Environmental Engineering Commons^™

Low Dissolved Oxygen Operation Enhances Biological Phosphorus Removal In Wastewater Treatment, Haley Morgan

Civil & Environmental Engineering Theses & Dissertations

Biological phosphorus (bio-P) removal occurs when bacteria are exposed to anaerobic/aerobic conditions that stimulate polyphosphate-accumulating organisms (PAOs) to uptake phosphorus. In most treatment plants, dissolved oxygen (DO) concentrations in the aeration tanks are commonly at or above 2.0 mg O₂/L, which is often referred to as the most optimal aeration condition for bio-P. If bio-P can happen efficiently at lower DO (< 0.3 mg O₂/L), then the energy demand of aeration can be decreased appreciably. This research was conducted in a biological nutrient removal (BNR) pilot plant to assess the performance of bio-P at progressively lower DO operation. This …

Passive Phosphorus Filtering System Design, Ryan T. Bailey

Williams Honors College, Honors Research Projects

The objective of this project is to find an efficient way to remove phosphorus from surface water through passive filtration. Specifically, the project will focus on the upper Cuyahoga River. Ongoing research being conducted by Dr. Teresa Cutright from The University of Akron and Jessica Glowczewski from the City of Akron’s Watershed Division serves as a basis for this project.

Fertilizers used in agriculture are often washed off by rainfall and enter the groundwater and nearby streams. The phosphorus contained in the fertilizer can be harmful to the environment by increasing the frequency of large algal blooms. To reduce the …

Transport Of Nutrients By Overland Flow On Sites Containing Beef Cattle Manure, John E. Gilley, Ryan P. Mcgehee, Kenneth M. Wacha

Department of Agricultural and Biological Systems Engineering: Faculty Publications

In an inductive metastudy, we investigated the effects of varying rates of overland sheet flow on the transport of phosphorus (P) and nitrogen (N) from sites containing beef cattle manure. The analyzed data were collected during previously reported field rainfall simulation investigations conducted on cropland sites and a beef cattle feedlot in the US state of Nebraska. During the experiments, inflow was incrementally added to the top of the experimental plots to simulate runoff rates occurring at greater downslope distances. Runoff rates on the experimental plots ranged from 2.9 to 22.9 Lmin⁻¹, and the maximum equivalent downslope distances …

Nutrient Removal Of Biochar Amended Modified Bioretention Systems Treating Nursery Runoff, Nicholas Richardson

USF Tampa Graduate Theses and Dissertations

Excess inputs of nutrients, such as nitrogen and phosphorus, to surface water bodies can lead to the presence of harmful algal blooms (HABs). HABs can damage their surrounding environments and the economies dependent on them. Nutrient pollution can be properly controlled and monitored at point-sources, such as wastewater treatment plants, but is more difficult to control for non-point sources, such as fertilizer runoff. One form of fertilizer runoff that remains overlooked is runoff from plant nurseries. Controlled release fertilizers (CRFs) embedded in plant containers at nurseries can leach excess nutrients into the runoff. For nurseries in Florida, best management practices …

Stream Water Quality Under Baseflow Conditions In A Livestock Production Area, Maryi Lorena Chavarro Chaux

Theses and Dissertations

This study evaluates the spatial and temporal impacts of implemented Best Management Practices (BMP) on stream water quality under baseflow conditions in a stream segment affected by livestock production. The BMPs includes 10-m fenced riparian zone and crossing paths along the reach segment. Grab water samples and water quality monitoring were collected biweekly from July 2019 to March 2022. Water quality parameters included temperature, dissolved oxygen, electric conductance, total dissolved solids, turbidity, and pH. Water samples were lab analyzed for sediments and nutrients. Results evidenced poor water quality before BMPs implementation, with nutrient concentrations exceeding the nation's and state's criteria. …

Comparing Phosphorus Removal Efficiencies And Mechanisms Via Two Cost-Effective Specialty Adsorbents In A Cascade Upflow Filtration System, Sydney Kilgus-Vesely

