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Chemical Engineering

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Articles 1 - 28 of 28

Full-Text Articles in Operations Research, Systems Engineering and Industrial Engineering

Laboratory Evaluation Of High-Temperature Resistant Lysine-Based Polymer Gel Systems For Leakage Control, Tao Song, Xuyang Tian, Baojun Bai, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Thomas P. Schuman Mar 2024

Laboratory Evaluation Of High-Temperature Resistant Lysine-Based Polymer Gel Systems For Leakage Control, Tao Song, Xuyang Tian, Baojun Bai, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In-situ crosslinking gel known for its cost-effectiveness, has been employed for decades to plug high-permeability features in subsurface environments. However, some commonly used crosslinkers are being phased out due to the increasingly rigorous environmental regulations. As a newly discovered environmentally friendly crosslinker, lysine can crosslink the partially hydrolyzed polyacrylamide through transamidation reaction. The present work aimed to study the effect of polymer composition and concentration on the gelation behavior of lysine and high molecular weight acrylamide-based polymers. Several commercial high molecular weight polymers with different contents of 2-Acrylamido-2-methyl-1-propane sulfonic acid (AMPS) including AN-105/125, SAV-55/37/28, and SAV-10 were deployed in this …


Fugacity-Based Lattice Boltzmann Method For Multicomponent Multiphase Systems, Muzammil Soomro, Luis F. Ayala, Cheng Peng, Orlando M. Ayala Jan 2023

Fugacity-Based Lattice Boltzmann Method For Multicomponent Multiphase Systems, Muzammil Soomro, Luis F. Ayala, Cheng Peng, Orlando M. Ayala

Engineering Technology Faculty Publications

The free-energy model can extend the lattice Boltzmann method to multiphase systems. However, there is a lack of models capable of simulating multicomponent multiphase fluids with partial miscibility. In addition, existing models cannot be generalized to honor thermodynamic information provided by any multicomponent equation of state of choice. In this paper, we introduce a free-energy lattice Boltzmann model where the forcing term is determined by the fugacity of the species, the thermodynamic property that connects species partial pressure to chemical potential calculations. By doing so, we are able to carry out multicomponent multiphase simulations of partially miscible fluids and generalize …


Development Of Directed Randomization For Discussing A Minimal Security Architecture, Henrique Oyama, Dominic Messina, Keshav Kasturi Rangan, Akkarakaran Francis Leonard, Kip Nieman, Helen Durand, Katie Tyrrell, Katrina Hinzman, Michael Williamson Dec 2022

Development Of Directed Randomization For Discussing A Minimal Security Architecture, Henrique Oyama, Dominic Messina, Keshav Kasturi Rangan, Akkarakaran Francis Leonard, Kip Nieman, Helen Durand, Katie Tyrrell, Katrina Hinzman, Michael Williamson

Chemical Engineering and Materials Science Faculty Research Publications

Strategies for mitigating the impacts of cyberattacks on control systems using a control-oriented perspective have become of greater interest in recent years. Our group has contributed to this trend by developing several methods for detecting cyberattacks on process sensors, actuators, or both sensors and actuators simultaneously using an advanced optimization-based control strategy known as Lyapunov-based economic model predictive control (LEMPC). However, each technique comes with benefits and limitations, both with respect to one another and with respect to traditional information technology and computer science-type approaches to cybersecurity. An important question to ask, therefore, is what the goal should be of …


Cybersecurity And Dynamic Operation In Practice: Equipment Impacts And Safety Guarantees, Kip Nieman, Dominic Messina, Matthew Wegener, Helen Durand Nov 2022

Cybersecurity And Dynamic Operation In Practice: Equipment Impacts And Safety Guarantees, Kip Nieman, Dominic Messina, Matthew Wegener, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Though dynamic operation of chemical processes has been extensively explored theoretically in contexts such as economic model predictive control or even considering the potential for cyberattacks on control systems creating non-standard operating policies, important practical questions remain regarding dynamic operation. In this work, we look at two of these with particular relevance to process safety: (1) evaluating dynamic operating policies with respect to process equipment fidelity and (2) evaluating procedures for determining the parameters of an advanced control law that can promote both dynamic operation as well as safety if appropriately designed. Regarding the first topic, we utilize computational fluid …


