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Full-Text Articles in Physical Sciences and Mathematics

Towards Sociobiogeochemistry: Critical Perspectives On Anthropogenic Alterations To Soil Nitrogen Chemistry Via U.S. Urban And Suburban Development, Christopher D. Ryan Feb 2024

Towards Sociobiogeochemistry: Critical Perspectives On Anthropogenic Alterations To Soil Nitrogen Chemistry Via U.S. Urban And Suburban Development, Christopher D. Ryan

Dissertations, Theses, and Capstone Projects

The ecological impacts of changes to land use are relevant to concerns about climate change, eutrophication of waterbodies, and reductions in biodiversity. As a foundational component of ecosystem functioning, changes to soil biogeochemistry have significant effects on overall ecosystem health. With cities continuing to grow and develop in extent, the impacts of urbanization and suburbanization on soils are of particular concern. Despite a wide range of natural climatic and geologic conditions, several factors have driven similar patterns of land transformation and management across the United States. In particular, federal initiatives including the Home Owners Loan Corporation, the Federal Housing Administration, …


Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford Oct 2023

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …


Investigating The Role Of Plant Traits And Interactions In Emergent Wetland Nutrient Removal, Andrew Ryan Sample Aug 2023

Investigating The Role Of Plant Traits And Interactions In Emergent Wetland Nutrient Removal, Andrew Ryan Sample

Theses and Dissertations

Increasing wetland restoration in the Lower Mississippi Alluvial Valley has been identified as a method to reduce nutrient loading in the Gulf of Mexico. Wetlands have historically been used to treat water through processes facilitated by wetland plants, and relatively few species and plant traits have been identified as important in carrying out these processes. This study focuses on some of those species and traits and aims to identify species differences and plant traits that may be important for wetland nutrient mitigation. Chapter I provides background information on nutrient pollution, wetland biogeochemical mechanisms for nutrient sequestration, and the focal species …


Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle Aug 2023

Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle

Theses and Dissertations

This study examined the nutrient environment of sediments in the Milwaukee River estuary and the dynamics of those nutrients during simulated disturbance experiments within the context of large-scale dredging remediation. Surface sediments were collected from throughout the Milwaukee estuary (including river, harbor, and nearshore stations) by PONAR, centrifuged to separate porewater (interstitial water) from solid material, and filtered to further isolate and stabilize dissolved material. Porewaters were analyzed for dissolved nutrients including ammoniacal nitrogen (AN), nitrate, nitrite, and soluble reactive phosphorus (SRP). Surface sediment porewaters within the estuary were often highly enriched in AN and SRP, which were often 10-2000x …


Sulfur Cycling Connects Microbiomes And Biogeochemistry In Deep-Sea Hydrothermal Plumes, Zhichao Zhou, Patricia Q. Tran, Alyssa M. Adams, Kristopher Kieft, John A. Breier, Caroline S. Fortunato, Cody S. Sheik, Julie A. Huber, Meng Li, Gregory J. Dick, Karthik Anantharaman Aug 2023

Sulfur Cycling Connects Microbiomes And Biogeochemistry In Deep-Sea Hydrothermal Plumes, Zhichao Zhou, Patricia Q. Tran, Alyssa M. Adams, Kristopher Kieft, John A. Breier, Caroline S. Fortunato, Cody S. Sheik, Julie A. Huber, Meng Li, Gregory J. Dick, Karthik Anantharaman

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

In globally distributed deep-sea hydrothermal vent plumes, microbiomes are shaped by the redox energy landscapes created by reduced hydrothermal vent fluids mixing with oxidized seawater. Plumes can disperse over thousands of kilometers and their characteristics are determined by geochemical sources from vents, e.g., hydrothermal inputs, nutrients, and trace metals. However, the impacts of plume biogeochemistry on the oceans are poorly constrained due to a lack of integrated understanding of microbiomes, population genetics, and geochemistry. Here, we use microbial genomes to understand links between biogeography, evolution, and metabolic connectivity, and elucidate their impacts on biogeochemical cycling in the deep sea. Using …


Getting The Dirt On Phosphorus Pollution In Mountain Lakes: Are Rising Soil Temperatures Contributing To Eutrophication In Mountain Watersheds?, Gordon O. Gianniny May 2023

