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Articles 1 - 6 of 6
Full-Text Articles in Physical Sciences and Mathematics
Naio4 Oxidation Of Mussel Adhesive Protein Film And Its Corrosion Protection For Mg-1.0ca Alloy, Rui-Qing Hou, Ping-Li Jiang, Shi-Gang Dong, Chang-Jian Lin
Naio4 Oxidation Of Mussel Adhesive Protein Film And Its Corrosion Protection For Mg-1.0ca Alloy, Rui-Qing Hou, Ping-Li Jiang, Shi-Gang Dong, Chang-Jian Lin
Journal of Electrochemistry
The effect of oxidation of mussel adhesive protein (Mefp-1) film on the corrosive resistance for Mg-1.0Ca alloy was investigated by scanning electron microscopy (SEM), atom force microscopy (AFM), electron probe microanalysis (EPMA), Infrared reflection absorption spectroscopy (IRAS) and electrochemical methods. The results showed that the NaIO4 induced oxidation of the pre-formed Mefp-1 film with porous morphology involved structural change of the DOPA group in the protein and resulted in a more uniform film with net-like morphology. The protein film without oxidation had an increasing resistance for the corrosion of Mg-1.0Ca alloy up to 7 days exposure. After oxidation, Epit …
Corrosion Electrochemical Behavior Of Aluminum Flake Pigmented Water-Borne Epoxy Coating On Carbon Steel In Nacl Solution, Li-Li Xue, Li-Kun Xu, Qing-Fen Li, Hong-Qing Song, Wen-Juan Zhou, Guang-Zhang Chen
Corrosion Electrochemical Behavior Of Aluminum Flake Pigmented Water-Borne Epoxy Coating On Carbon Steel In Nacl Solution, Li-Li Xue, Li-Kun Xu, Qing-Fen Li, Hong-Qing Song, Wen-Juan Zhou, Guang-Zhang Chen
Journal of Electrochemistry
The corrosion electrochemical behavior of a water-borne epoxy coating pigmented with aluminum flake on carbon steel with artificial scratch defect was studied in 3.5% NaCl solution using electrochemical impedance spectroscopy(EIS)and scanning vibrating electrode technique(SVET).The results indicated that the defect presented anodic electroactivity at the initial stage of immersion,which extended gradually with time from the scratch into the neighboring coating,lowering the coating impedance.With further immersion,however,the electroactivity of the coating/steel interface decreased significantly due to the self-repairing of the corrosion products,causing an obvious increase of the coating impedance.In the later period of immersion,more scattered electroactive areas appeared under the coating because of …
Composite Electroplating And Characterizations Of Sn-Sba15 Anode For Lithium-Ion Batteries, Xiao-Yong Fan, Jin-Mei Xu, Quan-Chao Zhuang, Hong-Hong Jiang, Ling Huang, Yan-Xia Jiang, Quan-Feng Dong, Shi-Gang Sun
Composite Electroplating And Characterizations Of Sn-Sba15 Anode For Lithium-Ion Batteries, Xiao-Yong Fan, Jin-Mei Xu, Quan-Chao Zhuang, Hong-Hong Jiang, Ling Huang, Yan-Xia Jiang, Quan-Feng Dong, Shi-Gang Sun
Journal of Electrochemistry
Sn-SBA15 anode was prepared by composite electroplating.The first discharge and charge capacity was 1075mAh/g and 630mAh/g respectively.After fifty charge/discharge cycles,the charge and discharge capacity of Sn-SBA15 were retained above 400mAh/g.XRD patterns indicated that the Sn-SBA15 has tetragonal crystal type.SEM images showed that the Sn-SBA15 had a honeycombed surface.EIS results indicated that there was SEI film formed on the surface of Sn-SBA15 electrode.
Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma
Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma
Journal of Electrochemistry
The air electrodes with different mass ratio of Pt/active carbon or carbon nanotube as catalyst layer material have been prepared. The electrocatalytic performances for oxygen reduction were evaluated by means of polarization curve and electrochemical impedance spectroscopy (EIS). The results disclosed that carbon nanotubes dealt with nitric acid in the catalyst layer had been improved obviously on the electrocatalytic activity. After the surface of carbon nanotube was oxygenated and aggraded with platinum, the catalyst had obviously effects on the electrocatalytic activity. The air electrode with the mass ratio of active carbon to Pt/carbon nanotube in 4∶1 showed better electrocatalytic activity, …
Stability And Electrochemical Performance Of Nio Cathode Modified By Zno Additive For Mcfc In Molten Carbonates, Huang Bo
Journal of Electrochemistry
The ZnO/Ni composite cathode was fabricated by tape-casting method, which microstructures and phases were studied. The electrochemical behaviors of ZnO impregnated NiO cathodes were also evaluated in molten 62 mol%Li_2CO_3+(38 mol%) K_2CO_3eutectic at 650 ℃ by electrochemical impedance spectroscopy (EIS) as a function of ZnO content and immersion time. The ZnO impregnated nickel cathodes showed the similar porosity, pore size and morphology to the reference nickel cathode. The stability tests of ZnO impregnated NiO cathodes showed that the ZnO additive could dramatically reduce the solubility of NiO in a eutectic carbonate mixture under the standard cathode gas condition. The cathode …
Electrochemistry Characteristic Of Carbon Steel Under Biofilm And Sulfide Film, Ze-Hua Dong, Xing-Peng Guo, Jia-Shen Zheng, Li-Ming Xu
Electrochemistry Characteristic Of Carbon Steel Under Biofilm And Sulfide Film, Ze-Hua Dong, Xing-Peng Guo, Jia-Shen Zheng, Li-Ming Xu
Journal of Electrochemistry
Wire Beam Electrode (WBE) made of Q235 carbon steel was applied to study the heterogeneous corrosion beneath biofilm formed by Sulfate Reducing Bacteria (SRB) in culture and sulfide film in solution with 1% NaCl and 300 mg/L S 2- . The potential,galvanic density mapping,as well as polarization curve and Electrochemical Impedance Spectrum (EIS) were measured to predict the localized corrosion under biofilm and sulfide film.As a result,the mapping showed the potential fluctuation on the WBE surface decreased over time due to the conductivity of the biofilm and sulfide film.Therefore,the potential mapping could not be a criterion of localized corrosion under …