Physical Sciences and Mathematics Commons^™

Marine Vertebrate Remains From Middle-Late Devonian Bone Beds At Little Hardwick Creek In Vaughns Mill, Kentucky And At The East Liberty Quarry In Logan County, Ohio, John M. James

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Stratigraphic, lithologic, faunal and condont biozone analysis will provide insight to whether or not East Liberty Bone Bed, in Logan County, Ohio, and Little Hardwick Creek Bone Bed C, in Vaughns Mill, Kentucky, are chronostratigraphic correlations to one another; they are separated by 370 kilometers (230 miles). Material from each bed was collected and broken down in acid and analyzed. Remaining residue after acid treatment was analyzed under a dissecting microscope for lithological and fossil contents, identified from previous fossil vertebrate findings at other locations.

Final analysis of these beds showed that lithologically and faunally they are very similar. However, …

Estimating Permeability From The Grain-Size Distributions Of Natural Sediment, Lawrence Mastera

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Permeability, k, can be estimated using the Kozeny-Carman equation, given a grain-size distribution with any number of grain-size categories and the porosity of a sediment. A recursive method was developed to calculate the effective grain-size parameter, d, for sediment mixtures with more than three grain sizes. The method was tested on four sediment models of sand, gravelly sand, sandy gravel, and open-framework gravel created from grain-size distributions. The k estimated from the recursive method were consistent with physical measurements of k.

Dimethylmercury Production In Freshwater Sediments, David C. Kelly

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Dimethylmercury (DMHg) has been examined almost exclusively in marine environments to date, plays an uncertain role in the global cycling of Hg, and is produced by a currently unknown mechanism in natural systems. We examined DMHg production in microcosms containing 100 cm3 of freshwater sediment sampled from 3 wetlands and a lake near Dayton, Ohio. DMHg was produced from all sediments analyzed, and found that production is increased significantly by the addition of inorganic Hg from ~0.1pM to ~10pM, its production is unaffected by autoclaving the sediment, and organic carbon additions had no discernible effect on production. Its total concentrations …

How The Growth Of The Frampton Fold Affected The Growth Of The Green Knoll Diapir, John A. Zinck

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The growth of structural features formed by the movement of the Louann Salt within the study area follows a fold-first model (Rowan et al., 2000), in which the formation of the Frampton Fold predates the formation of the Green Knoll Diapir. The Frampton Fold was formed during two growth episodes driven by movement of the Louann Salt within the study area. The folding and faulting resulting from these growth episodes created a conduit through which the autochthonous Louann Salt was extruded to the sea floor during the Pliocene. Following a depositional episode consisting of the early sequences of the Mississippi …

Reservoir Analysis Of The Clinton Interval In Stark And Summit Counties, Ohio, Dominick Andrew Wytovich

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The characteristics of a sandstone reservoir of Silurian age (the "Clinton interval") were analyzed using 382 geophysical well logs from the Dominion Gas storage field located in Stark and Summit Counties, Ohio. These sandstones have long been identified by the informal drillers' terms, White, Red, and Stray Clinton. Gamma ray logs were used to analyze the distribution of net stand thickness and its relation to initial production through the construction of isopach and net sand isolith maps. I constructed eight cross sections to identify and correlate the tops of three prominent sandstones and two marine flooding surfaces to evaluate reservoir …

Functional Identification Of Microorganisms That Transform Mercury In Marine Sediments, Lisa Romas

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Monomethylmercury (MMHg) is the toxic form of mercury (Hg) that biomagnifies in food webs, and human exposure to MMHg occurs predominantly via consumption of fish. The primary source of MMHg to the marine environment is thought to be in situ sedimentary production by benthic microorganisms, namely sulfate-reducing bacteria (SRB). I collected sediments from the continental shelf (stations 2 and 6) and slope (station 9) of the NW Atlantic Ocean, and amended them with various inhibitor and promoter solutions to target specific functional groups capable of Hg transformations. I also added stable enriched Hg isotopes to quantify gross Hg methylation and …

