meant to address the need to educate consultants, contractors, and other professionals in the use of living shoreline strategies. It provides the necessary information to determine where they are appropriate and what is involved in their design and construction. The guidelines focus on the use of created marsh fringes …

Cedarbush Creek Dredge Channel Data Report, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox, Cameron Green

Reports

Cedarbush Creek is located in Gloucester County, Virginia. It is a long, but narrow creek that empties into the York River. The mouth is a wide embayment, but farther north, the creek narrows to about 400 feet wide and extends for about 1.5 miles to its marshy headwaters. Cedarbush Creek has never been dredged, but due to shoaling within the creek, it needs dredging to accommodate vessel traffic. Oliver’s Landing, located near the mouth of Cedarbush Creek, is a working waterfront that supports commercial and recreational boaters in Gloucester. (...)

Data Collection At Fifteen Selected Creeks In Support Of Shallow Water Dredging On Virginia’S Middle Peninsula - Methods & Data Report, Nicholas J. Dinapoli, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox, Cameron Green, Scott Lerberg, Eduardo J. Miles, Alex Demeo, George Brooks

Reports

Federal funding has been historically available for the Army Corps of Engineers for shallow draft navigation projects. However, past and recent subsidies have not provided ample funding at levels to sustain maintenance dredging for the 17 federal navigation channels on the Middle Peninsula. Further, funding for maintenance of non-federal channels has been historically neglected by the Commonwealth of Virginia until the Virginia General Assembly established the Virginia Waterway Maintenance Fund in 2018. For the past decade the Middle Peninsula Chesapeake Bay Public Access Authority, the Middle Peninsula Planning District Commission and its member jurisdictions, and the Virginia Institute of Marine …

Parrotts Creek Dredge Channel Data Report, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox, Cameron W. Green

Reports

Parrotts Creek is located along the Rappahannock River in Middlesex County, VA. The mouth of the creek is about 850 ft wide, but just inside the mouth of the creek, a spit extends from the upland narrowing the creek to about 300 ft before it widens again. Overall, this is a relatively short, undeveloped creek. Most of the development (wharfs, ramps, piers) occur near the mouth. Most of the more inland areas of the creek are surrounded by woodland. The federally-authorized channel was established in 1955 due to the presence of a public ramp and landing area, as well as …

Effects Of Tidal Flooding On Estuarine Biogeochemistry: Quantifying Flood-Driven Nitrogen Inputs In An Urban, Lower Chesapeake Bay Sub-Tributary, Alfonso Macías-Tapia, Margaret R. Mulholland, Corday R. Selden, Jon Derek Loftis, Peter W. Bernhardt

VIMS Articles

Sea level rise has increased the frequency of tidal flooding even without accompanying precipitation in many coastal areas worldwide. As the tide rises, inundates the landscape, and then recedes, it can transport organic and inorganic matter between terrestrial systems and adjacent aquatic environments. However, the chemical and biological effects of tidal flooding on urban estuarine systems remain poorly constrained. Here, we provide the first extensive quantification of floodwater nutrient concentrations during a tidal flooding event and estimate the nitrogen (N) loading to the Lafayette River, an urban tidal sub-tributary of the lower Chesapeake Bay (USA). To enable the scale of …

Differential Nitrogen Uptake By Aquatic Communities In A Chesapeake Bay Tributary And In The Coastal Alaskan Arctic, Brianna Stanley

Dissertations, Theses, and Masters Projects

Nitrogen (N) is one of the essential building blocks for all life and is available in the form of dissolved N in aquatic ecosystems. It is important to understand how this N can support primary and secondary production mediated by phytoplankton and bacteria, respectively, as it can affect both microbial loop biogeochemistry and the higher trophic levels of food webs. Nitrogen studies have traditionally focused on dissolved inorganic N (DIN) as a labile N source. Dissolved organic N (DON), while still often considered refractory, has been increasingly recognized as an important N source supporting primary and secondary production. However, the …

Polyaromatic-Terminated Iron Polypyridyl Complexes For The Functionalization Of Carbon Surfaces And Electrocatalytic Hydrogen Generation, Caroline Marie Margonis

Dissertations, Theses, and Masters Projects

Artificial Photosynthesis (AP) focuses on developing methods for the conversion of solar energy into chemical fuel in the form of H2 and O2. Heterogeneous photocatalytic systems incorporating carbon nanotubes (CNTs) have shown much promise but are currently limited and expensive due to their reliance on noble metals. To that end, this work focuses on the development and synthesis of cheaper naphthalene- and pyrene-terminated iron polypyridyl complexes for use in the simultaneous functionalization of carbon surfaces, electrocatalytic proton reduction, and eventual incorporation in photocatalytic systems. Cyclic voltammetry was used to characterize the adsorption behavior of each complex on the surface of …

Membrane Inlet Mass Spectrometry Method (Reox/Mims) To Measure 15n-Nitrate In Isotope-Enrichment Experiments, Xianbiao Lin, Kaijun Lu, Amber K. Hardison, Et Al

