Physical Sciences and Mathematics Commons^™

A Mechanistically Guided Approach To Treatment Of Multi-Wavelet Reentry: Experiments In A Computational Model Of Cardiac Propagation, Richard T. Carrick

Graduate College Dissertations and Theses

Atrial fibrillation (AF) is the most common cardiac arrhythmia in the United States today. However, treatment options remain limited despite the enormous magnitude of both AF prevalence and the associated economic cost. Of those treatment options that are available, ablation-based interventional methods have demonstrated the highest rates of long-term cure. Unfortunately, these methods have substantially lower efficacy in patients with heavier burdens of disease, thus leaving the most affected individuals with the least hope for successful treatment.

The focus of this research is to develop a mechanistically guided approach towards the treatment of multi-wavelet reentry (MWR), one of the primary …

Evaluating Stormwater Pollutant Removal Mechanisms By Bioretention In The Context Of Climate Change, Amanda Cording

Graduate College Dissertations and Theses

Stormwater runoff is one of the leading causes of water quality impairment in the U.S. Bioretention systems are ecologically engineered to treat stormwater pollution and offer exciting opportunities to provide local climate change resiliency by reducing peak runoff rates, and retaining/detaining storm volumes, yet implementation is outpacing our understanding of the underlying physical, biological, and chemical mechanisms involved in pollutant removal. Further, we do not know how performance will be affected by increases in precipitation, which are projected to occur in the northeastern U.S. as a result of climate change, or if these systems could act as a source or …

Quantifying Soil Greenhouse Gas Emissions And Soil Carbon Storage To Determine Best Management Practices In Agroecosystems, Tyler Goeschel

Graduate College Dissertations and Theses

Intensive agriculture, coupled with an increase in nitrogen fertilizer use, has contributed significantly to the elevation of atmospheric greenhouse gases (GHGs), including carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O). Rising GHG emissions usually mean a decrease in soil carbon. Currently, soil C is twice that of all standing crop biomass, making it an extremely important player in the C cycle. Fortunately, agricultural management practices have the potential to reduce agricultural GHG emissions whilst increasing soil C. Management practices that impact GHG emissions and soil C include various tillage practices, different N fertilization amounts and treatments (synthetic N, cattle …

An Alternative Sensor Fusion Method For Object Orientation Using Low-Cost Mems Inertial Sensors, Joshua Lee Bouffard

Graduate College Dissertations and Theses

This thesis develops an alternative sensor fusion approach for object orientation using low-cost MEMS inertial sensors. The alternative approach focuses on the unique challenges of small UAVs. Such challenges include the vibrational induced noise onto the accelerometer and bias offset errors of the rate gyroscope. To overcome these challenges, a sensor fusion algorithm combines the measured data from the accelerometer and rate gyroscope to achieve a single output free from vibrational noise and bias offset errors.

One of the most prevalent sensor fusion algorithms used for orientation estimation is the Extended Kalman filter (EKF). The EKF filter performs the fusion …

High Flow Events As Hot Moments Of Reactive Fe And P Export: Impacts Of Land Cover And Seasonality, Braden Rosenberg

Graduate College Dissertations and Theses

High flow events often comprise the majority of annual discharge and riverine geochemical flux of phosphorus (P) and metals such as iron (Fe) and manganese (Mn) due to glacial melt, snowmelt, and storm-driven sustained high flow. Aquatic ecosystem productivity in receiving water bodies such as Lake Champlain and the Gulf of Alaska (GoA) are impacted by the riverine import of nutrients. The magnitude of these high flow events can be a strong predictor of receiving water body conditions, and in some cases can contribute to eutrophication. We explore the intersection of high flow events and land cover in contrasting catchments …

The Impacts Of Climate Change On Precipitation And Hydrology In The Northeastern United States, Justin Guilbert

Graduate College Dissertations and Theses

Shifting climatic regimes can increase or decrease the frequency of extreme hydrologic events (e.g., high and low streamflows) causing large societal and environmental impacts. The impacts are numerous and include human health and safety, the destruction of infrastructure, water resources, nutrient and sediment transport, and within stream ecological health. It is unclear how the hydrology of a given region will shift in response to climate change. This is especially the case in areas that are seasonally snow covered as the interplay of changing temperature, precipitation, and resulting snowpack can lead to an increased risk of flood or drought.

