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2007

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Articles 1 - 30 of 132

Full-Text Articles in Engineering Science and Materials

Property Measurements And Evaluation Of Heat Leak, Nathan Race Dec 2007

Property Measurements And Evaluation Of Heat Leak, Nathan Race

All Theses

Heat transport in capillary wick structures is an important parameter in loop heat pipe (LHP) design. The purpose of this study was to investigate the conductive heat leak in operating capillary wick structures. The heat leak is the portion of applied heat load conducted through the wick in spite of the convection of working fluid. Four sintered 316 stainless steel wicks were tested for porosity, effective thermal conductivity, pore size, and heat leak. Pore sizes were found to correlate well with the nominal pore size and pores were very narrowly distributed within a size range of approximately 1-10μm. Effective thermal …

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The Role Of Computer Aided Engineering In Developing A Combined Trash And Recycling Truck : A Case Study, Peter Johnston Dec 2007

The Role Of Computer Aided Engineering In Developing A Combined Trash And Recycling Truck : A Case Study, Peter Johnston

All Theses

This work will illustrate how Environmental America Inc., EAI, and the Clemson University design team utilized lean manufacturing principles to revolutionize the curbside waste collection process. Through the application of lean manufacturing principles the number of non-value added steps was significantly reduced and the information gathered from the lean process tree acted as a framework to develop initial constraints and criteria for the vehicle's development. The design team was asked to construct the fifth iteration of the prototype collection vehicle in an effort to minimize vehicle cost, size and weight. An extensive case study will be presented which illustrates how …

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Thermal Diffusion Coefficient Modeling For High Pressure Combustion Simulations, Soundararaghavan Vasudevan Dec 2007

Thermal Diffusion Coefficient Modeling For High Pressure Combustion Simulations, Soundararaghavan Vasudevan

All Theses

The effects of Soret and Dufour diffusion on the behavior of high pressure laminar diffusion flames relevant to modern combustion devices are investigated. A novel model for thermal diffusion coefficients is developed based on experimental data found in the literature and the principle of corresponding states. The new model is first compared with existing models and experimental data and is shown to be more accurate and to exhibit correct behavior in the limit of high temperature relevant to combustion. The model furthermore does not exhibit sensitivity to the equation of state, its mixing rules, or unphysical sign changes observed in …

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A Case Study Investigating Rule Based Design In An Industrial Setting, Siva Chavali Dec 2007

A Case Study Investigating Rule Based Design In An Industrial Setting, Siva Chavali

All Theses

This thesis presents a case study on the implementation of a rule based design (RBD) process for an engineer-to-order (ETO) company. The time taken for programming and challenges associated with this process are documented in order to understand the benefits and limitations of RBD. These times are obtained while developing RBD programs for grid assemblies of bottle packaging machines that are designed and manufactured by Hartness International (HI). In this project, commercially available computer-aided design (CAD) and RBD software are integrated to capture the design and manufacturing knowledge used to automate the grid design process of HI. The stages involved …

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An Investigation Of Cavity Pressure As A Process And Quality Indicator In The Micro-Injection Molding Process, Soon-Chun Kuek Dec 2007

An Investigation Of Cavity Pressure As A Process And Quality Indicator In The Micro-Injection Molding Process, Soon-Chun Kuek

All Theses

Increased demand for micro-scale parts and devices is being met in many cases by micro-injection molding of polymer parts. However, part inspection is difficult due to the micro-scale dimension in the micro-injection molding process. In addition, process control also becomes challenging since the process is susceptible to slight changes in process parameters such as mold temperature, injection velocity, and packing pressure. To address these issues, a suitable process monitoring method such as cavity pressure monitoring can be employed to detect any process deviation that may cause defects in part quality. Cavity pressure has been found to be a reliable process …

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Least Squares Fitting Of Analytic Primitives On A Gpu, Meghashyam Panyam Mohan Ram Dec 2007

Least Squares Fitting Of Analytic Primitives On A Gpu, Meghashyam Panyam Mohan Ram

All Theses

Metrology systems take coordinate information directly from the surface of a manufactured part and generate millions of (X, Y, Z) data points. The inspection process often involves fitting analytic primitives such as sphere, cone, torus, cylinder and plane to these points which represent an object with the corresponding shape. Typically, a least squares fit of the parameters of the shape to the point set is performed. The least squares fit attempts to minimize the sum of the squares of the distances between the points and the primitive. The objective function however, cannot be solved in the closed form and numerical …