Getting The Dirt On Phosphorus Pollution In Mountain Lakes: Are Rising Soil Temperatures Contributing To Eutrophication In Mountain Watersheds?, Gordon O. Gianniny

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Mountain watersheds provide a critical supply of clean water to millions of people around the world. In recent years, evidence of a concerning trend has emerged in these watersheds: rising phosphorus (P) concentrations. P often acts as the limiting nutrient in mountain lake ecosystems, so increasing P availability in mountain lakes and streams has the potential to drastically increase algal growth in these systems. In extreme cases, increasing mountain lake P concentrations may even cause harmful algal blooms that degrade downstream water quality. While the implications of rising P concentrations in mountain lakes are serious, the cause driving this widespread …


Carbonate Chemistry And Carbon Sequestation Driven By Inorganic Carbon Outwelling From Mangroves And Saltmarshes, Gloria M. S. Reithmaier, Alex Cabral, Anirban Akhand, Matthew J. Bogard, Alberto V. Borges, Steven Bouillon, David J. Burdige, Mitchell Call, Nengwang Chen, Xiaogang Chen, Luiz C. Cotovicz Jr., Meagan J. Eagle, Erik Kristensen, Kevin D. Kroeger, Zeyang Lu, Damien T. Maher, J. Lucas Pérez-Lloréns, Raghab Ray, Pierre Taillardat, Joseph J. Tamborski, Rob C. Upstill-Goddard, Faming Wang, Zhaohui Aleck Wang, Kai Xiao, Yvonne Y.Y. Yau, Isaac R. Santos Jan 2023

Carbonate Chemistry And Carbon Sequestation Driven By Inorganic Carbon Outwelling From Mangroves And Saltmarshes, Gloria M. S. Reithmaier, Alex Cabral, Anirban Akhand, Matthew J. Bogard, Alberto V. Borges, Steven Bouillon, David J. Burdige, Mitchell Call, Nengwang Chen, Xiaogang Chen, Luiz C. Cotovicz Jr., Meagan J. Eagle, Erik Kristensen, Kevin D. Kroeger, Zeyang Lu, Damien T. Maher, J. Lucas Pérez-Lloréns, Raghab Ray, Pierre Taillardat, Joseph J. Tamborski, Rob C. Upstill-Goddard, Faming Wang, Zhaohui Aleck Wang, Kai Xiao, Yvonne Y.Y. Yau, Isaac R. Santos

OES Faculty Publications

Mangroves and saltmarshes are biogeochemical hotspots storing carbon in sediments and in the ocean following lateral carbon export (outwelling). Coastal seawater pH is modified by both uptake of anthropogenic carbon dioxide and natural biogeochemical processes, e.g., wetland inputs. Here, we investigate how mangroves and saltmarshes influence coastal carbonate chemistry and quantify the contribution of alkalinity and dissolved inorganic carbon (DIC) outwelling to blue carbon budgets. Observations from 45 mangroves and 16 saltmarshes worldwide revealed that >70% of intertidal wetlands export more DIC than alkalinity, potentially decreasing the pH of coastal waters. Porewater-derived DIC outwelling (81 ± 47 mmol m−2 …


Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson Jan 2023

Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson

Theses and Dissertations (Comprehensive)

The subarctic shield near Yellowknife, Northwest Territories (NWT), is populated with thousands of small lakes (<1.5 km2) and several large lakes. Historic mining activities in the region have left a legacy of environmental impacts and widespread arsenic (As) contamination in both aquatic and terrestrial environments. In particular, several small subarctic lakes near Yellowknife have been previously documented to be contaminated with high levels of As. Subarctic lakes are characterized by seasonal ice-cover that can persist for more than half of the year, yet little is known about the under-ice spatial and seasonal dynamics of As cycling. The objective of …


Assessing Recovery And Reuse Of Nutrients Using Grid-Based Spatial Modeling: A Case Study Of Sri Lanka, Maya Fein-Cole Jan 2022

Assessing Recovery And Reuse Of Nutrients Using Grid-Based Spatial Modeling: A Case Study Of Sri Lanka, Maya Fein-Cole

