Physical Sciences and Mathematics Commons^™

Comparative Geochemical Analysis Of Ordovician And Mississippian Cherts In Relation To The Northern Arkansas And The Tri-State Mississippi Valley-Type Ore Districts, Jonathan T. Chick

Graduate Theses and Dissertations

It has been hypothesized that Ordovician, Mississippian, and younger carbonate and clastic formations found within the Ouachita Basin of west-central Arkansas and northward onto the Ozark Dome have experienced interaction with hydrothermal fluids due to tectonic forces produced by the Ouachita Orogeny. Lead (Pb) isotope analyses and resulting values produced through previous and concurrent geochemical studies of several formations indicate that the Mississippi Valley-type (MVT) ores were produced from a mixing and cooling of these sedimentary basinal brines by meteoric or connate waters. Reduction of sulfate to sulfide is one of the possible mechanisms by which MVT ore precipitation may …

Characterizing Hydrothermal System Groundwater Dynamics Using Conservative And Non-Conservative Tracers: Insights And Implications Drawn From Study At The Taupo Volcanic Zone (New Zealand) And Valles Caldera (Usa), Joshua Michael Blackstock

Graduate Theses and Dissertations

Hydrothermal systems constitute an important component of heat and mass transport within Earth’s crust having direct and indirect impacts to society. Investigating contemporary hydrochemical differences and change are critical to evaluating and deconvolving factors that influence geothermal systems through time. In this dissertation, groundwater mixing approaches were used to study hydrochemical differences in two globally significant hydrothermal areas, which included fabrication of a low-cost dissolved CO2 monitoring for dissolved inorganic carbon (DIC). In the Taupo Volcanic Zone (New Zealand), empirical spatial relations were used to derive low-temperature groundwater end-members of Cl and Cl/Br for end-member mixing analysis (EMMA). Using EMMA, …

The Shelf To Basin Transition And Tectonostratigraphy Of The Atoka Formation (Lower Pennsylvanian) In The Arkoma Basin, Northwest Arkansas, Travis Gibson White

Graduate Theses and Dissertations

The east-to-west oriented Arkoma Basin is a peripheral foreland basin or depositional trough that developed during the Carboniferous Period. This formation covers an aerial extent of approximately 33,800 square miles and spans from west-central Arkansas into southeastern Oklahoma (McGilvery, Manger, and Zachry, 2016; Perry, 1995). The Atoka Formation, deposited during the early Pennsylvanian, is the largest Paleozoic formation by aerial extent in the state of Arkansas and is located within and comprises the bulk of Arkoma Basin sediments (McFarland, 2004; Nance, 2018). This formation has been informally divided into three divisions, the lower, middle, and upper, based on their stratigraphic …

An Investigation Of Metal Sulfides As The Source Of The Low Emissivity Anomaly On The Highlands Of Venus, Sara Taeko Port

Graduate Theses and Dissertations

Since its detection in the 1960s the source of the unusual radar emissivity signal seen on several highlands on Venus has long eluded researchers. Researchers have determined that a mineral with a high dielectric constant could explain the signal. Using a Venus simulation chamber, we experimentally investigated this enigma to build upon the candidate mineral list that has been compiled over the last several decades. We tested the stability of 8 different minerals and elements at two to three different temperature/pressure regimes in three different gas mixtures meant to simulate the conditions found on Venus for a period of no …

Suitability Assessment For Integrated Urban Development In Makkah City Of Saudi Arabia, Mislat Alotaibi

Graduate Theses and Dissertations

Makkah – the third most populated city in Saudi Arabia with a population of 1,684,408 according to the 2010 demographic survey conducted by the Saudi General Authority for Statistics – is experiencing urban sprawl, which can be defined as an unplanned urban expansion that might degrade the environment and diminish the aesthetic view. This is a persisting problem in Makkah driven by multitude of processes involving the random expansion in its undeveloped land and the removal of its historic mountains surrounding Al-Masjid Al-Haram (the Holy Mosque) in an attempt to push the city limit of urban capacity within its administrative …

The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo

Graduate Theses and Dissertations

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …

Provenance And Maximum Depositional Age Analysis Of The Moenave Formation Using Detrital Zircon U-Pb Geochronology And Sandstone Petrography, Asher Rea Boudreaux