Mercury Speciation In Temperate Tree Foliage, Melissa Danielle Tabatchnick

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Cycling of mercury (Hg) and monomethylmercury (MMHg) in forest ecosystems can affect exposures of terrestrial and aquatic wildlife within the watershed. Litterfall has been posited to be a major source of MMHg and total Hg to the forest floor; however, the origin of MMHg associated with tree foliage is largely unknown. I tested the hypothesis that leaf MMHg would be controlled by root uptake and thereby proportional to levels in soil. Fresh leaves and associated soil samples were sampled from nine tree species (deciduous and coniferous) at 30 locations spanning a 1145 km2 area in southwest Ohio, a region presumed …

Trace Metal Fluxes In Southwest Ohio Watersheds, Avani Naik

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Land-use and watershed characteristics affect the cycling and transport of trace metals in rivers. I investigated the influence of different land uses and water physicochemistry on loadings, partitioning, and speciation of Hg, Zn, Cr, Ni, V, Cd, Cu, and Pb in three contrasting watersheds near the Dayton, Ohio metropolitan area over a 13-month period; Wolf Creek (urban/residential), Holes Creek (urban/residential), and Little Miami River (agricultural). Metal concentrations were related positively to discharge in each stream. Dissolved organic ligands appear to influence trace-metal partitioning between filtered and particle phases, however, particle-associated metals were dominant in each site. Total Hg concentrations and …

Conversion Of Carbon Dioxide And Hydrogen Into Methane In Bench-Scale Microcosms And Packed Column Reactors, Brian Alexander Congiu

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Escalating energy demands, rising costs, and increasing awareness of the environmental impacts of current energy sources have created an immediate need for sustainable, alternative energy resources and innovative fuel technologies. It is believed that a potential carbon-neutral fuel source can be generated through the microbial production of methane gas by methanogenic archaea. Carbon dioxide captured from the atmosphere and renewable production of hydrogen can be used to support these microorganisms for the large-scale production of methane. Bench-scale investigations involving 160 mL serum bottle batch experiments and two 11L packed-column reactors were conducted to evaluate the feasibility and efficiency of microbial …

Transport Through Georeservoirs: Spatial Entropy In Hydraulic Properties, And Temporal Entropy In Residence Time Distributions, Lumeng Huang

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The general principle of maximum entropy can be used to guide the construction of flow and transport models parameters when are uncertain. The principle states that the model which maximizes the entropy should be chosen so that the full multiplicity or uncertainty is represented in the model outcomes.

In models for flow and transport through georeservoirs, the principle would commonly be applicable to the uncertainty in the model outcome for the time of travel through the system, in order to represent the full range of multiplicity in the distribution of residence times. Importantly, the model which maximizes the entropy in …

Measuring The Permeability Of Open-Framework Gravel, James Thomas Ferreira Jr.

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Open-framework gravel has permeability, k, above the measurement range of most conventional constant-head permeameters used in laboratories. Here I addressed the challenge of measuring such high k by using a permeameter long enough that the differences in head across it were on the order of 10-3 m and therefore measurable. I collected data over the range from linear-laminar flow to non-linear, non-Darcian flow. In doing so, I verified that k was measured under Darcian flow. I measured k between 4,000 and 100,000 Darcies among experiments using different sediments.

Porosity And Permeability In Ternary Sediment Mixtures, Jason Dennis Esselburn

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Porosity and permeability were measured in mixtures of fine, medium, and coarse sand, where the volume fraction of each of the three components was systematically varied. The porosity varies non-linearly with the volume fractions, and can be modeled with a piecewise-linear approach. The permeability also varies non-linearly with the volume fractions. Permeability can be modeled with the Kozeny-Carman equation using a recursive approach for computing the representative grain size from those of the components in the mixture.

