Physical Sciences and Mathematics Commons^™

Effects Of Urbanization On Eutrophication Parameters In Three Tidal Creeks, Ella Swantek

Honors Theses

Marshes and swashes are vital environments as a controlling barrier between land affected by various pollutants and the ocean. Eutrophication and the effects of this process can be detrimental for the areas experiencing it. I am interested in ways areas that have little contact with human interactions compare to areas that are heavily urbanized, and whether either of these locations is at a higher risk for eutrophication. Using spectrophotometry and fluorometry, I analyzed samples collected from the relatively undeveloped and restricted-access locations of Waities Island Beach and Dunn Sound monthly for dissolved nutrients, and chlorophyll. At the time of sampling, …

Impacts Of Hurricane Idalia’S Surge On Coastal Sand Biogeochemistry, Wendy "Cor" Mchone

Honors Theses

Beaches are heavily influenced by extreme events, such as hurricanes. Biological and chemical processes, such as primary production and diagenesis are often interrupted by these events. To examine the effects of hurricanes on coastal biogeochemistry, this study used sand and porewater samples from Waties Island, SC, which were collected before and after Hurricane Idalia. The samples were analyzed for macronutrient concentrations, organic content, and chlorophyll concentrations. Macronutrient pore water concentration changes were not uniform. The inventory of nitrite decreased significantly after the storm, which was reflected in slight increases in the inventories of nitrate and ammonium. Concentrations of nitrate, which …

Sedimentary Conditions At A Tidal Creek That Exhibits Seasonal Pelagic-Benthic Variations, Jack B. Corbin

Honors Theses

Tidal creeks in the Grand Strand of South Carolina are small but numerous connectors between land and ocean. One of these creeks, White Point Swash, exhibits a seasonal switch between planktonic and benthic photosynthesizers. As plankton become less abundant in fall, benthic macroalgae bloom, aided by lower water levels due to fall-winter dredging of the main channel, until late Spring. This study builds on previous findings and examines sedimentary conditions at this site further. Sedimentary chlorophyll a (in microphytobenthos) and pore water nutrient concentrations are confirmed to be higher than water-column concentrations. Sedimentary nutrient fluxes to the sediment-water interface, calculated …

An Analysis Of Pollution In Liverpool, Uk, Luke W. Lawson

Honors Theses

Within this experiment the different levels of pollution in areas around Liverpool were tested. These areas were Stanley Park, Lunt Meadows, and Woolton Road. At Stanley Park one of two transects had a geochemical analysis as well as magnetic measurements run to investigate source attribution within the urban environment resulting in data showing high variability in soil properties among the transect. With data supporting evidence of diamagnetic, paramagnetic, and ferromagnetic properties in soil along the same transect. At Lunt Meadows, through the use of XRF for soil samples and nitrate and phosphate testing for water samples, it was found that …

Evaluating Field Evidence Of Fine-Grained Sediment Abrasion In Gravel-Bedded Rivers: A Case Study Of The Lillooet And Suiattle Rivers In The Cascade Volcanic Arc (British Columbia, Canada, And Washington, Usa), Devin T. Johnson

Honors Theses

Steep, gravel-bedded rivers are important sites for studying gravel abrasion, where material transported as bed load experiences size reduction and rounding due to grain-to-grain collisions. Studying fine sediment (diameter) abrasion and grain shape changes in fluvial systems is more challenging due to difficulties in quantifying sediment shape at this scale, but it is assumed that fine particles traveling in suspension do not experience abrasion. Improvements in particle characterization technology now allow for the accurate, rapid quantification of particle shape for sediments as fine as 0.8 μm through dynamic image analysis. Here we use the Camsizer X2 (CX2) to test the …

Suboxic And Anaerobic Respiration Across A Sandy-Shore-To-Estuarine Gradient, Jacey Ballard

Honors Theses

Sulfate is an inorganic ion that is one of the major ions of seawater. Sulfate is also an essential reactant in microbially mediated anaerobic respiration that produces sulfide, an energy source during chemosynthesis. Sulfide is widely found in sediment, and water rich in decaying organic material, as well as hydrothermal vents. While sulfate reduction occurs extensively in muds, such as those of marshes, it is not expected to occur in sand which is much better aerated. Recent research in our group documented extensive sub aerobic respiration in coastal sands which suggests that sulfate reduction may have also been happening. This …