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Surface Finish Control Of 3d Printed Metal Tooling, Brady Godbey Dec 2007

Surface Finish Control Of 3d Printed Metal Tooling, Brady Godbey

All Theses

Solid freeform fabrication (SFF) technology has shown a great deal of promise for the plastic injection molding industry due to its ability to produce complex geometry tooling relatively quickly. However, one shortcoming of metal-based SFF processes is that they have difficulty producing parts with acceptable surface quality. As such, secondary operations, such as machining, are frequently required thereby increasing fabrication time and cost. In addition, there is variation in the surface quality that is dependent upon the surface orientation during the build process. For example, parts produced using the metal-based 3-D printing process have vertical faces with a typical roughness …

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Development Of A Design Enabler Tool For Frame Analysis For A Small Enterprise: A Case Study, Madhusudan Kayyar Dec 2007

Development Of A Design Enabler Tool For Frame Analysis For A Small Enterprise: A Case Study, Madhusudan Kayyar

All Theses

This case study investigates the design process followed by a small to medium scale enterprise (SME) that primarily depends on special expertise in the form of a few key individuals. These individuals design products mainly based on past experience, augmented by trial and error. This is an inefficient, time consuming, and expensive way of designing products and evaluating their performance. This study critiques the different steps in the current design process, identifying areas of potential improvement and enhancement through application of formal design methods and innovative design enablers. The 'Design Enablers' are design tools that assist the designer at various …

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A Case Study On The Use Of Design Exemplar As A Search And Retrieval Tool, Narasimha Murty Srirangam Dec 2007

A Case Study On The Use Of Design Exemplar As A Search And Retrieval Tool, Narasimha Murty Srirangam

All Theses

This thesis presents a case study examining the suitability of design exemplar technology as a CAD query tool for an industrial scenario. The search and retrieval of geometrically similar mold inserts to save tooling cost for a tire manufacturing company is taken as the case study. During the implementation of the design exemplar as a CAD search and retrieval tool, several limitations of it are identified, such as the difficulty and tediousness in authoring exemplars for real world problems. To overcome these limitations, a new mathematical-based exemplar approach (mathematical model) is developed for tire mold insert retrieval. This approach calculates …

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Effects Of Support Grid Vane Angles On Single Phase Heat Transfer Within Rod Bundle Subchannels, Michael Cosby Dec 2007

Effects Of Support Grid Vane Angles On Single Phase Heat Transfer Within Rod Bundle Subchannels, Michael Cosby

All Theses

The main goal of this project is to investigate how changes in support grid mixing vane angles affect the single phase heat transfer coefficient for rod bundle flows. Since other studies have been done on these types of flows, the present study also serves the purpose of further solidifying conclusions made in those works. A split-pair mixing vane support grid without weld nugget cutouts is thought to have optimum flow characteristics at a vane angle of 29 degrees. Results obtained from this work have shown this to be true. Vane angles were modified to angles of 37 ¡, 33¡ and …

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Morphological Charts: A Systematic Exploration Of Qualitative Design Space, Gregory Smith Dec 2007

Morphological Charts: A Systematic Exploration Of Qualitative Design Space, Gregory Smith

All Theses

A morphological chart is a tool that represents a large qualitative design space. These charts list the functions identified for the design problem, and the means (solutions) that can perform each function. Combining one means for each function will produce a potential integrated conceptual design solution. Repeating this process with every possible combination contained in the morphological chart will generate a long list of conceptual design solutions. Not all of these solutions will be practical, or even physically possible.
As it is difficult to analyze a long list of design solutions and as at present, there are no systematic design …

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Mixed Convective Heat Transfer And Evaporation At The Air-Water Interface, Prasad Gokhale Dec 2007

Mixed Convective Heat Transfer And Evaporation At The Air-Water Interface, Prasad Gokhale

All Theses

Functional forms for mixed convective heat transfer and evaporation from an air-water interface were obtained. To obtain these functions, heat transfer and evaporation rates from the air-water interface of an evaporating body of water were quantified in a wind/water tunnel in the presence of an oleyl alcohol monolayer on the water surface. The Nusselt (Nu) and Sherwood (Sh) numbers, parameterizing the dimensionless heat and mass transfer respectively, for transport from the water bulk to air were expressed as functions of the air side Rayleigh (Ra) and Reynolds (Re) numbers. The Nu and Sh were calculated for a range of Ra …