Graduate Theses and Dissertations

In southwestern Utah and northeastern Arizona, Moenave Formation (latest Triassic(?)-Jurassic) is bracketed by well-studied Mesozoic units extensively sampled for detrital zircon geochronology and is poorly documented in regard to provenance, representing an important gap in knowledge. The Moenave Formation provides a unique opportunity to employ detrital zircon U-Pb geochronology and sandstone petrography relevant to completing the paleogeographic, evolutionary, and climatic story of the region. This study aims to characterize the sedimentary provenance of the Moenave Formation and to identify, or at least improve constraints on, the stratigraphic position of the Triassic-Jurassic boundary (TJB) and placement of the end-Triassic extinction (ETE), …

Geochemical Analysis Of Mississippian Cherts And Devonian-Mississippian Novaculites, Southern Midcontinent Region, Julie Mary Cains

Graduate Theses and Dissertations

This study uses trace elements and radiogenic isotopes (Pb, Sr, and Nd) to investigate the origin and mode of formation for the siliceous deposits in the Lower Mississippian Boone Formation and the Devonian-Mississippian Arkansas Novaculite in the southern midcontinent. Mississippi Valley-type Pb-Zn ore deposits in the Tri-State District and the Northern Arkansas District were deposited by hydrothermal fluids, and highly radiogenic Pb isotope ratios suggest a genetic relationship between the Boone Formation chert (206Pb/204Pb ~ 21.59, 207Pb/204Pb ~ 15.87, 208Pb/204Pb ~ 40.10) and the MVT ores. Due to the very low concentration of Pb in the Boone chert (~2 ppm) …

A Bayesian Framework For Estimating Seismic Wave Arrival Time, Hua Zhong

Graduate Theses and Dissertations

Because earthquakes have a large impact on human society, statistical methods for better studying earthquakes are required. One characteristic of earthquakes is the arrival time of seismic waves at a seismic signal sensor. Once we can estimate the earthquake arrival time accurately, the earthquake location can be triangulated, and assistance can be sent to that area correctly. This study presents a Bayesian framework to predict the arrival time of seismic waves with associated uncertainty. We use a change point framework to model the different conditions before and after the seismic wave arrives. To evaluate the performance of the model, we …

Stratigraphy And Depositional Characterization Of The Moorefield Shale (Middle-Late Mississippian) In Its Type Area, Northeastern Arkansas (Eastern Arkoma Basin), Griffin Warner

Graduate Theses and Dissertations

The Moorefield Shale represents the Meramecian Series in the Eastern Arkoma Basin in northern Arkansas. Lying on the margin of the Mississippi Embayment and Reelfoot Rift, sequence stratigraphic interpretations have labelled the Moorefield Shale a lowstand wedge succeeding the Early Mississippian (Osagean) Boone Limestone conformably and overlain conformably by the Hindsville Limestone/Batesville Sandstone. The unit contains a basal brown-black limestone and succeeding brown-black phosphatic shale. The Moorefield Shale was deposited along the broad, stable cratonic platform on the southern flank of Laurasia, before it’s collision with Gondwanaland to form the supercontinent Pangea at the end of the Paleozoic. During this …

Incorporating Recent Geochemical And Isotopic Constraints In Age Dating The Waters Of Hot Springs National Park, Arkansas, Kristina Marie Raley

Graduate Theses and Dissertations

Mean water age for spring discharge in Hot Springs National Park was calculated as approximately 4,400 years by Bedinger et al (1978) using carbon-14. Their analysis indicated that the water was a mixture of a small portion of cold water that was less than twenty years old with a preponderance of hot water. However, this result includes some error due to Bedinger et al. using general isotopic values for soil dissolved inorganic carbon and mineral carbon instead of obtaining actual values from the study area. A more accurate age calculation for the springs has been made possible by additional geological …

Subsurface Stratigraphic Interpretation Of The Lower Atoka Formation, Northern Arkoma Basin, Arkansas, William Stephen Denham

Graduate Theses and Dissertations

The Arkoma Basin is a Carboniferous peripheral foreland basin creating a structural depression covering an approximate area of 33,800 miles2 that extends through east-central Oklahoma and west-central Arkansas. The entire basin fill includes Pre-Mississippian carbonate shelf deposits, Mississippian marine carbonates and black shales, and Pennsylvanian mixed carbonated/clastic and shore zone/deltaic deposits. The Lower Atoka formation (Pennsylvanian) occurs in outcrop along the southern Boston Mountain Plateau in northern Arkansas and extends into the subsurface of the Arkoma Basin over an area of 2,300 miles2. The Lower Atoka ranges from 600 to 1500 feet in thickness and represents a cyclic succession of …