A Morphometric Analysis Of The Highly Variable Clypeasteroid, Periarchus Lyelli, Lauren Elizabeth Williamson

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The Late Eocene echinoid, Periarchus lyelli (Conrad, 1834), known for its wide geographic range, high abundance, and specific stratigraphic range, is an ideal example of a guide fossil. However, due to its highly variable test morphology, many have questioned if, in fact, this sand dollar is actually two or three distinct species that have been misclassified. A preliminary study on this subject has been performed on specimens from Mississippi, North Carolina and South Carolina (Williamson, 2006), showing significant separation in test shapes. Continuing previous research, this study analyzes the test shapes of P. lyelli over its entire North American geographic …

Bench-Scale Conversion Of Carbon Dioxide To A Hydrocarbon Fuel, Melissa L. Kennedy

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There is a growing concern about the effects of global warming that many believe is anthropogenically caused. As such, scientists are trying to uncover a viable alternative fuel source and establish a way to reduce atmospheric carbon dioxide levels. A potential solution that addresses both of these aspects would be to capture atmospheric carbon dioxide and convert it into a natural gas, in particular methane, which could be used as an energy source. A laboratory-scale experiment using 6 160 mL microcosms (3 with anaerobic wetland soil and 3 relatively soil free) and 2 7.2 L bioreactors was conducted to learn …

Using Morphometrics, Phylogenetic Systematics And Parsimony Analysis To Gain Insight Into The Evolutionary Affinities Of The Calymenidae Trilobita, Alex J. Chestnut

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The most common trilobite in the Silurian carbonates of Ohio - especially the Springfield Dolomite - is a species that has been assigned to at least five genera over the past 100 years. This trilobite has been variously referred to as Calymene celebra, Apocalymene celebra, Flexicalymene celebra, Gravicalymene celebra, and Sthenarocalymene celebra. Reexamination of the species "Calymene" celebra through parsimony and morphometric analysis was conducted to properly place this calymenid species within the correct genus. What compounds the confusion is that the characters used to seperate the genera within the family Calymenidae, and therefore create the basis for the argument …

Hydrogeochemistry And Water Quality Of Echo Hills, Joel M. Kimball

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Ground water of the Echo Hills area in Clark County, Ohio was investigated for common water contaminants such as nitrate and coliform bacteria. Thirty-four water samples were collected from locations including private wells, streams and a spring. Nine of those samples were selected for nitrogen isotope analysis. Three locations were chosen for a tracer test. Additionally, well log data, historical water quality data, and GIS data were obtained from the Clark County Health Department in Springfield, Ohio. Results show that local agriculture likely has the greatest impact on ground water quality in Echo Hills especially the north-eastern portion, with local …

Percolation-Based Techniques For Upscaling The Hydraulic Conductivity Of Semi-Realistic Geological Media, Bilal Idriss

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I tested three schemes for "upscaling" the hydraulic conductivity (K) on aquifers with bimodal K distributions. This bimodality (e.g., sand and mud deposits) was intended to capture typical geological conditions. Results were tested with a numerical model. Upscaling techniques used were inspired by schemes interpolating between arithmetic and harmonic means, but are based on percolation theory: 1) Critical path analysis (CPA), 2) Percolation path analysis (PPA, or standard scaling), and a novel scaling approach. Models chosen were both spatially correlated and uncorrelated, with important differences in critical percolation probabilities, Pc. Volume fractions Ps and 1-Ps (with Ps = sand volume …

Geologic Mapping Of The Changgo Dome In Southern Tibet Using Aster Imagery, Andrew Paul Folfas

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Within the thick TSS, south of the Indus-Tsangpo Suture, a series of granitic intrusions and gneissic domes crop out along the NHA. These culminations are common features that are seen in orogenic belts; therefore, understanding the nature and development of these features is an integral part of this study and other collisional orogenic studies. Changgo Dome is a granitic dominated feature that is characterized by the presence of two spectrally similar Tertiary granites. This zone is nearly inaccessible for ground mapping, thus it is an ideal setting for the use of satellite imagery as a cartographic medium. In a previous …

Estimation Of Evapotranspiration Of Cottonwood Trees In The Cibola National Wildlife Refuge, Cibola, Arizona, Amity J. Jetton

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This study used sap flow measurements and satellite imagery to estimatewater use by cottonwood (Populus fremontii S. Wats. ssp) trees in an irrigated restoration plot at Cibola National Wildlife Refuge on the Lower Colorado River. Several thousand hectares of irrigated plots of this type are planned to improve riparian habitat on the river, hence it is important to know how much water the trees require. In this study, the ET rates for 20 Freemont cottonwood trees, from an 8 ha plot, were monitored over a 30-day period. ET rates were estimated by measuring sap flow through branches of the trees. …

