Physical Sciences and Mathematics Commons^™

Invasive Plant Ecology In Vermont: Insights From Spatial Analysis And Interactions Of Garlic Mustard (Alliaria Petiolata) With Native Plants And Invertebrates, Chenin Kathleen Limback

Graduate College Dissertations and Theses

Causes and patterns of invasive plant species establishment and success depend broadly upon their ecology, including habitat suitability and interactions with other plants and animals. Here I examine the traits and distribution of invasive plants in Vermont, using spatial analysis, laboratory and field studies. I used GIS to investigate environmental factors correlated with presence of 19 invasive plant species in Vermont campgrounds. My results support the assumption that human dispersal of invasive plant seed and stock may be more important than natural dispersal of these plant species to new sites. I also investigate in-depth the relationships of invasive herbaceous garlic …

Homology Modeling And Molecular Docking Of Antagonists To Class B G-Protein Coupled Receptor Pituitary Adenylate Cyclase Type 1 (Pac1r), Suzanne Louise Stanton

Graduate College Dissertations and Theses

Recent studies have identified the Class B g-protein coupled receptor (GPCR) pituitary adenylate cyclase activating polypeptide type 1 (PAC1R) as a key component in physiological stress management. Over-activity of neurological stress response systems due to prolonged or extreme exposure to traumatic events has led researchers to investigate PAC1R inhibition as a possible treatment for anxiety disorders such as post-traumatic stress disorder (PTSD). In 2008, Beebe and coworkers identified two such small molecule hydrazide antagonists and a general pharmacaphore for PAC1R inhibition. However, a relative dearth of information about Class B GPCRs in general, and PAC1R in specific, has significantly hindered …

The Role Of Green Leafy Plants In Atmospheric Chemistry: Volatile Emissions And Secondary Organic Aerosol, Rebecca Harvey

Graduate College Dissertations and Theses

Aerosols play important roles in atmospheric and environmental processes. Not only do they impact human health, they also affect visibility and climate. Despite recent advances made to under their sources and fate, there remains a limited understanding of the mechanisms that lead to the formation of aerosols and their ultimate fate in the atmosphere. These knowledge gaps provide the crux of the research reported herein, which has focused on identifying novel sources of atmospheric aerosol, characterizing its physical and optical properties, and rationalizing these properties using an in-depth knowledge of the molecular level mechanisms that led to its formation.

Upon …

Comparing Meteoric 10be, In Situ 10be, And Native 9be Across A Diverse Set Of Watersheds, Emily Sophie Greene

Graduate College Dissertations and Theses

The cosmogenic nuclide 10Be is a tool for quantifying earth surface processes that occur on millennial timescales. 10Be is produced in the atmosphere (meteoric 10Be) or in mineral grains (in situ 10Be). Well-understood nuclear physics, physical mixing processes, and the denudation of regolith control concentrations of in situ 10Be; in contrast, a combination of geomorphic, pedogenic, geochemical, and biological processes influence meteoric 10Be concentrations. Some have hypothesized that meteoric 10Be can be used as a tracer of sediment movement if meteoric 10Be is normalized against the concentration of native 9Be in grain coatings. This study aims to better understand Be …

Impacts Of Forest Disturbance On Small Mammal Distribution, Allyson Lenora Degrassi

Graduate College Dissertations and Theses

Natural habitat in the eastern United States has diminished over the past century because of the effects of invasive species. Both plant and animal invaders can alter habitat structure and may decrease survival of native species. The degree to which an invasive species alters ecosystem function depends on the functional characteristics of affected species and the resulting cascading effects. The loss of important native species, such as foundation species, can potentially influence the structure and distribution of animal communities because of the foundation species' unique ecosystem roles. The foundation species concept is relatively new to the terrestrial ecology and the …

The Impacts Of Climate Change On Precipitation And Hydrology In The Northeastern United States, Justin Guilbert

Graduate College Dissertations and Theses

Shifting climatic regimes can increase or decrease the frequency of extreme hydrologic events (e.g., high and low streamflows) causing large societal and environmental impacts. The impacts are numerous and include human health and safety, the destruction of infrastructure, water resources, nutrient and sediment transport, and within stream ecological health. It is unclear how the hydrology of a given region will shift in response to climate change. This is especially the case in areas that are seasonally snow covered as the interplay of changing temperature, precipitation, and resulting snowpack can lead to an increased risk of flood or drought.

