Physical Sciences and Mathematics Commons^™

Essays On Environmental Policy And Technological Change, Sahar Milani

Theses and Dissertations

This dissertation is comprised of three empirical essays on technological change. The first chapter examines how industrial R&D intensities respond to environmental regulations when considering specific industry characteristics such as pollution intensity and immobility. Specifically, I study the impact of environmental regulations on R&D intensities in 21 manufacturing industries in 28 OECD countries from 2000-2007. I consider pollution intensity and the relative ease of relocation (immobility) as industry characteristics that determine the optimal industry response to increased environmental policy stringency. I find that more pollution intensive industries innovate less as regulatory environments become more restrictive relative to less pollution intensive …

Relationships, Knowledge, And Resilience: A Comparative Study Of Stakeholder Participation In Great Lakes Areas Of Concern, Kathleen Colin Williams

Theses and Dissertations

This dissertation investigates the current practices of environmental governance in the Great Lakes region, where at one time the rivers that fed the Great Lakes were choked with debris and on fire. The Great Lakes Water Quality Agreement of 1978 and the 1987 updates inspired collective action to remediate and restore the rivers and nearshore zones of the lakes through the implementation of an ecosystem approach, which included a public participation dimension. While funding and momentum has fluctuated, the constructs – Areas of Concern (AOC), Remedial Action Plans (RAP), and Public Advisory Councils (PAC) persist. In 2010, the Great Lakes …

Modeling Lake Michigan Nearshore Carbon And Phosphorus Dynamics, Joseph Henry Fillingham

Theses and Dissertations

Dreissenid mussels, in particular quagga mussels (Dreissena rostiformis bugensis), are transforming the Lake Michigan ecosystem by clearing the water column, recycling phosphorus and modifying benthic habitat. These impacts are thought to have caused observed declines in the spring phytoplankton bloom in Lake Michigan, as well as changes to food web structure and declines in the abundance of critical invertebrate and fish species. In the nearshore zone, the resurgence of benthic Cladophora algae to nuisance levels not observed since phosphorus loading abatement policies instituted in the 1970s has also been attributed to water column clearing and phosphorus recycling by mussels. Using …

Sustainable Decolorization Of Reactive And Acid Dye Wastewater Using Photo-Fenton Oxidation Both With And Without Biodegradation: Laboratory And Field Studies, Marissa R. Jablonski

Theses and Dissertations

Photo-Fenton oxidation is an advanced oxidation process (AOP) used to degrade low-concentration textile dye wastewater using expensive chemicals. The technique has shown promise in laboratory-scale projects, but has not been scaled up sustainably to function for industry. Aerobic biodegradation is a common biological treatment method used in large-scale textile industrial applications that generates large amounts of hazardous biological waste. This waste is often left open to the elements and subsequently leaches into natural waterways or onto land. This is the first study of its kind to combine the two to treat cottage-scale industry-grade textile wastewater with a dye concentration of …

A New Correlation For Predicting Aeration Efficiency For Air Diffused Systems, Hasan Baker Mohammad Al Ba'ba'a

Theses and Dissertations

Aeration efficiency is defined as the ratio of the oxygen transfer to the power consumed. It provides the best evaluation of the effectiveness of any aeration system. Most recent studies in oxygenation process focused on investigating the vital parameters affecting the oxygenation process without paying attention to the power consumption. The goal of this study is to establish an empirical correlation that describes aeration efficiency behavior with different orifice diameters.

This work has two main parts: studying bubble hydrodynamics and aeration efficiency investigation. The first goal of examining bubble hydrodynamics was to calculate some necessary parameters that have a known …

Evaluation And Forecast Of Energy Consumption In Different Sectors Of The United States Using Artificial Neural Networks, Arash Kialashaki

Theses and Dissertations

The United States is a country which consumes a vast amount of energy. In order to keep the development of the United States sustainable (diverse and productive over the time) energy planning should be carried out comprehensively and precisely. This dissertation presents a specific mathematical modeling approach towards energy demand modeling of the United States and forecast future energy demand. To generate more detailed and accurate results, this dissertation investigates the energy demand of each sector separately using the analysis of trend for unique set of independent parameters which affect the energy demand in that sector.