The Impact Of Nutrient Availability And Algal Community On Carbon Isotope Fractionaion In Crystal Lake, Clark County, Ohio, April R. Wisebaker

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Crystal Lakes are a group of four interconnected lakes, located in southwestern Clark County, Ohio. Several studies have looked at separate geochemical and isotopic information at this location. However, no one has thoroughly studied the relationship between the algal community, geochemistry, and carbon isotope fractionation within Crystal Lake. The fractionation of carbon isotopes of dissolved inorganic carbonate is greatly affected by the process of photosynthesis; the amount of photosynthesis is affected by the amount of algae in the aquatic community; the amount of algae is affected by the available nutrients in system. Therefore, there should be a correlation between the …

Paleoenvironment And Lateral Extent Of An Exposed Carbonate Build-Up: Horry County, South Carolina, Lisa A. Raterink

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A carbonate build-up exposed in the Intracoastal Waterway in Horry County, South Carolina is estimated to be Pleistocene to Pliocene in age. The carbonate build-up discontinuously spans approximately 12 kilometers of the waterway. Prominent formations in the area consist of the Waccamaw and the Canepatch Formation. A distinct sand layer is present laterally between the build-up and the excavated waterway bank, which consists primarily of well preserved fossil molluscs and echinoderms.

Field observations show that the carbonate build-up is bluish-gray in color and composed of shell fragments, predominantly mollusc, in a mud matrix. Thin sections analyzed, using a petrographic microscope, …

Availability And Toxicity Of Nickel To Lotic Periphyton And Macroinvertebrates, Stephanie Marie Bessom

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There is a lack of information regarding the bioaccumulation and toxicity of nickel (Ni) to lotic ecosystems. The objective of this study was to investigate the source, uptake, and toxicity of Ni by periphyton and macroinvertebrates (Hyalella azteca and Daphnia magna) in simulated stream ecosystems that included sediment and water. Periphyton were exposed to two types of sediment, a low-organic sandy mixture and a high organic silt, treated with varying levels of Ni. After 96 h, Ni levels in overlying water and periphyton were related to those in sediments, although differences existed between sediment types. Tests with 64Ni added to …

Analysis And Interpretation Of 2d Seismic Data Over The Ancona Gas Storage Facility, Illinois, Using Petrel Visualization Software, Nilanjan Roy

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Intriguing features of the North American mid-continent are the widespread and prominent subhorizontal seismic reflectors that are thought to be associated with thick sequences of layered rocks beneath the Phanerozoic cover of the Illinois Basin. The present investigation was an effort to identify and interpret new structural features of the pre-Paleozoic crust at the Ancona Gas Storage field in north-central Illinois. A grid of existing seismic data was reprocessed using the technique of extended correlation.

The reprocessed data was then analyzed using Schlumberger's Petrel visualization software for seismic interpretation and reconstruction of the 2D and 3D crustal geometry. The reprocessing …

Degradation Of Chlorinated Ethenes In Mesocosms Simulating A Constructed Wetland, At Wpafb, Ohio, Dibyendu Mukherjee

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The main purpose of this research was to study the degradation of chlorinated ethenes in upwardflowing mesocosms, simulating a constructed wetland at Wright Patterson Air Force Base (WPAFB) in Dayton, Ohio. This research was intended to compare biogeochemical processes and PCE degradation occurring in the mesocosms and in the field site. This research also tries to look at the effects of vegetation and season on the degradation efficiency of the mesocosms. Twelve PVC column reactors were built within the greenhouse of Wright State University in September 2005 to simulate the hydraulic conditions of a constructed wetland at WPAFB. The columns …

Geological Mapping Of Orhon, Tariat, And Egiin Dawaa, Central Mongolia, Through The Interpretation Of Remote Sensing Data, Tara Alexandra Stolz

