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Articles 181 - 210 of 1143
Full-Text Articles in Physical Sciences and Mathematics
Temporal Stability Of A Hybrid Swarm Between The Migratory Marine And Estuarine Fishes Acanthopagrus Australis And A. Butcheri, David G. Roberts, Charles A. Gray, Ronald J. West, David J. Ayre
Temporal Stability Of A Hybrid Swarm Between The Migratory Marine And Estuarine Fishes Acanthopagrus Australis And A. Butcheri, David G. Roberts, Charles A. Gray, Ronald J. West, David J. Ayre
Faculty of Science - Papers (Archive)
We predict estuaries to be hotspots of hybridisation between migratory marine and estuary-restricted species, although hybridisation rates may vary in space and time, reflecting the dynamic nature of estuaries and potentially widespread but erratic dispersal of marine taxa. Within estuaries, genotype frequencies may reflect past hybridisation events, with genetically intermediate and backcrossed individuals contributing to persistent hybrid swarms. In southeastern Australia, hybridisation has occurred between estuarine black bream Acanthopagrus butcheri and marine yellowfin bream A. australis, but it is unclear whether this reflects a contemporary process. We recently found that, within lakes and lagoons at the southern range limit of …
The Art Of Learning: Wildfire, Amenity Migration And Local Environmental Knowledge, Christine Eriksen, T Prior
The Art Of Learning: Wildfire, Amenity Migration And Local Environmental Knowledge, Christine Eriksen, T Prior
Faculty of Science - Papers (Archive)
Communicating the need to prepare well in advance of the wildfire season is a strategic priority for wildfire management agencies worldwide. However, there is considerable evidence to suggest that although these agencies invest significant effort towards this objective in the lead up to each wildfire season, landholders in at-risk locations often remain under-prepared. One reason for the poor translation of risk information materials into actual preparation may be attributed to the diversity of people now inhabiting wildfire-prone locations in peri-urban landscapes. These people hold widely varying experiences, beliefs, attitudes and values relating to wildfire, which influence their understanding and interpretation …
Integrated Coastal Zone Management Research In Australia And China, X H. Wang, X Xu, S G. Pearson, G Xue, Robert J. Morrison, D Liu, P Shi
Integrated Coastal Zone Management Research In Australia And China, X H. Wang, X Xu, S G. Pearson, G Xue, Robert J. Morrison, D Liu, P Shi
Faculty of Science - Papers (Archive)
This paper reviews the current Integrated and Coastal Zone Management (ICZM) research in coastal zone science and policy for Australia and China. It seeks to make a coherent contribution to understanding the Chinese and Australian research and management through a brief description of the similarities and differences in an integrated way. The paper draws together the research needs for the ICZM in both countries with the aim of justifying the research investments needed in the future. Based on this review, we recommend five research programs: Coastal Ocean Observing and Forecasting System and its Socio-economic Impact; Review and Utilization of Space-borne …
In The Heat Of The Night - Alternative Pathway Respiration Drives Thermogenesis In Philodendron Bipinnatifidum, Rebecca Miller, N. Grant, L. Giles, Miquel Ribas-Carbo, J. A. Berry, Jennifer Watling, Sharon A. Robinson
In The Heat Of The Night - Alternative Pathway Respiration Drives Thermogenesis In Philodendron Bipinnatifidum, Rebecca Miller, N. Grant, L. Giles, Miquel Ribas-Carbo, J. A. Berry, Jennifer Watling, Sharon A. Robinson
Faculty of Science - Papers (Archive)
Philodendron bipinnatifidum inflorescences heat up to 42ºC and thermoregulate. We investigated whether they generate heat via the cytochrome oxidase pathway uncoupled by uncoupling proteins (pUCPs), or the alternative oxidase (AOX). Contribution of AOX and pUCPs to heating in fertile (FM) and sterile (SM) male florets was determined using a combination of oxygen isotope discrimination, protein and substrate analyses. FM and SM florets thermoregulated independently for up to 30h ex planta. In both floret types, AOX contributed more than 90% of respiratory flux during peak heating. AOX protein increased 5-fold with the onset of thermogenesis in both floret types, whereas pUCP …
