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Nanoscale Electrochemistry By In-Situ Transmission Electron Microscopy, Qi Gao Jan 2013

Nanoscale Electrochemistry By In-Situ Transmission Electron Microscopy, Qi Gao

Dissertations, Master's Theses and Master's Reports - Open

Nanoscale research in energy storage has recently focused on investigating the properties of nanostructures in order to increase energy density, power rate, and capacity. To better understand the intrinsic properties of nanomaterials, a new and advanced in situ system was designed that allows atomic scale observation of materials under external fields. A special holder equipped with a scanning tunneling microscopy (STM) probe inside a transmission electron microscopy (TEM) system was used to perform the in situ studies on mechanical, electrical, and electrochemical properties of nanomaterials. The nanostructures of titanium dioxide (TiO2) nanotubes are characterized by electron imaging, diffraction, and chemical …


High Voltage Electrophoretic Deposition For Electrochemical Energy Storage And Other Applications, Sunand Santhanagopalan Jan 2013

High Voltage Electrophoretic Deposition For Electrochemical Energy Storage And Other Applications, Sunand Santhanagopalan

Dissertations, Master's Theses and Master's Reports - Open

High voltage electrophoretic deposition (HVEPD) has been developed as a novel technique to obtain vertically aligned forests of one-dimensional nanomaterials for efficient energy storage. The ability to control and manipulate nanomaterials is critical for their effective usage in a variety of applications. Oriented structures of one-dimensional nanomaterials provide a unique opportunity to take full advantage of their excellent mechanical and electrochemical properties. However, it is still a significant challenge to obtain such oriented structures with great process flexibility, ease of processing under mild conditions and the capability to scale up, especially in context of efficient device fabrication and system packaging. …


Local Digital Control Of Power Electronic Converters In A Dc Microgrid Based On A-Priori Derivation Of Switching Surfaces, Bibaswan Banerjee Jan 2013

Local Digital Control Of Power Electronic Converters In A Dc Microgrid Based On A-Priori Derivation Of Switching Surfaces, Bibaswan Banerjee

Dissertations, Master's Theses and Master's Reports - Open

In power electronic basedmicrogrids, the computational requirements needed to implement an optimized online control strategy can be prohibitive. The work presented in this dissertation proposes a generalized method of derivation of geometric manifolds in a dc microgrid that is based on the a-priori computation of the optimal reactions and trajectories for classes of events in a dc microgrid. The proposed states are the stored energies in all the energy storage elements of the dc microgrid and power flowing into them. It is anticipated that calculating a large enough set of dissimilar transient scenarios will also span many scenarios not specifically …


Synthesis Of Graphene And Its Applications For Dye-Sensitized Solar Cells, Hui Wang Jan 2013

Synthesis Of Graphene And Its Applications For Dye-Sensitized Solar Cells, Hui Wang

Dissertations, Master's Theses and Master's Reports - Open

Graphene, which is a two-dimensional carbon material, exhibits unique properties that promise its potential applications in photovoltaic devices. Dye-sensitized solar cell (DSSC) is a representative of the third generation photovoltaic devices. Therefore, it is important to synthesize graphene with special structures, which possess excellent properties for dye-sensitized solar cells.

This dissertation research was focused on (1) the effect of oxygen content on the structure of graphite oxide, (2) the stability of graphene oxide solution, (3) the application of graphene precipitate from graphene oxide solution as counter electrode for DSSCs, (4) the development of a novel synthesis method for the three-dimensional …


Experimental Investigation Into Particulate Matter Distribution In Catalyzed Particulate Filters Using A 3d Terahertz Wave Scanner, Ryan Kristopher Foley Jan 2013

Experimental Investigation Into Particulate Matter Distribution In Catalyzed Particulate Filters Using A 3d Terahertz Wave Scanner, Ryan Kristopher Foley

Dissertations, Master's Theses and Master's Reports - Open

The particulate matter distribution (PM) trends that exist in catalyzed particulate filters (CPFs) after loading, passive oxidation, active regeneration, and post loading conditions are not clearly understood. These data are required to optimize the operation of CPFs, prevent damage to the CPFs caused by non-uniform distributions, and develop accurate CPF models. To develop an understanding of PM distribution trends, multiple tests were conducted and the PM distribution was measured in three dimensions using a terahertz wave scanner. The results of this work indicate that loading, passive oxidation, active regeneration, and post loading can all cause non-uniform PM distributions. The density …