This research …

Evolving Spatially Aggregated Features For Regional Modeling And Its Application To Satellite Imagery, Sam Kriegman

Graduate College Dissertations and Theses

Satellite imagery and remote sensing provide explanatory variables at relatively high resolutions for modeling geospatial phenomena, yet regional summaries are often desirable for analysis and actionable insight. In this paper, we propose a novel method of inducing spatial aggregations as a component of the statistical learning process, yielding regional model features whose construction is driven by model prediction performance rather than prior assumptions. Our results demonstrate that Genetic Programming is particularly well suited to this type of feature construction because it can automatically synthesize appropriate aggregations, as well as better incorporate them into predictive models compared to other regression methods …

Oxygen-Sensitive Luminophores: A Survey Of The Literature And Efforts Toward A Novel Porphyrin-Pillared Zirconium Phosphonate, Joseph Wright

Graduate College Dissertations and Theses

Measurement and mapping of the pressure distribution across the surface of a suitably scaled model is an integral step in the design of any aircraft or automobile. For this purpose, the traditional workhorses of the aeronautic and automotive industries have been pressure taps--small orifices that contain electronic pressure transducers. Unfortunately, in addition to the limited spatial resolution achievable with such devices, their technical complexity and cost constitute serious disadvantages. For more than 35 years, researchers have pursued a fundamentally different alternative: indirect measurement of pressure via oxygen-induced quenching of the luminescence emitted by certain chemical species. Porphyrin complexes of dipositive …

The Role Of Green Leafy Plants In Atmospheric Chemistry: Volatile Emissions And Secondary Organic Aerosol, Rebecca Harvey

Graduate College Dissertations and Theses

Aerosols play important roles in atmospheric and environmental processes. Not only do they impact human health, they also affect visibility and climate. Despite recent advances made to under their sources and fate, there remains a limited understanding of the mechanisms that lead to the formation of aerosols and their ultimate fate in the atmosphere. These knowledge gaps provide the crux of the research reported herein, which has focused on identifying novel sources of atmospheric aerosol, characterizing its physical and optical properties, and rationalizing these properties using an in-depth knowledge of the molecular level mechanisms that led to its formation.

Upon …

Modeling The Spatiotemporal Dynamics Of Cells In The Lung, Joshua Jeremy Pothen

Graduate College Dissertations and Theses

Multiple research problems related to the lung involve a need to take into account the spatiotemporal dynamics of the underlying component cells. Two such problems involve better understanding the nature of the allergic inflammatory response to explore what might cause chronic inflammatory diseases such as asthma, and determining the rules underlying stem cells used to engraft decellularized lung scaffolds in the hopes of growing new lungs for transplantation. For both problems, we model the systems computationally using agent-based modeling, a tool that enables us to capture these spatiotemporal dynamics by modeling any biological system as a collection of agents (cells) …

Comparing Meteoric 10be, In Situ 10be, And Native 9be Across A Diverse Set Of Watersheds, Emily Sophie Greene

Graduate College Dissertations and Theses

The cosmogenic nuclide 10Be is a tool for quantifying earth surface processes that occur on millennial timescales. 10Be is produced in the atmosphere (meteoric 10Be) or in mineral grains (in situ 10Be). Well-understood nuclear physics, physical mixing processes, and the denudation of regolith control concentrations of in situ 10Be; in contrast, a combination of geomorphic, pedogenic, geochemical, and biological processes influence meteoric 10Be concentrations. Some have hypothesized that meteoric 10Be can be used as a tracer of sediment movement if meteoric 10Be is normalized against the concentration of native 9Be in grain coatings. This study aims to better understand Be …

Measurement And Modeling Of Stormwater From Small Suburban Watersheds In Vermont, Joel Nipper

Graduate College Dissertations and Theses

Despite decades of U.S. water quality management efforts, over half of assessed waterbody units were threatened or impaired for designated uses in the most recent assessments, with urban runoff being a leading contributor to those impairments. This cumulative research explores several aspects of urban runoff dynamics through a combination of field study and modeling.