Digit Ratio, Color Polymorphism And Egg Testosterone In The Australian Painted Dragon, Michael Tobler, Mo Healey, Mats Olsson
Digit Ratio, Color Polymorphism And Egg Testosterone In The Australian Painted Dragon, Michael Tobler, Mo Healey, Mats Olsson
Faculty of Science - Papers (Archive)
Variation in exposure to sex hormones during early development contributes to phenotypic plasticity in vertebrate offspring. As a proposed marker for prenatal sex hormone exposure and because of their association with various physiological and behavioral characteristics, digit ratio and/or digit length have received notable interest within the field of evolutionary ecology. However, the validity of digit measures as a proxy of prenatal sex hormone exposure is controversial and only few studies have provided direct evidence for the link between digit development and prenatal sex hormones. Here, we report morph- and sex-specific variation in digit ratio in wild painted dragon lizards …
Speciation Of Dissolved Inorganic Arsenic By Diffusive Gradients In Thin Films: Selective Binding Of Asiii By 3-Mercaptopropyl-Functionalized Silica Gel, William W. Bennett, Peter R. Teasdale, Jarad G. Panther, David T. Welsh, Dianne F. Jolley
Speciation Of Dissolved Inorganic Arsenic By Diffusive Gradients In Thin Films: Selective Binding Of Asiii By 3-Mercaptopropyl-Functionalized Silica Gel, William W. Bennett, Peter R. Teasdale, Jarad G. Panther, David T. Welsh, Dianne F. Jolley
Faculty of Science - Papers (Archive)
A diffusive gradients in thin films (DGT) technique for selectively measuring AsIII utilizes commercially available 3-mercaptopropyl- functionalized silica gel. Deployment of the new technique alongside the Metsorb-DGT for total inorganic arsenic allows the calculation of As III directly and AsV by difference. Uptake of As III by mercapto-silica was quantitative and elution with a mixture of 1 mol L-1 HNO3 and 0.01 mol L-1 KIO 3 gave a recovery of 85.6 + 1.7%. DGT validation experiments showed linear accumulation of AsIII over time (R2 > 0.998). Accumulation was unaffected by varying ionic strength (0.0001-0.75 mol L-1 NaNO3) and pH (3.5-8.5). Deployment …
Sources Of Carbonaceous Aerosols And Deposited Black Carbon In The Arctic In Winter-Spring: Implications For Radiative Forcing, Q Wang, D J. Jacob, J A. Fisher, J Mao, E M. Leibensperger, C C. Carouge, P Le Sager, Y Kondo, J L. Jimenez, M J. Cubison, S J. Doherty
Sources Of Carbonaceous Aerosols And Deposited Black Carbon In The Arctic In Winter-Spring: Implications For Radiative Forcing, Q Wang, D J. Jacob, J A. Fisher, J Mao, E M. Leibensperger, C C. Carouge, P Le Sager, Y Kondo, J L. Jimenez, M J. Cubison, S J. Doherty
Faculty of Science - Papers (Archive)
We use a global chemical transport model (GEOS-Chem CTM) to interpret observations of black carbon (BC) and organic aerosol (OA) from the NASA ARCTAS aircraft campaign over the North American Arctic in April 2008, as well as longer-term records in surface air and in snow (2007-2009). BC emission inventories for North America, Europe, and Asia in the model are tested by comparison with surface air observations over these source regions. Russian open fires were the dominant source of OA in the Arctic troposphere during ARCTAS but we find that BC was of prevailingly anthropogenic (fossil fuel and biofuel) origin, particularly …
Analysis Of Macrobenthic Assemblages Of Lake Illawarra, New South Wales, B Li, Robert John Morrison
Analysis Of Macrobenthic Assemblages Of Lake Illawarra, New South Wales, B Li, Robert John Morrison
Faculty of Science - Papers (Archive)
1 - A survey of the macrobenthos community was carried out in Lake Illawarra, NSW, Australia, during April and May 2011. 2 - The aim of this study was to understand the current status of the characteristic macrobenthic fauna community, and the temporal changes over the past 30 years, as well as the impacts of anthropogenic activities on the benthic ecosystem. 3- Fifteen stations were selected as representative of three main areas of the lake (the entrance channel, the central basin and the sublittoral fringe), which might be impacted by different kinds of human activities. 4 - A total of …
Sources, Distribution, And Acidity Of Sulfate-Ammonium Aerosol In The Arctic In Winter-Spring, Jenny A. Fisher, Daniel J. Jacob, Q Wang, Roya Bahreini, C C. Carouge, M J. Cubison, Jack E. Dibb, Thomas Diehl, J L. Jimenez, E M. Leibensperger, Zifeng Lu, Marcel B.J Meinders, H. O T. Pye, Patricia K. Quinn, Sangeeta Sharma, David G. Streets, Aaron Van Donkelaar, R M. Yantosca
