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Theses/Dissertations

1962

<p>Beryllium<br />Beryllium -- Dissolution -- Testing<br />Chemical kinetics<br />Hydrofluoric acid</p>

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Full-Text Articles in Metallurgy

A Study Of The Chemical Kinetics, Activation Energy And Difference Effect On Beryllium Dissolving In Mineral Acids, Daniel Santhamurthi Gnanamuthu Jan 1962

A Study Of The Chemical Kinetics, Activation Energy And Difference Effect On Beryllium Dissolving In Mineral Acids, Daniel Santhamurthi Gnanamuthu

Masters Theses

"The rate of dissolution of polycrystalline beryllium was studied in hydrofluoric, hydrochloric and sulfuric acids. Two samples of beryllium containing different amounts of beryllium oxide were used. The experiments were performed at temperatures ranging from 20 to 50°C, and at various acid concentrations. The kinetics of these heterogeneous processes conformed to a reaction order of approximately one in all the cases. Since the conditions of the surface were complex during dissolution, these might complicate the reaction. This might be due to the oxide layer, which is present as impurity.

The difference effect was determined at various acid concentrations at 25°C …