Physical Sciences and Mathematics Commons^™

Session 2b: Groundwater And Karst, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Incorporating Machine Learning with LiDAR for Delineating Sinkholes
• Advances in Urban Karst Hydrological and Contaminant Monitoring Techniques for Real-Time and High-Resolution Applications
• Finding the Edge: How Can We Apply Edge of Field Monitoring to Karst?
• An Urban Karst Groundwater Evaluation and Monitoring Toolbox
• Center-Pivot Irrigation in Western Kentucky: Adding Context to the Discussion

Session 1a: Nutrients And Sediment, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Nutrient Concentrations, Loads, and Yields at Ambient Water Quality Monitoring Stations
• Advancement in Watershed and Sediment Transport Modeling Using Dynamic Lateral, Longitudinal, and Vertical Sediment (Dis)connectivity Prediction
• Canine Nutrient Contributions to the Urban Environment
• Continuous Nutrient and Turbidity Sensors Reveal the Response of Watershed Sources Connected During Storm Events

Session 1b: Ecological Restoration, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• The Restoration of Cane Run Creek through Lexington’s Coldstream Park and UK’s Coldstream Research Campus
• Using Multiple Methods for Better Stream Restoration: Including 2-Dimensional Modeling
• An Ongoing Success Story: What Data, Persistence, and Patience has Enabled in the Hanging Fork Watershed
• Reclaiming Mill Creek: A Case Study in Urban Stream Restoration

Poster Session 1, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• 1.1 Evaluating Soil Characteristics in Rural and Urban Areas
• 1.2 Use of eDNA in Detection of Multiple Salamander Species in Eastern Kentucky Streams
• 1.3 Evaluation of biomass and filtration method on eDNA detection of fantail darters (Etheostoma flabellare)
• 1.4 The Impact of Agricultural Development on Nutrient Contamination Hotspots Within a Small, Intermittent Watershed at EKU’s Meadowbrook Farm, Madison County, Kentucky
• 1.5 How Does Drought Length Impact the Runoff and Nutrient Storm Response in an Agricultural, Intermittent Catchment in Central Kentucky?
• 1.6 Analyzing Sanitary Sewer Overflow Sensitivity to Storm Characteristics
• 1.7 Evaluating Soil Properties in No-Till and Conventional Tillage Systems
• 1.8 …

Plenary Session, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

No abstract provided.

Proceedings Of 2019 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This symposium was planned and conducted as a part of the state water resources research institute annual program that is supported by Grant/Cooperative Agreement Number G16AP00055 from the United States Geological Survey. The contents of this proceedings document and the views and conclusions presented at the symposium are solely the responsibility of the individual authors and presenters and do not necessarily represent the official views of the USGS or of the symposium organizers and sponsors. This publication is produced with the understanding that the United States Government is authorized to reproduce and distribute reprints for government purposes. Mention of trade …

Photocatalytic Degradation Of Profenofos And Triazophos Residues In The Chinese Cabbage, Brassica Chinensis, Using Ce-Doped Tio2, Xiangying Liu, You Zhan, Zhongqin Zhang, Lang Pan, Lifeng Hui, Kailin Liu, Xuguo Zhou, Lianyang Bai

Entomology Faculty Publications

Pesticides have revolutionized the modern day of agriculture and substantially reduced crop losses. Synthetic pesticides pose a potential risk to the ecosystem and to the non-target organisms due to their persistency and bioaccumulation in the environment. In recent years, a light-mediated advanced oxidation processes (AOPs) has been adopted to resolve pesticide residue issues in the field. Among the current available semiconductors, titanium dioxide (TiO₂) is one of the most promising photocatalysts. In this study, we investigated the photocatalytic degradation of profenofos and triazophos residues in Chinese cabbage, Brassica chinensis, using a Cerium-doped nano semiconductor TiO₂ (TiO …