Honors Undergraduate Theses

Finding solutions to treat water that contains phosphorus is an important effort due to the harmful impacts it presents to both human health and the environment. Phosphorus is considered a limiting factor in water oftentimes and therefore controls the growth of algal bloom in a water body. The increase of algal populations due to wastewater effluent, stormwater runoff, and agricultural discharge in Florida waters has a direct link to the event of harmful algal blooms such as red tide in coastal regions, eutrophication of waterbodies, and fish kills. Finding low cost, energy efficient, and low maintenance green sorption media (GSM) …

Efficiency Of Bank Filtration In The Removal Of Cyanotoxins Under Different Levels Of Nutrients, Luke Walkenhorst

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Harmful Algal Blooms (HABs) are an increasing concern not only in Nebraska, but across the world. Increasing global temperatures in conjunction with overuse of synthetic fertilizers are leading causes to the increasing frequency and concern of HABs. In the present work, the effectiveness of simulated bank filtration (BF), as an economical water treatment option, to remove cyanotoxins under different levels of nutrients (nitrates and phosphates) was investigated. Vertical flow-through columns pre-acclimated with two levels of nutrients (e.g., nitrate and phosphate—10 vs. 50 mg/L) were exposed to two different levels of cyanotoxins (10 vs. 75 μg/L). Results from the study confirmed …

Elemental Sulfur And Metal Sulfide Minerals For Autotrophic Denitrification: Applications To Aquaculture, Groundwater Treatment, And Domestic Wastewater Treatment, Erica Amah Dasi

USF Tampa Graduate Theses and Dissertations

Nutrient pollution of waterways, from excess N and P, is a global concern that results in harmful impacts the environment, human health, and aquatic animals. This dissertation harnesses sulfur autotrophic denitrification to remove nutrients from groundwater, domestic wastewater, and wastewaters produced from marine recirculating aquaculture systems (RAS). Part 1 evaluates the denitrification performance of woodchips and elemental sulfur in cyclic denitrification filters (WS-CDFs) integrated into marine RAS operated under saline conditions. Part 2 investigates the use of metal sulfide minerals, with and without oyster shells, for supporting nutrient removal from groundwater in batch reactors. Part 3 assesses …

Recovery Of Phosphorus From Florida Phosphatic Waste Clay, Amir Eskanlou

Graduate Theses, Dissertations, and Problem Reports (ETD)

This MS thesis examines the recovery of phosphorus (P) from Florida waste clay (WC). A comprehensive literature review revealed that: (i)-The most important values being lost to WC are P and rare earth elements (REEs). For the recovery of these values from WC, two crucial attempts are the removal of extremely fine-sized clays, followed by the recovery of phosphate content, which can pave the path for the recovery of REEs; (ii)-Any scientific/ technological solution should, at the same time, be economically and environmentally attractive to the industry. As such, moving from mostly chemical separation processes to the primarily physical/ physicochemical …

Agrochemical Indicators Of New Irrigated Graph-Meadow Soils Formed On The Iii Underfladder Terrace Of Syrdarya, J.M. Kuziev

Irrigation and Melioration

Presents material on the geographical location, geomorphological and geological structure, as well as the agrochemical state of irrigated serozem-meadow soils, common in the Mirzaabad district of the Syrdarya region. According to the data obtained on the chemical analysis of soils, the studied soils are medium- and heavily loamy in texture, where particles of coarse sand predominate (0.05-0.01%). In the arable horizon of these soils, the humus content is 1.088-1.214%, total nitrogen 0.079-0.089%, total phosphorus 0.109-0.124%, and total potassium within 1.15-1.24%, and on the basis of these data, a regularity of the underlying horizon of these soils. The degree of provision …

Accumulation And Release Of Nutrients By Immersed Stalks Collected On Selected Dates Following Harvest, John E. Gilley, David B. Marx

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The concentrations of phosphorus (P) and nitrogen (N) in runoff from cropland areas may be influenced by accumulation and release of P and N by stalk residues. A laboratory study was conducted to measure the effects of time since harvest and immersion period on accumulation and release of P and N by corn, soybean, and wheat stalks. Experimental variables included type of stalk material (corn, soybean, and wheat), time since harvest (six residue collection dates over an approximate 1-year period), and stalk immersion period (25 s (0.42 min), 250 s (4.2 min), 2500 s (42 min), 25,000 s (6.9 h), …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Hannah Young

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Kristin Moore

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Ronald Simpson, Sara Kidd, Samantha Zidd

