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Advancing Structure-Property Relationships In Functional Materials Via Thiol-Ene Photopolymerization, Brian Richard Donovan
Advancing Structure-Property Relationships In Functional Materials Via Thiol-Ene Photopolymerization, Brian Richard Donovan
Dissertations
Thiol-ene photopolymerizations provide a robust and versatile synthetic pathway to functional materials, and owing to the radical step-growth nature of polymerization and the resulting homogenous network structure, provide non-convoluted insight into how network chemistry influences and dictates macromolecular properties.
The first facet of this dissertation focuses on the design and synthesis of bio-inspired, thin film adhesives for dry and aqueous adhesion. Drawing inspiration from the intertidal marine mussel, Chapter II details the synthesis of adhesive networks containing a monofunctional catechol-based monomer. The inclusion of a catechol group resulted in significant improvements in adhesion on a variety of substrates. In Chapter …