Physical Sciences and Mathematics Commons^™

Klimchouk’S Impact On The Development Of Speleogenetic Models For Castile Evaporites: West Texas And Southeastern New Mexico, Usa, Kevin W. Stafford

International Journal of Speleology

Due to the pioneering work of Alexander Klimchouk (2007), hypogene karst is now recognized as being complex and extensive throughout Permian strata of the greater Delaware Basin in West Texas and southeastern New Mexico (USA). Klimchouk heavily influenced our current understanding of hypogene speleogenesis in the Permian Ochoan Castile Formation where we now recognize diverse hypogene manifestations that include vertically-extensive breccia pipes, laterally-extensive blanket breccias, morphologically-varied caves, diagenetically-altered sulfates, and unique venting structures. Underlying Bell Canyon strata provide the transmissive zone for delivery and removal of solutionally aggressive fluids to the conformably overlying Castile evaporites. Current speleogenetic models indicate that …

Dispersion Of Artificial Tracers In Ventilated Caves, Claudio Pastore, Eric Weber, Frédéric Doumenc, Pierre-Yves Jeannin, Marc Lütscher

International Journal of Speleology

Artificial CO₂ was used as a tracer along ventilated karst conduits to infer airflow and investigate tracer dispersion. In the karst vadose zone, cave ventilation is an efficient mode of transport for heat, gases and aerosols and thus drives the spatial distribution of airborne particles. Modelling this airborne transport requires geometrical and physical parameters of the conduit system, including the cross-sectional areas, the airflow and average air speed, as well as the longitudinal dispersion coefficient which describes the spreading of a solute. Four gauging tests were carried out in one mine (artificial conduit) and two ventilated caves (natural conduits). …

Rates Of Diagenesis Of Tropical Insectivorous Bat Guano Accumulations: Implications For Potential Paleoenvironmental Reconstruction, Donald A. Mcfarlane, Joyce Lundberg

International Journal of Speleology

Cave guano deposits are increasingly being recognized as valuable repositories of paleo-climatic and paleo-environmental information. However, that value is constrained by rates of guano decomposition, and these rates have not been previously well-studied. Here we show that field and laboratory studies of deep insectivorous bat guano sequences in the caves of Borneo demonstrate the extreme dependence of decomposition rate on guano water content. Under tropical conditions, moist guanos exhibit decomposition coefficients (k) values of ~ 0.01, implying the loss of most of the organic content on decadal timescales. Under similar temperatures but drier conditions, k values drop to …

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág

International Journal of Speleology

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …

Climate Monitoring In The Caumont Cave And Quarry System (Northern France) Reveal Near Oxygen Isotopic Equilibrium Conditions For Carbonate Deposition, Ingrid Bejarano-Arias, Carole Nehme, Sebastian Breitenbach, Hanno Meyer, Sevasti Modestou, Damase Mouralis

International Journal of Speleology

The study of modern cave deposits forming under near isotopic equilibrium conditions can potentially help disentangle the processes influencing the oxygen isotope system and suitability of stalagmites as archives of past hydrological or thermal changes. We used cave monitoring to evaluate the impact of kinetic isotope fractionation and assess the conditions under which modern cave carbonates form in the Caumont cave and quarry system, located in Normandy, northwest France. Over 20 months, we collected climatological data, dripwater, and modern carbonate samples at 2–4-week intervals at three different stations inside the Caumont cave and quarry system. We find highly stable (10.4 …

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …

Determining The P-Wave Velocity Structure In The Near-Surface Of Nw Miami, Florida, Using Quarry Blasts, Elham Moslemi

USF Tampa Graduate Theses and Dissertations

The fact that Florida is an earthquake-free region has caused seismologists to pay less attention to it. Few earthquakes in this state mean it is not a usual practice to study the propagation of seismic waves. However, utilizing data from quarry blasts, we studied wave propagation in this region. The primary objective of the project is to investigate the near-surface P-wave velocity structure and factors that may affect it. We also analyzed the amplitude of signals versus distance and blast size. A network of up to 10 Raspberry Shake instruments around the NW Miami-Lakes mining area was deployed where four …

Examining Paleoshorelines In The Eastern Gulf Of Mexico: Insights On Sea Level History And Potential Areas Of Interest For Habitat Management, Catalina Rubiano

USF Tampa Graduate Theses and Dissertations

An inventory of multibeam bathymetry containing relict drowned and lithified paleoshorelines has been compiled and analyzed in the first ever shelf-wide investigation of paleo sea level indicators on the west Florida shelf (WFS). On the largest scale, the WFS is a wide and gently sloping terrain that is characterized by a carbonate-rich sediment regime. This framework coupled with the region’s tectonic stability provided a setting in which sea level changes since ~ 20 ka have been recorded to a remarkable degree of resolution in the form of paleoshorelines which formed at sea level and were subsequently drowned and preserved in …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Understanding Controls On Spring Hydrographs In An Eogenetic Karst Aquifer In North-Central Florida, Ryan Almeqhem