Graduate College Dissertations and Theses

Identifying and implementing strategies for recovering resources from waste streams for reuse helps to minimize natural resource extraction and reduces waste generation. Spatial modeling can guide resource cycling by optimizing co-location of recovery and reuse. These models can help assess feasibility and effectiveness (e.g., meeting crop nutrient needs) of circular economy practices at a landscape scale. Though many useful models exist, there is a need for an adaptable grid-based tool to address reuse on a per area basis (e.g., kg nitrogen per hectare of cropland). A model like this could be applied to any landscape and would utilize input data …


Frayed Connections: How Long-Term Nitrogen Additions Disrupt Plant-Soil Interactions And The Carbon Cycle Of A Temperate Forest, Brooke A. Eastman Jan 2022

Frayed Connections: How Long-Term Nitrogen Additions Disrupt Plant-Soil Interactions And The Carbon Cycle Of A Temperate Forest, Brooke A. Eastman

Graduate Theses, Dissertations, and Problem Reports

Forests are expected to mitigate some of the negative effects of climate change by sequestering anthropogenic carbon (C) from the atmosphere, but the degree to which they drawn down C will depend on the availability of key nutrients, such as nitrogen (N). There is a fair amount of uncertainty in the future of the forest C sink, mostly owing to the fate of soil organic matter (SOM) and soil heterotrophic respiration to future conditions. In N limited systems, plants allocate a significant amount of their photosynthate belowground for the acquisition of nutrients, but under conditions of chronic N deposition, plants …


The Photochemical Evolution Of Dissolved Black Carbon In Snow: A Case Study From The North Cascades, Molly Peek Jan 2022

The Photochemical Evolution Of Dissolved Black Carbon In Snow: A Case Study From The North Cascades, Molly Peek

WWU Graduate School Collection

Black carbon (BC) is partially combusted organic material from natural and anthropogenic sources, and is a highly effective driver of melt in the cryosphere. BC has been found in both populated and remote areas around the globe. This study follows the evolution of UV-exposed dissolved BC (DBC) in the cryosphere using the Benzenepolycarboxylic Acid (BPCA) markers B4CA, B5CA, and B6CA. Samples were collected from Mount Baker, Washington, and from both an in situ field study and a controlled photodegradation study, both using natural and anthropogenic BC standards. Both natural and experimental samples had a dominance of B5CA relative to other …


Transport And Fate Of Phosphorus In The Nearshore Zone Of Lake Michigan, Nathan Van Ee Dec 2021

Transport And Fate Of Phosphorus In The Nearshore Zone Of Lake Michigan, Nathan Van Ee

Theses and Dissertations

Bioavailable phosphorus loads exported to Lake Michigan from the Milwaukee and Sheboygan River Watersheds appear to have increased in the last 40 years despite meeting total phosphorus (TP) loading goals set by the Great Lakes Water Quality Agreement (GLWQA).Overall, bioavailability of P delivered from the Milwaukee and Sheboygan Rivers was highest during the warmer months, which coincides with the nearshore nuisance algae growth season. However, first order loss rates of SRP calculated during baseflow recession were also greatest during the summer, suggesting that increased river residence time during the summer could reduce export of bioavailable P. Observations of phosphorus partitioning …


Quantifying How Coastal Flooding And Stormwater Runoff Drive Spatiotemporal Variability In Carbon And Nutrient Processing In Urban Aquatic Ecosystems, Matthew A. Smith Oct 2021

Quantifying How Coastal Flooding And Stormwater Runoff Drive Spatiotemporal Variability In Carbon And Nutrient Processing In Urban Aquatic Ecosystems, Matthew A. Smith

FIU Electronic Theses and Dissertations

Coastal river networks alter the transport and transformation of dissolved organic carbon (DOC) and dissolved organic matter (DOM), which can vary in concentration and composition across spatiotemporal scales. Given climate-induced shifts in rainfall and tidal variation in low-lying coastal regions, there is an increasing need to quantify effects of flooding on biogeochemical cycling. Specifically, urban flooding is becoming increasingly common due to biophysical alterations to hydrology from urbanization and climate change. Urban ecosystems have been characterized as having a distinct biogeochemistry compared to other systems, largely due to increased frequency and magnitude of riverine and coastal flooding. Consequently, the role …