On-Line Process Physics Tests Via Lyapunov-Based Economic Model Predictive Control And Simulation-Based Testing Of Image-Based Process Control, Henrique Oyama, Akkarakaran Francis Leonard, Minhazur Rahman, Govanni Gjonaj, Michael Williamson, Helen Durand Jun 2022

On-Line Process Physics Tests Via Lyapunov-Based Economic Model Predictive Control And Simulation-Based Testing Of Image-Based Process Control, Henrique Oyama, Akkarakaran Francis Leonard, Minhazur Rahman, Govanni Gjonaj, Michael Williamson, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Next-generation manufacturing involves increas- ing use of automation and data to enhance process efficiency. An important question for the chemical process industries, as new process systems (e.g., intensified processes) and new data modalities (e.g., images) are integrated with traditional plant automation concepts, will be how to best evaluate alternative strategies for data-driven modeling and synthesizing process data. Two methods which could be used to aid in this are those which aid in testing data-based techniques on-line, and those which enable various data-based techniques to be assessed in simulation. In this work, we discuss two techniques in this domain which can …


Lyapunov-Based Economic Model Predictive Control For Online Model Discrimination, Henrique Oyama, Helen Durand Apr 2022

Lyapunov-Based Economic Model Predictive Control For Online Model Discrimination, Henrique Oyama, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Economic model predictive control (EMPC) is a flexible control design strategy that can be modified to achieve many operating goals while also ensuring safe operation (e.g., by adding Lyapunov-based stability constraints to form Lyapunov-based EMPC, or LEMPC). Prior works have investigated LEMPC capabilities for achieving goals online beyond optimizing process economics, including aiding in model structure selection to benefit model-based control system design since the accuracy and quality of the process model are important for achieving an expected performance from such systems. This work further probes the capabilities of LEMPC to accomplish multiple objectives during process operation, including aiding in …


Data Driven Bayesian Network To Predict Critical Alarm, Joseph Mietkiewicz, Anders Madsen Jan 2022

Data Driven Bayesian Network To Predict Critical Alarm, Joseph Mietkiewicz, Anders Madsen

Articles

Modern industrial plants rely on alarm systems to ensure their safe and effective functioning. Alarms give the operator knowledge about the current state of the industrial plants. Trip alarms indicating a trip event indicate the shutdown of systems. Trip events in power plants can be costly and critical for the running of the operation.This paper demonstrates how trips events based on an alarm log from an offshore gas production can be reliably predicted using a Bayesian network. If a trip event is reliably predicted and the main cause of it is identified, it will allow the operator to prevent it. …


Efficient Removal Of Lead Ions From Aqueous Media Using Sustainable Sources On Marine Algae, Hannah Namkoong, Erik Biehler, Gon Namkoong, Tarek M. Abdel-Fattah Jan 2022

Efficient Removal Of Lead Ions From Aqueous Media Using Sustainable Sources On Marine Algae, Hannah Namkoong, Erik Biehler, Gon Namkoong, Tarek M. Abdel-Fattah

Electrical & Computer Engineering Faculty Publications

The goal of this project is to explore a new method to efficiently remove Pb(II) ions from water by processing Undaria pinnatifida into immobilized beads using sodium alginate and calcium chloride. The resulting biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). Using immobilized U. pinnatifida, we investigated the effect of various factors on Pb(II) ion removal efficiency such as temperature, pH, ionic strength, time, and underlying biosorption mechanisms. For Pb(II) ion biosorption studies, Pb(II) ion biosorption data were obtained and analyzed using Langmuir and Freundlich adsorption models. It …


Evaluating The Scalability Of The Sonication Method Of Graphene Oxide Synthesis, Evan Dexter May 2019

Evaluating The Scalability Of The Sonication Method Of Graphene Oxide Synthesis, Evan Dexter

Honors Program Projects

Graphene is a new material that was first isolated in 2004, and consists of one to a few atomic layers of carbon in a lattice sheet structure. Graphene has high tensile strength, high surface area, very low electrical resistance, and various other special properties that make it an excellent material for use in emerging technologies in the categories of electrical components, energy systems, and high strength applications. The production scale of graphene sheets and its variations is currently limited to laboratory use, with increasing research being conducted toward the development of manufacturing techniques of the material. We conducted experiments to …


On Accounting For Equipment-Control Interactions In Economic Model Predictive Control Via Process State Constraints, Helen Durand Feb 2019