An Integrated Well Log And 3d Seismic Interpretation Of Missourian Clinoforms, Osage County, Oklahoma, Abram Max Barker

Graduate Theses and Dissertations

Integrated analysis of well and geophysical data can provide detailed geologic interpretation of the subsurface in Osage County, Oklahoma. Systems tracts and depositional system successions can be interpreted at marginal seismic resolution using well log motif with seismic reflector character within a depositional context. Shelf-prism and subaqueous, delta-scale clinoforms of Missourian age observed in 3D seismic were interpreted with greater sequence stratigraphic detail when coupled with wireline well logs. The Late Pennsylvanian Midcontinent Sea was thought to be approximately 150 feet average depth across the southern Midcontinent during the Missourian Stage, and deepen towards the Arkoma and Anadarko Basins to …

Subsurface Analysis Of Mississippian Tripolitic Chert In Northwest Arkansas, Thomas Jason Liner

Graduate Theses and Dissertations

Over the past 70 years the Mississippian strata of Northwest Arkansas have been studied in great detail. The study area is located on the escarpment between the Boston Mountains Plateau and the Springfield Plateau where a surface occurrence of Mississippian age rock allows for access to outcrops in close proximity to gas wells that encounter subsurface Mississippian strata. Many outcrops found in Northwest Arkansas expose Lower Mississippian (Kinderhookian-Osagean) strata that represent a full third order transgressive/regressive sequence that is unconformity bounded. These Mississippian outcrops are commonly treated as surface analogs to the Mississippi Lime Play in North Central Oklahoma. This …

Speleogenesis In Turbulent Flow, Max P. Cooper

Graduate Theses and Dissertations

Existing models of speleogenesis neglect the shape of cross-sections, which can hold information related to climate, tectonics, and sediment supply in their widths. The first study of this dissertation simulates cross-sections of phreatic tubes, vadose canyons, and paragenetic galleries using a method developed for bedrock channels. Successful simulation of these cross-sections depends on erosion scaling with shear stress, in conflict with speleogenesis theory. Scaling of equilibrium width in paragenetic galleries was explored through analytical derivation and simulations, showing that width scales positively with discharge to the 1/2 power, and negatively with a weak power of sediment supply. Negative scaling of …

Margaret White Springs Recharge Study, Buffalo National River, North-Central Arkansas, Usa, Ashlon Elizabeth Leonard

Graduate Theses and Dissertations

Margaret White Springs (MWS) is one of the largest springs in the middle section of the Buffalo National River (BNR) and contributes several tens of cubic feet per second of flow to river discharge on average, yet the source of the water has not been fully studied or documented. The spring is located approximately 4 miles downstream from Robertson Hole, a losing reach of the river. At Robertson Hole the river loses a significant amount of flow to groundwater, which during the dry season (summer) can be as much as 100%. Flow in the main channel is re-established at MWS; …

Estimating Watershed Mercury Contribution To Lake Fort Smith State Park, Arkansas, Usa, William Miles Harmon

Graduate Theses and Dissertations

Mercury contamination associated with human activities poses global human health and environmental risks. A fish-consumption advisory has been in effect at Lake Fort Smith in central west Arkansas for more than a decade due to observed methylmercury concentrations in fish tissue. Lake Fort Smith is an important municipal drinking water supply and recreational resource. Water samples from the majority contributing tributary stream, Frog Bayou creek, were collected periodically, under differing hydrologic conditions in order to quantify the allochthonous mercury load delivered to the lake. Temperature, specific conductance, and turbidity data were collected and used to estimate dissolved organic carbon, methylmercury …

Mapping Lower Austin Chalk Secondary Porosity Using Modern 3-D Seismic And Well Log Methods In Zavala County, Texas, David Kilcoyne

Graduate Theses and Dissertations

Establishing fracture distribution and porosity trends is key to successful well design in a majority of unconventional plays. The Austin Chalk has historically been referred to as an unpredictable producer due to high fracture concentration and lateral variation in stratigraphy, however recent drilling activity targeting the lower Austin Chalk has been very successful. The Upper Cretaceous Austin Chalk (AC) and underlying Eagle Ford (EF) units are considered by many to act as a single hydrocarbon system, with communication between these two units largely through expulsion or dewatering fractures, extensional faults or along the AC/EF unconformity. Total porosity for the Eagle …

Quantifying Carbon Dioxide Fluxes In The Air And Water In Blowing Springs Cave, Arkansas, Holly Young