The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The sunlight photochemistry of the organic chromophore pyruvic acid (PA) in water generates ketyl and acetyl radicals that contribute to the production and processing of atmospheric aerosols. The photochemical mechanism is highly sensitive to dissolved oxygen content, [O₂(aq)], among other environmental conditions. Thus, herein we investigate the photolysis (λ ≥ 305 nm) of 10–200 mM PA at pH 1.0 in water covering the relevant range 0 ≤ [O₂(aq)] ≤ 1.3 mM. The rapid consumption of dissolved oxygen by the intermediate photolytic radicals is monitored in real time with a dissolved oxygen electrode. …

Fischer–Tropsch: Product Selectivity–The Fingerprint Of Synthetic Fuels, Wilson D. Shafer, Muthu Kumaran Gnanamani, Uschi M. Graham, Jia Yang, Cornelius M. Masuku, Gary Jacobs, Burtron H. Davis

Center for Applied Energy Research Faculty and Staff Publications

The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a wide range (C₁–C₇₀₊) of hydrocarbons, primarily straight-chained paraffins. Additional hydrocarbon products, which can also be a majority, are linear olefins, specifically: 1-olefin, trans-2-olefin, and cis-2-olefin. Minor hydrocarbon products can include isomerized hydrocarbons, predominantly methyl-branched paraffin, cyclic hydrocarbons mainly derived from high-temperature FTS and internal olefins. Combined, these products provide 80–95% of the total products (excluding CO₂) generated from syngas. A vast number of different oxygenated species, such as aldehydes, ketones, acids, and alcohols, are also embedded in this product range. …

Effect Of Stoniness On The Hydraulic Properties Of A Soil From An Evaporation Experiment Using The Wind And Inverse Estimation Methods, Nerea Arias, Iñigo Virto, Alberto Enrique, Paloma Bescansa, Riley Walton, Ole O. Wendroth

Plant and Soil Sciences Faculty Publications

Stony soils are distributed all over the world. The study of their characteristics has gained importance lately due to their increasing use as agricultural soils. The effect that rock fragments exert on the soil hydraulic properties is difficult to measure in situ, and is usually derived from the fine earth properties. However, the corrections used so far do not seem accurate for all types of stony soils. Our objective was to assess the adequacy of estimating the hydraulic properties of a stony soil from the fine earth ones by correcting the latter by the volume occupied by rock fragments. To …

Method Of Increasing Mass Transfer Rate Of Acid Gas Scrubbing Solvents, Joseph E. Remias, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty Patents

A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

Pt represents an effective promoter of supported Ni catalysts in the transformation of tristearin to green diesel via decarbonylation/decarboxylation (deCO_x), conversion increasing from 2% over 20% Ni/Al₂O₃ to 100% over 20% Ni-0.5% Pt/Al₂O₃ at 260 °C. Catalyst characterization reveals that the superior activity of Ni-Pt relative to Ni-only catalysts is not a result of Ni particle size effects or surface area differences, but rather stems from several other phenomena, including the improved reducibility of NiO when Pt is present. Indeed, the addition of a small amount of Pt to the supported Ni …

Potential Economic Impacts Of Allocating More Land For Bioenergy Biomass Production In Virginia, Thomas O. Ochuodho, Janaki R. R. Alavalapati, Pankaj Lal, Domena A. Agyeman, Bernabas Wolde, Pralhad Burli

Forestry and Natural Resources Faculty Publications

The growing attention to renewable energy and rural development has created greater demand for production of biomass feedstock for bioenergy. However, forest growth rates and the amount of land in most existing forests may not be sufficient to sustainably supply the forest biomass required to support existing forest products industries and the expanding bioenergy industry. Additionally, concerns about agricultural land use competition have dampened expansion of biomass production on agricultural land base. One of the ways to meet the growing forest biomass feedstock demand for bioenergy production is by allocating currently marginal non-forested land for growing bioenergy feedstocks. In Virginia, …

Carboxylic Acids Accelerate Acidic Environment-Mediated Nanoceria Dissolution, Robert A. Yokel, Matthew L. Hancock, Eric A. Grulke, Jason M. Unrine, Alan K. Dozier, Uschi M. Graham