Sources, Distribution, And Acidity Of Sulfate-Ammonium Aerosol In The Arctic In Winter-Spring, Jenny A. Fisher, Daniel J. Jacob, Q Wang, Roya Bahreini, C C. Carouge, M J. Cubison, Jack E. Dibb, Thomas Diehl, J L. Jimenez, E M. Leibensperger, Zifeng Lu, Marcel B.J Meinders, H. O T. Pye, Patricia K. Quinn, Sangeeta Sharma, David G. Streets, Aaron Van Donkelaar, R M. Yantosca
Faculty of Science - Papers (Archive)
We use GEOS-Chem chemical transport model simulations of sulfate–ammonium aerosol data from the NASA ARCTAS and NOAA ARCPAC aircraft campaigns in the North American Arctic in April 2008, together with longer-term data from surface sites, to better understand aerosol sources in the Arctic in winter–spring and the implications for aerosol acidity. Arctic pollution is dominated by transport from mid-latitudes, and we test the relevant ammonia and sulfur dioxide emission inventories in the model by comparison with wet deposition flux data over the source continents. We find that a complicated mix of natural and anthropogenic sources with different vertical signatures is …
Effects Of Aging On Organic Aerosol From Open Biomass Burning Smoke In Aircraft And Laboratory Studies, M J. Cubison, A M. Ortega, P L. Hayes, D K. Farmer, D Day, M J. Lechner, W H. Brune, E Apel, G S. Diskin, J A. Fisher, H E. Fuelberg, A Hecobian, D J. Knapp, T Mikoviny, D Riemer, G W. Sachse, W Sessions, R Weber, A J. Weinheimer, A Wisthaler, J L. Jimenez
Effects Of Aging On Organic Aerosol From Open Biomass Burning Smoke In Aircraft And Laboratory Studies, M J. Cubison, A M. Ortega, P L. Hayes, D K. Farmer, D Day, M J. Lechner, W H. Brune, E Apel, G S. Diskin, J A. Fisher, H E. Fuelberg, A Hecobian, D J. Knapp, T Mikoviny, D Riemer, G W. Sachse, W Sessions, R Weber, A J. Weinheimer, A Wisthaler, J L. Jimenez
Faculty of Science - Papers (Archive)
Biomass burning (BB) is a large source of primary and secondary organic aerosols (POA and SOA). This study addresses the physical and chemical evolution of BB organic aerosols. Firstly, the evolution and lifetime of BB POA and SOA signatures observed with the Aerodyne Aerosol Mass Spectrometer are investigated, focusing on measurements at high-latitudes acquired during the 2008 NASA ARCTAS mission, in comparison to data from other field studies and from laboratory aging experiments. The parameter f60 , the ratio of the integrated signal at m/z 60 to the total signal in the organic component mass spectrum, is used as a …
Nanoesi Mass Spectrometry Of Rubisco And Rubisco Activase Structures And Their Interactions With Nucleotides And Sugar Phosphates, Michelle Blayney, Spencer M. Whitney, Jennifer L. Beck
Nanoesi Mass Spectrometry Of Rubisco And Rubisco Activase Structures And Their Interactions With Nucleotides And Sugar Phosphates, Michelle Blayney, Spencer M. Whitney, Jennifer L. Beck
Faculty of Science - Papers (Archive)
Ribulose bisphosphate carboxylase/oxygenase (Rubisco) is the protein that is responsible for the fixation of carbon dioxide in photosynthesis. Inhibitory sugar phosphate molecules, which can include its substrate ribulose-1,5- bisphosphate (RuBP), can bind to Rubisco catalytic sites and inhibit catalysis. These are removed by interaction with Rubisco activase (RA) via an ATP hydrolytic reaction. Here we show the first nanoESI mass spectra of the hexadecameric Rubisco and of RA from a higher plant (tobacco). The spectra of recombinant, purified RA revealed polydispersity in its oligomeric forms (up to hexamer) and that ADP was bound. ADP was removed by dialysis against a …
The Influence Of Sediment Particle Size And Organic Carbon On Toxicity Of Copper To Benthic Invertebrates In Oxic/Suboxic Surface Sediments, David Strom, Stuart L. Simpson, Graeme E. Batley, Dianne F. Jolley
The Influence Of Sediment Particle Size And Organic Carbon On Toxicity Of Copper To Benthic Invertebrates In Oxic/Suboxic Surface Sediments, David Strom, Stuart L. Simpson, Graeme E. Batley, Dianne F. Jolley
Faculty of Science - Papers (Archive)
The use of sediment quality guidelines to predict the toxicity of metals in sediments is limited by an inadequate understanding of exposure pathways and by poor causal links between exposure and effects. For a 10-d exposure to Cu-spiked sediments, toxicity to the amphipod Melita plumulosa was demonstrated to occur through a combination of dissolved and dietary Cu exposure pathways, but for the bivalves Spisula trigonella and Tellina deltoidalis, toxicity occurred primarily by exposure to dissolved Cu. For relatively oxidized sediments that had moderate amounts of organic carbon (2.6-8.3% OC), silt (20-100%