USF Tampa Graduate Theses and Dissertations

Florida has one of the largest karst aquifers in the United States, with a significant portion of its water resources originating from the eogenetic karst system in north central Florida. Despite the importance of this system, eogenetic karst still needs to be studied compared to telogenetic karst. The hydrological behavior of karst aquifers is complex, with numerous factors influencing the timing, magnitude, and shape of spring hydrographs. One hypothesis, by Florea and Vacher (2006), suggests that matrix permeability is the primary control of spring hydrographs in karst systems. However, this thesis challenges this hypothesis by presenting evidence that the recharge …

Book Review: Australian Caves And Karst Systems, John Webb, Susan White, Garry K. Smith, Jo De Waele

International Journal of Speleology

No abstract provided.

Seasonal Dynamics Of Karst Surface Dissolution Based On A Limestone Tables Experiment (Slovak Karst), Alena Gessert, Zdenko Hochmuth

International Journal of Speleology

Chemical denudation in karst is the basic process of karst relief formation. However, it is influenced by many factors of varying intensity that depend on the climatic conditions and characteristics of each given location. Based on measurable results of weight loss of limestone tablets, we monitored the intensity of chemical denudation in two areas of the Slovak Karst, Silica Plateau and Jasov Plateau that are situated in the most developed karst plateau region of Slovakia. Both experimental sites are similar in terms of geographical conditions, thus comparable between them. In each locality, we placed three sets of standardized tablets at …

Paleokarst Coastal Caves At Torricelle Hills (Lessini Mountains, Venetian Prealps, Italy), Guido Gonzato, Enrico Borghi, Roberto Chignola, Nereo Preto, Guido Rossi

International Journal of Speleology

This paper describes a set of paleokarst caves at Torricelle Hills near Verona (Southern Alps, Italy.) At this locality, erosional surfaces and paleokarst cavities show that sedimentation of late Paleogene neritic limestones was interrupted by subaerial exposure. Karst features developed during a phase of marine regression that started after the early Oligocene and ended in the mid Miocene. These caves were originally completely filled by iron oxides- and hydrated oxides-rich paleosol sediments (ochre) that, for centuries, have been mined for pigments. Mining activity emptied the caves, leaving the voids and related shapes mostly intact; as a result, the original morphologies …

An Attempt To Identify Source Areas Of Clastic Deposits From Selected Caves Of The Prokletije Mountains (Montenegro): A Mineralogical And U-Series Geochemistry Approach, Ditta Kicińska, Jacek Pawlak, Jacek Stienss

International Journal of Speleology

The Prokletije Mountains/Albanian Alps are the highest part of the Dinaric Mountains. Paradoxically, these mountains and their cave areas remain among the most enigmatic in Europe, having only recently become subjects of scientific research and cave exploration. This paper focuses on the Kolata and Greben massifs, where the highest, and thus the oldest, cave systems are located. Through the analysis of heavy mineral composition, the apatite-tourmaline index, and cluster analysis for mineralogical composition and uranium isotopic data, it becomes possible to identify the source areas for the cave clastic deposits. It also allow to distinguish multiple paleoflow directions, each corresponding …

Predictive Modeling Of Cave Entrance Locations: Relationships Between Surface And Subsurface Morphology, William Blitch, Adia R. Sovie, Benjamin W. Tobin

International Journal of Speleology

Cave entrances directly connect the surface and subsurface geomorphology in karst landscapes. Understanding the spatial distribution of these features can help identify areas on the landscape that are critical to flow in the karst groundwater system. Sinkholes and springs are major locations of inflow and outflow from the groundwater system, respectively, however not all sinkholes and springs are equally connected to the main conduit system. Predicting where on the landscape zones of high connectivity exist is a challenge because cave entrances are difficult to detect and imperfectly documented. Wildlife research has a similar issue of understanding the complexities of where …

Detection Of Subsidence In West-Central Florida Using Persistent Scatterer Interferometry And Near-Surface Geophysics, Tonian R. Robinson

USF Tampa Graduate Theses and Dissertations

This dissertation consists of three studies that employ Persistent Scatterer Interferometry (PSI, also known as PSInSAR) to better understand how subsidence in west-central Florida relates to underlying geological processes. In the first study, near-surface geophysical methods (Ground Penetrating Radar (GPR) and Electrical Resistivity (ERT)), terrestrial remote sensing applications (Light Detection and Ranging (LiDAR) and Structure from Motion (SfM)), and PSI were used to monitor the spatial and temporal behaviors of a suspected growing sinkhole in the Sandhill Boyscout Reservation, Hernando County, Florida. The survey area was located within and around a topographic low assumed to be the surface of the …

