Physical Sciences and Mathematics Commons^™

Quantum Circuit Optimization Leveraging Multi-Qubit Exchange Interactions In Spin Qubits, Miguel Gonzalo Rodriguez

Open Access Theses & Dissertations

This thesis looks into how multi-qubit exchange interactions can be used to improve quantumcircuits in semiconductor quantum devices. Pairwise interactions between qubits are a common tenet of traditional quantum computing paradigms, although they can impose complexity and depth constraints on circuits. In order to improve the efficiency and scalability of quantum circuits, this research explores the theoretical underpinnings and practical uses of multi-qubit interactions. A thorough theoretical framework is formulated, outlining the mathematical equivalence of a unitary matrix representing interactions between multiple qubits. We obtain the timeevolution operator by analyzing the Hamiltonian of three spin-1/2 particles. A number of quantum …

Novel Physics In Unconventional Superconductors, Adil Amin

Theses and Dissertations

In this work, we consider the interplay of different magnetic orders and superconductivity.We consider both phenomenological and microscopic models to capture these interactions. The models are built using group theoretic arguments to ensure the constraints provided by the crystal symmetry are satisfied. We first consider a phenomenological theory for two transitions in superfluid 3He which involves coupling superfluidity and spin fluctuations through an approach called spin fluctuation feedback effect. We then apply this phenomenological approach to UPt3, PrOs4Sb12 and U1−xThxBe13 to obtain a common underlying mechanism for two superconducting transitions. We then consider odd-parity multipolar antiferromagnetic order i.e. Kramers’ degenerate …

Investigations Of Sulfurized Polymers For Their Use In Lithium-Sulfur Cells, Alan M. Rowland

All Theses

With the invention of the Lithium-Ion cell in the latter half of the 20th century, there has been a continued endeavor for innovation in compact energy-storage. Combined with the ever-growing need to move away from fossil fuels, electrochemical energy storage has seen a myriad of research projects in the pursuit of finding the ‘beyond-lithium’ cell. One of these projects that I personally assisted with was lithium-sulfur cells, which allow for a significantly greater energy storage capacity when compared to lithium-ion cells. In investigating a popular cathode in lithium-sulfur cells, sulfurized polyacrylonitrile (SPAN), it was hinted that there may be more …

Tuning Electronic Transport And Magnetic Properties Of Layered Magnetic Materials, Md Rafique Un Nabi

Graduate Theses and Dissertations

Two-dimensional magnetic materials (2DMMs) have gained significant interest due to their potential for novel physical phenomena and device applications. Mn2-xZnxSb, with its tunable magnetic properties and stable tetragonal layered structure, offers a rich platform for exploring these phenomena. The introduction of Zn into the Mn2Sb lattice efficiently tunes magnetic and electronic properties, making it a compelling candidate for high-performance spintronic devices. With this motivation, we synthesized Mn2-xZnxSb (0 ≤ x ≤ 1) single crystals using a flux method. Mn2Sb exhibits ferrimagnetic order below 550 K with antiparallel spins aligned along the c-axis for two Mn magnetic sublattice Mn(I) and Mn(II), …

Quantum Classical Algorithm For Solving The Hubbard Model Via Dynamical Mean-Field Theory, Anshumitra Baul

LSU Doctoral Dissertations

Modeling many-body quantum systems is widely regarded as one of the most promising applications for near-term noisy quantum computers. However, in the near term, system size limitation will remain a severe barrier for applications in materials science or strongly correlated systems. A promising avenue of research is to combine many-body physics with machine learning for the classification of distinct phases. I present a workflow that synergizes quantum computing, many-body theory, and quantum machine learning (QML) for studying strongly correlated systems. In particular, it can capture a putative quantum phase transition of the stereotypical strongly correlated system, the Hubbard model. Following …

Spin And Charge Transport In Metallic Ferrimagnets And Disordered Magnetic Oxides, Leopoldo A. Hernandez

Electronic Theses and Dissertations

Recent efforts have been exploring the use of thin film synthetic ferrimagnets and disordered magnetic oxides for applications in spintronic devices. Due to the antiferromagnetic exchange interaction, ferrimagnetic materials offer the ultrafast dynamics of the antiferromagnetic exchange, with a net magnetization that can be influenced externally. With two, or more, competing ferromagnet sublattices, interesting properties arise that depend on the final magnetic landscape after growth of the material and it’s inherent magnetic anisotropy energies. Properties such as magnetic compensation temperatures, and perpendicular magnetic anisotropy are attractive for applications in spintronic memory and logic devices, some already being implemented in MRAM …

