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Full-Text Articles in Physical Sciences and Mathematics

The Forensic Analysis Of Triacetone Triperoxide (Tatp) Precursors And Synthetic By-Products, Kimberly Painter Jan 2009

The Forensic Analysis Of Triacetone Triperoxide (Tatp) Precursors And Synthetic By-Products, Kimberly Painter

Electronic Theses and Dissertations

Triacetone Triperoxide (TATP) is a primary high explosive that can be synthesized using commercially available starting materials and has grown in use among terrorists over the past several years. Additives present in the precursors were investigated to see if they carry through the TATP synthesis and can be detected in the final product potentially aiding in the identification of the source. Additives identified in the acetones were also identified in pre-blast and in some post-blast samples. However, these additives are present in trace quantities relative to the TATP, which coupled with the volatility and short lifetimes of some of the …


Forensic Analysis Of Automobile Paints By Atomic And Molecular Spectroscopic Methods And Statistical Data Analyses, Erin Mcintee Jan 2008

Forensic Analysis Of Automobile Paints By Atomic And Molecular Spectroscopic Methods And Statistical Data Analyses, Erin Mcintee

Electronic Theses and Dissertations

The analysis of 110 automotive paint samples was conducted for the research presented here. Laser-induced breakdown spectroscopy (LIBS) was the central instrument utilized for analysis although scanning electron microscopy / energy dispersive x-ray spectroscopy (SEM/EDS) and Fourier transform infrared spectroscopy - attenuated total reflection (FTIR-ATR) analyses were also performed. Two separate methods of LIBS analysis of samples were used: a cross sectional analysis and a drill down analysis. SEM/EDS analysis focused on the cross section while FTIR-ATR analysis concentrated on the clearcoat layer. Several different data/statistical analyses were evaluated including principal components analysis (PCA), two tailed t-tests based on several …


The Identification Of Ignitable Liquids In The Presence Of Pyrolysis Products: Generation Of A Pyrolysis Product Database, Joseph Castelbuono Jan 2008

The Identification Of Ignitable Liquids In The Presence Of Pyrolysis Products: Generation Of A Pyrolysis Product Database, Joseph Castelbuono

Electronic Theses and Dissertations

The fire debris analyst is often faced with the complex problem of identifying ignitable liquid residues in the presence of products produced from pyrolysis and incomplete combustion of common building and furnishing materials. The purpose of this research is to investigate a modified destructive distillation methodology provided by the Florida Bureau of Forensic Fire and Explosive Analysis to produce interfering product chromatographic patterns similar to those observed in fire debris case work. The volatile products generated during heating of substrate materials are extracted from the fire debris by passive headspace adsorption and subsequently analyzed by GC-MS. Low density polyethylene (LDPE) …


Chromatographic And Mass Spectral Analyses Of Oligosaccharides And Indigo Dye Extracted From Cotton Textiles With Manova And Ano, Jessica Frisch Jan 2008

Chromatographic And Mass Spectral Analyses Of Oligosaccharides And Indigo Dye Extracted From Cotton Textiles With Manova And Ano, Jessica Frisch

Electronic Theses and Dissertations

Research was conducted on thirteen 100% cotton denim samples using an acid wash, established by Murray, to extract oligosaccharides from the cellulosic material. The oligosaccharide ion groups (+, +, and +) for molecules with degrees of polymerization between two and seven (DP2-DP7) were analyzed using liquid chromatography coupled to mass spectrometry with an electrospray ionization interface (LC-ESI-MS). The results were compared using the least-squares means in a Multivariate ANOVA (MANOVA) test followed by Univariate ANOVA and Tukey HSD tests and demonstrated that the method could correctly determine that two samples were statistically different 85.9% of the time when analyzing the …


Development And Forensic Application Of Dye Probe Fluorescence Resonance Energy Transfer For Improved Detection Of Changes In Dn, Micah Halpern Jan 2008

Development And Forensic Application Of Dye Probe Fluorescence Resonance Energy Transfer For Improved Detection Of Changes In Dn, Micah Halpern