Graduate Theses and Dissertations

Prior work has shown that the concentration of carbon dioxide (CO2) within cave atmospheres is a function of cave airflow patterns. The dynamics of CO2 within karst systems are of increasing interest as they can control periods of precipitation or dissolution in speleothems and influence potential interpretations of paleoclimate records. Similarly, CO2 is an important driver of speleogenesis, and air-water CO2 dynamics can control patterns of cave passage evolution. Karst also plays an uncertain role in the global carbon cycle and understanding CO2 dynamics within karst systems will aid the development of carbon budgets. Here, a monitoring station was deployed …

The Occurrence Of The Greta Sandstone, Frio Formation (Late Oligocene), Texas Gulf Coastal Plain, Sean C. Kincade

Graduate Theses and Dissertations

The Greta sandstone is an informal lithostratigraphic unit of the upper Frio Formation (Oligocene) that occurs across the Texas Gulf Coastal Plain. The Greta sandstone has been known to geologists since it was first drilled in the 1930’s, yet there has been very little research into this un-depleted and overlooked reservoir. This study provides insights into the lateral distribution and reservoir facies of the Greta sandstone. The unit represents an aggradational to transgressive barrier sandstone package grading up to mud-rich open marine inner shelf deposits. The interval is easily recognizable in well logs based on its strong SP and Gamma-ray …

Comparative Microbial Community Dynamics In A Karst Aquifer System And Proximal Surface Stream In Northwest Arkansas, Josue Rodriguez

Graduate Theses and Dissertations

Northwest Arkansas has well-developed karst systems, with numerous sinking streams and springs. Karst conduits make it easy for contaminants to enter groundwater systems, degrading the water quality and destroying fragile karst ecosystems. With the increase of urbanization, potential threats in the form of fecal contamination may prove to be more of a problem. The purpose of this research is to compare the difference between microbial communities within two different settings, a karst aquifer and a surface stream. The microbial communities within Blowing Spring Cave and Little Sugar Creek were detected and identified in water and sediment samples. Samples were also …

Stratigraphic Evaluation Of The St. Joe-Boone Boundary Interval, Kinderhookian-Osagean Series, Lower Mississippian System, Tri-State Region, Southern Midcontinent, Forrest Dalton Mcfarlin

Graduate Theses and Dissertations

The Lower Mississippian interval comprises a single, third-order, eustatic cycle subdivided lithostratigraphically into the St. Joe Limestone (Hopkins 1893) and overlying Boone Formation (Branner 1891, Simonds 1891) with type areas in northern Arkansas. Coeval, homotaxial limestones occur in adjacent southwestern Missouri and northeastern Oklahoma. Missouri formation names for the St. Joe interval are recognized in Arkansas as members (ascending order): Bachelor, Compton, Northview, Pierson. The Boone interval in Missouri is represented by the (ascending order): Reeds Spring, Elsey, Burlington-Keokuk undifferentiated, but utilization of those names in Arkansas is problematic. in northern Arkansas, the Boone Formation is subdivided into informal lower …

Structural Cross Sections And Subsurface Maps Of The Atoka Formation In The Northern Arkoma Basin, Western And Northwestern Arkansas, David Nance

Graduate Theses and Dissertations

The Arkoma Basin is one of several peripheral foreland basins situated on the front of the Ouachita orogenic fold and thrust belt. The transition from the foredeep to the Ozark Plateaus is a short one in terms of latitude. The Atoka Formation in Arkansas comprises the bulk of the sediments in the Arkoma Basin. Three divisions of the Atoka Formation have been informally assigned as the Upper, Middle, and Lower based on differences in sedimentary response to tectonic processes that occurred during the formation and subsidence of the Arkoma Basin. In the Arkansas portion of the Arkoma Basin, the lower …

Interpretation And Fracture Characterization Of Early-Cretaceous Buda Limestone Formation Using Post-Stack 3d Seismic Data In Zavala County, Texas, Andrey Smirnov

Graduate Theses and Dissertations

The Buda Limestone is a naturally fractured Early Cretaceous carbonate formation in south Texas which unconformably underlies the Eagle Ford Shale. Matrix porosity of the Buda is less than 6%, therefore natural fractures improve the potential for commercial hydrocarbon production from this tight limestone formation. This presents a challenge for producers to identify these zones using well log and post stack 3D seismic data typically available to medium or small exploration companies. This project provides a workflow based on well log analysis tied to seismic acoustic impedance (AI) inversion to locate areas of probable natural fractures. Acoustic impedance inversion was …