This research …

Oxygen-Sensitive Luminophores: A Survey Of The Literature And Efforts Toward A Novel Porphyrin-Pillared Zirconium Phosphonate, Joseph Wright

Graduate College Dissertations and Theses

Measurement and mapping of the pressure distribution across the surface of a suitably scaled model is an integral step in the design of any aircraft or automobile. For this purpose, the traditional workhorses of the aeronautic and automotive industries have been pressure taps--small orifices that contain electronic pressure transducers. Unfortunately, in addition to the limited spatial resolution achievable with such devices, their technical complexity and cost constitute serious disadvantages. For more than 35 years, researchers have pursued a fundamentally different alternative: indirect measurement of pressure via oxygen-induced quenching of the luminescence emitted by certain chemical species. Porphyrin complexes of dipositive …

A Mechanistically Guided Approach To Treatment Of Multi-Wavelet Reentry: Experiments In A Computational Model Of Cardiac Propagation, Richard T. Carrick

Graduate College Dissertations and Theses

Atrial fibrillation (AF) is the most common cardiac arrhythmia in the United States today. However, treatment options remain limited despite the enormous magnitude of both AF prevalence and the associated economic cost. Of those treatment options that are available, ablation-based interventional methods have demonstrated the highest rates of long-term cure. Unfortunately, these methods have substantially lower efficacy in patients with heavier burdens of disease, thus leaving the most affected individuals with the least hope for successful treatment.

The focus of this research is to develop a mechanistically guided approach towards the treatment of multi-wavelet reentry (MWR), one of the primary …

Second Coordination Sphere Of Heme In Mycobacterium Tuberculosis Mhud, And The Mechanism Of Heme Degradation, Amanda Graves

Graduate College Dissertations and Theses

MhuD is a heme degrading enzyme from Mycobacterium tuberculosis that catalyzes both monooxygenation and dioxygenation leading to novel chromophores, mycobilins. The X-ray crystal structure of heme-bound, cyanide-inhibited MhuD displays a ruffled heme substrate where pyrrole rings are rotated around the Fe-N bonds, distorting the heme. The electronic structure of the heme in heme-bound, cyanide-inhibited MhuD (MhuD-heme-CN) is characterized here to provide insight into the mechanism of heme degradation by MhuD. Analysis of nuclear magnetic resonance (NMR) and magnetic circular dichroism (MCD) data for MhuD-heme-CN leads to the conclusion that the ground, (dxz,yz)4(dxy)1 electron configuration (2B2g state) and excited (dxy)2(dxz,yz)3 electron …

Importance Of Agricultural Systems As Multifunctional Landscapes, Flavio Sutti

Graduate College Dissertations and Theses

Agricultural landscapes provide our society with many benefits. While food production is the primary role of these landscapes, sociocultural and ecological benefits are also provided. However, the full scope of benefits that we obtain from agricultural landscapes are not always taken into account, and with the intensification of agricultural activities, more complex multifunctional landscapes are converted into simpler and less-functional landscapes. I used a heterogeneous agricultural landscape, the Champlain Valley of Vermont, as a case study to examine the interactions between landscape structure and the provision of landscape functions and services.

I analyzed sociocultural and production functions indices obtained via …

Using Long- And Short-Lived Sediment-Associated Isotopes To Track Erosion And Sediment Movement Through Rivers In Yunnan, Sw China, Thomas Bundgaard Neilson

Graduate College Dissertations and Theses

This research aims to understand the natural and human influences on erosion in three tributary watersheds to the Mekong River, Yunnan Province, China and to assess the utility of a novel application of isotopic indicators of erosion. It explores how erosion varies through time and space as a function of physical characteristics of the landscape, tectonic forces, and human alteration of the landscape for forestry and agriculture. To accomplish these goals, I use four sediment-associated radionuclides: in situ 10Be, meteoric 10Be, 210Pbex, and 137Cs. These isotopes accumulate in or on sediment grains, and each accumulates to a different depth on …

A Genetic Programming Approach To Cost-Sensitive Control In Wireless Sensor Networks, Afsoon Yousefi Zowj

Graduate College Dissertations and Theses

In some wireless sensor network applications, multiple sensors can be used to measure the same variable, while differing in their sampling cost, for example in their power requirements. This raises the problem of automatically controlling heterogeneous sensor suites in wireless sensor network applications, in a manner that balances cost and accuracy of sensors. Genetic programming (GP) is applied to this problem, considering two basic approaches. First, a hierarchy of models is constructed, where increasing levels in the hierarchy use sensors of increasing cost. If a model that polls low cost sensors exhibits too much prediction uncertainty, the burden of prediction …

