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Full-Text Articles in Physical Sciences and Mathematics
Isotopic Evidence For Sources Of Dissolved Carbon And The Role Of Organic Matter Respiration In The Fraser River Basin, Canada, Britta M. Voss, Timothy I. Eglinton, Bernhard Peucker-Ehrenbrink, Valier Galy, Susan Q. Lang, Cameron Mcintyre, Robert G.M. Spencer, Ekaterina Bulygina, Zhaohui Aleck Wang, Katherine A. Guay
Isotopic Evidence For Sources Of Dissolved Carbon And The Role Of Organic Matter Respiration In The Fraser River Basin, Canada, Britta M. Voss, Timothy I. Eglinton, Bernhard Peucker-Ehrenbrink, Valier Galy, Susan Q. Lang, Cameron Mcintyre, Robert G.M. Spencer, Ekaterina Bulygina, Zhaohui Aleck Wang, Katherine A. Guay
OES Faculty Publications
Sources of dissolved and particulate carbon to the Fraser River system vary significantly in space and time. Tributaries in the northern interior of the basin consistently deliver higher concentrations of dissolved organic carbon (DOC) to the main stem than other tributaries. Based on samples collected near the Fraser River mouth throughout 2013, the radiocarbon age of DOC exported from the Fraser River does not change significantly across seasons despite a spike in DOC concentration during the freshet, suggesting modulation of heterogeneous upstream chemical and isotopic signals during transit through the river basin. Dissolved inorganic carbon (DIC) concentrations are highest in …
What Is Refractory Organic Matter In The Ocean?, Federico Baltar, Xosé A. Alvarez-Salgado, Javier Arístegui, Ronald Benner, Dennis A. Hansell, Gerhard J. Herndl, Christian Lønborg
What Is Refractory Organic Matter In The Ocean?, Federico Baltar, Xosé A. Alvarez-Salgado, Javier Arístegui, Ronald Benner, Dennis A. Hansell, Gerhard J. Herndl, Christian Lønborg
Faculty Publications
About 20% of the organic carbon produced in the sunlit surface ocean is transported into the ocean’s interior as dissolved, suspended and sinking particles to be mineralized and sequestered as dissolved inorganic carbon (DIC), sedimentary particulate organic carbon (POC) or “refractory” dissolved organic carbon (rDOC). Recently, the physical and biological mechanisms associated with the particle pumps have been revisited, suggesting that accepted fluxes might be severely underestimated (Boyd et al., 2019; Buesseler et al., 2020). Perhaps even more poorly understood are the mechanisms driving rDOC production and its potential accumulation in the ocean. On the basis of …
What Is Refractory Organic Matter In The Ocean?, Federico Baltar, Xosé A. Alvarez-Salgado, Javier Arístegui, Ronald Benner, Dennis A. Hansell, Gerhard J. Herndl, Christian Lønborg
What Is Refractory Organic Matter In The Ocean?, Federico Baltar, Xosé A. Alvarez-Salgado, Javier Arístegui, Ronald Benner, Dennis A. Hansell, Gerhard J. Herndl, Christian Lønborg
Faculty Publications
About 20% of the organic carbon produced in the sunlit surface ocean is transported into the ocean’s interior as dissolved, suspended and sinking particles to be mineralized and sequestered as dissolved inorganic carbon (DIC), sedimentary particulate organic carbon (POC) or “refractory” dissolved organic carbon (rDOC). Recently, the physical and biological mechanisms associated with the particle pumps have been revisited, suggesting that accepted fluxes might be severely underestimated (Boyd et al., 2019; Buesseler et al., 2020). Perhaps even more poorly understood are the mechanisms driving rDOC production and its potential accumulation in the ocean. On the basis of …
Soil Aggregates As A Source Of Dissolved Organic Carbon To Streams: An Experimental Study On The Effect Of Solution Chemistry On Water Extractable Carbon, Malayika M. Cincotta, Julia N. Perdrial, Aaron Shavitz, Arianna Libenson, Maxwell Landsman-Gerjoi, Nicolas Perdrial, Jesse Armfield, Thomas Adler, James B. Shanley
Soil Aggregates As A Source Of Dissolved Organic Carbon To Streams: An Experimental Study On The Effect Of Solution Chemistry On Water Extractable Carbon, Malayika M. Cincotta, Julia N. Perdrial, Aaron Shavitz, Arianna Libenson, Maxwell Landsman-Gerjoi, Nicolas Perdrial, Jesse Armfield, Thomas Adler, James B. Shanley
College of Arts and Sciences Faculty Publications
