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Full-Text Articles in Metallurgy

Studies Of High Temperature Hydrogen Related Damage In Welded Carbon Steel Components Used In Refineries, Maneel Bharadwaj May 2015

Studies Of High Temperature Hydrogen Related Damage In Welded Carbon Steel Components Used In Refineries, Maneel Bharadwaj

Masters Theses

Five materials encompassing various grades of carbon steel were received from retired and ex-service petroleum refinery equipment for root-cause evaluation of High Temperature Hydrogen Attack (HTHA) damage at UTK. These materials were submitted by three contributors: Irving Oil Refinery (IOR #1110-2), Valero (#67 & #1252134), and Phillips 66 (#555-S1 & #555-S2) on behalf of American Petroleum Institute (API). These materials originated from various flange-to-pipe welded components that were exposed in hydrogen pressure environment at elevated temperatures (> 640°F and >70 psia).

A singular crack originating at the flange inside surface just outside of the visible HAZ was observed in IOR …


Factors Affecting The Heat Transfer During The Dip Testing Of Potential Third Generation Advanced High Strength Steels, Kramer Michael Pursell Jan 2015

Factors Affecting The Heat Transfer During The Dip Testing Of Potential Third Generation Advanced High Strength Steels, Kramer Michael Pursell

Masters Theses

"A dip tester was designed and built at Missouri University of Science and Technology to test the effects of the primary alloying elements (Mn, Si, and Al) of Fe-Mn-Al-Si-C type 3rd generation advanced high strength steel (AHSS) alloys, dipping superheat, and dipping speed on the heat transfer during rapid solidification. The difficulties associated with casting 3rd generation AHSS were compiled as well to serve as a best-practices guide. An extensive list of potential 3rd generation AHSS alloys was developed and tested, and the effects of various dip testing parameters were examined.

Manganese was found to increase the heat flux by …


Formation And Evolution Of Spinel In Aluminum Killed Calcium Treated Linepipe Steels, Obinna Adaba Jan 2015

Formation And Evolution Of Spinel In Aluminum Killed Calcium Treated Linepipe Steels, Obinna Adaba

Masters Theses

"Magnesium aluminate (Spinel) inclusions have been observed to cause hook crack in line pipe steels. These inclusions are typically formed during liquid steel processing at the ladle metallurgy furnace (LMF) and subsequently modified by calcium to form less harmful liquid inclusions. Unfortunately, spinel inclusions are still sometimes observed in samples taken from the tundish and coil after calcium treatment.

The formation and evolution of spinel inclusions during liquid steel processing at two industrial mini mills was investigated by analysis of lollipop samples taken at different stages of the steelmaking process. The effect of reoxidation on the formation of spinels after …


Understanding Impurities In Copper Electrometallurgy, Paul Laforest Jan 2015

Understanding Impurities In Copper Electrometallurgy, Paul Laforest

Masters Theses

"This work involves examining two industrial reports of methods to handle impurities in copper electrowinning and electrorefining. The first part evaluates the addition of Hydrostar, Cyquest N-900, DXG-F7, and Guartec EW to copper electrowinning electrolyte to affect MnO2 deposition on coated titanium anodes (CTAs). The second part examines the effects of anode chemistry and thiourea addition on the ductility of electrorefined copper starter sheet.

In part one, a laboratory cell was used to simulate a short cycle electrowinning cell via chronopotentiometric operation with an IrO2-Ta2O5 CTA at 40⁰C. A cyclic voltammetric sweep was applied …