VIMS Articles

Using ¹⁵N stable isotope as a tracer to quantify N transformation rates in isotope-enrichment experiments improves understanding of the N cycle in various ecosystems. However, measuring ¹⁵N-nitrate (¹⁵NO₃⁻) in small volumes of water for these experiments is a major challenge due to the inconvenience of preparing samples by traditional techniques. We developed a “REOX/MIMS” method by applying membrane inlet mass spectrometry (MIMS) to determining ¹⁵NO₃⁻ concentrations in a small volumes of water from isotope-enrichment experiments after converting the dissolved inorganic N to N₂. The nitrates (NO₃^{− …}

Living Shoreline Sea-Level Resiliency: Performance And Adaptive Management Of Existing Sites Year 3 Summary Report, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox, Nick J. Dinapoli

Reports

The focus of this study was to research the resiliency of rock/sand/plant living shoreline protection systems. These systems have been used in Chesapeake Bay for 40 years to reduce erosion, protect infrastructure, and create habitat that is disappearing from the shoreline as sea level rises. The goal was to determine how they have been affected by storm surge and associated wind-driven waves, sea-level rise. This data informed adaptive management strategies to create site-specific morphologically-resilient projects.

The objectives of this 3-year project is monitoring the effectiveness of nature-based resilience projects over time such as those that use hybrid living shoreline management …

Performance Optimization With An Integrated View Of Compiler And Application Knowledge, Ruiqin Tian

Dissertations, Theses, and Masters Projects

Compiler optimization is a long-standing research field that enhances program performance with a set of rigorous code analyses and transformations. Traditional compiler optimization focuses on general programs or program structures without considering too much high-level application operations or data structure knowledge. In this thesis, we claim that an integrated view of the application and compiler is helpful to further improve program performance. Particularly, we study integrated optimization opportunities for three kinds of applications: irregular tree-based query processing systems such as B+ tree, security enhancement such as buffer overflow protection, and tensor/matrix-based linear algebra computation. The performance of B+ tree query …

Data-Driven Reflectance Estimation Under Natural Lighting, Victoria Cooper

Dissertations, Theses, and Masters Projects

Bidirectional Reflectance Distribution Functions, (BRDFs), describe how light is reflected off of a material. BRDFs are captured so that the materials can be re-lit under new while maintaining accuracy. BRDF models can approximate the reflectance of a material, but are unable to accurately represent the full BRDF of the material. Acquisition setups for BRDFs trade accuracy for speed with the most accurate methods, gonioreflectometers, being the slowest. Image-based BRDF acquisition approaches range from using complicated controlled lighting setups to uncontrolled known lighting to assuming the lighting is unknown. We propose a data-driven method for recovering BRDFs under known, but uncontrolled …

Ultrafast Optical Control And Characterization Of Carrier And Spin Dynamics In Novel Magnetic Topological Insulator Systems, Peiwen Liu

Dissertations, Theses, and Masters Projects

Magnetic topological insulators (MTIs) are of considerable interest in developing novel spintronics and quantum computing applications. Under the topological protection by time-reversal Z2 invariant number, magnetic topological insulators are provided with robust electronic and magnetic properties against local perturbations. The quantum anomalous Hall effect (QAHE), which harbors dissipationless chiral edge states in MTIs, provides a competitive platform for future low-power consumption and high-speed spintronic devices. Although the present studies on both bulk and surface magnetic properties in MTIs have made significant progress, the in-depth understanding of the exchange couplings and the interaction between the two magnetization sources is far from …

Measurement Of The Beam-Normal Single-Spin Asymmetry For Elastic Electron Scattering From ^12c And ^27al, D. Androic, David S. Armstrong, Et Al.

Arts & Sciences Articles

We report measurements of the parity-conserving beam-normal single-spin elastic scattering asymmetries Bn on 12C and 27Al, obtained with an electron beam polarized transverse to its momentum direction. These measurements add an additional kinematic point to a series of previous measurements of Bn on 12C and provide a first measurement on 27Al. The experiment utilized the Qweak apparatus at Jefferson Lab with a beam energy of 1.158 GeV. The average laboratory scattering angle for both targets was 7.7∘, and the average Q2 for both targets was 0.024 37 GeV2 (Q=0.1561 GeV). The asymmetries are Bn=−10.68±0.90(stat)±0.57(syst) ppm for 12C and Bn=−12.16±0.58(stat)±0.62(syst) ppm …

Evaluating Epoxy Cure And Adhesion Strength Through Single-Sided Nmr Measurements Of Molecular Mobility, Kayla Copeman

Dissertations, Theses, and Masters Projects

Commonly used in aerospace, automotive, marine, defense, electronic, and manufacturing industries, epoxy adhesives offer advantages over mechanical joints by providing stronger and/or more flexible bonds, more uniform stress distribution, low shrinkage, and lightweight connections between materials. Determination of curing kinetics and properties of interfaces between epoxy and inorganic substrates provides insight that is useful for quality control and defect detection for such applications. Single-sided NMR provides a nondestructive and inexpensive method for probing epoxy materials and spatially resolving the decay of spin-lattice and spin-spin relaxation times (T1 and T2) during and after curing of epoxy resins onto substrates. In this …