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A Comparative Fault Diagnosis Methodology Based On Time Series Analysis Of System's Signals, Hany Bassily Dec 2007

A Comparative Fault Diagnosis Methodology Based On Time Series Analysis Of System's Signals, Hany Bassily

All Dissertations

The detection of system anomalies represents an important task in safety critical systems. Over the past two decades, advances in data manipulation techniques and sensor technology have contributed to the widespread application of signal processing concepts for fault diagnosis. However, the majority of these signal processing, or data driven, diagnostics do not possess the redundancy level exhibited in conventional model-based methods. Among signal processing methods, time series analysis is advantageous since it offers insight into the underlying dynamics and forecasts system behavior. Furthermore, the data driven method allows the depiction of system dynamics with an increased level of redundancy. This …

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Modelagem Da Vida De Fadiga E Do Acúmulo De Deformações Permanentes Em Pavimentos Asfálticos Por Meio De Um Modelo De Dano Contínuo, Victor Ferreira Teixeira, Flavio V. Souza, Jorge Barbosa Soares Dec 2007

Modelagem Da Vida De Fadiga E Do Acúmulo De Deformações Permanentes Em Pavimentos Asfálticos Por Meio De Um Modelo De Dano Contínuo, Victor Ferreira Teixeira, Flavio V. Souza, Jorge Barbosa Soares

Department of Mechanical and Materials Engineering: Faculty Publications

: It is known that the conditions of the Brazilian roadways have an enormous impact over the national economy. In face of this problem, there is a need for new methodologies for pavement analyses and design that can more accurately predict pavement distresses. Among the main methods currently used, one can find purely empirical methods and mechanistic-empirical methods which make use of the pavement structure response. The evolution of numerical methods such as the Finite Element Method (FEM) or the Boundary Element Method (BEM) has made the mechanistic-empirical methods more popular for pavement analysis applications. This work shows a mechanistic …

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Electrochemical Oxidization Of Herring Sperm Dna And Its Interaction With Histone, Juan Xu, Gui-Ping Huang, Hong Li, Wei Zhu Nov 2007

Electrochemical Oxidization Of Herring Sperm Dna And Its Interaction With Histone, Juan Xu, Gui-Ping Huang, Hong Li, Wei Zhu

Journal of Electrochemistry

The voltammetric behavior of herring sperm DNA at glassy carbon electrode and its interaction with histone have been investigated by using cyclic voltammetry,differential pulse voltammetry,and fluorescence measurement.In the potential range of 0.20 V to 1.25 V,it is found that an irreversible oxidative peak is exhibited in acid solution,but in the neutral or alkaline solution two oxidative peaks are observed.Oxidative peak potential values show a negative shift with increasing pH via a slope of-57 mV·pH-1 and a linear relation with DNA concentration in the range of 0.45 to 8.20 mmol·L-1.In the presence of histone,the oxidative peak current of DNA …

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Eiectro-Oxidation Of Methanol On Pdnio/C Catalyst In Alkaline Medium, Mei-Li Wang, Lin Sang, Cheng-De Huang Nov 2007

Eiectro-Oxidation Of Methanol On Pdnio/C Catalyst In Alkaline Medium, Mei-Li Wang, Lin Sang, Cheng-De Huang

Journal of Electrochemistry

The electro-oxidation of methanol in alkaline electrolyte at in-house synthesized PdNiO/C and Pd/C catalysts and the effect of heat treatment on the structure and performance of catalysts were studied by cyclic voltammetry,chronoamperometry,chronopotentiometry and X-ray diffraction methods.It is shown that when the reduction temperature is 70℃ and the ratio between Pd and Ni is 8∶2,The PdNiO/C catalyst presents a highest activity for methanol electrooxidation.Calcining can increase the particle size and crystallinity of catalysts,but decrease the dispersion and activity of catalysts, too.Besides,the NiO is disengaged from Pd lattice by heat-treatment.The optimal PdNiO/C catalyst shows higher catalytic activity and much better poisoning resistance …

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Preparation And Properties Of High Capacity Lifepo4, Jun Li, Gui-Tang Lai, Hui-Min Huang, Da-Guang Li, Xin-De Xia Nov 2007