In solving a forecast …

Molecular Dynamics (Md) Study On The Electrochemical Properties Of Electrolytes In Lithium-Ion Battery (Lib) Applications, Negin Salami

Theses and Dissertations

While the high energy density and the power along with longer cycle life and less requirements of maintenance distinguish the rechargeable lithium-ion batteries (LIBs) from other energy storage devices, development of an electrolyte of LIBs with optimized properties still constitutes a challenge towards next-generation LIB systems with robust electrochemical performance. The electrolytes serve as the medium to provide ionic conduction path between the electrodes as their basic function. Conductivity of the solutions are mainly affected by their transport properties and the electrolyte electrode/separator interfacial phenomena. Although many contributions on thermodynamic properties of the electrolytes consist of alkyl carbonates mixed with …

Urban River Restoration And Environmental Justice: Addressing Flood Risk Along Milwaukee's Kinnickinnic River, Nicholas Joel Schuelke

Theses and Dissertations

Flood risk has only recently received attention in environmental justice research. Few `flood justice' studies in the US have focused on urban inland flooding or flood control efforts. I develop a conceptual framework of a paradigm shift from a technocratic, utilitarian approach to river engineering to that of bioengineering and public participation. Qualitative analysis of a combination of archival, interview, and observational data is conducted using the Kinnickinnic River in Milwaukee as a case study. I demonstrate that the channelization of the river in the early 1960s was largely the result of political pressures following significant flood events, rather than …

A Decision Support System To Analyze, Predict, And Evaluate Solar Energy System Performance: Pvsysco (Photovoltaic System Comparison), Lisa Bosman

Theses and Dissertations

In 2010, the U.S. Department of Energy announced the SunShot Initiative, which aims to reduce the total installation cost of solar technologies by 75% between 2010 and 2020. This implies that solar energy is a top priority in the U.S. and many other countries. The purpose of this dissertation research is focused on creating a model to better understand the performance and reliability of photovoltaic (PV) energy systems over time. The model will be used to analyze, predict, and evaluate the performance of PV systems, taking into consideration technological and geographical location attributes. The overall research goal is to build …

Evaluation Of Alternative Culling Strategies For Maintenance Of Genetic Variaton In Bison (Bison Bison), Rachael Marie Toldness

Theses and Dissertations

Bison (Bison bison) once numbered in the millions and roamed across much of the lower 48 states. By the late 1800s, overhunting had reduced the population to around 1,000 individuals. Strong efforts to establish managed herds have resulted in a steady bison population increase. Currently, six herds are maintained by the U.S. Fish and Wildlife Service (FWS) at National Wildlife Refuges (NWRs) and are intensively managed through annual culling to keep herd size at targeted levels. Although various criteria have historically been used to select individuals for culling, the FWS currently employs an allele frequency based strategy that we have …

The Occurrence, Fate, Environmental Impact, And Management Implications Of Pharmaceutical And Personal Care Products In Wastewater And The Environment, Benjamin Donald Blair

Theses and Dissertations

Pharmaceuticals and personal care products (PPCPs) are a critical part of modern life. However, there is growing evidence that the levels of PPCPs detected in wastewater effluent and in the environment have the potential to cause damage to aquatic organisms. These pollutants enter the aquatic environment primarily through human use, disposal in the drain or toilet, land application of biosolids, and veterinary sources. Numerous questions remain regarding the occurrence, fate, and impacts of PPCPs in wastewater, along with limited feasible management recommendations that would adequately mitigate the risk from these pollutants. This dissertation will present three advances in the field …

Impacts Of Spatial, Environmental, And Compositional Differences On Community-Level Flowering Phenology, Isaac William Park