How Well Do Predators Adjust To Climate-Mediated Shifts In Prey Distribution? A Study On Australian Water Pythons, Beata Ujvari, Rick Shine, Thomas Madsen
How Well Do Predators Adjust To Climate-Mediated Shifts In Prey Distribution? A Study On Australian Water Pythons, Beata Ujvari, Rick Shine, Thomas Madsen
Faculty of Science - Papers (Archive)
Climate change can move the spatial location of resources critical for population viability, and a species resilience to such changes will depend upon its ability to flexibly shift its activities away from no-longer-suitable sites to exploit new opportunities. Intuition suggests that vagile predators should be able to track spatial shifts in prey availability, but our data on water pythons (Liasis fuscus) in tropical Australia suggest a less encouraging scenario. These pythons undergo regular long-range (to .10 km) seasonal migrations to follow flooding-induced migrations by their prey (native dusky rats, Rattus colletti ). However, when an extreme flooding event virtually eliminated …
Daily And 3-Hourly Variability In Global Fire Emissions And Consequences For Atmospheric Model Predictions Of Carbon Monoxide, M Mu, James Randerson, G R. Van Der Werf, L Giglio, Prasad Kasibhatla, D Morton, G J. Collatz, R S. Defries, E J. Hyer, E M. Prins, David W. Griffith, Debra Wunch, G C. Toon, V Sherlock, Paul O. Wennberg
Daily And 3-Hourly Variability In Global Fire Emissions And Consequences For Atmospheric Model Predictions Of Carbon Monoxide, M Mu, James Randerson, G R. Van Der Werf, L Giglio, Prasad Kasibhatla, D Morton, G J. Collatz, R S. Defries, E J. Hyer, E M. Prins, David W. Griffith, Debra Wunch, G C. Toon, V Sherlock, Paul O. Wennberg
Faculty of Science - Papers (Archive)
"Attribution of the causes of atmospheric trace gas and aerosol variability often requires the use of high resolution time series of anthropogenic and natural emissions inventories. Here we developed an approach for representing synoptic-and diurnal-scale temporal variability in fire emissions for the Global Fire Emissions Database version 3 (GFED3). We disaggregated monthly GFED3 emissions during 2003-2009 to a daily time step using Moderate Resolution Imaging Spectroradiometer (MODIS)-derived measurements of active fires from Terra and Aqua satellites. In parallel, mean diurnal cycles were constructed from Geostationary Operational Environmental Satellite (GOES) Wildfire Automated Biomass Burning Algorithm (WF_ABBA) active fire observations. Daily variability …
Retrieval Of Atmospheric Co2 With Enhanced Accuracy And Precision From Sciamachy: Validation With Fts Measurements And Comparison With Model Results, M Reuter, H Bovensmann, M Buchwitz, Jp Burrows, B Connor, Nicholas M. Deutscher, David W. Griffith, J Heymann, Gretchen Keppel-Aleks, Janina Messerschmidt, Justus Notholt, Christof Petri, J Robinson, O Schneising, V Sherlock, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, Debra Wunch
Retrieval Of Atmospheric Co2 With Enhanced Accuracy And Precision From Sciamachy: Validation With Fts Measurements And Comparison With Model Results, M Reuter, H Bovensmann, M Buchwitz, Jp Burrows, B Connor, Nicholas M. Deutscher, David W. Griffith, J Heymann, Gretchen Keppel-Aleks, Janina Messerschmidt, Justus Notholt, Christof Petri, J Robinson, O Schneising, V Sherlock, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, Debra Wunch
Faculty of Science - Papers (Archive)
The Bremen Optimal Estimation differential optical absorption spectroscopy (DOAS) (BESD) algorithm for satellite based retrievals of XCO 2 (the column-average dry-air mole fraction of atmospheric CO 2) has been applied to Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) data. It uses measurements in the O 2-A absorption band to correct for scattering of undetected clouds and aerosols. Comparisons with precise and accurate ground-based Fourier transform spectrometer (FTS) measurements at four Total Carbon Column Observing Network (TCCON) sites have been used to quantify the quality of the new SCIAMACHY XCO 2 data set. Additionally, the results have been compared to …