Hydrologic Controls On Phosphorus Speciation And Mobilization In A Subalpine Watershed (East River, Colorado), Lucia Isobel Arthen-Long Oct 2021

Hydrologic Controls On Phosphorus Speciation And Mobilization In A Subalpine Watershed (East River, Colorado), Lucia Isobel Arthen-Long

Masters Theses

The cycling of phosphorus (P) through floodplain environments is critical to ecosystem productivity and has significant implications on both water quality and soil fertility. P export from soils in response to saturation has been well documented, but the relative vulnerability of specific P pools to mobilization remains poorly constrained, as do the mechanisms mediating its release. The prediction of P availability in and export from mountainous floodplain soils is of great importance as global climate change is projected to significantly alter precipitation regimes in alpine systems. This study combined a thorough characterization of P distribution across a hillslope to floodplain …


Net Geochemical Release Of Base Cations From 25 Forested Watersheds In The Catskill Region Of New York, Sara C. Nieman, Chris E. Johnson Jul 2021

Net Geochemical Release Of Base Cations From 25 Forested Watersheds In The Catskill Region Of New York, Sara C. Nieman, Chris E. Johnson

Civil and Environmental Engineering

Chemical weathering of minerals is the principal mechanism by which base cations (Ca2+, Mg2+, K+, and Na+) are released and acidity is neutralized in soils, bedrock and drainage waters. Quantifying the release of base cations from watershed soils is therefore crucial for the calculation of “critical loads” of atmospheric acidity to forest ecosystems. We used a mass-balance approach to estimate the rate of release of base cations in 25 headwater catchments in the Catskill region of New York, an area historically subject to high inputs of acid deposition. In 2010-2013, total net …


In-Depth Analysis Of N2o Fluxes In Tropical Forest Soils Of The Congo Basin Combining Isotope And Functional Gene Analysis, Nora Gallarotti, Matti Barthel, Elizabeth Verhoeven, Engil Isadora Pujol Pereira, Marijn Bauters, Simon Baumgartner, Travis W. Drake, Pascal Boeckx, Joachim Mohn, Manon Longepierre May 2021

In-Depth Analysis Of N2o Fluxes In Tropical Forest Soils Of The Congo Basin Combining Isotope And Functional Gene Analysis, Nora Gallarotti, Matti Barthel, Elizabeth Verhoeven, Engil Isadora Pujol Pereira, Marijn Bauters, Simon Baumgartner, Travis W. Drake, Pascal Boeckx, Joachim Mohn, Manon Longepierre

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Primary tropical forests generally exhibit large gaseous nitrogen (N) losses, occurring as nitric oxide (NO), nitrous oxide (N2O) or elemental nitrogen (N2). The release of N2O is of particular concern due to its high global warming potential and destruction of stratospheric ozone. Tropical forest soils are predicted to be among the largest natural sources of N2O; however, despite being the world’s second-largest rainforest, measurements of gaseous N-losses from forest soils of the Congo Basin are scarce. In addition, long-term studies investigating N2O fluxes from different forest ecosystem types (lowland and montane forests) are scarce. In this study we show that …


How A Simple Question About Freshwater Inflow To Estuaries Shaped A Career, Paul A. Montagna Jan 2021

How A Simple Question About Freshwater Inflow To Estuaries Shaped A Career, Paul A. Montagna

Gulf and Caribbean Research

Chance and good luck led to a career studying how freshwater inflow drives estuary processes. In 1986, someone asked me: How much fresh water has to flow to a bay for it to be healthy? The question shaped my career. There is probably no better place on Earth to compare effects caused by inflow differences than the Texas coast, because the major estuarine systems lie in a climatic gradient where runoff decreases 56—fold from the Louisiana border in the northeast to the Mexico border in the southwest. This estuary—comparison experiment was used to study inflow effects. The science evolved from …


Sediment Nutrient Dynamics In Fondriest Agricultural Settling Pond, Marie Grace Bezold Jan 2021

Sediment Nutrient Dynamics In Fondriest Agricultural Settling Pond, Marie Grace Bezold