Investigation Of A Possible Switch Of Benthic Photosynthetic Organisms And Phytoplanktonic Organisms In White Point Swash, South Carolina, Nathan Easterling

Honors Theses

This research study examined the possible switch from benthic photosynthetic organisms to phytoplankton in the water column at White Point Swash, Long Bay, South Carolina, and what is causing this switch to occur. During Dr. Hannides’ and his group’s studies at this and other swashes in the past, they noticed this phenomenon of the benthic photosynthetic organisms taking over during a certain time and then the phytoplankton in the water column taking over during a different time. In this study, I measured the relative benthic macroalgal area coverage and sedimentary chlorophyll a concentration as measures of the abundance of benthic …

The Dynamics Of Sedimentary Chlorophyll Α At A High-Energy Beach, Sarah (Gray) Abel

Honors Theses

Productive sandy beaches are one of the most crucial areas serving our ecosystem today. While often overlooked in scientific research, productive beaches have many essential functions that lead to the preservation and protection of many different species as well as ecological wellness and stability. A key factor that is linked to this productivity is the presence of chlorophyll in the sediments. Piston cores of the sediments at the low-tide mark at Waties Island, South Carolina, were collected across multiple years and subsequently analyzed for chlorophyll concentrations through fluorometry after acetone extraction and acidification. Each core profile was processed to calculate …

Dissolved Copper Distributions In The Western Mississippi Sound: Characterizing An Unrecognized Endmember, Megan Hansen

Honors Theses

This study examined the distribution of dissolved copper (Cu) in the western Mississippi Sound, as the element can be beneficial or harmful to organisms depending on its concentration and its chemical form. A mixing experiment eliminated flocculation as a control on Cu distributions during estuarine mixing in both dissolved and colloidal fractions. Field sampling of the western Mississippi Sound occurred during a low river discharge period, and distributions of Cu indicated conservative mixing between fresh ([Cu] ≈ 17 nM) and saline ([Cu] ≈ 2 nM) sources in mid-to-high salinities. Storm outfalls were sampled after rain events to evaluate the impact …

Petrographic Observations Of Stromatolites In The Late Cambrian To Early Ordovician Knox Group, Northwest Georgia And Their Relationship To Stromatolitic Fabrics Over Geologic Time, Evan Ritchey

Honors Theses

Silica deposits are common in Proterozoic carbonate platforms and are interpreted to form early in the diagenetic history of the carbonate strata. Black early diagenetic chert deposits are often associated with evidence of ancient microbial mats, or stromatolites. Proterozoic chert nodules can contain well-preserved microfossils, because silicification occurs rapidly; however, silica deposition has changed over time and it is unclear if similar deposits exist in the Cambrian period after silica-utilizing organisms evolved. The Copper Ridge Dolomite in the Knox Group, northwest Georgia, which was deposited in the late Cambrian to early Ordovician, contains black chert nodules that follow the structure …

Tracing North Atlantic Continental Erosion Events During The Mid-Pleistocene Transition, Cecilia T. Bowe

Honors Theses

The Mid-Pleistocene Transition (MPT), which occurred between 1.2 and 0.7 Mya, is characterized by changes in the periodicity and intensity of glacial-interglacial cycles. Early research into this event found that it was not triggered by changes in orbital forcing, but rather by internal climate processes. Previous studies have constrained a probable two-step mechanism, in which erosion of regolith under ice sheets increased glacial volumes and contributed to increased carbon sequestration in the Southern Ocean. Additional research has built on this, suggesting that increased glacial erosion of cratons surrounding the North Atlantic preceded a major weakening of the Atlantic Meridional Overturning …

Pfas Mass Balance, Donovan Vitale

Honors Theses

First-generation, PFOS-dominant Aqueous Film Forming Foam (AFFF) concentrate of approximately 200 gallons was released to the sewer system from the Kalamazoo/Battle Creek International Airport on March 30, 2021. The AFFF release migrated to the Kalamazoo Water Reclamation Plant (KWRP), raising plant effluent above the Department of Environment, Great Lakes, and Energy (EGLE) PFOS water quality standard for a total of 46 days post-spill, although the influent concentrations exhibited sharp declines after only 7 days. By sampling influent, effluent, and biosolids daily, the only known long duration, high-frequency PFAS data set of an accidental AFFF release was generated. This study has …