The Age Of The 20 Meter Solo River Terrace, Java, Indonesia And The Survival Of Homo Erectus In Asia, Etty Indriati, Carl C. Swisher, Christopher Lepre, Rhonda L. Quinn, Rusyad A. Suriyanto, Agus T. Hascaryo, Rainer Grun, Craig S. Feibel, Briana L. Pobiner, Maxime Aubert, Wendy Lees, Susan C. Anton
The Age Of The 20 Meter Solo River Terrace, Java, Indonesia And The Survival Of Homo Erectus In Asia, Etty Indriati, Carl C. Swisher, Christopher Lepre, Rhonda L. Quinn, Rusyad A. Suriyanto, Agus T. Hascaryo, Rainer Grun, Craig S. Feibel, Briana L. Pobiner, Maxime Aubert, Wendy Lees, Susan C. Anton
Faculty of Science - Papers (Archive)
Homo erectus was the first human lineage to disperse widely throughout the Old World, the only hominin in Asia through much of the Pleistocene, and was likely ancestral to H. sapiens. The demise of this taxon remains obscure because of uncertainties regarding the geological age of its youngest populations. In 1996, some of us co-published electron spin resonance (ESR) and uranium series (U-series) results indicating an age as young as 35-50 ka for the late H. erectus sites of Ngandong and Sambungmacan and the faunal site of Jigar (Indonesia). If correct, these ages favor an African origin for recent humans …
The Dirt On Assessing Post-Fire Erosion In The Mount Lofty Ranges: Comparing Methods, Rowena H. Morris, Solomon Buckman, Paul Connelly, Deirdre Dragovich, Bertram Ostendorf, Ross A. Bradstock
The Dirt On Assessing Post-Fire Erosion In The Mount Lofty Ranges: Comparing Methods, Rowena H. Morris, Solomon Buckman, Paul Connelly, Deirdre Dragovich, Bertram Ostendorf, Ross A. Bradstock
Faculty of Science - Papers (Archive)
Land managers are required to assess a range of environmental attributes prior to and after prescribed burning. Current environmental assessments vary depending on the organisation involved and the existing information about localised soil erosion. Auditing successful environmental assessments requires ongoing field monitoring to evaluate whether the magnitude and extent of predicted post-fire impacts are comparable. The impacts of post-fire erosion were assessed by the authors using the techniques of water sampling, sediment traps, erosion pins, laser scanning, photogrammetry and visual field assessment. Each data collecting method varies in its spatial and temporal reach in terms of monitoring landscape changes in …
Revealing Indigenous Indonesian Traditional Medicine: Anti-Infective Agents, Paul A. Keller, Ari Satia Nugraha
Revealing Indigenous Indonesian Traditional Medicine: Anti-Infective Agents, Paul A. Keller, Ari Satia Nugraha
Faculty of Science - Papers (Archive)
Indonesia is rich in medicinal plants which the population has used traditionally from generation to generation for curing diseases. Our interest in the treatment of infectious diseases has lead to the investigation of traditional Indonesian treatments. In this review, we present a comprehensive review of ethnopharmacologically directed screening in Indonesian medicinal plants to search for new anti-viral, antimalarial, anti-bacterial and anti-fungal agents. Some potent drug leads have been isolated from Indonesian medicinal plants. Further research is still required for the lead development as well as the search for new bioactive compounds from the enormous medicinal plant resources.
Isolation Of Linobiflavonoid, A Novel Biflavonoid From Linostoma Pauciflorum Griff, Tawesin Navarat, Stephen G. Pyne, Uma Prawat, Pittaya Tuntiwachwuttikul
Isolation Of Linobiflavonoid, A Novel Biflavonoid From Linostoma Pauciflorum Griff, Tawesin Navarat, Stephen G. Pyne, Uma Prawat, Pittaya Tuntiwachwuttikul
Faculty of Science - Papers (Archive)
A novel biflavonoid, that we have named linobiflavonoid, and the known biscoumarin ether, daphnoretin, were isolated from the root extracts of Linostoma pauciflorum Griff. The structure of linobiflavonoid was determined from interpretation of its NMR spectroscopic data and from a comparison of this data with those of known biflavonoids and biflavones. The known flavones, 5,4'-dihydroxy- 7,3',5'-trimethoxyflavone and 5,4'-dihydroxy-7-methoxyflavone along with stigmasterol were isolated from the vines of the same plant. 4'-Dihydroxy-7,3'-5'-trimethoxyflavone was active against Mycobacterium tuberculosis (MIC 3.13 mu M) and KB-oral cavity cancer (IC50 17.41 mu M). (C) 2011 Phytochemical Society of Europe. Published by Elsevier B.V. All …
Identification Of Phospholipids In Human Meibum By Nano-Electrospray Ionisation Tandem Mass Spectrometry, Jennifer T. Saville, Zhenjun Zhao, Mark Dp Willcox, Manjula A. Ariyavidana, Stephen J. Blanksby, Todd W. Mitchell