Theses and Dissertations

This dissertation investigates three important topics related to flowering phenology throughout the United States. First, this work evaluates the utility of herbarium records for estimating historical variation in community-level flowering phenology, and evaluate the relationship of such estimates to satellite-derived greenup timing at regional scales. This dissertation then reconstructs historical variations in flowering phenology throughout the spring, summer, and autumn across South Carolina for the years 1951 through 2009. These estimates will then be compared to seasonal temperature variations throughout this period. Finally, this dissertation develops novel herbarium-based methods to separate intraspecific phenological variations over space from changes in flowering …

Three Essays On The Role Of It In Environmental Sustainability: Motivating Individuals To Use Green It, Enhancing Their User Experience, And Promoting Electricity Conservation, Abdullah Al Bizri

Theses and Dissertations

This dissertation focuses on the role of IT in environmental sustainability and electricity conservation through three research essays. The first essay makes a case for behavior research, with the focus on individuals' use of Green IT. Moreover, environmental studies lack a coherent theory that could identify the motivators of Green-IT beliefs. We develop the hedonic motivation theory, which synthesizes theoretical and philosophical thoughts on hedonism with concepts from environmental research. Using this theory, we develop a conceptual model that identifies the motivators of context-specific beliefs, attitudes, and uses of Green IT. We theorize that there are significant generational differences in …

A Mathematical Model Of Moisture Movement And Bacterial Growth In Two-Dimensional Porous Medium, Rachel Elizabeth Tewinkel

Theses and Dissertations

Bacterial growth in sand is of concern in regard to the health of beaches. A mathematical model is presented that represents the movement of moisture and the growth of bacteria through a beach. Simulations were run by numerically solving Richards Equation using a Finite Volume Method in order to track moisture movement. A model of moisture-dependent bacterial growth was then implemented. These simulations show that elevated bacteria counts following rain events do not necessarily result from bacteria in the body of water, but can also be sourced from the sand. Additionally, four different moisture-dependent bacterial growth models are compared to …

Tap Versus Bottle: A Mixed Methods Analysis Of Public Water Supply And The Bottled Water Industry In The United States, Catherine Simons

Theses and Dissertations

Discrepancies exist between the regulation of public tap water by the EPA and bottled water by the FDA. The Safe Drinking Water Act mandates the EPA to set national contaminant standards for drinking water as well as regulations to ensure source water protection, treatment, monitoring, compliance, enforcement, waste water, and public access to water quality information. Bottled water is subject to a differing mandate. As a food product regulated by the FDA, bottled water is required to comply with FDA food regulations as well as specific bottled water regulation regarding standards of identity, quality and cGMP. As a result of …

Wind Turbine Controls For Farm And Offshore Operation, Zhongzhou Yang

Theses and Dissertations

Development of advanced control techniques is a critical measure for reducing the cost of energy for wind power generation, in terms of both enhancing energy capture and reducing fatigue load. There are two remarkable trends for wind energy. First, more and more large wind farms are developed in order to reduce the unit-power cost in installation, operation, maintenance and transmission. Second, offshore wind energy has received significant attention when the scarcity of land resource has appeared to be a major bottleneck for next level of wind penetration, especially for Europe and Asia. This dissertation study investigates on several wind turbine …

Transcending Microbial Source Tracking Techniques Across Geographic Borders: An Examination Of Human And Animal Microbiomes And The Integration Of Molecular Approaches In Pathogen Surveillance In Brazil And The United States, Amber Mae Koskey

Theses and Dissertations

Waterborne illnesses, attributed to the ingestion or contact with contaminated water, present a significant global health concern. Surface water sources can be impacted by wide array of pollution inputs, but fecal pollution generates the most significant and acute threat to human health. Therefore, the detection of fecal bacteria in surface water sources remains an important public health objective. Current surface water monitoring employs the use of fecal indicator bacteria (FIB) including E. coli and enterococci as proxies for pathogenic organisms carried in fecal pollution. These traditional indicators, detected by culture-based microbiological methods, do not discriminate fecal sources from another. New …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …

Phylogeographic Inference Of Insular Mule Deer (Odocoileus Hemionus) Divergence In North America's Desert Southwest, Ona Alminas

Theses and Dissertations

Though mule deer (Odocoileus hemionus) persist in robust populations throughout most of their North American distribution, nearly 60% of their historic range in México has declined due to habitat loss and unregulated hunting. Two of the six subspecies inhabiting México's deserts and Baja California peninsula are of conservation concern, occurring on land bridge islands in the Pacific Ocean (O. h. cerrosensis on Cedros Island: threatened) and in the Sea of Cortés (O. h. sheldoni on Tiburón Island: endangered). Focusing on the desert southwest (n=449 deer), we obtained 1,611 bp of mtDNA sequence (control region: 583 bp; cytochrome b gene: 1,028 …

Landscape Ecological Analysis Of Patterns Influencing Bat Activity In Southeast Glacial Plains Of Wisconsin, Angela Leckie Jackson

Theses and Dissertations

Nearly half of the world's bat species are threatened by anthropogenic land use. To contribute to the conservation of these cryptic mammals, it is imperative to understand bat habitat selection in human-dominated landscapes. Bat activity was calculated using active acoustic surveys conducted June and July for three years along river and lake transects in an agricultural matrix. Using multiple logistic regression and ANOVA regression tree analyses, I examined the relationship between bat activity of four species and habitat structure at multiple scales.

Aquatic features were determined to be the greatest predictor of bat activity with rivers supporting greater amount of …

Hydrogen Generation From Magnesium Hydride By Using Organic Acid, Yen-Hsi Ho

Theses and Dissertations

In this paper, the hydrolysis of solid magnesium hydride has been studied with the high concentration of catalyst at the varying temperature. An organic acid (acetic acid, CH3COOH) has been chosen as the catalyst. The study has three objectives: first, using three different weights of MgH2 react with aqueous solution of acid for the hydrogen generation experiments. Secondly, utilizing acetic acid as the catalyst accelerates hydrogen generation. Third, emphasizing the combination of the three operating conditions (the weight of MgH2, the concentration of acetic acid, and the varying temperature) influence the amount of hydrogen generation. The experiments results show acetic …

Phytoplankton Life History Events: Resting Stages And Physiological Cell Death, Christine R. Kozik

Theses and Dissertations

Understanding and predicting changes in phytoplankton populations requires knowledge of key life history processes such as recruitment from benthic resting stages and losses due to sedimentation and cell death. Currently, these processes are poorly understood in freshwater systems. Phytoplankton resting stage and cell death life history events were separately examined in two freshwater systems in Wisconsin, four northern lakes and an urban pond. In the norther lakes, sedimentation and benthic recruitment were examined using sediment and recruitment traps that were sampled weekly over two summers. Sedimentation and benthic recruitment contributed little to changes in standing crop chl a, but rather …

Nearshore Benthic Oxygen Dynamics In Lake Michigan, Emily H. Tyner

Theses and Dissertations

The intense colonization of the Laurentian Great Lakes by dreissenid mussels has profoundly changed ecosystem processes, particularly benthic oxygen dynamics. Dissolved oxygen concentrations in mussel beds, sloughed Cladophora mats, and sediment indicate that hypoxia forms and disappears in some substrata (ephemeral Cladophora mats), while occurring consistently in others (depositional areas of sloughed Cladophora). Dissolved organic carbon concentrations are high (mean: 143 ± ± 28 ppm) in depositional Cladophora mats but lower (˂ 10 ppm) in most other environments. Field sampling and laboratory experiments suggest that under conditions of low water velocity and thick Cladophora cover, hypoxia may develop atop …

Low Turbulence Wind Tunnel Design And Wind Turbine Wake Characterization, Andrew Welsh

Theses and Dissertations

As the prevalence of wind turbines in the energy market increases, so too does the demand for high-wind real-estate. As a result, wind turbines are placed closer together, which leads to structural challenges due to the cyclical fatigue loading from the wake of upwind turbines. Characterizing the wake behind wind turbines with respect to those downwind is especially important given the 20-year wind turbine lifetime that commercial wind turbine consumers expect. This project aimed to characterize the near wake behind a model wind turbine.