Preparation And Properties Of High Capacity Lifepo4, Jun Li, Gui-Tang Lai, Hui-Min Huang, Da-Guang Li, Xin-De Xia

Journal of Electrochemistry

Carbon-doped LiFePO4/C and pure phase LiFePO4 cathode materials were prepared by liquid-state precipitation reaction. The results of XRD, SEM, elemental analysis,FTIR and A.C.impedance tests show that the samples have had olivine structure and a 3.4V discharge platform.The tapped density of LiFePO4/C sample could reach 1.46g/cm3, the initiate discharge capacity is 144.6mAh/g at 0.1C,which remained capacity is 93.2% after 20 cycles. The first discharge capacity is 133.5mAh/g at 1C and the capacity decreased 8.76% after 20 cycles.

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Electrochemical Behavor Of Zinc-Indium Alloy Electrodes In Concentrated Alkaline Solution, Zhi-Lin Wang, Xiao-Ge Zhang, Rong-Gui Du, Chang-Jian Lin Nov 2007

Electrochemical Behavor Of Zinc-Indium Alloy Electrodes In Concentrated Alkaline Solution, Zhi-Lin Wang, Xiao-Ge Zhang, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

The electrochemical behavior of zinc-indium alloy electrodes in 35%KOH solutions has been investigated by electrochemical methods including the potentiodynamic polarization and discharge measurements under constant current density.The results indicate that the anodic current density and passive current density increase after the indium addition.The discharge measurement shows that the addition of indium shortens the time to passive state for the Zn alloy compared to pure zinc at a large discharge conditions,that is the addition of indium may enhance the electrochemical activity of Zn alloy electrodes.It is found that the anodic dissolution of zinc-indium alloy electrodes in the concentrated KOH solution occurs …

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Study On The Corrosion Of Chlorine Condenser By Electrochemical Method, Bin Xiang, Wen Chen, Wen-Zhang Huang, Shao-Hua Xing, Sheng-Tao Zhang Nov 2007

Study On The Corrosion Of Chlorine Condenser By Electrochemical Method, Bin Xiang, Wen Chen, Wen-Zhang Huang, Shao-Hua Xing, Sheng-Tao Zhang

Journal of Electrochemistry

Corrosion of condenser is very seriously in chlorine-alkali industry,which could lead to fatal disaster.The most commonly used material in low pressure condenser includes steel of 16MnR,10#,and welding rod of J507.Electrochemical analysis of the three materials in 29.9%(by mass) calcium chloride(CaCl2) solution was carried out.The corrosion current density icorr and impedance parameters of the three materials in 29.9% CaCl2 solution were estimated separately.The result showed that in the tripartite phase regions where the 10# seamless tube and 16MnR armor plate were jointed by welding,the weld was firstly eroded and suggested that the chlorine condenser should be examined and …

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Determination Of Malathion Based On Carbon Nanotubes Modified Electrode Incorporating Acetylcholinesterase, Lu Zhang, Yao-Dong Zhang, Hong-Lan Qi Nov 2007

Determination Of Malathion Based On Carbon Nanotubes Modified Electrode Incorporating Acetylcholinesterase, Lu Zhang, Yao-Dong Zhang, Hong-Lan Qi

Journal of Electrochemistry

A biosensor for determination of organophosphorus pesticide based on the acetylcholinesterase and multi-wall carbon nanotubes modified electrode is fabricated.Under the optimal conditions,the chronoamperometric current at +0.70V(vs.SCE) increased linearly with the concentration of malathion in the range from 6.0×10-10 to 6.0×10-9 mol·L-1 with a detection limit of 1.0×10-10 mol·L-1.The recoveries of malathion in lake water is 97% to 105% determinated by this method.

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Ion-Implanting Modification Of Layered Manganese Dioxide And Its Electrochemical Performance, He-Ning Huang, Dong-Ping Lv, Xing-Kang Huang, Qi-Wei Zhang, Yong Yang Nov 2007

Ion-Implanting Modification Of Layered Manganese Dioxide And Its Electrochemical Performance, He-Ning Huang, Dong-Ping Lv, Xing-Kang Huang, Qi-Wei Zhang, Yong Yang

Journal of Electrochemistry

Layered MnO2(δ-MnO2) was prepared by thermal decomposition of potassium permanganate.Ti was ion-implanted into such δ-MnO2 by physical techniques,forming a composite(δ-MnO2-Ti).These materials were characterized by XRD,SEM,XPS techniques and their electrochemical proprieties were investigated.The results showed that the layered structure of δ-MnO2 did not been destroyed after Ti ion implantation,and the implanted Ti element was mainly Ti4+ as indicated by XPS.Both of the first and the highest discharge specific capacities of the ion-implanted layered MnO2(δ-MnO2-Ti),compared to those of δ-MnO2,were improved significantly.