Integrating Management For Old-Growth Characteristics With Enhanced Carbon Storage Of Northern Hardwood-Conifer Forests, Sarah Eliot Ford

Graduate College Dissertations and Theses

Forest management practices emphasizing stand structural complexity are of interest across the northern forest region of the United States because of their potential to enhance carbon storage. Our research is nested within a long-term study evaluating how silvicultural treatments promoting late-successional forest characteristics affect aboveground biomass development in northern hardwood forests. We are testing the hypothesis that biomass development (carbon storage) will be greater in structural complexity enhancement (SCE) treatments when compared to conventional uneven-aged treatments. SCE treatments were compared against selection systems (single-tree and group) modified to retain elevated structure. Manipulations and controls were replicated across 2-hectare treatment units …

Edge-Of-Field Water And Phosphorus Losses In Surface And Subsurface Agricultural Runoff, Laura B. Klaiber

Graduate College Dissertations and Theses

Quantifying effectiveness of soil management practices on surface and subsurface water quality at the field scale is becoming increasingly important in the Lake Champlain Basin and other agricultural watersheds. During 2012 and 2013, field plots (22.9 x 45.7 m) were established at the Lake Alice Wildlife Area in Chazy, NY to begin a long-term water quality monitoring study. Plots were established in a cool season grass field (1 ha) leased and managed by the William H. Miner Agricultural Research Institute in Chazy, NY. The soil type transitions from an excessively drained outwash soil on the upslope to a very poorly …

High Flow Events As Hot Moments Of Reactive Fe And P Export: Impacts Of Land Cover And Seasonality, Braden Rosenberg

Graduate College Dissertations and Theses

High flow events often comprise the majority of annual discharge and riverine geochemical flux of phosphorus (P) and metals such as iron (Fe) and manganese (Mn) due to glacial melt, snowmelt, and storm-driven sustained high flow. Aquatic ecosystem productivity in receiving water bodies such as Lake Champlain and the Gulf of Alaska (GoA) are impacted by the riverine import of nutrients. The magnitude of these high flow events can be a strong predictor of receiving water body conditions, and in some cases can contribute to eutrophication. We explore the intersection of high flow events and land cover in contrasting catchments …

Influence Of Mission, Audience, And Policy Context On Issue Framing: A Case Study Of Mobilization Against Hydraulic Fracturing In The Marcellus Shale, Rezwana Zafar

Graduate College Dissertations and Theses

The case of mobilization against hydraulic fracturing by interest groups provided an opportunity to examine the influence of three factors (mission, audience, and policy context) on diagnostic, prognostic, and motivational framing. A comparative analysis was conducted of the mobilization activities of five national environmental organizations with a local presence in the Pennsylvania and New York Marcellus Shale regions. The organizations varied with respect to organizational mission, the audiences they were targeting (urban and rural), and the policy context in which they worked (pro and anti-hydraulic fracturing). Data came from eleven semi-structured in-depth interviews with organization personnel, and from the organizations' …

A Hybrid Approach To Semantic Hashtag Clustering In Social Media, Ali Javed

Graduate College Dissertations and Theses

The uncontrolled usage of hashtags in social media makes them vary a lot in the quality of semantics and the frequency of usage. Such variations pose a challenge to the current approaches which capitalize on either the lexical semantics of a hashtag by using metadata or the contextual semantics of a hashtag by using the texts associated with a hashtag. This thesis presents a hybrid approach to clustering hashtags based on their semantics, designed in two phases. The first phase is a sense-level metadata-based semantic clustering algorithm that has the ability to differentiate among distinct senses of a hashtag as …

The Structural Evolution Of A Portion Of The Median Batholith And Its Host Rock In Central Fiordland, New Zealand: Examples Of Partitioned Transpression And Structural Reactivation, Hannah Jane Blatchford

Graduate College Dissertations and Theses

This thesis presents the results of structural analyses and detailed field mapping from a region near Adams Burn in central Fiordland, New Zealand. The region preserves assemblages of metasedimentary and metaigneous rocks deposited, intruded, and ultimately metamorphosed and deformed during the growth of a Gondwana-margin continental arc from Cambrian-Early Cretaceous. Evidence of arc growth is preserved in the Late Devonian-Early Cretaceous Median Batholith, a belt of intrusive rock whose growth culminated with the emplacement of the Western Fiordland Orthogneiss (WFO) into the middle-lower crust of the margin. Following this magmatic flare-up, the margin experienced Late Cretaceous extensional orogenic collapse and …

