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Full-Text Articles in Physical Sciences and Mathematics
Precipitation And Coacervation In Polyelectrolyte-Colloid Systems, Fatih Comert
Precipitation And Coacervation In Polyelectrolyte-Colloid Systems, Fatih Comert
Doctoral Dissertations
Complex coacervation between oppositely charged polyelectrolytes (PEs) and colloids (i.e. micelles and proteins) has increasingly become popular due to the use of these materials in a range of applications including but not limited to personal care, biomaterials, protein purification, and food science. In taking advantage of complex coacervation, which is a liquid-liquid phase separation, precipitation has always represented a problem by introducing inhomogeneities, irreversibility and irreproducible kinetics. Therefore, understanding the dominant factors driving the formation of precipitates is important to control outcomes. In this work, we have performed comparative studies of coacervation and precipitation in model PE-colloid systems to investigate …
Patterning And Mechanical Analysis Of Fiber-Based Materials, Samuel A. Pendergraph
Patterning And Mechanical Analysis Of Fiber-Based Materials, Samuel A. Pendergraph
Doctoral Dissertations
The ability to define and control the topography of a surface has been studied extensively due to its importance in a wide variety of applications. The control of a non-planar topography would be very valuable since a number of structures that are pervasive in artificial applications (e.g. fibers, lenses) are curved interfaces. This potential of enabling applications that incorporate non-planar geometries was the motivation for this thesis. The first study of this thesis comprises the study of patterning the circumference of micrometer sized fibers. Specifically, a unique technique was described to pattern the fiber with a periodic array of colloids. …