Browse all Theses and Dissertations

Excess loading of nitrogen (N) and phosphorus (P) is a serious global problem and has numerous negative impacts on water quality of aquatic ecosystems including eutrophication, harmful algal blooms, and hypoxia. Anthropogenic activities (such as the Haber-Bosch process, burning of fossil fuels, sewage treatment, and manure reuse) have led to excess N loading to aquatic systems. Sediment N dynamics were examined from Oct 2019 – Oct 2020 in an agricultural settling pond connected to a constructed wetland adjacent to an agricultural field. Intact sediment cores were amended with 15N for continuous-flow incubations to measure denitrification and N fixation rates, as …


The Quantitative Assessment Of Pond Scum: An Examination Of The Biogeochemistry Of Phosphorus Cycling In The Belgrade Lakes, Abbey M. Sykes Jan 2021

The Quantitative Assessment Of Pond Scum: An Examination Of The Biogeochemistry Of Phosphorus Cycling In The Belgrade Lakes, Abbey M. Sykes

Honors Theses

The internal recycling phosphorus in freshwater lake bottom sediments represents a significant source of hypolimnetic phosphorus (P) release for many of Maine’s lakes. In summer months, Maine lakes often thermally stratify and the lake hypolimnion develops anoxia, leading to a reduction in redox potential at the sediment-water interface. These reducing conditions facilitate the reductive dissolution of ferric iron, and, since phosphorus is often present in freshwater lake sediments as solid FeOOH-PO4 complexes, results in release of soluble phosphorus into the water column. Our current study presents field and laboratory data from sediment fractionation extractions designed to quantify concentrations of …


Diversity And Function Of Algal Biofilms In The Laurentian Great Lakes, Leon R. Katona Jan 2021

Diversity And Function Of Algal Biofilms In The Laurentian Great Lakes, Leon R. Katona

Browse all Theses and Dissertations

Attached algae are ubiquitous components of lake benthic habitats wherever sufficient light reaches submerged surfaces. Attached algae interact with heterotrophic bacteria and fungi to form complex biofilms (“periphyton”) that provide a nutritious food source for consumers and influence biogeochemical cycling by regulating redox potential at the sediment-water interface. Despite their ecological importance, there are limited data on the role of periphyton in the Laurentian Great Lakes. I quantified wave exposure and light availability in rocky nearshore habitats in Lake Erie and Lake Huron. Periphyton biomass and productivity in nearshore Lake Erie was very high while algal biomass and productivity in …


Internal Loading Of Nitrogen (N) And Phosphorus (P), Reduced N Forms, And Periodic Mixing Support Cyanobacterial Harmful Algal Blooms (Habs) In Shallow, Eutrophic Honeoye Lake (New York, Usa), Justin Adam Myers Jan 2021

Internal Loading Of Nitrogen (N) And Phosphorus (P), Reduced N Forms, And Periodic Mixing Support Cyanobacterial Harmful Algal Blooms (Habs) In Shallow, Eutrophic Honeoye Lake (New York, Usa), Justin Adam Myers

Browse all Theses and Dissertations

Cyanobacteria are important primary producers, but large cyanobacterial harmful algal blooms (HABs) have many negative ecological and health impacts and are becoming increasingly common. Honeoye Lake (New York, USA) is a shallow, eutrophic lake characterized by increasingly frequent HABs. Nitrogen (N) and phosphorus (P) loads often drive HABs in lakes, and sediment processes can contribute to N removal (e.g., denitrification) or loading (e.g., N fixation, remineralization). Sediment cores and lake water were collected during May–October (2016–2018) at two sites and incubated with no amendments (controls) or 15N stable isotopes to measure sediment nutrient fluxes and N cycling dynamics in Honeoye …


The Simulated Biological Response To Southern Ocean Eddies Via Biological Rate Modification And Physical Transport, Tyler Rohr, Cheryl S. Harrison, Matthew C. Long, Peter Gaube, Scott C. Doney Apr 2020

The Simulated Biological Response To Southern Ocean Eddies Via Biological Rate Modification And Physical Transport, Tyler Rohr, Cheryl S. Harrison, Matthew C. Long, Peter Gaube, Scott C. Doney