Impact Of Canyon Upwelling And Downwelling In The Mid-Atlantic Bight, Haixing Wang

Dissertations, Theses, and Masters Projects

Submarine canyons can impact regional oceanography and provide a conduit for shelf-slope exchanges via topographically induced processes such as canyon upwelling and downwelling. Between Virginia and New York in the Mid-Atlantic Bight (MAB), there are five major shelf-incising canyons (Norfolk, Washington, Baltimore, Wilmington, and Hudson canyons) and four sizable slope-confined canyons (Accomac, Spencer, Lindenkhol, and Toms canyons). Canyon upwelling and downwelling at these canyons have not been well studied. Consequently, the associated hydrographic variability and dynamics inside the canyons and on the adjacent shelf are largely unknown, and the integrated impact of submarine canyons on MAB shelf hydrography and shelf-slope …

Predicting Road Quality Using High Resolution Satellite Imagery: A Transfer Learning Approach, Ethan Brewer, Jason Lin, Peter Kemper, John Hennin, Daniel Runfola

Arts & Sciences Articles

Recognizing the importance of road infrastructure to promote human health and economic development, actors around the globe are regularly investing in both new roads and road improvements. However, in many contexts there is a sparsity—or complete lack—of accurate information regarding existing road infrastructure, challenging the effective identification of where investments should be made. Previous literature has focused on overcoming this gap through the use of satellite imagery to detect and map roads. In this piece, we extend this literature by leveraging satellite imagery to estimate road quality and concomitant information about travel speed. We adopt a transfer learning approach in …

Low-Overhead Techniques For Secure And Reliable Gpu Computing, Gurunath Kadam

Dissertations, Theses, and Masters Projects

In recent years, Graphics Processing Units (GPUs) have become a de facto choice to accelerate the computations in various domains such as machine learning, security, financial and scientific computing. GPUs leverage the inherent data parallelism in the target applications to provide high throughput at superior energy efficiency. Due to the rising usage of GPUs for a large number of applications, they are facing new challenges, especially in the security and reliability domains. From the security side, recently several microarchitectural attacks targeting GPUs have been demonstrated. These attacks leak the secret information stored on GPUs, for example, the parameters of a …

Water Clarity And Suspended Particle Dynamics In The Chesapeake Bay: Local Effects Of Oyster Aquaculture, Regional Effects Of Reduced Shoreline Erosion, And Long-Term Trends In Remotely Sensed Reflectance, Jessica Turner

Dissertations, Theses, and Masters Projects

Water clarity is a key indicator of the ecosystem health in the Chesapeake Bay. Estuarine water clarity fluctuates due to external inputs from the watershed as well as processes occurring within the estuary itself, such as sediment resuspension and organic matter production. Therefore, water clarity requires study at multiple spatial and temporal scales and with multiple metrics. One local-scale process potentially influencing water clarity is shellfish aquaculture. One part of this dissertation examined how water quality and hydrodynamics varied among oyster farms as well as inside versus outside the extent of caged areas located in southern Chesapeake Bay. Current speed …

Estuarine Microbiomes And Biogeochemistry: Impacts Of Spatiotemporal Variation, Algal Blooms, And Microplastics, Samantha Grace Fortin

Dissertations, Theses, and Masters Projects

Estuaries are biogeochemical hotspots connecting terrestrial and coastal ecosystems. Anthropogenic disturbances, including increased nitrogen loading and plastic pollution, may have significant impacts on estuarine carbon and nitrogen cycling by altering microbiome structure and functions. The overarching goal of this dissertation was to examine how microbiomes and their associated biogeochemical processes are influenced by natural variation and anthropogenic disturbances in the York River Estuary (YRE). In chapter 2, spatial and temporal variation in benthic microbiomes and the rates of denitrification, anaerobic ammonium oxidation (anammox), and dissimilatory nitrate reduction to ammonium (DNRA) were examined to determine biotic and abiotic drivers of nitrogen …

Sediment Transport And Trapping On The Ayeyarwady-Martaban Continental Shelf, Matthew Joshua Fair

Dissertations, Theses, and Masters Projects

The Ayeyarwady and Thanlwin Rivers, which primarily drain Myanmar, are together one of the largest point sources of freshwater and sediment to the global ocean. Much of the estimated 600 Mt of river sediment annually carried by the combined Ayeyarwady and Thanlwin River system is delivered to a wide continental shelf in the northern Andaman Sea. Called here the Ayeyarwady-Martaban continental shelf, this area is influenced by strong tides, monsoon conditions, and periodic cyclones; however, the processes that dominate dispersal of fluvial material in the coastal ocean of this system remain poorly understood. The shelf exhibits a dramatic asymmetry of …