Flow Generation And Propagation From Headwater Wetlands To Downstream Waters, Leanne Marie Stepchinski

USF Tampa Graduate Theses and Dissertations

Headwater wetlands are connected to one another and to downstream waters by dynamic hydrologic flowpaths, functioning as integrated hydrologic networks at the watershed scale. Headwater wetlands perform a variety of hydrologic lag, sink, and source functions, including flow generation and propagation, thereby contributing to the natural flow regimes of downgradient waters. The functions of individual wetlands and their contributions to hydrologic connectivity and subsequently to the natural flow regime have been widely studied and are well understood. Comparatively, the functions and hydrologic connectivity within wetland complexes as a whole and their collective subsequent contributions to the natural flow regime of …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Applications Of Seismic And Geodetic Data To Earthquake Hazard Research, Mahsa Afra

USF Tampa Graduate Theses and Dissertations

Being a part of a seismically active zone, including large and crowded cities such asTehran, Qazvin and Semnan, Central Alborz experiences many local earthquakes. Knowl- edge of crustal velocity structure in this area is thus necessary considering its economical and political importance, a large concentration of population, and relatively poor construc- tion practice which increases the earthquake risks in this region. In second chapter of this thesis, we aim at obtaining the 3D crustal velocity structure of the Central Alborz region in northern Iran using local earthquake tomography. We also validate anomalies inferred from our velocity model using an independent …

Preliminary Data Of Potentially Hazardous Radon Concentrations In Modrič Cave (Croatia), Robert Lončarić, Vanja Radolić, Maša Surić, Igor Miklavčić, Matea Šatalić, Dalibor Paar, Lukrecija Obšivač

International Journal of Speleology

Instigated by relatively high cave-air CO₂ concentrations in Modrič Cave (Croatia) recorded for the purpose of speleothem-based paleoclimate research, we established preliminary monitoring of radon (²²²Rn) concentrations within the cave for a 4.5-year period (2018–2022). As radioactive geogenic gas, radon, which often correlates with cave-air CO₂ concentrations, presents a potential health hazard in cases of longer exposure time in high concentration conditions. Since the Modrič Cave is open to tourists and long-term scientific research has been performed within, a safety assessment for radon concentrations was essential. The integrated measurements of radon concentrations were performed by passive …

4d Flow Pattern Of The Longest Cave In The Eastern Alps (Schönberg-Höhlensystem, Totes Gebirge), Lukas Plan, Eva Kaminsky, Pauline Oberender, Clemens Tenreiter, Maximilian Wimmer

International Journal of Speleology

The Schönberg-Höhlensystem (SBH) is not only the longest cave system in the Eastern Alps (length 156 km, depth 1061 m), but a significant proportion of the passages have developed on or just below two surfaces that dip 1.7° to the NE. These so-called "speleogenetic phases" are rarely developed in caves of the Northern Calcareous Alps and have not yet been confirmed by detailed morphological mapping. Furthermore, the deep parts of the cave offer the possibility to study the active epiphreatic zone for a distance of 1.6 km. Detailed morphological mapping shows that the main level at about 1500 m a.s.l. …

A Seismic Investigation Of Uturuncu Volcano And The Lazufre Volcanic Complex, Heather L. Mcfarlin

USF Tampa Graduate Theses and Dissertations

The following dissertation is a study of three seismological techniques used to determine the geophysical properties of two large, inflating magma bodies in the upper crust in South America: one under Uturuncu volcano and one beneath Lastarria and Cordon del Azufre volcanoes. First, I use the method of teleseismic receiver functions to image the top and bottom of the magma body beneath Uturuncu volcano. Depths to the top of this body vary between 6 and 12 km below sea level, while depths to the bottom vary between 13 and 22 km below sea level, with the thickness ranging from 6 …

Lithium And Lithium Isotope Behavior During High Temperature Solid/Fluid Exchanges: Examples From Iceland And The Izu-Bonin Forearc, Alex Maruszczak

USF Tampa Graduate Theses and Dissertations

The development of a method for lithium isotopic measurement was developed using a quadrupole, single-collector ICP-MS. Measured precision was ±1.00‰ 2σ over a 15-month period based on measurements of international rock standards. A 1-hour leach using cold, HCl was sufficient to remove alteration-related Li in minimally to moderately altered seafloor basalts. Measurements on the Holocene ages lavas from the neovolcanic zones of Iceland suggest no systematic Li isotopic variability among the differing Icelandic sources. Felsic samples from Hekla and Pumice contain elevated Li contents of >18ug/g while the tholeiitic and alkaline basalts are <8ug/g Li. Most of the island lies around MORB values of ~+3 to +5‰ with the exception of Western Volcanic Zone samples that show evidence for seawater inputs. The RN-17 drillcore, which penetrates >3000m through a hydrothermal system in the …