Faunal Comparison And Analysis Of The Blufftown Formation-Cusseta Sand Contact At Hannahatchee Creek, Georgia, Seth Fradella

Honors Theses

The origin of fossil material in the highly fossiliferous bed above the Upper Cretaceous (Campanian) Blufftown Formation-Cusseta Sand contact at Hannahatchee Creek, Georgia, has long been a subject of scientific curiosity; however, no research has yet been conducted to specifically investigate discrepancies between the fossil assemblages of the upper Blufftown Formation and the basal Cusseta Sand, which overlies it unconformably. In the most recent published hypothesis, Case and Schwimmer (1988) propose that the basal Cusseta Sand contains a mixture of original fauna as well as material reworked and redeposited from the underlying Blufftown Formation, resulting in a lag deposit above …

A Faunal Composition Of The Late Cretaceous Blue Springs Site In Northeastern Mississippi And Evidence For Potential Paleoenvironmental Differences Between Beds, Ginger Trochesset

Honors Theses

The Maastrichtian-age Blue Springs locality of the Coon Creek Member of the Ripley Formation is known for abundant, well-preserved marine fossils, including many genera of microfossils, bivalves, gastropods, decapods, cephalopods, actinopterygians, and other vertebrate organisms. This research contributes to the understanding of the paleontology of the site, as well as the changing paleoenvironmental conditions of the beds throughout deposition.

This project analyzed bulk material collected in 2021 from three fossiliferous beds at Blue Springs: the Lower Corbula Bed (Bed C), the Pebble Bed (Bed G), and the Exogyra-Pycnodonte Bed (Bed J). Unconsolidated material from Beds C and J was processed …

Characterization Of Mumian And Host Rock In Al-Amerat Cave, Oman., Sara Alqamshouai

Honors Theses

Mumian is a sticky black-brown material found in the Mumian cave in Wadi Al Mayh, Al Amerat, Oman. Mumian has been used for centuries as traditional medicine by the local Omani people. Though commonly ingested orally to resolve a variety of common ailments, very little is known about the Mumian material in terms of its chemical composition. The principle aim of this study is to characterize the Mumian and the host rock in terms of the mineralogy and chemical characteristics using a variety of analytic instruments, including XRD, NMR, FT-IR, XRF, and UV- VIS. A secondary goal of this study …

Investigating The Thermodynamics And Seismic Profile Of The Europan Hydrosphere Through Pure-Water Modeling And Saltwater Experiments, Samantha Rosenfeld

Honors Theses

We explore the properties of the hydrosphere on Europa involving both a modeling technique and experimental methods. We perform a computational analysis of the thermodynamic properties for an ideal, pure-water Europan ice shell using a Python programming framework called SeaFreeze. We create four models assuming surface temperatures of either 50 K or 140 K and ice shell thicknesses of either 3 km or 30 km. We observe mostly linear trends for the density and seismic wave velocities with respect to depth and find that surface temperature has the greatest effect on the models. Simultaneously, we experimentally investigate the phase diagram …

Sewer System Infrastructure And Stressors On Water Quality In Streams Within The Alplaus Watershed In Upstate Ny, Camryn Ragland

Honors Theses

Healthy aquatic ecosystems require clean water, but many creeks and streams may be impaired by human activity. This study is focused on surface water quality of the Alplaus, and Indian Kill streams located within the Alplaus Watershed in Schenectady and Saratoga Counties (NY). The primary goal of this study is to understand the extent of water quality impairment within the Alplaus and Indian Kill using a range of indicators to understand the impacts of failing infrastructure and stressors to surface water. Sixty-five water samples were collected in the fall of 2021 from six locations in the Alplaus and Indian Kill …

Fluid Pathways In Magmatic Fluid-Dominated Hydrothermal System: Upper Resurgent Cone, Brothers Volcano, New Zealand, Esther G. Goita

Honors Theses

The Tonga-Kermadec Arc is an active volcanic arc located between New Zealand and Fiji. The arc expands over an approximate distance of 2530 km. The Kermadec Arc is currently host to over 30 volcanoes, the majority of which are submarine. The magmatic activity along the arc is characterized by the convergence between the Pacific and Australian plates. Brothers volcano is the most active hydrothermal system along the Kermadec arc and hosts two distinct hydrothermal systems, one magmatic fluid dominated, and the other seawater dominated, making the site perfect for studying nascent volcanogenic massive sulfide formation and fluid pathways. The International …