Quantics Tensor Trains: The Study Of A Continuous Lattice Model And Beyond, Aleix Bou Comas

Dissertations, Theses, and Capstone Projects

This four-chapter dissertation studies the efficient discretization of continuous variable functions with tensor train representation. The first chapter describes all the methodology used to discretize functions and store them efficiently. In this section, the algorithm tensor renormalization group is explained for self-containment purposes. The second chapter centers around the XY model. Quantics tensor trains are used to describe the transfer matrix of the model and compute one and two-dimensional quantities. The one dimensional magnitudes are compared to analytical results with an agreement close to machine precision. As for two dimensions, the analytical results cannot be computed. However, the critical temperature …

Aspects Of Parity Breaking In Classical And Quantum Fluids, Dylan J. Reynolds

Dissertations, Theses, and Capstone Projects

Parity-breaking is ubiquitous across many scales of physics, from the rotation of galaxies at the largest of scales, to the cyclotron orbits of electrons at the microscopic scale. In describing the collective dynamics of many particle systems, parity breaking effects typically originate from some form of chirality, such as angular momentum, at the level of the constituent particles. External forces can also induce chiral motion, with the primary examples being the Lorentz and Coriolis forces.

The effects of parity breaking are perhaps most strikingly seen in active matter, systems of complex particles that tend to convert energy into some directed …

Defects And Deformation In Passive And Active Structural Glasses, Julia Ann Giannini

Dissertations - ALL

Glasses and disordered granular media represent a class of materials that are quite familiar to us, from the glass in windows and phone screens, to piles of fruits, grains, and sand. Further, living and active systems such as cellular tissues, collections of robots, and even human crowds behave as disordered solids when they are gathered at high enough densities. Despite their ubiquity, there are still many behaviors of these amorphous systems that lack a full understanding. Contrasting crystalline solids, the thermodynamic, vibrational, energetic, and mechanical properties of glasses are not well-characterized by solid state theory. In the case of active …

Encapsulated 2d Materials And The Potential For 1d Electrical Contacts, Sarah Wittenburg

Physics Undergraduate Honors Theses

The utilization of two-dimensional materials and heterostructures, particularly graphene and hexagonal boron nitride, have garnered significant attention in the realm of nanoelectronics due to their unique properties and versatile functionalities. This study focuses on the synthesis and fabrication processes of monolayer graphene encapsulated between layers of hBN, aiming to explore the potential of these heterostructures for various electronic applications. The encapsulation of graphene within hBN layers not only enhances device performance but also shields graphene from environmental contaminants, ensuring long-term stability. Experimental techniques, including mechanical exfoliation and stamp-assisted transfer, are employed to construct three-layer stacks comprising hBN-graphene-hBN. The fabrication process …

Manipulation Of The Magnetic Properties Of Van Der Waals Materials Through External Stimuli, Luis Martinez

Open Access Theses & Dissertations

A new revolutionary application dependent on the electron spin to carry information with greater efficiency in data storage, transfer, and processing, will rely heavily on 2D magnets and the ability to effectively control their electron spins and engineer their properties. Previously, magnetic thin films were heavily studied to achieve this goal, however, these materials came with pitfalls and lacked naturally occurring 2D magnetism. The recent discovery of intrinsic magnetism in few-layered van der Waals (vdW) magnets has inspired researchers to extensively study them because of the feasibility to exfoliate them down to a monolayer. Due to this dimensionality factor, vdW …

Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat

Electronic Theses and Dissertations

This research work reports investigations of structural and physical properties of novel magnetic and non-magnetic 2D alloys. Three techniques were utilized in this investigation: Angle-resolved polarized Raman spectroscopy (ARPRS), Electrical &Thermoelectric power measurements, Magneto-optic Kerr effect (MOKE) spectroscopy. ARPRS and MOKE experiments were constructed during the course of this work. ARPRS was used to study the anisotropy of 2-dimensional black-arsenic phosphors (b-AsxP1-x) as a function of arsenic concentration (x). It was observed experimentally that all Raman modes of the studied samples with x=0, 0.4, 0.8 exhibit polarization dependence. More interestingly, the polarization dependence of Raman modes due to the vibrations …