Pharmaceutical Sciences Faculty Publications

Ligands that accelerate nanoceria dissolution may greatly affect its fate and effects. This project assessed the carboxylic acid contribution to nanoceria dissolution in aqueous, acidic environments. Nanoceria has commercial and potential therapeutic and energy storage applications. It biotransforms in vivo. Citric acid stabilizes nanoceria during synthesis and in aqueous dispersions. In this study, citrate-stabilized nanoceria dispersions (∼4 nm average primary particle size) were loaded into dialysis cassettes whose membranes passed cerium salts but not nanoceria particles. The cassettes were immersed in iso-osmotic baths containing carboxylic acids at pH 4.5 and 37 °C, or other select agents. Cerium atom material …

Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

While commercial hydrodeoxygenation (HDO) processes convert fats, oils, and grease (FOG) to fuel-like hydrocarbons, alternative processes based on decarboxylation/decarbonylation (deCO_x) continue to attract interest. In this contribution, the activity of 20% Ni-5% Cu/Al₂O₃ in the deCO_x of waste free fatty acid (FFA)-based feeds—including brown grease (BG) and an FFA feed obtained by steam stripping a biodiesel feedstock—was investigated, along with the structure-activity relationships responsible for Ni promotion by Cu and the structural evolution of catalysts during use and regeneration. In eight-hour experiments, near quantitative conversion of the aforementioned feeds to diesel-like hydrocarbons was achieved. …

A Total Life Cycle Approach For Developing Predictive Design Methodologies To Optimize Product Performance, Buddhika M. Hapuwatte, Ibrahim S. Jawahir

Institute for Sustainable Manufacturing Faculty Publications

Sustainable products must be designed by considering how design decisions impact their total life cycle (TLC) sustainability content. Even more so important when designing products to incorporate the technological elements of sustainable manufacturing, the 6Rs (Reduce, Reuse, Recycle, Recover, Redesign and Remanufacture), to achieve Circular Economy (CE). This paper presents the preliminary work of an ongoing research project on developing a novel framework incorporating predictive models with TLC considerations. This unique approach develops and integrates models with associated risks, and optimizes for maximizing the sustainability benefits due to design decisions. Such predictive capability is extremely useful for process planning, where …

Process Sustainability Evaluation For Manufacturing Of A Component With The 6r Application, Ana E. Bonilla Hernández, Tao Lu, Tomas Beno, Claes Fredriksson, Ibrahim S. Jawahir

Institute for Sustainable Manufacturing Faculty Publications

Sustainability in manufacturing can be evaluated at product, process and system levels. The 6R methodology for sustainability enhancement in manufacturing processes includes: reduced use of materials, energy, water and other resources; reusing of products/components; recovery and recycling of materials/components; remanufacturing of products; and redesigning of products to utilize recovered materials/resources. Although manufacturing processes can be evaluated by their productivity, quality and cost, process sustainability assessment makes it a complete evaluation. This paper presents a 6R-based evaluation method for sustainable manufacturing in terms of specific metrics within six major metrics clusters: environmental impact, energy consumption, waste management, cost, resource utilization and …

Image-Based Roadway Assessment Using Convolutional Neural Networks, Weilian Song

Theses and Dissertations--Computer Science

Road crashes are one of the main causes of death in the United States. To reduce the number of accidents, roadway assessment programs take a proactive approach, collecting data and identifying high-risk roads before crashes occur. However, the cost of data acquisition and manual annotation has restricted the effect of these programs. In this thesis, we propose methods to automate the task of roadway safety assessment using deep learning. Specifically, we trained convolutional neural networks on publicly available roadway images to predict safety-related metrics: the star rating score and free-flow speed. Inference speeds for our methods are mere milliseconds, enabling …

Kentucky Water Resources Research Institute, University Of Kentucky: Annual Technical Report 2018, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