In order to accomplish this, a 12.8 meter-long and 1.22 meter-square test section low-turbulence wind tunnel …

Dc Microgrid Modeling And Energy Storage Placement To Enhance System Stability, Carl Westerby

Theses and Dissertations

The work of this thesis represents a joint venture between the University of Wisconsin-Milwaukee and the University of Wisconsin-Madison. A DC microgrid is selected for the efficiency benefits, lack of reactive power in the system, and ease of connecting to an AC grid. The system modeling relies on physical parameters and industry standard methods for the estimation of loads and lines. An example model is created for the University of Wisconsin - Milwaukee's Campus. Due to the high penetration of renewable energy sources in the example model, system stability is a concern. To help mitigate stability issues, analysis is performed …

Improved Estimation Of Pm2.5 Using Lagrangian Satellite-Measured Aerosol Optical Depth, Rolando Olivas Saunders

Theses and Dissertations

Suspended particulate matter (aerosols) with aerodynamic diameters less than 2.5 μm (PM2.5) has negative effects on human health, plays an important role in climate change and also causes the corrosion of structures by acid deposition. Accurate estimates of PM2.5 concentrations are thus relevant in air quality, epidemiology, cloud microphysics and climate forcing studies. Aerosol optical depth (AOD) retrieved by the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite instrument has been used as an empirical predictor to estimate ground-level concentrations of PM2.5. These estimates usually have large uncertainties and errors. The main objective of this work is to assess the value of …

Modeling Energy Production Of Solar Thermal Systems And Wind Turbines For Installation At Corn Ethanol Plants, Elizabeth Ehrke

Theses and Dissertations

Nearly every aspect of human existence relies on energy in some way. Most of this energy is currently derived from fossil fuel resources. Increasing energy demands coupled with environmental and national security concerns have facilitated the move towards renewable energy sources. Biofuels like corn ethanol are one of the ways the U.S. has significantly reduced petroleum consumption. However, the large energy requirement of corn ethanol limits the net benefit of the fuel. Using renewable energy sources to produce ethanol can greatly improve its economic and environmental benefits. The main purpose of this study was to model the useful energy received …

Complexity And Uncertainty In Human And Ecological Risk Assessment, Matthew Jordan Dellinger

Theses and Dissertations

Multiple interacting stressors in the environment present increasingly complex risks to human health. Too often, however, the data required for traditional risk assessment are either lacking or unavailable at the necessary spatial or temporal scale. In addition, assessment practices and management policies need to move away from single factor approaches in order to accommodate the reality of complex chemical mixtures and environmental stressors. Recent literature suggests that a paradigm shift is under way. This points to a need for the development of new techniques both for rapid data collection and flexible risk assessment strategies that can adapt to make use …

Decadal Changes And Future Projections Of Precipitation In The Metropolitan Area Of Milwaukee, Anke Petra Maria Keuser

Theses and Dissertations

This research investigated decadal changes and future projections of precipitation in the Metro Milwaukee and surrounding area, the largest urban area in Wisconsin. Spatial and temporal precipitation patterns derived for the Metro Milwaukee from the high-resolution gridded historical climatic dataset for Wisconsin were analyzed for 1950-2006. In addition, precipitation scenarios were generated via statistical downscaling of the Third Generation Coupled Global Climate Model (CGCM3) outputs. The delta method was chosen for the statistical downscaling of the CGCM3 output for the two future time periods, 2041-2070 (2050s) and 2071-2100 (2080s). The Mann-Kendall test and the Sen's slope test were applied to …