Identification Of Phospholipids In Human Meibum By Nano-Electrospray Ionisation Tandem Mass Spectrometry, Jennifer T. Saville, Zhenjun Zhao, Mark Dp Willcox, Manjula A. Ariyavidana, Stephen J. Blanksby, Todd W. Mitchell
Faculty of Science - Papers (Archive)
Meibum is believed to be the major source of tear !lm lipids, which are vital in the prevention of excessevaporation of the aqueous phase. The complete lipid composition of meibum has yet to be established.While earlier studies reported the presence of phospholipids in human meibum, recent mass spectrometricstudies have not detected them. In this study we use electrospray ionisation tandem massspectrometry to investigate the presence of phospholipids in meibum and provide comparison to thephospholipid pro!le of tears.Lipids were extracted from human meibum and tear samples using standard biphasic methods andanalysed by nano-electrospray ionisation tandem mass spectrometry using targeted ion scans. …
Global Co(2) Fluxes Inferred From Surface Air-Sample Measurements And From Tccon Retrievals Of The Co(2) Total Column, Frederic Chevallier, Nicholas M. Deutscher, T J. Conway, P Ciais, L Ciattaglia, S Dohe, M Frohlich, A J. Gomez-Pelaez, David W. Griffith, F Hase, L Haszpra, Paul Krummel, E Kyro, C Labuschagne, R Lagenfelds, T Machidda, F Maignan, H Matsueda, I Morino, Justus Notholt, M Ramonet, Y Sawa, M Schmidt, V Sherlock, P Steele, K Strong, R Sussmann, Paul O. Wennberg, Steven C. Wofsy, D Worthy, Debra Wunch, M Zimnoch
Global Co(2) Fluxes Inferred From Surface Air-Sample Measurements And From Tccon Retrievals Of The Co(2) Total Column, Frederic Chevallier, Nicholas M. Deutscher, T J. Conway, P Ciais, L Ciattaglia, S Dohe, M Frohlich, A J. Gomez-Pelaez, David W. Griffith, F Hase, L Haszpra, Paul Krummel, E Kyro, C Labuschagne, R Lagenfelds, T Machidda, F Maignan, H Matsueda, I Morino, Justus Notholt, M Ramonet, Y Sawa, M Schmidt, V Sherlock, P Steele, K Strong, R Sussmann, Paul O. Wennberg, Steven C. Wofsy, D Worthy, Debra Wunch, M Zimnoch
Faculty of Science - Papers (Archive)
"We present the first estimate of the global distribution of CO(2) surface fluxes from 14 stations of the Total Carbon Column Observing Network (TCCON). The evaluation of this inversion is based on 1) comparison with the fluxes from a classical inversion of surface air-sample-measurements, and 2) comparison of CO(2) mixing ratios calculated from the inverted fluxes with independent aircraft measurements made during the two years analyzed here, 2009 and 2010. The former test shows similar seasonal cycles in the northern hemisphere and consistent regional carbon budgets between inversions from the two datasets, even though the TCCON inversion appears to be …
Envisioning The Archipelago, Elizabeth Mcmahon, Carol Farbotko, Godfrey Baldacchino, Andrew Harwood, Elaine Stratford
Envisioning The Archipelago, Elizabeth Mcmahon, Carol Farbotko, Godfrey Baldacchino, Andrew Harwood, Elaine Stratford
Faculty of Science - Papers (Archive)
Certain limitations arise from the persistent consideration of two common relationsof islands in the humanities and social sciences: land and sea, and island andcontinent/mainland. What remains largely absent or silent are ways of being, knowing anddoing¿ontologies, epistemologies and methods¿that illuminate island spaces as inter-related,mutually constituted and co-constructed: as island and island. Therefore, this paper seeks tomap out and justify a research agenda proposing a robust and comprehensive exploration ofthis third and comparatively neglected nexus of relations. In advancing these aims, the paper¿sgoal is to (re)inscribe the theoretical, metaphorical, real and empirical power and potential ofthe archipelago: of seas studded with …
Synthesis Of 3-Halo-2,5-Disubstituted Furans Via Cux Mediated Cyclization-Halogenation Reactions, Arife Yazici, Stephen G. Pyne
Synthesis Of 3-Halo-2,5-Disubstituted Furans Via Cux Mediated Cyclization-Halogenation Reactions, Arife Yazici, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The Cu(I) halide (X = I, Br, Cl) mediated reactions of Cbz-protected cis-2-phenylethenyl-3-hydroxypyrrolidine gave novel 3-halo-2,5-trisubstituted furans in good yields, via a cyclization-halogenation, ring-opening reaction sequence. In contrast, the reactions with CuCN gave mainly the corresponding 3-cyanofuro[3,2-b]pyrrole formed from a cyclization-cyanation reaction.