In 2018, KWRRI launched a new website, https://www.research.uky.edu/kentucky-water-resources-research-institute, to better meet the needs of its stakeholders. KWRRI also established a repository for KWRRI’s reports, https://uknowledge.uky.edu/kwrri/. The repository includes historical KWRRI reports, annual symposium proceedings, technical reports, and the Water Distribution System Research Database. During the reporting period, KWRRI produced two editions of its semi-annual newsletter (Spring 2018 and Winter 2019). The newsletter provides updates, facilitates information sharing, and increases communication among those in the Kentucky water community. The 2019 Kentucky Water Resources Annual Symposium was held on March 25, 2019, in Lexington, Kentucky. The day-long symposium, attended by …

Effects Of Depositional Processes On Strength And Compressibility Of Sediments Using Elastic Shear Wave Velocity, Wisam Razzaq Muttashar

Theses and Dissertations--Earth and Environmental Sciences

Depositional processes are the most critical, complicated conditions that govern sediment properties and their variations, which in turn significantly affect the geotechnical behavior of the sediment. The complexity of depositional and post-depositional processes, which results in a variety of depositional environments, makes constructing a plausible model for the consolidation process of sediments difficult. The mutual influence between the temporal and spatial variation of depositional environments with their resultant physical and mechanical properties cause several compression issues, such as consolidation settlement and land subsidence, which mostly occur in estuarine-riverine regions throughout the world.

The first aim of this study is proposing …

Sustainable Production Through Balancing Trade-Offs Among Three Metrics In Flow Shop Scheduling, Amin Abedini, Wei Li, Fazleena Badurdeen, Ibrahim S. Jawahir

Institute for Sustainable Manufacturing Faculty Publications

In sustainable manufacturing, inconsistencies exist among objectives defined in triple-bottom-lines (TBL) of economy, society, and environment. Analogously, inconsistencies exist in flow shop scheduling among three objectives of minimizing total completion time (TCT), maximum completion time (MCT), and completion time variance (CTV), respectively. For continuous functions, the probability is zero to achieve the objectives at their optimal values, so is it at their worst values. Therefore, with inconsistencies among individual objectives of discrete functions, it is more meaningful and feasible to seek a solution with high probabilities that system performance varies within the …

Designing And Redesigning Products, Processes, And Systems For A Helical Economy, Ryan Bradley, Ibrahim S. Jawahir

Institute for Sustainable Manufacturing Faculty Publications

The Circular Economy (CE) concept has promised to unlock trillions of dollars in business value while driving a significant reduction in the world’s resource consumption and anthropogenic emissions. However, CE mainly lives in ambiguity in the manufacturing domain because CE does not address the changes needed across all of the fundamental elements of manufacturing: products, processes, and systems. Conceptually, CE is grounded in the concept of closed-loop material flows that fit within ecological limits. This grounding translates into a steady state economy, a result that is not an option for the significant portion of the world living in poverty. Therefore, …

Procure-To-Pay Software In The Digital Age: An Exploration And Analysis Of Efficiency Gains And Cybersecurity Risks In Modern Procurement Systems, Drew Lane

MPA/MPP/MPFM Capstone Projects

Procure-to-Pay (P2P) softwares are an integral part of the payment and procurement processing functions at large-scale governmental institutions. These softwares house all of the financial functions related to procurement, accounts payable, and often human resources, helping to facilitate and automate the process from initiation of a payment or purchase, to the actual disbursal of funds. Often, these softwares contain budgeting and financial reporting tools as part of the offering. As such an integral part of the financial process, these softwares obviously come at an immense cost from a set of reputable vendors. In the case of government, these vendors mainly …

Decomposing A Watershed’S Nitrate Signal Using Spatial Sampling And Continuous Sensor Data, Evan Clare

Theses and Dissertations--Civil Engineering

Watershed features, physiographic setting, geology, climate, and hydrologic processes combine to produce a time-variant nutrient concentration signal at the watershed outlet. Anthropogenic influences, such as increased agricultural pressures and urbanization, have increased overall nutrient loadings delivered to the fluvial network. The impact of such increased nutrient loadings on Kentucky’s drinking water remains a potential threat to the region.