Electronic Theses and Dissertations

Discovering, screening, and associating changes in DNA sequence are important to a broad range of disciplines and play a central role in Forensic Science. The typical types of changes include sequence variations [single nucleotide polymorphisms (SNP)] and length variations [short tandem repeats (STR)]. The steps for forensic DNA sample processing are similar for both types of changes but diverge at the point of detection. A number of approaches are being explored for SNP genotyping while STR analysis primarily consists of size-based analysis by capillary electrophoresis. Limitations exist for all current detection methods that pose significant impacts to forensic analysis. Bi-allelic …


Advances In Fire Debris Analysis, Mary Williams Jan 2007

Advances In Fire Debris Analysis, Mary Williams

Electronic Theses and Dissertations

Fire incidents are a major contributor to the number of deaths and property losses within the United States each year. Fire investigations determine the cause of the fire resulting in an assignment of responsibility. Current methods of fire debris analysis are reviewed including the preservation, extraction, detection and characterization of ignitable liquids from fire debris. Leak rates were calculated for the three most common types of fire debris evidence containers. The consequences of leaking containers on the recovery and characterization of ignitable liquids were demonstrated. The interactions of hydrocarbons with activated carbon during the extraction of ignitable liquids from the …


Maya Eclipses: Modern Data, The Triple Tritos And The Double Tzolkin, William Earl Beck Jan 2007

Maya Eclipses: Modern Data, The Triple Tritos And The Double Tzolkin, William Earl Beck

Electronic Theses and Dissertations

The Eclipse Table, on pages 51-58, of the Dresden Codex has long fascinated Maya scholars. Researchers use the mean-value method of 173.3 days to determine nodal passage that is the place where eclipses can occur. These studies rely on Oppolzer's Eclipse Canon and Schram's Moon Phase Tables to verify eclipse occurrences. The newer canons of Jean Meeus and Bao-Lin Liu use decimal accuracy. What would be the effect of modern astronomical data on the previous studies and the Maya Eclipse Table? The study utilizes a general view of eclipses that includes eclipses not visible to the Maya. Lunar eclipses are …


Analysis Of Mitochondrial Dna Coding Region Snps By Pyrosequencing, Kyle Robert Carl Parker Jan 2007

Analysis Of Mitochondrial Dna Coding Region Snps By Pyrosequencing, Kyle Robert Carl Parker

Electronic Theses and Dissertations

To date, the use of mitochondrial DNA in forensic analysis has relied on the presence of variations in the control region to differentiate between samples. One problem that this analysis has shown is the occurrence of common Haplogroup H haplotypes or identical sequences. Thus, there is a need to enhance the distinguishing power of this type of analysis. One option has been to investigate the mitochondrial coding region for polymorphisms that could differentiate between samples with identical control region haplotypes. The goal of this study has been to identify polymorphic coding region sites for development in a Pyrosequencing assay that …


Forensic Analysis Of C-4 And Commercial Blasting Agents For Possible Discrimination, Katie Steele Jan 2007

Forensic Analysis Of C-4 And Commercial Blasting Agents For Possible Discrimination, Katie Steele

Electronic Theses and Dissertations

The criminal use of explosives has increased in recent years. Political instability and the wide spread access to the internet, filled with "homemade recipes," are two conjectures for the increase. C-4 is a plastic bonded explosive (PBX) comprised of 91% of the high explosive RDX, 1.6% processing oils, 5.3% plasticizer, and 2.1% polyisobutylene (PIB). C-4 is most commonly used for military purposes, but also has found use in commercial industry as well. Current methods for the forensic analysis of C-4 are limited to identification of the explosive; however, recent publications have suggested the plausibility of discrimination between C-4 samples based …


Camera System Support For Highway Transportation Using Mobile Devices, Le Minh Jan 2004

Camera System Support For Highway Transportation Using Mobile Devices, Le Minh

Electronic Theses and Dissertations

With the very fast growing technology in wireless, advancement in hardware and the dramatically falling cost of mobile computing devices such as PDA, handheld device, People nowadays can have a personal device that fits in their hand but has computing power as a desktop did few years ago. The same device now is able to communicate over a wireless network and view office document at the same time. The combination of size, power and flexibility makes the personal devices increasingly appear in many aspects of life. In this proposal, we focus on a simple yet useful application of mobile devices …