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Multi-spectral satellite data from the Advanced Spaceborn Thermal Emission and Reflection Radiometer (ASTER) and Landsat Thematic Mapper (TM) were used to make interpretations regarding the surface lithology and structure of the Tariat, Egiin Dawaa, and Orhon regions in Central Mongolia. These areas experienced widespread Cenozoic volcanism. This study mapped the locations and extents of the volcanic flows, located cinder cones and faults evident in the areas, and identified a possible exposure of the Mongolian granitic batholith in the Orhon area. ER Mapper, a geospatial imaging software, was used to generate and run algorithms. Image transforms and supervised classifications were used …

Investigating Nickel Flux And Toxicity In Clay Sediments With Batch And Stream Recirculating Flume Experiments, Christina Elizabeth Cloran

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Using batch and stream recirculating flume experiments to compare and contrast one clayey sediment (Warden Ditch) and two analytical grade clay minerals (montmorillonite and kaolinite), the dynamic interactions between two aquatic stressors (suspended solids and nickel) were explored. Aldrich humic acid was incorporated to demonstrate the mitigating effects of dissolved organic carbon (DOC) on Ni toxicity. The flux of Ni between compartments (dissolved and sorbed) was quantified as a partition/distribution coefficient. The USEPA test organism Daphnia magna (neonates, < 24 h) was utilized to evaluate toxicity in dynamic non-renewal, short-term bioassays. Generally, toxicity showed a linear relationship with turbidity level. Conversely, sorption coefficients were experiment specific, making them difficult to predict and assess. Clay functioned as an adsorbent, scavenging Ni. Results support the hypotheses that solids and metals act as stressors in streams, DOC attenuates the toxicity of Ni, and Ni fluxes quickly between system compartments.

Seasonal Variation In The Redox Zones And Biogeochemical Processes Within The Constructed Wetland, Yussuf Mohamud

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This research investigation focuses on the vertical distribution of dissolved inorganic species in the pore-water affected by redox processes and seasonal changes within a small constructed wetland located at the Wright-Patterson Air Force Base. This is a follow up study to an earlier investigation (Lach, 2004) at this site in 2003. Water samples were collected from influent, effluent and three layers of the constructed wetland through a network of nested piezometers in the vertical flow wetland from June 2005 to June 2006. Onsite analysis of temperature, pH and conductivity were carried out onsite. Major anions and cations were measured by …

Evidence Of A Pre-Mount Simon, Half-Graben In Greene County, Ohio By Reprocessing A Wright State University Seismic Line, John Sink

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The reprocessing of the WSU2002 seismic line indicates the presence of a Precambrian half-graben. Also observed through this reprocessing is the possible presence of Paleozoic structures. Although Paleozoic features have been interpreted, variations in glacial drift thickness evidenced by glacial drift maps also may have contributed to a lower quality of stacked section in comparison to other seismic lines. WSU2002 was originally processed by Lauren Geophysical. The Lauren processing resulted in an image that was of much lower quality than corresponding seismic lines. The Lauren Geophysical processed section revealed many horizontal Paleozoic reflections, with no prominent reflectors beneath the Paleozoic. …

Geophysical Reconnaissance Of Karst Features Associated With Sinkholes On The Antioch University Campus In Yellow Springs, Ohio: Western Area, Brent Matthew Zerkel

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Antioch University is located in Yellow Springs, OH. This study was conducted on the Antioch University Campus in the commons area and is concentrated on the area west of the easternmost sinkhole. The primary purpose of this study is to locate and identify buried anomalous karst features, such as joints and collapses that may be hazardous to nearby buildings on the Antioch University Campus. The secondary purposes of this study are to identify remaining features in the geophysical data that may be related to manmade structures, and to identify areas for future studies. It is known that an 8-inch steel …

Porosity And Permeability Of Bimodal Sediment Mixtures Using Natural Sediment, Peter M. Phillips

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Porosity and permeability are parameters that affect the flow of ground water in the subsurface and have significant implications on the modeling of fate and transport of contaminants. However, little has been done to quantitatively examine the effect on porosity and permeability of packing in bimodal mixtures of natural sediment. This study compares measurements of porosity and permeability on model bimodal sediment mixtures with predictions from petrophysical models. The main goal is to evaluate how well these petrophysical models predict porosity and permeability in bimodal mixtures of natural sediment. The effect of the volume fraction of fines on porosity and …