An Unusually Flexible Expanded Hexaamine Cage And Its Cuii Complexes: Variable Coordination Modes And Incomplete Encapsulation, C-J Qin, Lloyd James, Jy D. Chartres, Leighton J. Alcock, Kimberley J. Davis, Anthony C. Willis, Alan M. Sargeson, Paul V. Bernhardt, Stephen F. Ralph
An Unusually Flexible Expanded Hexaamine Cage And Its Cuii Complexes: Variable Coordination Modes And Incomplete Encapsulation, C-J Qin, Lloyd James, Jy D. Chartres, Leighton J. Alcock, Kimberley J. Davis, Anthony C. Willis, Alan M. Sargeson, Paul V. Bernhardt, Stephen F. Ralph
Faculty of Science - Papers (Archive)
The bicyclic hexaamine "cage" ligand Me 8tricosaneN 6 (1,5,5,9,13,13,20,20-octamethyl-3,7,11,15,18, 22-hexaazabicyclo[7.7.7]tricosane) is capable of encapsulating octahedral metal ions, yet its expanded cavity allows the complexed metal to adopt a variety of geometries comprising either hexadentate or pentadentate coordination of the ligand. When complexed to Cu II the lability of the metal results in a dynamic equilibrium in solution between hexadentate- and pentadentate- coordinated complexes of Me 8tricosaneN 6. Both [Cu(Me 8tricosaneN 6)](ClO 4) 2 (6-coordinate) and [Cu(Me 8tricosaneN 6)](S 2O 6) (5-coordinate) have been characterized structurally. In weak acid (pH 1) a singly protonated complex [Cu(HMe 8tricosaneN 6)] 3+ has been …
Preliminary Validation Of Column-Averaged Volume Mixing Ratios Of Carbon Dioxide And Methane Retrieved From Gosat Short-Wavelength Infrared Spectra, David W. Griffith, G C. Toon, B Connor, R Sussmann, Thorsten Warneke, Nicholas M. Deutscher, Paul O. Wennberg, Justus Notholt, V Sherlock, J Robinson, O Uchino, C M. Roehl, I Morino, Debra Wunch, Janina Messerschmidt, Y Yoshida, M Inoue, M Rettinger
Preliminary Validation Of Column-Averaged Volume Mixing Ratios Of Carbon Dioxide And Methane Retrieved From Gosat Short-Wavelength Infrared Spectra, David W. Griffith, G C. Toon, B Connor, R Sussmann, Thorsten Warneke, Nicholas M. Deutscher, Paul O. Wennberg, Justus Notholt, V Sherlock, J Robinson, O Uchino, C M. Roehl, I Morino, Debra Wunch, Janina Messerschmidt, Y Yoshida, M Inoue, M Rettinger
Faculty of Science - Papers (Archive)
Column-averaged volume mixing ratios of carbon dioxide and methane retrieved from the Greenhouse gases Observing SATellite (GOSAT) Short-Wavelength InfraRed observation (GOSAT SWIR XCO2 and XCH4 ) were compared with the reference calibrated data obtained by ground-based high-resolution Fourier Transform Spectrometers (g-b FTSs) participating in the Total Carbon Column Observing Network (TCCON). Preliminary results are as follows: the GOSAT SWIR XCO2 and XCH4 (Version 01.xx) are biased low by 8.85 ±4.75 ppm (2.3±1.2 %) and 20.4±18.9 ppb (1.2±1.1 %), respectively. The standard deviation of the GOSAT SWIR XCO2 and XCH4 is about 1% after correcting the negative biases of XCO2 and …
An Assessment Of Three Harpacticoid Copepod Species For Use In Ecotoxicological Testing, Daniel J. Ward, Victor Perez-Landa, David A. Spadaro, Stuart L. Simpson, Dianne F. Jolley
An Assessment Of Three Harpacticoid Copepod Species For Use In Ecotoxicological Testing, Daniel J. Ward, Victor Perez-Landa, David A. Spadaro, Stuart L. Simpson, Dianne F. Jolley
Faculty of Science - Papers (Archive)
The relatively short life cycles of harpacticoid copepods makes them appropriate animals for use in tests that rapidly assess the #180, sublethal, or chronic effects of sediment contaminants. In this study, four harpacticoid copepod species (Nitocra spinipes, Tisbe tenuimana, Robertgurneya hopkinsi, and Halectinosoma sp.) were isolated from clean marine sediments, and procedures for laboratory culturing were developed. Halectinosoma sp. was abandoned due to handling difficulties. For the remaining species, the influence of food type and quantity on life-cycle progression was assessed. A mixed diet, comprising two species of algae (Tetraselmis sp. and Isochrysis sp.) and fish food (Sera …
Extensional And Colisional Magmatic Records In The Apiai Terrane, South-Southeastern Brazil: Integration Of Geochronological U-Pb Zircon Ages, Oswaldo Siga Junior, Miguel Angelo Stipp Basei, Allen P. Nutman, Kei Sato, Ian Mcreath, Claudia Regina Passarelli, Dunyi Liu