Mechanical And Thermal Measurement Techniques For Crystalline-Core/Crystalline-Clad Optical Fibers, Evan Watkins

All Theses

Optical fiber laser systems offer advantages such as high optical gain, efficient cooling, and the production of high-quality optical beams. Fiber lasers are characterized by their unique core-cladding structure, providing optical benefits and mechanical properties that impact their performance. Interests in materials such as yttrium aluminum garnets (YAG) and lutetium oxide (Lu2O3 also lutetia) as laser mediums are due to their high average power capabilities, but thermal management remains a challenge. This thesis discusses the choice of ytterbium (Yb3+) as a dopant in YAG and lutetia, exploring its electronic structure and relevance to thermal properties. The thesis focuses on the …

Investigate The Importance Of Local Magnetic Moment And Magnetic Interaction In Superconducting Fese Monolayer Using Density Functional Calculations, Sudip Pokharel

Graduate Theses and Dissertations

In this dissertation, we present two projects to study superconducting FeSe monolayer using first-principles density functional calculations. Monolayer FeSe/SrTiO3 system has very different properties as compared to its bulk counterpart in terms of critical superconducting temperature, Fermi surface topology and antiferromagnetic (AFM) stability. For FeSe monolayer, local magnetic moment (LMM) and AFM fluctuation are closely linked to superconductivity. However, LMM is not studied enough for FeSe monolayer. For FeSe/SrTiO3 system, the substrate SrTiO3 constrains the in-plane lattice constant for FeSe and also plays a crucial role in the onset and enhancement of superconductivity by providing charge transfer. The height of …

Luminescence And Structural Properties Of Silicon-Germanium Quantum Structures Fabricated By Ion Implantation, Matheus Coelho Adam

Electronic Thesis and Dissertation Repository

The advancement of semiconductor materials has played a crucial role in driving positive technological breakthroughs that impact humanity in numerous ways. The presence of defects significantly alters the physical properties of semiconductors, making their analysis essential in the fabrication of semiconductor devices. I presented a new method to quantify surface and near-surface defects in single crystal semiconductors. Epitaxially-grown silicon was measured by low energy electron diffraction (LEED) to obtain the surface Debye temperature (θ_D). The results showed the surface θ_D of bulk Si (001), 1.0 μm, and 0.6 μm Si on sapphire of 333 K, 299 K, …

Interfacial Magnetism And Anisotropy In Dirac And Weyl Semimetals, Noah Schulz

USF Tampa Graduate Theses and Dissertations

Semimetals have gained intense interest recently due to their exotic magnetic and electronic properties. One of the most widely studied semimetals is graphene, a Dirac semimetal. The utilization of graphene in devices and sensors requires interfacing it with other materials, which may induce potentially strong interfacial effects. Furthermore, graphene alone does not possess magnetic order. Studying the interfacial effects between graphene and magnetic materials is therefore of great importance in the application of graphene to meet modern technological needs. Furthermore, by understanding the fundamental interfacial physics between graphene and magnetic materials, new properties can be unlocked, broadening the possible applications …

The Interplay Of Spin, Charge, And Heat: From Metal/Insulator Heterostructures To Perovskite Bilayers, Sam M. Bleser

Electronic Theses and Dissertations

In this dissertation begin with an investigation of non-local spin transport in an amorphous germanium (a-Ge) sample via the inverse spin Hall effect (ISHE). In that study we show that commonly used techniques such as differential conductance and delta mode of a paired Keithley 6221/2182a for non-local resistance measurements can lead to false indicators of spin transport. Next, we turn out attention to a thickness dependent study in thermally-evaporated chromium (Cr) thin films on a bulk polycrystalline yttrium-iron-garnet (YIG) substrate. This project analyzed the spin transport in the Cr films versus thickness via the longitudinal spin Seebeck effect (LSSE). This …

Thermal, Electrical, And Spin Transport: Encompassing Low-Damping Ferromagnets And Antiferromagnetic/Ferromagnetic Heterostructures, Matthew Ryan Natale

Electronic Theses and Dissertations

Continuing technological advancements bring forth escalating challenges in global energy consumption and subsequent power dissipation, posing significant economic and environmental concerns. In response to these difficulties, the fields of thermoelectrics, spintronics, and spincaloritronics emerge as contemporary solutions, each presenting unique advantages. Thermoelectric devices, based on the Seebeck effect, other a passive, carbon-free energy generating solution from waste heat. Although current thermoelectric technology encounters hurdles in achieving optimal efficiencies without intricate designs or complex materials engineering, recently research into low-damping metallic ferromagnetic thin films have provided a new method to enhance spin wave lifetimes, thus contributing to thermoelectric voltage improvements. As …