Impacts Of Transportation Infrastructure On Stormwater And Surface Waters In Chittenden County, Vermont, Usa, Joseph Hollis Bartlett

Graduate College Dissertations and Theses

Transportation infrastructure is a major source of stormwater runoff that can alter hydrology and contribute significant loading of nutrients, sediment, and other pollutants to surface waters. These increased loads can contribute to impairment of streams in developed areas and ultimately to Lake Champlain. In this study we selected six watersheds that represent a range of road types (gravel and paved) and road densities (rural, suburban, and urban) present in Chittenden County, one of the most developed areas in Vermont. The location and density of road networks were characterized and quantified for each watershed using GIS analysis. Monitoring stations in each …

Patterns Of Asthma Exacerbation Related To Climate And Weather In The Northeast Kingdom Of Vermont, Quincy Mckenzie Campbell

Graduate College Dissertations and Theses

Asthma is a chronic respiratory disease characterized by long- and short-term inflammation and bronchospasm susceptible to multiple triggers that affects patients across the lifespan. Asthma management is a primary care priority in Vermont, where there continues to be an above-average prevalence of asthma among both children and adults as compared to other states. However, many of Vermont's children and especially adults with asthma are not participating in regular check-ups for asthma management that would best prevent exacerbation of asthma symptoms. Several climate and weather elements including, but not limited to, extreme temperatures and particulate matter are known asthma triggers. Vermont's …

Measurement And Modeling Of Stormwater From Small Suburban Watersheds In Vermont, Joel Nipper

Graduate College Dissertations and Theses

Despite decades of U.S. water quality management efforts, over half of assessed waterbody units were threatened or impaired for designated uses in the most recent assessments, with urban runoff being a leading contributor to those impairments. This cumulative research explores several aspects of urban runoff dynamics through a combination of field study and modeling.

Stormwater ponds are ubiquitous in developed landscapes due to their ability to provide multiple forms of treatment for stormwater runoff. However, evolving design goals have reduced the applicability of much of the early work that was done on pond effectiveness. In this study, we instrumented a …

Long-Term Forest Carbon Storage And Structural Development As Influenced By Land-Use History And Reforestation Approach, Andrea Rose Urbano

Graduate College Dissertations and Theses

Temperate forests are an important carbon sink, yet there is uncertainty regarding land-use history effects on biomass accumulation and carbon storage potential in secondary forests. Understanding long-term biomass dynamics is important for managing forests as carbon sinks and for co-benefits such as watershed protection and biodiversity. However there are many unanswered questions regarding these dynamics in northeastern U.S. forests: How have secondary forests of the U.S. Northeast recovered post nineteenth century agricultural abandonment? How has the region's extensive land-use history influenced long-term structural development and aboveground carbon storage? To answer these questions, we employed a longitudinal study based on twelve …

Establishing Chemical Mechanisms And Estimating Phase State Of Secondary Organic Aerosol From Atmospherically Relevant Organic Precursors, Shashank Jain

Graduate College Dissertations and Theses

Organic aerosol (OA) is a ubiquitous component of atmospheric particulate that influences both human health and global climate. A large fraction of OA is secondary in nature (SOA), being produced by oxidation of volatile organic compounds (VOCs) emitted by biogenic and anthropogenic sources. Despite the integral role of SOA in atmospheric processes, there remains a limited scientific understanding of the chemical and physical changes induced in SOA as it ages in the atmosphere. This thesis describes work done to increase the knowledge of processes and properties of atmospherically relevant SOA.

In the work presented in this thesis, I have worked …

Mathematical Modeling Of Public Opinion Using Traditional And Social Media, Emily Cody

Graduate College Dissertations and Theses

With the growth of the internet, data from text sources has become increasingly available to researchers in the form of online newspapers, journals, and blogs. This data presents a unique opportunity to analyze human opinions and behaviors without soliciting the public explicitly. In this research, I utilize newspaper articles and the social media service Twitter to infer self-reported public opinions and awareness of climate change. Climate change is one of the most important and heavily debated issues of our time, and analyzing large-scale text surrounding this issue reveals insights surrounding self-reported public opinion. First, I inquire about public discourse on …

Uncommon Numerical Instability In The Method Of Characteristic Applied To Hyperbolic Equations, Zihao Deng

Graduate College Dissertations and Theses

This thesis presents the stability analysis of the numerical method of characteristic (MoC) that is applied to hyperbolic partial differential equations (PDEs). Simple Euler method, Modified Euler method and Leapfrog method are used for numerical integration along the characteristics. The corresponding MoC schemes are referred to as MoC-SE, MoC-ME, and MoC-LF respectively.