Over the past two decades, headwater streams of the northern hemisphere have shown increased amounts of dissolved organic carbon (DOC), coinciding with decreased acid deposition. The exact nature of the mechanistic link between precipitation composition and stream water DOC is still widely debated in the literature. We hypothesize that soil aggregates are the main source of stream water DOC and that DOC release is greater in organic rich, riparian soils vs. hillslope soils. To test these hypotheses, we collected soils from two main landscape positions (hillslope and riparian zones) from the acid-impacted Sleepers River Research Watershed in northeastern Vermont. We …
Estuarine Dissolved Organic Carbon Flux From Space: With Application To Chesapeake And Delaware Bays, Sergio R. Signorini, Antonio Mannino, Marjorie A.M. Friedrichs, Pierre St-Laurent, John Wilkin, Aboozar Tabatabai, Raymond G. Najjar, Eileen E. Hofmann, Fei Da, Hanqin Tian, Yuanzhi Yao
Estuarine Dissolved Organic Carbon Flux From Space: With Application To Chesapeake And Delaware Bays, Sergio R. Signorini, Antonio Mannino, Marjorie A.M. Friedrichs, Pierre St-Laurent, John Wilkin, Aboozar Tabatabai, Raymond G. Najjar, Eileen E. Hofmann, Fei Da, Hanqin Tian, Yuanzhi Yao
CCPO Publications
This study uses a neural network model trained with in situ data, combined with satellite data and hydrodynamic model products, to compute the daily estuarine export of dissolved organic carbon (DOC) at the mouths of Chesapeake Bay (CB) and Delaware Bay (DB) from 2007 to 2011. Both bays show large flux variability with highest fluxes in spring and lowest in fall as well as interannual flux variability (0.18 and 0.27 Tg C/year in 2008 and 2010 for CB; 0.04 and 0.09 Tg C/year in 2008 and 2011 for DB). Based on previous estimates of total organic carbon (TOCexp) exported by …
Role Of The Atchafalaya River Basin In Regulating Export Fluxes Of Dissolved Organic Carbon, Nutrients, And Trace Elements To The Louisiana Shelf, Dongjoo Joung, Laodong Guo, Alan M. Shiller
Role Of The Atchafalaya River Basin In Regulating Export Fluxes Of Dissolved Organic Carbon, Nutrients, And Trace Elements To The Louisiana Shelf, Dongjoo Joung, Laodong Guo, Alan M. Shiller
Faculty Publications
The abundance and fluxes of selected dissolved trace elements (TE), nutrients, and dissolved organic carbon (DOC) were quantified in the Atchafalaya River Basin to better understand its influence on the chemical regime of the Louisiana Shelf, a region where bottom water hypoxia occurs annually during late spring to early fall. Water samples were collected from throughout the entire Atchafalaya River Basin including from the Mississippi and Red Rivers as well as basin swamp waters during April and November 2010, and June 2011, which represent “typical” high and low, and “unusual” high river discharges, respectively. Within the total dissolved (< 0.45 µm) pool, most of the TEs were mainly partitioned to the < 0.02 µm dissolved phase with the exception of Cr, Cs, Fe, Pb and Zn which were dominantly in the colloidal (0.02-0.45 µm) phase. In the Atchafalaya River, seasonal concentration variations in nutrients, DOC and most TEs were similar to those in the Mississippi River, reflecting a major contribution of water from the Mississippi River. Contributions of the Red River to the Atchafalaya River’s DOC and nutrients were estimated to be 1-35%, similar to previous estimates for this system. The Red River contribution to the fluxes of Co, Cr, Cs, Fe, Mn, Pb, Rb, and Zn was generally disproportionally high (>20%), …
Testing The Underlying Chemical Principles Of The Biotic Ligand Model (Blm) To Marine Copper Systems: Measuring Copper Speciation Using Fluorescence Quenching, Tara N. Tait, James C. Mcgeer, Scott Smith
Testing The Underlying Chemical Principles Of The Biotic Ligand Model (Blm) To Marine Copper Systems: Measuring Copper Speciation Using Fluorescence Quenching, Tara N. Tait, James C. Mcgeer, Scott Smith
Chemistry Faculty Publications
Speciation of copper in marine systems strongly influences the ability of copper to cause toxicity. Natural organic matter (NOM) contains many binding sites which provides a protective effect on copper toxicity. The purpose of this study was to characterize copper binding with NOM using fluorescence quenching techniques. Fluorescence quenching of NOM with copper was performed on nine sea water samples. The resulting stability con- stants and binding capacities were consistent with literature values of marine NOM, show- ing strong binding with log K values from 7.64 to 10.2 and binding capacities ranging from 15 to 3110 nmole mg C −1 …
Sources, Distributions, And Dynamics Of Dissolved Organic Matter In The Canada And Makarov Basins, Yuan Shen, Ronald Benner, Lisa Robbins, Jonathan Wynn
Sources, Distributions, And Dynamics Of Dissolved Organic Matter In The Canada And Makarov Basins, Yuan Shen, Ronald Benner, Lisa Robbins, Jonathan Wynn
Faculty Publications
A comprehensive survey of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) was conducted in the Canada and Makarov Basins and adjacent seas during 2010–2012 to investigate the dynamics of dissolved organic matter (DOM) in the Arctic Ocean. Sources and distributions of DOM in polar surface waters were very heterogeneous and closely linked to hydrological conditions. Canada Basin surface waters had relatively low DOC concentrations (69 ± 6 μmol L−1), CDOM absorption (a325: 0.32 ± 0.07 m−1) and CDOM-derived lignin phenols (3 ± 0.4 nmol L−1), and high spectral slope values (S275–295: 31.7 ± …
Sources, Distributions And Dynamics Of Dissolved Organic Matter In The Canada And Makarov Basins, Yuan Shen, Ronald Benner, Lisa L. Robbins, Jonathan G. Wynn
Sources, Distributions And Dynamics Of Dissolved Organic Matter In The Canada And Makarov Basins, Yuan Shen, Ronald Benner, Lisa L. Robbins, Jonathan G. Wynn
Faculty Publications
A comprehensive survey of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) was conducted in the Canada and Makarov Basins and adjacent seas during 2010–2012 to investigate the dynamics of dissolved organic matter (DOM) in the Arctic Ocean. Sources and distributions of DOM in polar surface waters were very heterogeneous and closely linked to hydrological conditions. Canada Basin surface waters had relatively low DOC concentrations (69 ± 6 μmol L−1), CDOM absorption (a325: 0.32 ± 0.07 m−1) and CDOM-derived lignin phenols (3 ± 0.4 nmol L−1), and high spectral slope values (S275–295: 31.7 ± …
Biological Hot Spots And The Accumulation Of Marine Dissolved Organic Matter In A Highly Productive Ocean Margin, Yuan Shen, Cédric G. Fichot, Sheng-Kang Liang, Ronald Benner
Biological Hot Spots And The Accumulation Of Marine Dissolved Organic Matter In A Highly Productive Ocean Margin, Yuan Shen, Cédric G. Fichot, Sheng-Kang Liang, Ronald Benner
Faculty Publications
Concentrations of dissolved organic carbon (DOC) and major biochemicals (amino acids and carbohydrates) were measured during five cruises (2009–2010) to the Louisiana margin in the northern Gulf of Mexico. Concentrations of amino acids and carbohydrates were elevated at mid-salinities and were indicative of plankton production of dissolved organic matter (DOM) in surface waters. Hot spots of two compositionally distinct types of labile DOM were identified based on the relative abundances of amino acids and carbohydrates. Amino acid-rich hot spots occurred sporadically in regions of high phytoplankton biomass and were mostly observed between dusk and dawn, reflecting a grazing source. In …
The Removal Kinetics Of Dissolved Organic Matter And The Optical Clarity Of Groundwater, Francis H. Chapelle, Yuan Shen, Eric W. Strom, Ronald Benner
The Removal Kinetics Of Dissolved Organic Matter And The Optical Clarity Of Groundwater, Francis H. Chapelle, Yuan Shen, Eric W. Strom, Ronald Benner
Faculty Publications
Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at …
Characterization And Photodegradation Of Dissolved Organic Matter (Dom) From A Tropical Lake And Its Dominant Primary Producer, The Cyanobacteria Microcystis Aeruginosa, Thais B. Bittar, Aron Stubbins, Armando A. H. Vieira, Kenneth Mopper
Characterization And Photodegradation Of Dissolved Organic Matter (Dom) From A Tropical Lake And Its Dominant Primary Producer, The Cyanobacteria Microcystis Aeruginosa, Thais B. Bittar, Aron Stubbins, Armando A. H. Vieira, Kenneth Mopper
Chemistry & Biochemistry Faculty Publications
This study investigates optical and high-resolution molecular signatures and photochemical degradation of DOM from the Barra Bonita Reservoir (BB-DOM), a tropical eutrophic lake, as well as from its dominant phytoplankton species, the cyanobacteria Microcystis aeruginosa (Microcystis-DOM). Consistent with a predominantly autotrophic source, BB-DOM and Microcystis-DOM exhibited high protein-like fluorescence and contained a large number of aliphatics. Microcystis-DOM was enriched in peptide-like formulae, while BB-DOM had higher chromophoric and fluorescent DOM(CDOM and FDOM) and was enriched in moderately unsaturated formulae, indicating additions of terrigenous DOM and/or in situ processing of autochthonous material in the lake. Consistent with …
Surface Production Fuels Deep Heterotrophic Respiration In Northern Peatlands, J. Elizabeth Corbett, David J. Burdige, Malak M. Tfaily, Angela R. Dial, William T. Cooper, Paul H. Glaser, Jeffrey P. Chanton
Surface Production Fuels Deep Heterotrophic Respiration In Northern Peatlands, J. Elizabeth Corbett, David J. Burdige, Malak M. Tfaily, Angela R. Dial, William T. Cooper, Paul H. Glaser, Jeffrey P. Chanton
OES Faculty Publications
Multiple analyses of dissolved organic carbon (DOC) from pore waters were conducted to define the processes that govern carbon balance in peatlands: (1) source, reactivity, and transport of DOC with respect to vegetation, peat, and age of carbon substrate, (2) reactivity of DOC with respect to molecular size, and (3) lability to photoxidation of surficial DOC. We found that surface organic production fuels heterotrophic respiration at depth in advection-dominated peatlands, especially in fens. Fen DOC was Δ14Cenriched relative to the surrounding fen peat, and fen respiration products were similar to this enriched DOC indicating that DOC was the …
Radiocarbon Evidence For The Importance Of Surface Vegetation On Fermentation And Methanogenesis In Contrasting Types Of Boreal Peatlands, J. P. Chanton, P. H. Glaser, L. S. Chasar, David J. Burdige, M. E. Hines, D. I. Seigel, L. B. Tremblay, W. T. Cooper
Radiocarbon Evidence For The Importance Of Surface Vegetation On Fermentation And Methanogenesis In Contrasting Types Of Boreal Peatlands, J. P. Chanton, P. H. Glaser, L. S. Chasar, David J. Burdige, M. E. Hines, D. I. Seigel, L. B. Tremblay, W. T. Cooper
OES Faculty Publications
We found a consistent distribution pattern for radiocarbon in dissolved organic carbon (DOC), dissolved inorganic carbon (DIC), and methane replicated across spatial and temporal scales in northern peatlands from Minnesota to Alaska. The 14C content of DOC is relatively modern throughout the peat column, to depths of 3 m. In sedge-dominated peatlands, the 14C contents of the products of respiration, CH4 and DIC, are essentially the same and are similar to that of DOC. In Sphagnum- and woody plant-dominated peatlands with few sedges, however, the respiration products are similar but intermediate between the 14C contents of …
Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige
Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige
OES Faculty Publications
Most studies of the organic complexation of Cu in natural waters have focused on distributions and processes in the water column, where a significant fraction of Cu-complexing ligands may be biologically produced. We present direct evidence for a flux of Cu-complexing ligands from estuarine sediments, demonstrating that sediments are a significant, yet previously unrecognized source of the ligands. Fluxes of Cu-complexing ligands from Chesapeake Bay sediments range from 300 to 1,200 nmol m-2 d-1, exceeding fluxes of total dissolved Cu by 3->40-fold, suggesting that any Cu fluxing from the sediments is likely to be organically complexed. …
The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens
The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens
OES Faculty Publications
Benthic fluxes (sediment-water exchange) of dissolved organic carbon (DOC) represent a poorly quantified component of sedimentary and oceanic carbon cycling. In this paper we use pore water DOC data and direct DOC benthic flux measurements to begin to quantitatively examine this problem. These results suggest that marine sediments represent a significant source of DOC to the oceans, as a lower limit of the globally-integrated benthic DOC flux is comparable in magnitude to riverine inputs of organic carbon to the oceans. Benthic fluxes of DOC also appear to be similar in magnitude to other sedimentary processes such as organic carbon oxidation …
Lingin Derived Organic Matter In Georgia Coastal Waters, Mary Ann Moran, Lawrence R. Pomeroy, Edward S. Sheppard, Larry P. Atkinson
Lingin Derived Organic Matter In Georgia Coastal Waters, Mary Ann Moran, Lawrence R. Pomeroy, Edward S. Sheppard, Larry P. Atkinson
CCPO Publications
The importance of riverine- and saltmarsh-derived organic matter to the food web of Georgia coastal waters has been a focus of ecological research over the past thirty years. Studies based on energy budgets, carbon flux measurements, and stable isotope ratios have generally implicated marsh detritus as an important, although not always dominant, source of organic matter within the marshes and adjacent estuaries (Teal 1962, Odum and de la Cruz 1967, Haines 1977, Peterson and Howarth 1987). However, data on the contribution of exported marsh and riverine organic matter to productivity futher offshore, in continental shelf waters off the coast of …