Gis Modeling Of The Prominent Geohazards In Arkansas, Kyle Walker Rowden

Graduate Theses and Dissertations

The State of Arkansas is prone to numerous geohazards. This thesis is a twofold study of prominent geohazards in Arkansas: the first fold includes a novel triggerless approach for mass wasting susceptibility modeling applied to the Boston Mountains in NW Arkansas, and the second fold is a GIS-based regression modeling of the extreme weather patterns at the state level. Each study fold is presented in this thesis as a separate chapter embracing a published peer-reviewed paper. In the first paper, I have used the analytical hierarchy process to assign preliminary statistical weights to the most cogent variables influencing mass wasting …

Paleozoic Sandstones In The Tri-State Region, Southern Ozarks: Tectono-Stratigraphic Sequence Development And Compositional Evolution, The Source And Delivery Conundrum, And The Regional Tectonic History, Elvis Chekwube Bello

Graduate Theses and Dissertations

The Paleozoic stratigraphic record of the Ozark Region, southern midcontinent has been divided into at least 33 formations, with the most significant thickness of 9692 feet preserved in northwest Arkansas. The potential thickness would have been much greater, but epeirogenic movements and sea-level rise and fall produced regional surfaces of erosion reducing the record. That interplay between tectonics (epeirogenic movements) and eustatic change (transgressive-regressive cycles) preserved in the Ozark sedimentary history provides the basis for recognition of five distinct, but related, tectonostratigraphic units designated TS 1 through TS 5: Late Precambrian-Middle Cambrian (TS 1), Late Cambrian-Earliest Ordovician (TS 2), Early …

3d Seismic Interpretation Of A Plio-Pleistocene Mass Transport Deposit In The Deepwater Taranaki Basin Of New Zealand, Francisco Jose Rusconi

Graduate Theses and Dissertations

A series of Plio-Pleistocene mass transport deposits (MTD) have been identified in the deepwater Taranaki Basin, in New Zealand, using the Romney 3D seismic survey, which covers an area of approximately 2000 km2. One of these MTDs has been chosen for description and interpretation based on high confidence mapping of its boundary surfaces. The deposit exhibits an array of interesting features similar to those documented by researchers elsewhere plus a unique basal feature unlike those previously observed. The basal shear surface exhibits erosional features such as grooves, “monkey fingers”, and glide tracks. Internally, the MTD is typically characterized by low …

Using Stable Isotope Geochemistry To Determine Changing Paleohydrology And Diagenetic Alteration In The Late Cretaceous Kaiparowits Formation, Ut Usa, Daigo Yamamura

Graduate Theses and Dissertations

The Western Interior Basin of the North America preserves one of the best sedimentary and paleontological records of the Cretaceous in the world. The Upper Cretaceous Kaiparowits Formation is a rapidly deposited fluvial sequence and preserves one of the most complete terrestrial fossil record of the North America. Such a unique deposit provides an opportunity to investigate the interaction between the physical environment and ecology. In an effort to decipher such interaction, stable isotope composition of cements in sedimentary rocks, concretions and vertebrate fossils were analyzed.

Despite the difference in facies and sedimentary architecture, the isotope composition does not change …

Near Surface Geophysics For Lithostratigraphic Interpretation At Pedro, Benton County, Arkansas, Matthew David Ruggeri

Graduate Theses and Dissertations

The roadcut on highway 412 near Pedro, Benton County, Arkansas (MArkUP site L15), has been of geological interest since its excavation in the 1980s. The roadcut is located within the Springfield Plateau and displays formations of Lower Mississippian age. The roadcut contains three mound-like features believed to be olistoliths. This thesis research work adds geophysical evidence to the geological exposure at the site. The purpose of this research is to answer the question of whether near surface seismic methods can be used to extend information at the Pedro outcrop below the ground surface. Specifically, can the top of the Middle …

Lost Names In The Paleozoic Lithostratigraphy Of Arkansas, Noah Morris

Graduate Theses and Dissertations

The geology of Arkansas has been studied for nearly 160 years, and our understanding of it is continually evolving. Part of this ever-changing study is the nomenclature of the stratigraphy. From the early reports to today, several lithostratigraphic names have been proposed and abandoned to improve the accuracy and clarity of the understanding of Arkansas’ geology. Over these 160 years of study, 214 names have been proposed for the Paleozoic beds of Arkansas, with nearly 80 of them currently in use today. These names are a testimony and legacy of the history of Arkansas’ natural resource development and Arkansas’ geologists. …