We discovered and explained two unusual phenomena. First, certain non-periodic boundary condition (b.c.) could eliminate the numerical instability for some schemes such as the MoC-ME, where the instability exists for periodic b.c. However, it is commonly believed that

if von Neumann analysis, i.e., assuming periodic b.c., predicts numerical …

Quantifying Cultural Changes Through A Half-Century Of Song Lyrics And Books, Robert Bruce Woodward Iii

Graduate College Dissertations and Theses

Music is an ever-changing cultural reflection. It is deeply integrated into our society, ubiquitous

in movies, television shows, restaurants, sport venues, churches and a plethora of

other places. This thesis proposes that we consider the lyrics in popular music, as determined

by Billboards Hot 100 chart, as a natural medium to analyze the changes in culture

over the past half-century. Using this collection of lyrics, we analyze the change in relative

frequency of individual words over time, and compare to works of literature. Furthermore,

we use the ranking in the Top 100 as a metric with which to explore the …

Methods For The Spatial Modeling Of Forest Carbon In The Northern Forest, Alison Adams

Graduate College Dissertations and Theses

The ability to accurately assess forest carbon storage is critical to understanding global carbon cycles and the effects of changes in land cover on ecological processes. However, existing methods for calculating carbon storage do not explicitly account for differences in carbon stored by different species of trees. Those methods that do reflect some of this variability, such as remotely-sensing canopy structure to estimate biomass, can be resource-intensive and difficult to reproduce over past or future time steps in order to assess change. I examined the accuracy of several carbon mapping approaches to understand how specificity of forest type classification (for …

Quantifying Soil Greenhouse Gas Emissions And Soil Carbon Storage To Determine Best Management Practices In Agroecosystems, Tyler Goeschel

Graduate College Dissertations and Theses

Intensive agriculture, coupled with an increase in nitrogen fertilizer use, has contributed significantly to the elevation of atmospheric greenhouse gases (GHGs), including carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O). Rising GHG emissions usually mean a decrease in soil carbon. Currently, soil C is twice that of all standing crop biomass, making it an extremely important player in the C cycle. Fortunately, agricultural management practices have the potential to reduce agricultural GHG emissions whilst increasing soil C. Management practices that impact GHG emissions and soil C include various tillage practices, different N fertilization amounts and treatments (synthetic N, cattle …

A Study Of The Physicochemical Properties Of Dense And Mesoporous Silica Nanoparticles That Impact Protein Adsorption From Biological Fluids, Alden Michael Clemments

Graduate College Dissertations and Theses

At the intersection of materials chemistry and biology, biomaterials have been successfully employed in an array of medical applications. From diagnostic tools to targeted drug delivery, the modular physical and chemical properties of these materials provide numerous applications. For example, porous nanoparticles have been widely integrated as vehicles to carry chemotherapeutics to localized tumor sites. By encapsulating these cytotoxic compounds within a porous framework, the commonly associated adverse side effects of conventional chemotherapeutics, such as Doxorubicin, have been greatly reduced. One such material, mesoporous silica, has received widespread attention due to its excellent biocompatibility, high surface area to mass ratio, …

Investigating The Influence Of Gold Nanoparticles On The Photocatalytic And Catalytic Reactivity Of Porous Tungsten Oxide Microparticles, Daniel P. Depuccio

Graduate College Dissertations and Theses

Tungsten oxide (WO3) is a semiconducting transition metal oxide with interesting electronic, structural, and chemical properties that have been exploited in applications including catalysis, gas sensing, electrochromic displays, and solar energy conversion. Nanocrystalline WO3 can absorb visible light to catalyze heterogeneous photooxidation reactions. Also, the acidity of the WO3 surface makes this oxide a good thermal catalyst in the dehydration of alcohols to various industrially relevant chemicals. This dissertation explores the photocatalytic and thermal catalytic reactivity of nanocrystalline porous WO3 microparticles. Furthermore, investigations into the changes in WO3 reactivity are carried out after modifying the porous WO3 particles with gold …