Extensional And Colisional Magmatic Records In The Apiai Terrane, South-Southeastern Brazil: Integration Of Geochronological U-Pb Zircon Ages, Oswaldo Siga Junior, Miguel Angelo Stipp Basei, Allen P. Nutman, Kei Sato, Ian Mcreath, Claudia Regina Passarelli, Dunyi Liu
Faculty of Science - Papers (Archive)
The aim of this work is the presentation of a synthesis of available geochronological data for the basement inliers and metavolcano-sedimentary sequences which occur in the southern part of the Apiai Terrane, south-southeastern Brazil. These data, especially those obtained during the last decade, have made substantial modifi cations to the tectonic scenario of south-southeastern Brazil with the recognition of the presence of extensional basins (continental rifts) with magmatism and sedimentation at the late Paleoproterozoic (1790 - 1750 Ma) and of the Mesoproterozoic (1600 - 1450 Ma). These processes started at the late Paleoproterozoic in the Betara, Perau and Apiai Mirim …
An Automated Land Subdivision Tool For Urban And Regional Planning: Concepts, Implementation And Testing, Rohan Wickramasuriya, Laurie A. Chisholm, Marjetta Puotinen, Nicholas Gill, Peter Klepeis
An Automated Land Subdivision Tool For Urban And Regional Planning: Concepts, Implementation And Testing, Rohan Wickramasuriya, Laurie A. Chisholm, Marjetta Puotinen, Nicholas Gill, Peter Klepeis
Faculty of Science - Papers (Archive)
Simulation of the land subdivision process is useful in many applied and research areas. Planners use such tools to understand potential impacts of planning regulations prior to their implementation. While the credibility of both land-use change and urban growth models would be enhanced by integrating capabilities to simulate land subdivision, such research is lacking in the published literature. Of the few subdivision tools that exist, most are either not fully-automated or are unable to generate realistic subdivision layouts. This limits their applicability, particularly for high resolution land-use change models. In this paper, we present a fully-automated land subdivision tool that …
Films, Buckypapers And Fibers From Clay, Chitosan And Carbon Nanotubes, Thomas M. Higgins, Holly Warren, Marc In Het Panhuis
Films, Buckypapers And Fibers From Clay, Chitosan And Carbon Nanotubes, Thomas M. Higgins, Holly Warren, Marc In Het Panhuis
Faculty of Science - Papers (Archive)
The mechanical and electrical characteristics of films, buckypapers and fiber materials from combinations of clay, carbon nanotubes (CNTs) and chitosan are described. The rheological time-dependent characteristics of clay are maintained in clay–carbon nanotube–chitosan composite dispersions. It is demonstrated that the addition of chitosan improves their mechanical characteristics, but decreases electrical conductivity by three-orders of magnitude compared to clay–CNT materials. We show that the electrical response upon exposure to humid atmosphere is influenced by clay-chitosan interactions, i.e., the resistance of clay–CNT materials decreases, whereas that of clay–CNT–chitosan increases.
Chemically Activated Reactions On The C7h5 Energy Surface: Propargyl + Diacetylene, I-C5h3 + Acetylene, And N-C5h3 + Acetylene, Gabriel Da Silva, Adam J. Trevitt
Chemically Activated Reactions On The C7h5 Energy Surface: Propargyl + Diacetylene, I-C5h3 + Acetylene, And N-C5h3 + Acetylene, Gabriel Da Silva, Adam J. Trevitt
Faculty of Science - Papers (Archive)
This study uses computational chemistry and statistical reaction rate theory to investigate the chemically activated reaction of diacetylene (butadiyne, C4H2) with the propargyl radical (C •H2CCH) and the reaction of acetylene (C 2H2) with the i-C5H3 (CH 2CCCC•H) and n-C5H3 (CHCC •HCCH) radicals. A detailed G3SX-level C7H 5 energy surface demonstrates that the C3H3 + C4H2 and C5H3 + C2H 2 addition reactions proceed with moderate barriers, on the order of 10 to 15 kcal mol-1, and form activated open-chain C 7H5 species that can isomerize to the fulvenallenyl radical with the highest barrier still significantly below the entrance channel …