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Electrochemical Behavior And Determination Of Luteolin At A Glassy Carbon Electrode, Ai-Lin Liu, Shao-Bo Zhang, Xiao-Sha Wu, Li-Ping Li, Yang-Yuan Cao, Li-Ying Huang, Xin-Hua Lin Nov 2007

Electrochemical Behavior And Determination Of Luteolin At A Glassy Carbon Electrode, Ai-Lin Liu, Shao-Bo Zhang, Xiao-Sha Wu, Li-Ping Li, Yang-Yuan Cao, Li-Ying Huang, Xin-Hua Lin

Journal of Electrochemistry

The electrochemical behavior of luteolin was studied by voltammetry at a glassy carbon electrode in phosphate buffer solution.The results exhibited that the well-defined redox peak of luteolin is observed and the electrode process is adsorption-controlled.The charge transfer coefficient(α) was calculated as 0.66 in phosphate buffer solution(pH 4.0).The relationships between oxidation peak current and the concentration of luteolin are linear in the range of 1.0×10-8 ～ 5.0×10-6 mol·L-1 by differential pulse voltammetric method.The detection limit had been estimated as 1.0×10-8 molL-1.This method can be used for the determination of luteolin with satisfactory results.

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Selection Of Additions In The Process Of Electrochemical Synthesizing Of K2Feo4, Wei-Hua Yang, Dong-Qin Bi, Yan Zhou, Hong-Hui Wang, Xin-Ren Lan Nov 2007

Selection Of Additions In The Process Of Electrochemical Synthesizing Of K2Feo4, Wei-Hua Yang, Dong-Qin Bi, Yan Zhou, Hong-Hui Wang, Xin-Ren Lan

Journal of Electrochemistry

Some of different additions including KIO4 was added to the anodic electrolyte for electrochemical synthesizing of K2FeO4,the effects of these additions on current yield were investigated.XRD and SEM were used to characterize the structure and image of K2FeO4.The results show that KIO4 is a preferable addition.When the mass dosage of KIO4 is 0.02%,electrolysis time is 1 h,the current yield is enhanced by 31.6% and the corresponding purity of the product is improved by 3.85 %.

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Electrochemical Behavior Of Zinc Alloy Anode In Ca(Oh)2 Solutions Of Different Ph, Peng-Ying Ren, Ji-Quan He Nov 2007

Electrochemical Behavior Of Zinc Alloy Anode In Ca(Oh)2 Solutions Of Different Ph, Peng-Ying Ren, Ji-Quan He

Journal of Electrochemistry

The polarization curves of zinc alloy anodes in Ca(OH)2 solutions have been measured by potentiodynamic method,and the composition of corrosion products were examined by X-ray-diffraction(XRD).The experimental results indicated that not only the electrochemical behavior of zinc alloy anodes were absolutely different in every alkaline solutions,but also many electrochemical parameters were determined,such as zero current potential(E0),the density of corrosion current(icorr),passive current density(ip),breakdown potential(Eb),and so on.There were three zero current potential when zinc alloy anodes in some Ca(OH)2 solutions which made passive state unstable.The graphs of E-pH about zinc alloy anodes dipped in different Ca(OH)2 solutions were drawn,and compared …

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Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong Nov 2007

Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong

Journal of Electrochemistry

Corrosion behavior of carbon steel in methyldiethanolamine(MDEA) solution was investigated by Electrochemical Impedance Spectroscopy(EIS).The results were showed that the corrosion rate of carbon steel in solution containing dissolved oxygen is higher than that in solution removed of dissolved oxygen before cathodic activation.They were reversed after cathodic activation.The corrosion rate is increased at first and then decreased when the concentration of MDEA is increased in the blank solutions.In the simulated solutions containing quantities of!heat-stable salts(HSS),the corrosion rate is decreased monotonously with increase of the MDEA concentration.As anodic polarization potential is increased,the EIS of carbon steel in HSS simulated solution showed characteristics …