The Use Of Time-Lapse And Still Photographs To Document The Effects Of Seasonality On Dune Morphodynamic Evolution In Corolla, Nc., Briar Ownby-Connolly

Honors Theses

With climate change altering established seasonal and weather phenomena, understanding the physical behavior of barrier islands and the processes driving such physical changes, specifically within their dune zones, is crucial in promoting their resiliency. With ecosystem services provided by dunes to coastal economies and wildlife habitat, promoting dune conservation serves to advance the benefits of these systems, within a changing climate. Current findings by the Army Corps of Engineers Field Research Facility in Duck, NC, suggest the significance of local aeolian sediment transport in interplay with storm intensity in effecting dune stability, and that anthropogenic impacts, like the installment of …

Characterization Of The Initial Explosive Phases Of The 2021 Eruption At La Soufriere, St. Vincent, Sydney Walters

Honors Theses

The Soufriere Volcano on St. Vincent Island, in the Lesser Antilles volcanic arc, is one of the most active subaerial volcanos in the Caribbean, erupting both explosively and effusively at least 7 times in the last 500 years. In December of 2020, the volcano began erupting effusively, showing no evidence of degassing and on April 9^th of 2021, it transitioned to an explosive eruption that continued until April 22, with more than 30 eruptions classified as Vulcanian and sub-Plinian. Scoria samples from three units (U1-U3) erupted in the first 48-72 hours of the explosive eruptive phase were analyzed in …

Comparing Composite Severe Weather Indices Of Thunderstorm Activity On Sea-Breeze And Non-Sea-Breeze Days In The Mobile, Alabama Area, Elizabeth Seiler

Honors Theses

Sea breezes (SB) occur frequently from May through October along the U.S. Gulf of Mexico Coast. One reason why SBs interest forecasters is their ability to spawn summertime thunderstorms, which can cause flash flooding, lightning, and hail. However, forecasting the exact timing and location of SB-driven convection can be challenging. This thesis will focus on Mobile and Baldwin Counties in southwest Alabama, which experience two types of phenomena – SBs along the Gulf of Mexico Coast and bay breezes on either side of Mobile Bay. Over the past years, multiple undergraduate students have analyzed Mobile, Alabama radar imagery of past …

Defining The Leading Edge Of The Marine – Non-Marine Transition In The Pee Dee Basin: Influences, And Dynamic Parameters Of A Highly Dynamic System, Nicole Mchugh

Honors Theses

Among estuaries, there is a large block of co-dependent and independent variables shaping habitat and environmental conditions within a critical area. Historical data proxies and indexes from seven different stations were assessed to consider temporal and spatial variability of the marine and non-marine transition along the South Carolina Pee Dee River Basin. Historical datasets from the upper reaches of Winyah Bay and lower section of the Pee Dee River basin were compiled along with shorter termed deployments of a new instrument station installed near Georgetown, SC. This area is representative of the marine-non-marine transition in drowned river mouth estuaries. Water …

Pixe Analysis Of Heavy Metals In Soil Along The East River, Mia Villeneuve

Honors Theses

We collected samples of soil from along the East River in Queens, New York, near the Hell Gate Bridge, on the Astoria Park side of the bridge in 2019 and on the Randall’s Island Park side in 2021. We performed proton-induced X-ray emission (PIXE) analysis on the samples and found that soil closer to the Hell Gate Bridge contained higher concentrations of heavy metals, specifically lead and zinc. Many of the soil samples contained lead concentrations greater than the EPA standard of 400 ppm. We also performed PIXE analysis on a sample of the paint used on the bridge and …

Electron-Positron Annihilation Lifetime Spectroscopy Of Mgo And Aluminum-Doped Mgo, Elise Liebow

Honors Theses

Radiation is a form of energy that can damage materials at an atomic level. This has implications for the mobility of radioactive waste through containment materials. We are characterizing atomic defects in materials by using Electron-Positron Annihilation Lifetime Spectroscopy (EPALS). When an electron and positron come into contact with each other, they annihilate and release two antiparallel 511-keV gamma rays. In a pristine crystalline sample, positrons can easily annihilate with electrons, but in a sample with vacancies/defects in the crystal structure, positrons take longer to annihilate. Therefore, the more vacancies in a sample, the longer the average lifetime of a …

