Applied Mechanics Commons^™

Accelerated Controller Tuning For Wind Turbines Under Multiple Hazards, Aly Mousaad Aly, Milad Rezaee

Faculty Publications

During their lifecycle, wind turbines can be subjected to multiple hazard loads, such as high-intensity wind, earthquake, wave, and mechanical unbalance. Excessive vibrations, due to these loads, can have detrimental effects on energy production, structural lifecycle, and the initial cost of wind turbines. Vibration control by various means, such as passive, active, and semi-active control systems provide crucial solutions to these issues. We developed a novel control theory that enables semi-active controller tuning under the complex structural behavior and inherent system nonlinearity. The proposed theory enables the evaluation of semi-active controllers’ performance of multi-degrees-of-freedom systems, without the need for time-consuming …

Mechanical Properties Of Permanent Foaming Fixatives For Deactivation & Decommissioning Activities, Tristan Maximilian Simoes-Ponce

FIU Electronic Theses and Dissertations

The Department of Energy is investigating fixative technologies that encapsulate and/or immobilize residual contamination in voids during deactivation and decommissioning (D&D). These technologies must have adequate mechanical and adhesion properties to withstand seismic activity that may occur. One solution is the implementation of polyurethane foams used as permanent foaming fixatives (PFF), specifically intumescent foams that contain expandable graphite, making them fire resistant when exposed to extreme heat conditions.

Tensile, compression, seismic, and tensile adhesion testing was done on six commercial-off-the-self polyurethane foams to determine if the expandable graphite and other filler intumescent technologies improve its mechanical limits. It was found …

A Constructal Approach To The Design Of Inflected Airplane Wings, Shanae Powell

FIU Electronic Theses and Dissertations

Aeroelastic instabilities such as flutter can be accurately captured by state-of-the-art aeroelastic analysis methods and tools. However, these tools and methods fall short in exposing the reasons behind the occurrence of such instabilities. In this research, the constructal law is used to discover the main cause of the variation in the flutter speed and stress distribution for inflected aircraft wings when compared to its uninflected counterpart. This law considers the design as a physics phenomenon and uses an evolutionary flow principle to explain and predict the occurrence of energy flow configurations (i.e. the flow of stresses throughout the structure).

For …

Acoustic Manipulation And Alignment Of Particles For Applications In Separation, Micro-Templating, And Device Fabrication, Kamran Moradi

FIU Electronic Theses and Dissertations

This dissertation studies the manipulation of particles using acoustic stimulation for applications in microfluidics and templating of devices. The term particle is used here to denote any solid, liquid or gaseous material that has properties, which are distinct from the fluid in which it is suspended. Manipulation means to take over the movements of the particles and to position them in specified locations.

Using devices, microfabricated out of silicon, the behavior of particles under the acoustic stimulation was studied with the main purpose of aligning the particles at either low-pressure zones, known as the nodes or high-pressure zones, known as …

La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen

Faculty Publications

In this research, La_0.7Sr_0.3Fe_0.7Ga_0.3O_3−δ (LSFG) perovskite oxide was successfully prepared using a microwave-assisted combustion method, and employed as both anode and cathode in symmetrical solid oxide fuel cells. A maximum power density of 489 mW cm⁻² was achieved at 800 °C with wet H₂ as the fuel and ambient air as the oxidant in a single cell with the configuration LSFG|La_0.8Sr_0.2Ga_0.83Mg_0.17O_3−δ|LSFG. Furthermore, the cells demonstrated good stability in H₂ and acceptable sulfur tolerance.

La0.6Sr1.4Mno4+Δ Layered Perovskite Oxide: Enhanced Catalytic Activity For The Oxygen Reduction Reaction, Yarong Wang, Zhibin Yang, Fanliang Liu, Chao Jin, Jiao Wu, Ming Shen, Ruizhi Yang, Fanglin Chen

Faculty Publications

Efficient electrocatalysts for the oxygen reduction reaction (ORR) is a critical factor to influence the performance of lithium–oxygen batteries. In this study, La_0.6Sr_1.4MnO_4+δ layered perovskite oxide as a highly active electrocatalyst for the ORR has been prepared, and a carbon-coating layer with thickness <5 nm has been successfully introduced to enhance the electronic conductivity of the as-prepared oxide. XRD, XPS, Raman, SEM and TEM measurements were carried out to characterize the crystalline structure and morphology of these samples. Rotating ring-disk electrode (RRDE) technique has been used to study catalytic activities of the as-prepared catalysts for the ORR in 0.1 M KOH media. RRDE results reveal that carbon-coated La_0.6Sr_1.4MnO_4+δ exhibits better catalytic activity for the ORR. For the carbon-coated La_0.6Sr_1.4MnO_4+δ, the ORR proceeds predominately via a direct four electron process, and a maximum cathodic current density of 6.70 mA cm⁻² at 2500 rpm has been obtained, …

Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia

Faculty Publications

Directly converting CO₂ to hydrocarbons offers a potential route for carbon-neutral energy technologies. Here we report a novel design, integrating the high-temperature CO₂–H₂O co-electrolysis and low-temperature Fischer–Tropsch synthesis in a single tubular unit, for the direct synthesis of methane from CO₂ with a substantial yield of 11.84%.

Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen

Faculty Publications

Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …

Ni-Doped Sr2Fe1.5Mo0.5O6-Δ As Anode Materials For Solid Oxide Fuel Cells, Guoliang Xiao, Siwei Wang, Ye Lin, Zhibin Yang, Minfang Han, Fanglin Chen

Faculty Publications

10% Ni-doped Sr₂Fe_1.5Mo_0.5O_6-δ with A-site deficiency is prepared to induce in situ precipitation of B-site metals under anode conditions in solid oxide fuel cells. XRD, SEM and TEM results show that a significant amount of nano-sized Ni-Fe alloy metal phase has precipitated out from Sr_1.9Fe_1.4Ni_0.1Mo_0.5O_6-δ upon reduction at 800^◦C in H₂. The conductivity of the reduced composite reaches 29 S cm⁻¹ at 800^◦C in H₂. Furthermore, fuel cell performance of the composite anode Sr_{1.9 …}

Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao

Faculty Publications

The creation of A-site cation defects within a perovskite oxide can substantially alter the structure and properties of its stoichiometric analogue. In this work, we demonstrate that by vacating 2 and 5% of Asite cations from SrNb_0.1Co_0.9O_3-δ (SNC1.00) perovskites (Sr_1-sNb_0.1Co_0.9O_3-δ,s = 0.02 and 0.05; denoted as SNC0.98 and SNC0.95, respectively), a Jahn–Teller (JT) distortion with varying extents takes place, leading to the formation of a modified crystal lattice within a the perovskite framework. Electrical conductivity, electrochemical performance, chemical compatibility and microstructure of Sr_1-sNb_0.1Co …

Sr2Fe1.5Mo0.5O6-Δ – Sm0.2Ce0.8O1.9 Composite Anodes For Intermediate-Temperature Solid Oxide Fuel Cells, Beibei He, Ling Zhao, Shuxiang Song, Tong Liu, Fanglin Chen, Changrong Xia

Faculty Publications

Sr₂Fe_1.5Mo_0.5O_6−δ (SFM) perovskite is carefully investigated as an anode material for solid oxide fuel cells with LaGaO₃-based electrolytes. Its electronic conductivity under anodic atmosphere is measured with four-probe method while its ionic conductivity is determined with oxygen permeation measurement. Samaria doped ceria (SDC) is incorporated into SFM electrode to improve the anodic performance. A strong relation is observed between SDC addition and polarization losses, suggesting that the internal SFM-SDC contacts are active for H₂ oxidation. The best electrode performance is achieved for the composite with 30 wt% SDC addition, resulting …

In Situ Synthesis Of Ultrafine Ss-Mno2/Polypyrrole Nanorod Composites For High-Performance Supercapacitors, Jianfeng Zang, Xiaodong Li

Faculty Publications

We report a remarkable observation that is at odds with the established notion that β-MnO₂ was regarded as an undesirable candidate for supercapacitor applications. The specific capacitance of β-MnO₂ can reach as high as 294 F g⁻¹, which is comparable to the best crystallographic structure, like α-MnO₂. The key is to substantially decrease the size of β-MnO₂ powders to ultra small regime. We demonstrate a facile, simple, and effective approach to synthesizing ultrafine (<10 nm in diameter) β-MnO₂/polypyrrole nanorod composite powders for high-performance supercapacitor electrodes. Our observation may encourage a revisit of the other good …

Characteristics Of The Hydrogen Electrode In High Temperature Steam Electrolysis Process, Chao Jin, Chenghao Yang, Fanglin Chen

Faculty Publications

YSZ-electrolyte supported solid oxide electrolyzer cells (SOECs) using LSM-YSZ oxygen electrode but with three types of hydrogen electrode, Ni–SDC, Ni–YSZ and LSCM–YSZ have been fabricated and characterized under different steam contents in the feeding gas at 850°C. Electrochemical impedance spectra results show that cell resistances increase with the increase in steam concentrations under both open circuit voltage and electrolysis conditions, suggesting that electrolysis reaction becomes more difficult in high steam content. Pt reference electrode was applied to evaluate the contributions of the hydrogen electrode and oxygen electrode in the electrolysis process. Electrochemical impedance spectra and over potential of both electrodes …

A Generic Bamboo-Based Carbothermal Method For Preparing Carbide (Sic, B4C, Tic, Tac, Nbc, TiXNb1-XC, And TaX Nb1-XC) Nanowires, Xinyong Tao, Yiping Li, Jun Du, Yang Xia, Yingchao Yang, Hui Huang, Yongping Gan, Wenkui Zhang, Xiaodong Li

Faculty Publications

Finding a general procedure to produce a whole class of materials in a similar way is a desired goal of materials chemistry. In this work, we report a new bamboo-based carbothermal method to prepare nanowires of covalent carbides (SiC and B₄C) and interstitial carbides (TiC, TaC, NbC, Ti_xNb_1−xC, and Ta_xNb_1−xC). The use of natural nanoporous bamboo as both the renewable carbon source and the template for the formation of catalyst particles greatly simplifies the synthesis process. Based on the structural, morphological and elemental analysis, volatileoxides or halides assisted …

Effect Of Residual Thermal Stresses On Fracture Behavior And Mechanical Properties Of Al Sub 2 O Sub 3/Ni Cermets, Guo Jin Li, Da Ming Chen, Xiao Xian Huang, Jing Kun Guo

Faculty Publications

Effect of residual thermal stresses on fracture behavior and mechanical properties of Al₂O₃/Ni cermets was qualitatively explained by using theory on residual thermal stresses. When Ni particles are located within Al₂O₃ grains or Ni content is relatively low, tensile stresses are exerted at Al₂O₃-Al₂O₃ grain boundary. While fracturing, intergranular fracture is easily produced. When Ni particles are dispersed at Al₂O₃ grain boundary or Ni content is relatively high, compressive stresses are exerted at Al₂O₃-Al₂O₃grain boundary. …