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

We examine the structure and drivers of anomalous phytoplankton biomass in Southern Ocean eddies tracked in a global, multiyear, eddy-resolving, 3-D ocean simulation of the Community Earth System Model.We examine how simulated anticyclones and cyclones differentially modify phytoplankton biomass concentrations, growth rates, and physical transport. On average, cyclones induce negative division rate anomalies that drive negative net population growth rate anomalies, reduce dilution across shallower mixed layers, and advect biomass anomalously downward via eddy-induced Ekman pumping. The opposite is true in anticyclones. Lateral transport is dominated by eddy stirring rather than eddy trapping. The net effect on anomalous biomass can …


Eddy-Modified Iron, Light, And Phytoplankton Cell Division Rates In The Simulated Southern Ocean, Tyler Rohr, Cheryl S. Harrison, Matthew C. Long, Peter Gaube, Scott C. Doney Apr 2020

Eddy-Modified Iron, Light, And Phytoplankton Cell Division Rates In The Simulated Southern Ocean, Tyler Rohr, Cheryl S. Harrison, Matthew C. Long, Peter Gaube, Scott C. Doney

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

We examine the effects of Southern Ocean eddies on phytoplankton cell division rates in a global, multiyear, eddy‐resolving, 3‐D ocean simulation of the Community Earth System Model. We first identify and track eddies in the simulation and validate their distribution and demographics against observed eddy trajectory characteristics. Next, we examine how simulated cyclones and anticyclones differentially modify iron, light, and ultimately population‐specific cell division rates. We use an eddy‐centric, depth‐averaged framework to explicitly examine the dynamics of the phytoplankton population across the entire water column within an eddy. We find that population‐averaged iron availability is elevated in anticyclones throughout the …


Microbial Responses To Unconventional Oil And Gas Development May Alter Ecosystem Function In Headwater Streams, Rachel Michaels Jan 2020

Microbial Responses To Unconventional Oil And Gas Development May Alter Ecosystem Function In Headwater Streams, Rachel Michaels

Graduate Theses, Dissertations, and Problem Reports

The demand for natural gas, and the need for efficient extraction, has led to the development of unconventional oil and natural gas (UOG) techniques. Due to the novelty of UOG, the potential impacts to freshwater ecosystems are not fully understood. We used a dual pronged approach to study the effects of UOG development on microbial biodiversity and function via a laboratory microcosm experiment and a survey study of streams with and without UOG development within their watersheds. The laboratory microcosm study simulated stream contamination with produced water, a byproduct of UOG operation, using sediment collected from one high water-quality stream …


Regional Drivers Of Organic Carbon Age In Lotic Systems Of The Conterminous United States, Kaycee Faunce Jan 2020

Regional Drivers Of Organic Carbon Age In Lotic Systems Of The Conterminous United States, Kaycee Faunce

Theses and Dissertations

Rivers play a critical role in global carbon (C) budgets despite their comparatively small surface area. A significant portion of the terrestrial C that they receive is transformed, re-mineralized, or stored during transit to the ocean. Radiocarbon (∆14C) data show that a fraction of riverine organic C (OC) has been pre-aged in the terrestrial environment. Lateral export of carbon from these aged pools may contribute to atmospheric carbon dioxide emissions through microbial and photochemical oxidation. However, little is known about the regional climatic, anthropogenic, and landscape factors that promote the mobilization of aged OC to rivers. This study …


Enabling High Quality Oxygen Measurements During Robotic Based Studies Of Ocean Ecological And Biogeochemical Processes, Brianna A. Alanis Dec 2019

Enabling High Quality Oxygen Measurements During Robotic Based Studies Of Ocean Ecological And Biogeochemical Processes, Brianna A. Alanis

Theses and Dissertations

Dissolved oxygen is an essential parameter necessary for understanding marine ecological and biogeochemical processes. New robotic vehicles and autonomous platforms are being applied to an even wider range of ecological and biogeochemical studies. Thus, arises the opportunity for matching the best possible oxygen sensing techniques and methods to these new platforms. In so doing, we can enable both more targeted and higher resolution oxygen measurements than previously possible and potentially use oxygen measurements for a wider range of applications, including in situ incubation experiments and primary productivity measurements. This thesis tested three different oxygen sensors in a trade study for …