On Accounting For Equipment-Control Interactions In Economic Model Predictive Control Via Process State Constraints, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Traditionally, chemical processes have been operated at steady-state; however, recent work on economic model predictive control (EMPC) has indicated that some processes may be operated in a more economically-optimal fashion under a time-varying operating policy. It is unclear how time-varying operating policies may impact process equipment, which must be investigated for safety and profit reasons. It has traditionally been considered that constraints on process states can be added to EMPC design to prevent the controller from computing control actions which create problematic operating conditions for process equipment. However, no rigorous investigation has yet been performed to analyze whether, when a …


Economic Model Predictive Control Design Via Nonlinear Model Identification, Laura Giuliani, Helen Durand Aug 2018

Economic Model Predictive Control Design Via Nonlinear Model Identification, Laura Giuliani, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Increasing pushes toward next-generation/smart manufacturing motivate the development of economic model predictive control (EMPC) designs which can be practically deployed. For EMPC, the constraints, objective function, and accuracy of the state predictions would benefit from process models that describe the process physics. However, obtaining first- principles models of chemical process systems can be time-consuming or challenging such that it is preferable to develop physics-based process models automatically from process operating data. In this work, we take initial steps in this direction by suggesting that because experiments that are used to characterize first-principles models often target specific types of data, an …


Data-Based Nonlinear Model Identification In Economic Model Predictive Control, Laura Giuliani, Helen Durand Jul 2018

Data-Based Nonlinear Model Identification In Economic Model Predictive Control, Laura Giuliani, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Many chemical/petrochemical processes in industry are not completely modeled from a first-principles perspective because of the complexity of the underlying physico-chemical phenomena and the cost of obtaining more accurate, physically relevant models. System identification methods have been utilized successfully for developing empirical, though not necessarily physical, models for advanced model-based control designs such as model predictive control (MPC) for decades. However, a fairly recent development in MPC is economic model predictive control (EMPC), which is an MPC formulated with an economics-based objective function that may operate a process in a dynamic (i.e., off steady-state) fashion, in which case the details …


Chemical Storage Of Wind Energy By Renewable Methanol Production: Feasibility Analysis Using A Multi-Criteria Decision Matrix, Michael J. Matzen, Mahdi H. Alhajji, Yaşar Demirel Jan 2015

Chemical Storage Of Wind Energy By Renewable Methanol Production: Feasibility Analysis Using A Multi-Criteria Decision Matrix, Michael J. Matzen, Mahdi H. Alhajji, Yaşar Demirel

Department of Chemical and Biomolecular Engineering: Faculty Publications

This study is for the technoeconomic analysis of an integral facility consisting of wind energy-based electrolytic hydrogen production, bioethanol-based carbon dioxide capture and compression, and direct methanol synthesis. ASPEN Plus was used to simulate the facility producing 97.01 mt (metric tons) methanol/day using 138.37 mt CO2/day and 18.56 mt H2/day. A discounted cash flow diagram for the integral facility is used for the economic analysis at various hydrogen production costs and methanol selling prices. The feasibility analysis is based on a multi-criteria decision matrix consisting of economic and sustainability indicators comparing renewable and non-renewable methanol productions. …


An Integrated Approach To Developing Technical Communication Skills In Engineering Students, Ronald S. Harichandran, David J. Adams, Michael Collura, Nadiye O. Erdil, David Harding, Jean Nocito-Gobel, Amy Thompson Jun 2014

An Integrated Approach To Developing Technical Communication Skills In Engineering Students, Ronald S. Harichandran, David J. Adams, Michael Collura, Nadiye O. Erdil, David Harding, Jean Nocito-Gobel, Amy Thompson

Engineering and Applied Science Education Faculty Publications

The Project to Integrate Technical Communication Habits (PITCH) is being implemented across seven engineering and computer science undergraduate programs. The overarching goal of PITCH is to develop written, oral and visual communication skills and professional habits in engineering students. PITCH activities begin in the very first semester and are reinforced and extended through all four years of each program. Senior design becomes the culminating experience in which students demonstrate the skills and habits acquired through PITCH courses. Student outcomes for the project were established based on an extensive survey of employers, alumni and faculty. Communication instruments include technical memoranda, poster …