Probing Central Spin Decoherence Dynamics Of Electronic Point Defects In Diamond And Silicon, Ethan Que Williams

Dartmouth College Ph.D Dissertations

Electron spins of point defects in diamond and silicon can exhibit long coherence times, making them attractive platforms for the physical implementation of qubits for quantum sensing and quantum computing. To realize these technologies, it is essential to understand the mechanisms that limit their coherence. Decoherence of these systems is well described by the central spin model, wherein the central electron spin weakly interacts with numerous electron and nuclear spins in its environment. The dynamics of the resultant dephasing can be probed with pulse electron paramagnetic resonance (pEPR) experiments.

Using a 2.5 GHz pEPR spectrometer built in-house, we performed multi-pulse …

Exciton Dynamics, Interaction, And Transport In Monolayers Of Transition Metal Dichalcogenides, Saroj Chand

Dissertations, Theses, and Capstone Projects

Monolayers Transition metal dichalcogenides (TMDs) have attracted much attention in recent years due to their promising optical and electronic properties for applications in optoelectronic devices. The rich multivalley band structure and sizable spin-orbit coupling in monolayer TMDs result in several optically bright and dark excitonic states with different spin and valley configurations. In the proposed works, we have developed experimental techniques and theoretical models to study the dynamics, interactions, and transport of both dark and bright excitons.

In W-based monolayers of TMDs, the momentum dark exciton cannot typically recombine optically, but they represent the lowest excitonic state of the system …

Non-Hermitian Physics Achieved Via Non-Local Gilbert Damping, Trevor Joshua Macintosh

Electronic Theses and Dissertations

In this thesis, we study a simple model for a ferromagnet starting with Heisenberg exchange interaction including the effects of dissipation. Gilbert damping is consid- ered and generalized from an on-site term to include non-local damping interactions between neighbouring spins. The strength of the damping interaction between neigh- bours can be tuned individually to provide the freedom to change the parameters of the system and explore the range of possible non-Hermitian behaviours. We consider the example of a honeycomb lattice ferromagnet featuring Dirac cones and two sub- lattices and analyse the resulting spectra and eigenstates. Under periodic boundary conditions, we …

Theory Of Ultrafast Spin Crossover In Divalent Iron Systems, William Baker

Graduate Research Theses & Dissertations

A theory to account for the ultrafast, i.e. femtosecond timescale, singlet to quintet spin crossover in divalent iron molecules is developed. The model considers an iron cluster with ligands extending in all 6 cardinal directions initially at rest in a low spin singlet ground state. An optical excitation excites an electron from the d orbitals to the ligands, changing the system from the metal centered (MC) singlet state to the metal to ligand charge transfer (MLCT) singlet state. Experimentally, it is known that the system eventually relaxes into the quintet MC state, but there are no satisfactory explanations that model …

Photoluminescence Of Beryllium-Related Defects In Gallium Nitride, Mykhailo Vorobiov, Mykhailo Vorobiov

Theses and Dissertations

This study explores the potential of beryllium (Be) as an alternative dopant to magnesium (Mg) for achieving higher hole concentrations in gallium nitride (GaN). Despite Mg prominence as an acceptor in optoelectronic and high-power devices, its deep acceptor level at 0.22 eV above the valence band limits its effectiveness. By examining Be, this research aims to pave the way to overcoming these limitations and extend the findings to aluminum nitride and aluminum gallium nitride (AlGaN) alloy. Key contributions of this work include. i)Identification of three Be-related luminescence bands in GaN through photoluminescence spectroscopy, improving the understanding needed for further material …

Outpatient Fall Prevention In Ambulatory Adults 65 Years Old And Over, Dorothy L. Osborne-White

Doctor of Nursing Practice (DNP) Scholarly Projects

Abstract

Background: In the United States (U.S.), falls are the leading cause of injury among adults 65 and over, resulting in 36 million falls yearly (Moreland et al., 2020). According to the Centers for Disease Control and Prevention (CDC, 2023), one in four older adults experiences a fall each year. Falls are the world's second most prominent cause of accidental deaths (World Health Organization [WHO], 2021). Falls are the leading cause of both fatal and non-fatal injuries among older adults (Moreland et al., 2020).

