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A Study On Electrochemical Oxidation Of Reduced Nicotinamide Coenzyme Nadh In Organic Media, Fangzu Yang, Wuhuihuang Wuhuihuang, Xushukai Xushukai, Zhoushsomin Zhoushsomin
A Study On Electrochemical Oxidation Of Reduced Nicotinamide Coenzyme Nadh In Organic Media, Fangzu Yang, Wuhuihuang Wuhuihuang, Xushukai Xushukai, Zhoushsomin Zhoushsomin
Journal of Electrochemistry
The behaviour of electrochemical oxidation of the reduced nicotinamide coenzyme NADH on glassy carbon was studied and some kinetic parameters were measured by means of voltammometry in the N-dimethylformamide(DMF)and 1,4-dioxane media respectively. The eletrochemical oxidation of NADH shows completely irriversable both in the two solvents,and the diagnostic experiments support that the process involves a fast chemical step.The oxidation rate and the diffusion coefficient of N ADH in DMP are smaller than those in 1,4-dioxane,but the response current is more stable in DMF. The experimental results are discussed by solvent effects.