S-Stem Scholars, A Second Generation: Support For At-Risk Upper Division And Transfer Students In Ceas, Andrew A. Kline, Betsy M. Aller Jan 2013

S-Stem Scholars, A Second Generation: Support For At-Risk Upper Division And Transfer Students In Ceas, Andrew A. Kline, Betsy M. Aller

Academic Leadership Academy

Begun in 2010, the S-STEM Scholar Program increases opportunities for financially needy but academically talented students. These students:

•Are first-time, first year students •Demonstrate financial need through FAFSA applications

•Will enter a major in the College of Engineering and Applied Sciences

•Have a math ACT of 24 or above

Student awardees receive up to $3,000 per semester, and continue to receive this amount for up to eight semesters with continued academic success and progress to degree.


How Accurate Is Students’ Self Assessment Of Computer Skills?, Michael A. Collura, Samuel Bogan Daniels Jun 2008

How Accurate Is Students’ Self Assessment Of Computer Skills?, Michael A. Collura, Samuel Bogan Daniels

Engineering and Applied Science Education Faculty Publications

Self-evaluation by students is commonly used as a key element in program and course assessment plans. Such instruments are intended to provide crucial feedback for program improvement and thus play a significant role in closing our assessment loop. For many of the program outcomes, self-assessment by current students and graduates augments other, more objective measures. However, for some outcomes there are no practical means of obtaining objective assessment and we must rely on self-assessment. The heavy reliance on this metric begs the question “How accurate is student self-assessment?” This paper provides data from a second-semester engineering course in which students …


The Current Generation Of Integrated Engineering Curriculum, Michael A. Collura, Samuel Bogan Daniels, Jean Nocito-Gobel, David Harding Jun 2007

The Current Generation Of Integrated Engineering Curriculum, Michael A. Collura, Samuel Bogan Daniels, Jean Nocito-Gobel, David Harding

Engineering and Applied Science Education Faculty Publications

In September of 2004 our university adopted the Multidisciplinary Engineering Foundation Spiral Curriculum as the basis for disciplinary engineering programs in Chemical, Civil, Electrical, Mechanical and General Engineering. The curriculum includes a sequence of first and second year engineering courses, matched closely with the development of students’ mathematical sophistication and analytical capabilities and integrated with course work in the sciences. Students develop a conceptual understanding of engineering basics in this series of courses which stress practical applications of these principles. The new curriculum was designed to provide students with a multidisciplinary perspective while developing basic engineering skills and fostering an …


Civil And Mechanical Engineering Students Learning Mechanics In A Multidisciplinary Engineering Foundation Spiral, Jean Nocito-Gobel, Gregory Broderick, Samuel Bogan Daniels, Michael Collura, Richard Stanley Jun 2007

Civil And Mechanical Engineering Students Learning Mechanics In A Multidisciplinary Engineering Foundation Spiral, Jean Nocito-Gobel, Gregory Broderick, Samuel Bogan Daniels, Michael Collura, Richard Stanley

Engineering and Applied Science Education Faculty Publications

This paper describes how mechanical and civil engineering students are introduced to and develop an understanding of mechanics concepts through a sequence of integrated courses as part of a new curriculum taken during the freshman and sophomore years. The Multi- Disciplinary Engineering Foundation Spiral is a four-semester sequence of engineering courses, matched closely with the development of students’ mathematical sophistication and analytical capabilities and integrated with course work in the sciences. Students develop a conceptual understanding of engineering basics in this series of courses, which stress practical applications of these principles. Mechanics concepts are introduced in a pair of first …


Project-Based Introduction To Engineering - A University Core Course, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura Jun 2004

Project-Based Introduction To Engineering - A University Core Course, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura

Engineering and Applied Science Education Faculty Publications

This paper describes a first year engineering course that is taken by both engineering and non-engineering students. The project-based Introduction to Engineering course, EAS107P, fulfills a university core curriculum elective. Although engineering students take the course during their first year, students from other majors typically elect to take the course later in their curriculum. The focus of EAS107P is to have students experience the engineering design and problem solving process in a multi-disciplinary, team-based setting. In addition to learning about design, students develop an interest in the engineering profession and build a foundation of skills for future work. An additional …


Development Of A Multidisciplinary Engineering Foundation Spiral, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura Jun 2004

Development Of A Multidisciplinary Engineering Foundation Spiral, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura

Engineering and Applied Science Education Faculty Publications

To operate effectively in today’s workforce engineers need to have a muti-disciplinary perspective along with substantial disciplinary depth. This broad perspective cannot be achieved by merely taking 2 or 3 engineering courses outside of the major, but rather will require a radical change in the way we educate engineers. The faculty of the School of Engineering and Applied Science at the University of New Haven have developed a new approach: the Multidisciplinary Engineering Foundation Spiral. This curricular model provides the needed mix of breadth and depth, along with the desired professional skills, by providing carefully crafted, well-coordinated curricular experiences in …


Project-Based Introduction To Engineering -- Course Assessment, Samuel Bogan Daniels, Michael Collura, Bouzid Aliane, Jean Nocito-Gobel Jun 2004

Project-Based Introduction To Engineering -- Course Assessment, Samuel Bogan Daniels, Michael Collura, Bouzid Aliane, Jean Nocito-Gobel

Engineering and Applied Science Education Faculty Publications

The School of Engineering and Applied Science at the University of New Haven has a newly developed project-based Introduction to Engineering course. This new course plays a central role in the new Multi-Disciplinary Engineering Foundation Spiral curriculum as the first semester course for all engineering freshmen. An assessment process was developed to determine the effectiveness of this project-based course, specifically with attention towards assessing attitudes, impact on retention, problem-solving and engineering foundation topics. This paper addresses the particular portion of the assessment process for the individual course projects and their contribution to the last two assessment categories.


Project Planning & Development For Engineering Freshmen, Bouzid Aliane, Michael Collura, Samuel Bogan Daniels, Jean Nocito-Gobel Jun 2004

Project Planning & Development For Engineering Freshmen, Bouzid Aliane, Michael Collura, Samuel Bogan Daniels, Jean Nocito-Gobel

Engineering and Applied Science Education Faculty Publications

The nature and background of students seeking an engineering education has changed drastically in the last decade, as has the expectations of industrial employers. Many students lack the organizational skills needed for academic success. Similar organizational skills, although more advanced, are required for managing engineering projects. A new course was developed by the faculty at the School of Engineering and Applied Science at the University of New Haven. Through this course, a key component of the Multidisciplinary Engineering Foundation Spiral, seeks to promote higher retention rates, increase student motivation and begin a confidence-building transition to professional practice. Project management concepts …


7th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla Jan 1980

7th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.


University Of Missouri--Rolla Wood Energy Research, Yildirim Omurtag, V. J. Flanigan, Nathan E. Welch Oct 1978

University Of Missouri--Rolla Wood Energy Research, Yildirim Omurtag, V. J. Flanigan, Nathan E. Welch

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The overall objective of this project is to conduct a research and development program which will lead to the early commercialization of wood gasification technology to process wood residues typical of those found in the Ozark region.


5th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla Jan 1978

5th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

This volume is a collection of refereed papers presented at the Fifth Annual UMR-DNR Conference on Energy held at the University of Missouri--Rolla on the dates of October 10 - 12, 1978.

Guided by the President's goal of energy independence by 1980, the UMR-DNR Conference on Energy organized in 1974 with the purpose of providing social scientists, scientists and engineers a means for rapid communication of their most recent research results in the field of energy and to offer solutions to the energy related problems of local government, business, industry and the general public. Since that time, there has been …


The Impact Of Changing Net Returns On Minimum Energy Requirements For Grain Farms, James B. Kliebenstein, Robert M. Finley, Douglas C. Farthing Oct 1977

The Impact Of Changing Net Returns On Minimum Energy Requirements For Grain Farms, James B. Kliebenstein, Robert M. Finley, Douglas C. Farthing

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

With sources of energy more restricted and higher priced, optimal combinations of enterprises must logically be considered on the basis of energy efficiency. One method of ascertaining this efficiency is to optimize solutions for given levels of income on the basis of energy used (e.g., the objective function was in terms of energy kilocalories). In general, soybeans were most feasible at lower levels of income regardless of farm size and labor circumstance. As income levels increased, double-cropping (wheat soybeans) was first substituted and finally corn at highest income levels.


3rd Annual Umr-Mec Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla Jan 1976

3rd Annual Umr-Mec Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.


2nd Annual Umr-Mec Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla Oct 1975

2nd Annual Umr-Mec Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.