Electrical and Computer Engineering Commons^™

Comparison Of Lithium-Ion Anode Materials Using An Experimentally Verified Physics-Based Electrochemical Model, Rujian Fu, Xuan Joe Zhou, Hengbin Fan, Douglas Blaisdell, Ajay Jagadale, Xi Zhang, Rui Xiong

Electrical & Computer Engineering Publications

Researchers are in search of parameters inside Li-ion batteries that can be utilized to control their external behavior. Physics-based electrochemical model could bridge the gap between Li+ transportation and distribution inside battery and battery performance outside. In this paper, two commercially available Li-ion anode materials: graphite and Lithium titanate (Li4Ti5O12 or LTO) were selected and a physics-based electrochemical model was developed based on half-cell assembly and testing. It is found that LTO has a smaller diffusion coefficient (Ds) than graphite, which causes a larger overpotential, leading to a smaller capacity utilization and, correspondingly, a shorter duration of constant current charge …