Increasing Impacts Of Extreme Droughts On Vegetation Productivity Under Climate Change, Chonggang Xu, Nate G. Mcdowell, Rosie A. Fisher, Liang Wei, Sanna Sevanto, Bradley O. Christoffersen, Engsheng Weng, Richard S. Middleton Nov 2019

Increasing Impacts Of Extreme Droughts On Vegetation Productivity Under Climate Change, Chonggang Xu, Nate G. Mcdowell, Rosie A. Fisher, Liang Wei, Sanna Sevanto, Bradley O. Christoffersen, Engsheng Weng, Richard S. Middleton

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Terrestrial gross primary production (GPP) is the basis of vegetation growth and food production globally1 and plays a critical role in regulating atmospheric CO2 through its impact on ecosystem carbon balance. Even though higher CO2 concentrations in future decades can increase GPP2, low soil water availability, heat stress and disturbances associated with droughts could reduce the benefits of such CO2 fertilization. Here we analysed outputs of 13 Earth system models to show an increasingly stronger impact on GPP by extreme droughts than by mild and moderate droughts over the twenty-first century. Due to a dramatic increase in …


Decadal Changes Of Soil Physiochemical Properties In A Freshwater Wetland After Hydrologic Reconnection, Alina Spera Jun 2019

Decadal Changes Of Soil Physiochemical Properties In A Freshwater Wetland After Hydrologic Reconnection, Alina Spera

LSU Master's Theses

Sediment, nutrient deprivation and salt water intrusion, among other factors, are driving widespread organic soil collapse and marsh loss in the Mississippi River Delta. Freshwater diversions were designed to reintroduce Mississippi River water and dissolved nutrients into the adjacent basins to manage salinity and slow land loss by maintaining marsh vegetation and nutrient cycling functions. These diversions are controversial by a few, suggesting that nutrient enrichment without a sediment subsidy can lead to further wetland loss in the receiving basins. In this study, a soil characterization is presented for the receiving marsh of the Davis Pond diversion in 2007, just …


Dissolved Inorganic Nitrogen Dynamics In Swash Zone Sands Of Long Bay, Sc, Alexis F. Echols Apr 2019

Dissolved Inorganic Nitrogen Dynamics In Swash Zone Sands Of Long Bay, Sc, Alexis F. Echols

Honors Theses

A key component affecting the biogeochemistry of the sedimentary environment is pore water between grains of sediments. Sedimentary microorganisms are constantly modifying chemical compounds as part of their life functions which are then exchanged between the sediment column and the overlying water column. Dissolved inorganic nitrogen, a major element for life, takes on several forms including nitrate, nitrite, and ammonium which vary in concentration throughout the sediment and with respect to each other. The relative concentrations of these nitrogen species have been previously briefly explored in sandy columns, where redox gradients that control their relative concentrations can be fairly deep …


The Soda Lakes Of Nhecolândia: A Conservation Opportunity For The Pantanal Wetlands, Renato L. Guerreiro, Ivan Bergier, Michael M. Mcglue, Lucas V. Warren, Urbano Gomes Pinto De Abreu, Jônatas Abrahão, Mario L. Assine Jan 2019

The Soda Lakes Of Nhecolândia: A Conservation Opportunity For The Pantanal Wetlands, Renato L. Guerreiro, Ivan Bergier, Michael M. Mcglue, Lucas V. Warren, Urbano Gomes Pinto De Abreu, Jônatas Abrahão, Mario L. Assine

Earth and Environmental Sciences Faculty Publications

The Pantanal is the most conserved biome in Brazil and among the last wild refuges in South America, but intensification of agriculture and other land use changes present challenges for protecting this exceptionally biodiverse wetland ecosystem. Recent studies have shed new light on the origins and biogeochemistry of a suite of >600 small saline-alkaline lakes in Nhecolândia, a floodplain setting located south of the Taquari River in south-central Pantanal. These soda lakes form a unique aquatic environment in Pantanal and nascent research on their geomicrobiology suggests that their biota may be analogous to early life, and extreme life in Earth's …