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An Experimental Technique For The Evaluation Of Strain Dependent Material Properties Of Hard Coatings, Shad A. Reed, Anthony N. Palazotto, William P. Baker Oct 2007

An Experimental Technique For The Evaluation Of Strain Dependent Material Properties Of Hard Coatings, Shad A. Reed, Anthony N. Palazotto, William P. Baker

Faculty Publications

A novel vibration experiment consisting of a free-free boundary condition, an electromagnetic excitation source, a vacuum chamber, and a laser vibrometer based surface measurement system has been developed that permits high levels of excitation on highly damped specimens with a minimal amount of unwanted systematic error. While some of the aspects of this experiment are not unique, when combined with a processing technique that accounts for the nonlinearities present in the system, this experiment permits, accurate measurement of strain dependent stiffness and damping properties of hard coatings at high strain levels. This procedure has been demonstrated using a titanium beam …

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Cyclic Creep And Recovery Behavior Of Nextel™ 720/Alumina Ceramic Matrix Composite At 1200° C In Air And Steam Environments, Bridgett A. Whiting Sep 2007

Cyclic Creep And Recovery Behavior Of Nextel™ 720/Alumina Ceramic Matrix Composite At 1200° C In Air And Steam Environments, Bridgett A. Whiting

Theses and Dissertations

The cyclic creep and recovery behaviors of the N720/Al2O3 composite were investigated in this research. The ceramic matrix composite (CMC) contains a porous alumina matrix with laminated, woven mullite/alumina (NextelTM 720) fibers. The composite does not have an interface between the fiber and matrix. The CMC relies on the porous nature for flaw tolerance. The objective of this study the influences of monotonic creep and cyclic creep loading histories on the creep lifetime, creep strain rate, accumulated creep strain as well as on the recovery of creep strain at near zero stress. The cyclic creep and …

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Oxygen Enrichment Effect Of Mno2-Pt/C Compound Catalyst To The Cathode Of Pemfc, Hong-Feng Xu, Mao-Feng Zhang, Quan-Quan Gan, Cai-Sheng Huang Aug 2007

Oxygen Enrichment Effect Of Mno2-Pt/C Compound Catalyst To The Cathode Of Pemfc, Hong-Feng Xu, Mao-Feng Zhang, Quan-Quan Gan, Cai-Sheng Huang

Journal of Electrochemistry

TO study of the oxygen storage material of air cathode is crucial for increasing performance of proton exchange membrane fuel cell.Using the MnO2 as oxygen storage materials,a MnO2-Pt/C catalysts were prepared and is used to replace the conventional Pt/C in air cathode.The electrochemical performance of air cathode composed of MnO2 supported on Pt/C and the properties of fuel cell composed of MnO2-Pt/C were investigated by using the CV,galvanostatic dischange method and TEM.

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Growth Mechanism And Morphology Of Electrodeposited Micro-Nanocrystalline Iron, Qiao-Xin Zhang, Jia-Ming Zhang, Li-Ning Yang Aug 2007

Growth Mechanism And Morphology Of Electrodeposited Micro-Nanocrystalline Iron, Qiao-Xin Zhang, Jia-Ming Zhang, Li-Ning Yang

Journal of Electrochemistry

Effects of current density,reaction temperature,electrolyte concentration and surfactant on the electrochemical deposition of micro-nanocrystalline iron were studied.Morphologies and structures of the samples were characterized by SEM and XRD,the results showed that the electrodeposits is slice α-Fe under little current and the density,lower temperature and higher concentration,and the dentritic α-Fe is under opposite conditions,but the influence from surfactant is unconsicously.Moreover,the growth mechanism of the electrodeposits was also analysed here.

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Studies On Catalytic Mechanism Of Li/Socl2 Batteries By Metal Phthalocyanine Complexes, Zhan-Wei Xu, Qing-Jin Sun, Bi-Yun Su, Tu-Lin Che, Yan-Hong Song, Yao-Min Li, Jian-She Zhao Aug 2007

Studies On Catalytic Mechanism Of Li/Socl2 Batteries By Metal Phthalocyanine Complexes, Zhan-Wei Xu, Qing-Jin Sun, Bi-Yun Su, Tu-Lin Che, Yan-Hong Song, Yao-Min Li, Jian-She Zhao

Journal of Electrochemistry

Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.

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