Methods: A quality improvement project that included a fall bundle was implemented in a primary clinic. …

Doubly Rotating Coordinates: Wave Functions In Magnetic Resonance Problems, Sunghyun Kim

Graduate Thesis and Dissertation 2023-2024

The nuclear spin response to a rotating field H has been theoretically investigated from the 1930s to the 1950s. Building upon Majorana's probability theory, the behavior of spin 1/2 is well-illustrated in the joint review by Rabi, Ramsey, andSchwinger, and their spin wave function ψ is succinctly restated by Gottfried: ψ(t) = e^-iI_zωt/ℏe^{-i[I_z(ω₀-ω)+I_xω₁]t/ℏ}ψ(0).

However, the complexity involved in evaluating the wave function ψ in terms of probability amplitudes C_m attributed to the noncommutative nature of spin operators [I_x, I …

Complexity, Entanglement And Codes In Quantum Field Theory, Nikolaos Angelinos

Theses and Dissertations--Physics and Astronomy

In recent decades many deep connections between quantum information theory and quantum field theory have been unearthed. In this dissertation we study topics in high-energy physics through the lens of quantum information: 1) We develop connections between error-correcting codes and Narain conformal field theories. 2) We study the entanglement entropy of one-dimensional fermionic chains with long-range interactions. 3) We study the temperature dependence of Lanczos coefficients and Krylov complexity.

Design And Performance Of Superconducting Switches For Nanowire Detectors In Magnetic Fields, Timothy James Draher

Graduate Research Theses & Dissertations

Superconducting nanowire devices fit a broad spectrum of applications, including particle detection and quantum computing, and their expanding use across various fields highlights their role in the hybridization of superconducting and conventional semiconductor electronics. Despite their potential, the low signal output of these devices raises challenges in scalability and integration, particularly in applications for nuclear and high-energy physics, where resilience in magnetic fields is becoming a critical optimization factor. The superconducting nanowire cryotron (nTron) addresses these issues by providing operational gain and logic switching in superconducting nanowire circuits, demonstrating adaptability to multiple materials. This dissertation focuses on modifying the conventional …

Exploring Crystal Polymorphism In Additive-Assisted Chemical Vapor-Deposited Transition Metal Chalcogenides And Oxides, Lawrence Kirimi Mubwika

Graduate Theses, Dissertations, and Problem Reports

Crystal polymorphism is a phenomenon in which compounds with the same chemical formula can be crystallized into different crystal structures. This phenomenon can be observed in elemental materials, such as diamond and graphite, as well as in compounds, such as the trigonal (1H) or octahedral (1T) prismatic MoS₂. Crystals can also exhibit polytypism by stacking different polymorphs in a certain order, with the stacking sequence determining the variation between polytypes. Although all polymorphs and polytypes have the same chemical composition, each polymorph and polytype possesses unique electronic and physical properties.

This study explores the additive-assisted chemical vapor deposition …

Dynamic Exchange-Correlation Functional For Bandgap Optimization: Reparametrization And Machine Learning, Viviana Faride Dovale Farelo

Graduate Theses, Dissertations, and Problem Reports

This dissertation explores predicting the physical properties of solids using first-principles methods, with a focus on Density Functional Theory (DFT). DFT uses the electronic density within a material to predict its properties, simplifying the treatment of electron-electron interactions and allowing the study of realistic systems with a balanced treatment between accuracy and computational efficiency. Additionally, machine learning (ML) is employed to create correlations between some physical properties of solids and other properties or parameters that are more difficult to calculate.

The main problem addressed in this study is adjusting the parameters in the Strongly Constrained and Appropriately Normed (SCAN) semilocal …

Synthesis And Characterization Of Quantum Materials, Yunsheng Qiu

Doctoral Dissertations

"In this study, attempts were made to grow quantum materials that have recently undergone a profound change of perspective. These materials are involved in intricate macroscopic properties rooted in the subtle nature of quantum physics. To explore our understanding of quantum materials, this study includes three projects: Magnetic Topological Insulators, Topological Superconductors, and high-temperature superconductors.

A Cr-doped Sb₂Te₃ is added to the category for the magnetic topological insulators project. Their transport properties are studied, and the origin of ferromagnetism is studied. Anomalous Hall effect is observed in the Hall measurements, and serval factors (cooling rate, dopant deficiency) …