Stormwater ponds are ubiquitous in developed landscapes due to their ability to provide multiple forms of treatment for stormwater runoff. However, evolving design goals have reduced the applicability of much of the early work that was done on pond effectiveness. In this study, we instrumented a …

Long-Term Forest Carbon Storage And Structural Development As Influenced By Land-Use History And Reforestation Approach, Andrea Rose Urbano

Graduate College Dissertations and Theses

Temperate forests are an important carbon sink, yet there is uncertainty regarding land-use history effects on biomass accumulation and carbon storage potential in secondary forests. Understanding long-term biomass dynamics is important for managing forests as carbon sinks and for co-benefits such as watershed protection and biodiversity. However there are many unanswered questions regarding these dynamics in northeastern U.S. forests: How have secondary forests of the U.S. Northeast recovered post nineteenth century agricultural abandonment? How has the region's extensive land-use history influenced long-term structural development and aboveground carbon storage? To answer these questions, we employed a longitudinal study based on twelve …

Edge-Of-Field Water And Phosphorus Losses In Surface And Subsurface Agricultural Runoff, Laura B. Klaiber

Graduate College Dissertations and Theses

Quantifying effectiveness of soil management practices on surface and subsurface water quality at the field scale is becoming increasingly important in the Lake Champlain Basin and other agricultural watersheds. During 2012 and 2013, field plots (22.9 x 45.7 m) were established at the Lake Alice Wildlife Area in Chazy, NY to begin a long-term water quality monitoring study. Plots were established in a cool season grass field (1 ha) leased and managed by the William H. Miner Agricultural Research Institute in Chazy, NY. The soil type transitions from an excessively drained outwash soil on the upslope to a very poorly …

A Multiscale Analysis Of The Factors Controlling Nutrient Dynamics And Cyanobacteria Blooms In Lake Champlain, Peter D. F. Isles

Graduate College Dissertations and Theses

Cyanobacteria blooms have increased in Lake Champlain due to excessive nutrient loading, resulting in negative impacts on the local economy and environmental health. While climate warming is expected to promote increasingly severe cyanobacteria blooms globally, predicting the impacts of complex climate changes on individual lakes is complicated by the many physical, chemical, and biological processes which mediate nutrient dynamics and cyanobacteria growth across time and space. Furthermore, processes influencing bloom development operate on a variety of temporal scales (hourly, daily, seasonal, decadal, episodic), making it difficult to identify important factors controlling bloom development using traditional methods or coarse temporal resolution …

Invasive Plant Ecology In Vermont: Insights From Spatial Analysis And Interactions Of Garlic Mustard (Alliaria Petiolata) With Native Plants And Invertebrates, Chenin Kathleen Limback

Graduate College Dissertations and Theses

Causes and patterns of invasive plant species establishment and success depend broadly upon their ecology, including habitat suitability and interactions with other plants and animals. Here I examine the traits and distribution of invasive plants in Vermont, using spatial analysis, laboratory and field studies. I used GIS to investigate environmental factors correlated with presence of 19 invasive plant species in Vermont campgrounds. My results support the assumption that human dispersal of invasive plant seed and stock may be more important than natural dispersal of these plant species to new sites. I also investigate in-depth the relationships of invasive herbaceous garlic …

Earthworms In Vermont Forest Soils: A Study Of Nutrient, Carbon, Nitrogen And Native Plant Responses, Ryan Melnichuk

Graduate College Dissertations and Theses

Anthropogenic activities surrounding horticulture, agriculture and recreation have increased dispersal of invasive earthworms. The introduction of earthworms initiates many physical and chemical alterations in forest soils previously unoccupied by earthworms. Three trials were performed to assess the effects of earthworms on soil-water dynamics, C and N and defensive/storage compound production by a native plant.

The first trial was a greenhouse experiment, performed to assess the impact of two ecologically contrasting invasive earthworm species on percolate and evaporative soil water loss. Mesocosms were constructed to simulate a typical forest Entisol commonly penetrated by the species of interest, Lumbricus terrestris and Amynthas …

The Relationship Between Magmatism And Deformation During The Acadian Orogeny: A Case Study From Eastern-Central Vermont, Samuel William Lagor

Graduate College Dissertations and Theses

The Silurian-Devonian metasedimentary rocks of the Connecticut Valley-Gaspé trough (CVGT) were subjected to multiple deformational and metamorphic events during the Acadian orogeny in the Middle-Late Devonian. Plutons intruding the Devonian Waits River and Gile Mountain Formations have been considered post-tectonic, but microstructural studies of the intrusions and their metamorphic aureoles indicate some of these plutons intruded syntectonically. This study investigates the relationship between Acadian deformation and intrusion of the Knox Mountain pluton (KMP) of central Vermont. Structural and geochronological data were collected along a c. 15 km transect from the western limit of the CVGT, where the unconformable Richardson Memorial …

The Role Of Transportation In Expanding The Democratic Ideal Of National Parks, Xiao Xiao

Graduate College Dissertations and Theses

National parks have famously been called "America's best idea" and preserve the nation's natural and cultural resources for the enjoyment of all. One of the current working priorities of the National Park Service (NPS) is enhancing the relevancy and engagement of the national parks with diverse audiences, especially for underserved groups. To address this priority, transportation is needed to provide access to national parks, but transportation may not be equally accessible to all groups in society. Understanding the effects of transportation on visitation to the national parks by racial/ethnic groups is essential for the NPS to improve the accessibility of …

Methods For The Spatial Modeling Of Forest Carbon In The Northern Forest, Alison Adams

Graduate College Dissertations and Theses

The ability to accurately assess forest carbon storage is critical to understanding global carbon cycles and the effects of changes in land cover on ecological processes. However, existing methods for calculating carbon storage do not explicitly account for differences in carbon stored by different species of trees. Those methods that do reflect some of this variability, such as remotely-sensing canopy structure to estimate biomass, can be resource-intensive and difficult to reproduce over past or future time steps in order to assess change. I examined the accuracy of several carbon mapping approaches to understand how specificity of forest type classification (for …

Using Aqueous Soil Extracts To Study Organic Matter Leaching From Soils Of Different River Corridor Land Covers In Vermont, Alyson Hampsch

Graduate College Dissertations and Theses

Soils represent an important terrestrial carbon (C) sink, storing up to three times the amount of atmospheric C, however climate and land use changes may transform soils into C sources. River corridor (RC) soils and associated C are at risk to become mobilized by erosion such as bank failure and scour events. Once soil-derived organic C is transferred into the stream, microbial processes and photodegradation of the dissolved, labile (or bioavailable) fractions can lead to the production of CO2, which can evade and increase atmospheric CO2 levels. Because predicted increases in heavy precipitation will likely increase this type of riverine …

Using Long- And Short-Lived Sediment-Associated Isotopes To Track Erosion And Sediment Movement Through Rivers In Yunnan, Sw China, Thomas Bundgaard Neilson

Graduate College Dissertations and Theses

This research aims to understand the natural and human influences on erosion in three tributary watersheds to the Mekong River, Yunnan Province, China and to assess the utility of a novel application of isotopic indicators of erosion. It explores how erosion varies through time and space as a function of physical characteristics of the landscape, tectonic forces, and human alteration of the landscape for forestry and agriculture. To accomplish these goals, I use four sediment-associated radionuclides: in situ 10Be, meteoric 10Be, 210Pbex, and 137Cs. These isotopes accumulate in or on sediment grains, and each accumulates to a different depth on …

Connecting Every Bit Of Knowledge: The Structure Of Wikipedia’S First Link Network, Mark Ibrahim

Graduate College Dissertations and Theses

Apples, porcupines, and the most obscure Bob Dylan song'is every topic a few clicks from Philosophy? Within Wikipedia, the surprising answer is yes: nearly all paths lead to Philosophy. Wikipedia is the largest, most meticulously indexed collection of human knowledge ever amassed. More than information about a topic, Wikipedia is a web of naturally emerging relationships. By following the first link in each article, we algorithmically construct a directed network of all 4.7 million articles: Wikipedia's First Link Network.

Here we study the English edition of Wikipedia's First Link Network for insight into how the many inventions, places, people, objects, …

Placing Natural Resource Decisions In Social And Historical Contexts: Sociological Inquiries Into Agency Communications, Management Rationalities, And Community Change, Emilian Geczi

Graduate College Dissertations and Theses

A sociological understanding of natural resource management decisions traces the links between historical change (How does this historical period differ from other periods?), society (What social relations exist at this time and how do they persist or change?), and individuals (What types of conduct and discourse prevail in this society and in this period?). The papers submitted for this dissertation examine the connections between identity, social milieu, and historical change relative to three resource management issues:

(1) The promotion of nature play areas as a novel landscape form. Analysis of agency materials suggests that these spaces are advertised as bucolic …

Investigations Into Carbon Nanotube And Natural Product Synthesis., Geoffrey Giampa

Graduate College Dissertations and Theses

This dissertation describes research into the synthesis of carbon nanotubes using traditional organic synthetic methods, as well as work on the fragmentation of β-hydroxy-α-diazoesters with a γ-hetero group and applications of their reactivity towards natural product synthesis.

Carbon nanotubes are unique structures that can exhibit different electronic properties based on their chiral vector, and are a potential future source of semiconductors. Current methods of synthesis are unable to be adapted to commercial synthesis, providing the opportunity for the application of organic synthetic methods to generate them more uniformly and on a larger scale.

The generation of tethered aldehyde ynoates and …

Preservation And Sediment Cycling Beneath "Ghost Glaciers": How Cold-Based Ice Dictates Arctic Landscape Evolution, Lee Corbett

Graduate College Dissertations and Theses

Constraining past episodes of climate change and glacial response is critical for understanding future impacts of climate change, especially in the high latitudes where warming is expected to be rapid and most of Earth's glaciers exist. Many studies of past glacier size utilize rare isotopes called cosmogenic nuclides to perform surface exposure dating. Since most areas of Earth's surface that were previously glaciated were covered by erosive ice, which stripped away pre-existing cosmogenic nuclides, surface exposure dating yields the timing of the most recent deglaciation. However, in some high latitude areas where glacial ice is cold-based and non-erosive (so-called 'ghost …

Monomial Characters Of Finite Groups, John Mchugh

Graduate College Dissertations and Theses

An abundance of information regarding the structure of a finite group can be obtained by studying its irreducible characters. Of particular interest are monomial characters – those induced from a linear character of some subgroup – since Brauer has shown that any irreducible character of a group can be written as an integral linear combination of monomial characters. Our primary focus is the class of M-groups, those groups all of whose irreducible characters are monomial. A classical theorem of Taketa asserts that an M-group is necessarily solvable, and Dade proved that every solvable group can be embedded as a subgroup …

A Nanoparticle/Enzyme System For The Simultaneous Detection And Decontamination Of Organophosphates, Brendon Mark Miller

Graduate College Dissertations and Theses

The need for a direct visual response system for the detection of organophosphorus compounds stems from the continued threat and use of these toxic agents in military and terrorist conflicts. The development of an enzyme-inhibitor triggered release system allows for direct visual detection with high specificity. Mesoporous silica nanoparticles (MSNs) have physical features that make them attractive as scaffolds for the construction of these systems, such as pore diameters (20-500 Á) that can be synthetically controlled, large surface areas (300-1500 m2g-1), large pore volumes, chemical inertness, stability at elevated temperatures, and surfaces that can be easily functionalized. In our studies, …

Erosion Rates In Subtropical, Rapidly Developing Countries: An Isotopic Approach To Measuring Background Rates Of Erosion In Brazil And China, Veronica Sosa-Gonzalez

Graduate College Dissertations and Theses

Erosion, a surface process, can be quantified over long-term (assumed to be the natural erosion rate of the landscape) and contemporary (modern) timeframes. My research used the rare cosmogenic isotope 10Be in sand and cobbles collected from rivers in southeastern Brazil (Santa Catarina and Rio de Janeiro states) and southwestern China (Yunnan province) to quantify long-term, background rates of erosion and sediment supply. These measurements will also increase number of such measurements in tropical and subtropical climates. I assessed the relationship between landscape parameters (topographic and climatic) and background erosion rates in order to understand factors related to erosion.

My …

Polarization Charge Density In Strained Graphene, Noah Wilson

Graduate College Dissertations and Theses

Graphene, the world's first truly two-dimensional material, is unique for having an electronic structure described by an effective Lorentz invariant theory. One important consequence is that the ratio or Coulomb energy to kinetic energy is a constant, depending only on conditions within the lattice rather than on the average charge density as in a typical Galilean invariant material. Given this unusual property, a natural question would be how do phenomena, such as screening of a Coulomb impurity, happen in graphene? Moreover, how does the addition of uniaxial strain enhance or diminish this behavior? Here I discuss our work to calculate …