Evaluating The Relationship Between Floodplain Topography And Channel Avulsion: Evidence From The Devonian Catskill Formation, North-Central Pennsylvania, Usa, Molly O'Halloran

Honors Theses

Topographic complexity on floodplains can route flow, control sediment dispersal, and influence channel behavior, but studying floodplain-channel interactions in modern rivers is challenging because of human modifications and the short timescales of observable data. This project assesses the link between different types of floodplain microtopography and avulsion style in the Devonian Catskill Formation, north-central Pennsylvania, where thick stacks of fluvial strata provide a lengthy record of channel-floodplain interaction. Using a combination of field observations and computer modeling, this study identifies sedimentary features indicative of floodplain complexity and analyzes their impact on avulsion style at fourteen Catskill Formation outcrops.

Based on …

Mercury Emissions From Iron Mining And Copper Mining In The Upper Peninsula, Michigan, Ahmed Al Rahbi

Honors Theses

The wealth in the Upper Peninsula of Michigan has been intimately linked with mining, particularly the extraction of iron and copper. Iron was deposited in the Upper Peninsula 1.9 billion years ago (Gogebic and Ranges, 2020), and copper deposits are believed to be 1.1 billion years old (Blakemore et al., 2016). In the Upper Peninsula, mercury occurs naturally in taconite (iron ore) as elemental mercury (Hg⁰), and within the copper ores as “Mercury copper amalgam” (CuHg). When elemental mercury is released from the ores, it oxidizes in the atmosphere to form inorganic mercury (Hg²⁺) (Risher, 2003; …

Iron Geochemistry Across An Estuary-To-Coastal Gradient, Lissett G. Diaz

Honors Theses

Iron is a ubiquitous earth element that participates in biogeochemical processes that occur in marine sediments. Microorganisms utilize iron for many purposes, including cell growth, conserving energy, and for maintaining metabolic activity. In coastal sedimentary settings, understanding the redox reactions involving ferric iron, Fe³⁺, and ferrous iron, Fe²⁺, in its solid phase and pore-water phases, respectively, enable an appreciation of biogeochemical transformations occurring in the coastal zone. In this study, iron concentrations in sediment of ranging permeability were determined at four stations marking an estuary-coast transition zone in Singleton Swash in Myrtle Beach, South Carolina. The …

Differences In Erosion Rates And Elevation Among Natural, Living And Hardened Shorelines In Mississippi, And Alabama, Brittany Juneau

Honors Theses

Shoreline erosion is a phenomenon that currently threatens both natural ecosystems and human settlements along the coast. With trends showing gradual sea level rise as a result of climate change, erosion is becoming an increasing threat to these communities. This research aims to provide more insight into the relationship between shoreline morphology and three shoreline protection techniques: natural marsh, living shoreline, and hardened structures. Six sites along the Alabama and Mississippi coast that had all three shoreline types were evaluated to determine what the average erosion rate and slope was for each shoreline. Erosion rates were calculated by image analysis …

Heavy Metal Contamination In Drinking Water And Its Connection To Superfund Site Related Environmental Injustice, Emily Caruso

Honors Theses

Equal access to clean, potable drinking water is crucial for our society’s health and advancement. In 2014, the infamous water crisis in Flint, Michigan, shed light on the widespread water quality issues impacting numerous communities in America. In response to the Flint water crisis, Union College established the Union College Water Initiative, providing free drinking water analyses to the public. This initiative aims to raise awareness and educate people by analyzing heavy metals commonly found in drinking water—specifically lead, copper, and zinc.

As a part of this initiative, I collected over 300 cold drinking water samples from residences, schools, and …

Soil Inhomogeneity Effects On Seismic Wind Noise, Bipin Koirala

Honors Theses

Wind causes local pressure fluctuations over the ground. The pressure waves couples with the ground and transmits into the ground as seismic waves. The seismic wave, in turn, causes ground motion. Naderyan et al. [9] developed a prediction of the ground displacements spectra from the measured ground properties and predicted pressure and shear stress at the ground surface. Naderyan modeled the ground as a linearly elastic half space bounded by an infinite plane on one side. The quasi-static model for predicting displacement components in the ground is effective for the vertical component of the displacement response, but the model significantly …