By coupling spatial sampling of nitrate concentrations in surface water with contemporary nutrient and water quality sensor technology, a decomposition of the Upper South Elkhorn watershed’s nitrate signal and an estimation of source timing and loading in the watershed was completed. The …

A Compiler Target Model For Line Associative Registers, Paul S. Eberhart

Theses and Dissertations--Electrical and Computer Engineering

LARs (Line Associative Registers) are very wide tagged registers, used for both register-wide SWAR (SIMD Within a Register )operations and scalar operations on arbitrary fields. LARs include a large data field, type tags, source addresses, and a dirty bit, which allow them to not only replace both caches and registers in the conventional memory hierarchy, but improve on both their functions. This thesis details a LAR-based architecture, and describes the design of a compiler which can generate code for a LAR-based design. In particular, type conversion, alignment, and register allocation are discussed in detail.

Relation Prediction Over Biomedical Knowledge Bases For Drug Repositioning, Mehmet Bakal

Theses and Dissertations--Computer Science

Identifying new potential treatment options for medical conditions that cause human disease burden is a central task of biomedical research. Since all candidate drugs cannot be tested with animal and clinical trials, in vitro approaches are first attempted to identify promising candidates. Likewise, identifying other essential relations (e.g., causation, prevention) between biomedical entities is also critical to understand biomedical processes. Hence, it is crucial to develop automated relation prediction systems that can yield plausible biomedical relations to expedite the discovery process. In this dissertation, we demonstrate three approaches to predict treatment relations between biomedical entities for the drug repositioning task …

Scanning Probe Microscopy Measurements On 2d Materials And Iridates, Armin Ansary

Theses and Dissertations--Physics and Astronomy

In the past two decades, there has been a quest to understand and utilize novel materials such as iridates and two-dimensional (2D) materials. These classes of materials show a lot of interesting properties both in theoretical predictions as well as experimental results. Physical properties of some of these materials have been investigated using scanning probe measurements, along with other techniques.

One-dimensional (1D) catalytic etching was investigated in few-layer hexagonal boron nitride (hBN) films. Etching of hBN was shown to share several similarities with that of graphitic films. As in graphitic films, etch tracks in hBN commenced at film edges and …

Transforming A Circular Economy Into A Helical Economy For Advancing Sustainable Manufacturing, Ryan T. Bradley

Theses and Dissertations--Mechanical Engineering

The U.N. projects the world population to reach nearly 10 billion people by 2050, which will cause demand for manufactured goods to reach unforeseen levels. In order for us to produce the goods to support an equitable future, the methods in which we manufacture those goods must radically change. The emerging Circular Economy (CE) concept for production systems has promised to drastically increase economic/business value by significantly reducing the world’s resource consumption and negative environmental impacts. However, CE is inherently limited because of its emphasis on recycling and reuse of materials. CE does not address the holistic changes needed across …

The Use Of 3-D Highway Differential Geometry In Crash Prediction Modeling, Kiriakos Amiridis

Theses and Dissertations--Civil Engineering

The objective of this research is to evaluate and introduce a new methodology regarding rural highway safety. Current practices rely on crash prediction models that utilize specific explanatory variables, whereas the depository of knowledge for past research is the Highway Safety Manual (HSM). Most of the prediction models in the HSM identify the effect of individual geometric elements on crash occurrence and consider their combination in a multiplicative manner, where each effect is multiplied with others to determine their combined influence. The concepts of 3-dimesnional (3-D) representation of the roadway surface have also been explored in the past aiming to …

Oxidative Degradation Of Lignin And Investigation Of Utilization Of Lignin-Derived Materials As Building Blocks For Epoxy Resins, Zhen Fang

Theses and Dissertations--Chemistry

Lignin, the second most abundant biopolymer on earth, is potentially a replaceable source for bulky fuels and chemical feedstocks. There have been numerous reports on methods for the oxidative cleavage of β-O-4 linkages but relatively few reports of how those methods affect other linkages that are present in lignin. We investigated how the β-1 and β-5 linkages respond under oxidative conditions proposed for lignin deconstruction based on their effect on β-O-4 linkages. Mechanochemical treatment of lignin can greatly improve the yield of monomer products and we applied a mechanochemical approach, using powerful ring-and-puck milling to promote lignin degradation. Along with …