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Full-Text Articles in Physical Sciences and Mathematics

A Theoretical Study Of Synchronous Proton Transfer In (Hf)N, (H2O) N, And (Hcl) N Where N = 3, 4, 5, Johnny Yang May 2021

A Theoretical Study Of Synchronous Proton Transfer In (Hf)N, (H2O) N, And (Hcl) N Where N = 3, 4, 5, Johnny Yang

Honors Theses

For (HF)n, (H2O)n, and (HCl)n (n = 3 − 5), we have rigorously characterized the structures for the minima and transition states for synchronous proton transfer (SPT) with the CCSD(T) method and aug-cc-pVTZ basis set. The electronic barrier heights (∆E) associated with these transition states have also been computed with the explicitly correlated CCSD(T)-F12 method and the aug-cc-pVQZ-F12 basis set (abbreviated aQZ-F12). (HCl)n (n = 3 − 5) SPT transition states have not been previously identified to the best of our knowledge, and they have been found …


Study Of Neon Collisional Negative Ion Compound Resonance Using A Trochoidal Electron Monochromator, Will Brunner Mar 2021

Study Of Neon Collisional Negative Ion Compound Resonance Using A Trochoidal Electron Monochromator, Will Brunner

Honors Theses

This thesis describes the experimental apparatus and procedure used to measure the excitation function of the 2p53p 3D3 state of neon. First I describe the effect on this excitation of negative ion resonances and previous experiments to measure the excitation function, as well as suggestions for future applications of such studies. Then the experimental apparatus is described in three parts. The vacuum system uses a turbomolecular pump to decrease the pressure of the chamber to as low as 4*10-9 Torr. The electron beam system incorporates a trochoidal electron monochromator to send a highly monochromatic beam …


Electron Beam Dispersion Compensator Using A Wien Filter, Jackson Lederer Mar 2021

Electron Beam Dispersion Compensator Using A Wien Filter, Jackson Lederer

Honors Theses

When an electron beam travels through space, it spreads out over time which impedes the ability to work with short electron pulses in the lab. A Wien filter is a device consisting of perpendicular electric and magnetic fields which filters charged particles based on their velocities. For a specific velocity, the two forces from the two fields in the filter cancel each other out letting charges with that velocity travel straight through the filter. Charges moving at other speeds are deflected as they have a net force applied to them from the filter. If a particle is deflected from the …


Mot-Based Lifetime Measurements Of Potassium-39 5p1/2 And 5p3/2 States, Huan Q. Bui Jan 2021

Mot-Based Lifetime Measurements Of Potassium-39 5p1/2 And 5p3/2 States, Huan Q. Bui

Honors Theses

This thesis presents measurements of the lifetimes of 5p1/2 and 5p3/2 of K39 via exciting a cloud of K39 atoms in a magneto-optical trap by a linearly-polarized pulse of 405 nm light followed polarization-specific, time-resolved fluorescence detection. We find that $\tau_{5p1/2} = $ 138.8 $\pm$ 1.6 ns, which is consistent with past measurements \cite{triumf}, \cite{berends} and calculations \cite{safranova}. The $\tau_{5p3/2}$ measurement is naturally more involved since quantum beats due to hyperfine and Zeeman effect are present. Our observation of $\tau_{5p3/2} =$ 137.6 $\pm$ 3.1 ns and $\tau_{5p3/2} =$ 136.0 $\pm$ 2.4 ns, obtained from two slightly different approaches, are compared …