Land Use/Land Cover Uncertainty Analysis Using Hydrological Modeling In The Northern Watershed Of Lake Okeechobee, Andres Lora Santos

USF Tampa Graduate Theses and Dissertations

Over the past 150 years, Florida has undergone a major land-form transformation, transitioning from a natural to a primarily built environment. The state's population has grown exponentially, from less than 50,000 residents in the 1850s to approximately 22 million residents today. This population growth has led to significant changes in land use, including urbanization, mining, and agriculture. This trend is expected to continue, with projections indicating an increase in urbanization across the state. 2070 land use/land cover projections were used as input for the Watershed Assessment Model (WAM) to analyze the potential impact of these changes on flow, total nitrogen …

City Of Tampa Tree Canopy And Urban Forest Analysis 2021, Shawn M. Landry, Andrew K. Koeser, Rebecca Zarger, Kira Rib, Allyson Salisbury, Robert J. Northrop, Michael G. Andreu, Allison Bednar, Zach Freeman

School of Geosciences Faculty and Staff Publications

This report summarizes the fourth tree canopy and urban forest analysis conducted for the City of Tampa and represents the year 2021. The City of Tampa tree ordinance (Ord. No. 2006-74, § 9, 3-23-06) requires an assessment of the tree canopy and urban forest every five years (beginning in 20061). In an effort to reduce concerns over bias, this work has been conducted by a collaborative team from the University of South Florida and the University of Florida following established USDA Forest Service protocols.

This report provides detailed information about the current size, composition, health, and distribution of Tampa’s urban …

Mg Records Of Two Stalagmites From B7-Cave (Northwest Germany) Indicating Long-Term Precipitation Changes During Early To Mid-Holocene, Dana F. C. Riechelmann, Klaus Peter Jochum, Detlev K. Richter, Denis Scholz

International Journal of Speleology

Two stalagmites from B7-Cave in northwest Germany, which is part of the same cave system as the intensively studied Bunker Cave, were re-dated by multi collector inductively coupled plasma mass spectrometry (MC-ICPMS) ²³⁰Th/U-dating. Furthermore, the concentration of Mg, Sr, Ba, P, Y, Zn, and Al were determined at high-resolution by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Stalagmite B7-1 grew from 10.8 to 5.8 ka BP. Stalagmite B7-7 grew during three growth phases from 11.0 to 6.2, 3.13 to 2.86 (late Bronze Age), and 1.27 to 1.15 ka BP (early Medieval Period). Aluminium is a proxy for detrital …

Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom

International Journal of Speleology

Cryogenic cave carbonates have been described from several formerly or presently glaciated karst caves. In most of these occurrences, they precipitated as loose grains or aggregates with various morphologies and sizes. Here, we report on a new speleothem type (cryogenic ridges) identified in Sohodoalele Mici Cave (SW Romania) within a large chamber near the entrance shaft. This study was motivated by the presence of a network of calcite ridges over the stalactites’ surface and by the observation that during winter, these speleothems are covered by a thin ice layer. The higher δ¹⁸O (−3.5 to –1‰) and …

Using The 3-30-300 Rule To Assess Urban Forest Access And Preferences In Florida (United States), Andrew Koeser, Richard Hauer, Michael Andreu, Robert Northrop, Mysha Clarke, John Diaz, Deborah Hilbert, Cecil Konijnendijk, Shawn Landry, Grant Thompson, Rebecca K. Zarger

School of Geosciences Faculty and Staff Publications

Background: Public engagement is needed to make sure urban forestry management efforts align with the values of the public being served. Noting this, we determined current and desired urban forest access of Florida (United States) residents using the criteria from the 3-30-300 rule (i.e., 3 trees visible from home, 30% canopy in neighborhood, and a green space within 300 meters of home). Methods: A survey of 1,716 Florida residents was conducted to assess canopy coverage and green space access. Respondents were then asked if this level of urban forest access was sufficient for their needs. We also asked their perceptions …

Reorganizing The Waterscape: Asymmetric Loss Of Wetlands And Gain Of Artificial Water Features In A Mixed-Use Watershed, Mark Rains, Kurt Schmidt, Shawn Landry, William Kleindl, Kai Rains

School of Geosciences Faculty and Staff Publications

Between the 1780 and 1980s, more than half of the wetlands in the conterminous US were lost. As wetlands have been lost, numerous artificial water features (AWFs), such as stormwater retention ponds, golf course water features, and reservoirs, have been constructed. We contrasted the loss of wetland area and perimeter to the gain of AWF area and perimeter and further explored how this transformation has altered the spatial characteristics of the waterscape. We conducted this analysis in the Tampa Bay Watershed, a large coastal watershed that lost 33% of its wetland area between the 1950s-2007. Trends have been towards fewer, …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …