Physical Sciences and Mathematics Commons^™

Double Helical Hydrogen-Bonded Aaa-Ddd Complexes And Supramolecular Polymers, Hong-Bo Wang

Electronic Thesis and Dissertation Repository

The design and characterization of linear oligomers that self-assemble into double helical structures has been a subject of interest to chemists since the elucidation of the double helix structure of DNA in 1953. Transition metal templates have been widely used in the construction of artificial double helical complexes from linear multidentate ligands. The use of other non-covalent interactions as the driving force in the self-assembly of these types of complexes is less common. Aromatic stacking interactions, anion templates, and salt-bridges have all been applied in this context. The great majority of these investigations have been concerned with the dimerization of …

The Effect Of The Environment On The Corrosion Products And Corrosion Rates On Gas Transmission Pipelines, Brent Sherar

Electronic Thesis and Dissertation Repository

This thesis reports a series of investigations examining external corrosion processes along gas transmission pipelines. TransCanada PipeLines Ltd. (TCPL) has developed six proposed corrosion scenarios to describe external pipeline corrosion, based primarily on corrosion products and corrosion rates (CRs) observed at field sites. The six proposed corrosion scenarios can be divided into two groups: abiotic and biotic. The three abiotic corrosion scenarios are (1) anaerobic corrosion, (2) aerobic corrosion, and (3) anaerobic corrosion turning aerobic; while (4) anaerobic corrosion with microbial effects, (5) aerobic corrosion turning anaerobic with microbial effects, and (6) anaerobic corrosion with microbial effects turning aerobic comprise …

Surface Modifications Of Poly(Dimethylsiloxane) For Biological Application Of Microfluidic Devices, Jessica M. Dechene

Electronic Thesis and Dissertation Repository

The spatial control of cellular adhesion is fundamental to the development of studies of cell interaction, cellular microarrays, and cell based biosensors. The ability to pattern cell adhesion on flat substrates and in microfluidic channels is important for locating cell near microdetectors in cell based biosensor devices. Cell adhesion can be controlled by patterning a material's wettability, as cells are able to adhere to hydrophilic surface and will generally avoid hydrophobic materials.

This thesis focuses on patterning the surface wettability of poly(dimethylsilox-ane) (PDMS) in order to spatially control cell adhesion. The polymer is selectively modifed by the deposition of aluminum …