Williams Honors College, Honors Research Projects

Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bio-available phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Previous studies indicated that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss, 2007). In this project, we conducted experiments using higher quality concentration measurements to determine what grades of steel wool (SW-0000, SW-000, SW-00) and types of activated carbon (granulated …

The Impact Of Phosphorous Species On Dewaterability Of Wastewater Solids, Erik Anderson

Master's Theses (2009 -)

Phosphorus regulations are causing Water Resource Recovery Facilities (WRRFs) to implement new technologies to remove phosphorus (P) before they discharge liquid effluent. Enhanced Biological Phosphorus Removal (EBPR) is often employed to remove P from water. However, sludges from EBPR plants have shown decreases in dewaterability soon after EBPR was initiated. This decline in dewaterability is not well understood, nor is the best way to improve the dewatering EBPR sludge. Specifically, the role of different P species on sludge dewaterability is not well understood. Several laboratory experiments were conducted at the Marquette University Water Quality Center with the following objectives: i) …

Modeling Canopy Effect In The Great Lakes Cladophora Model, Ankita Bakshi

Dissertations, Master's Theses and Master's Reports

Cladophora glomerata is a filamentous green alga native to the Great Lakes. However, its nuisance growth in phosphorus rich waters negatively affects the lakes’ aesthetic and water quality. The Great Lakes Cladophora Model (GLCM) v1, developed in 1982, was the first mechanistic model to simulate Cladophora growth basing phosphorus availability and environmental conditions followed by Cladophora Growth Model and GLCM v2. In this study, the light and temperature mediation factors for Cladophora net growth are revised as a necessary step prior to the development of a self-shading algorithm. The concept of a fixed-value, maximum achievable biomass (carrying capacity) employed in …

Setback Distance Requirements For Removal Of Swine Slurry Constituents In Runoff, John E. Gilley, Shannon L. Bartelt-Hunt, Kent M. Eskridge, Xu Li, Amy M. Schmidt, Daniel D. Snow

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The use of setback distances for manure application on cropland areas adjacent to surface water bodies could serve a function similar to vegetative filter strips. However, little information currently exists to identify the setback distances necessary to effectively reduce the transport of contaminants in runoff. The objective of this study was to determine the effects of setback distance and runoff rate on concentrations of selected constituents in runoff following land application of swine slurry to a no-till cropland area in southeast Nebraska. The study site had a residue cover of 7.73 Mg ha-1 and a slope gradient of 4.9%. The …

Holistic Approach In Microalgae Conversion To Bioproducts And Biofuels Through Flash Hydrolysis, Ali Teymouri

Civil & Environmental Engineering Theses & Dissertations

In recent years, the demand for renewable energy, mainly biomass has increased. The U.S. Energy Information Administration reported that more than 13.3% of the total energy production in the first seven months of 2017 was produced from a biomass source. Among all biomass resources, microalgae has brought a lot of attention due to their numerous advantages such as higher growth rate and productivity compared with the conventional energy crops, higher energy conversion efficiency by photosynthesis, and less water requirement than terrestrial crops. However, its development is far behind industrial production. Several research efforts across the globe have been concerned with …

Impact Of Macropores And Gravel Outcrops On Phosphorus Leaching At The Plot Scale In Silt Loam Soils, Derek M. Heeren, Garey A. Fox, Chad Penn, Todd Halihan, Daniel E. Storm, Brian Haggard

Department of Agricultural and Biological Systems Engineering: Faculty Publications

In response to increased nutrient loads in surface waters, scientists and engineers need to identify critical nutrient source areas and transport mechanisms within a catchment to protect beneficial uses of aquatic systems in a cost-effective manner. It was hypothesized that hydrologic heterogeneities (e.g., macropores and gravel outcrops) in the vadose zone play an integral role in affecting flow and solute transport between the soil surface and shallow alluvial aquifers. The objective of this research was to characterize phosphorus (P) leaching through silt loam soils to alluvial gravel aquifers in the floodplains of the Ozark ecoregion at the plot scale. Solute …

Runoff Water Quality Characteristics Following Swine Slurry Application Under Broadcast And Injected Conditions, Nicole R. Schuster, Shannon L. Bartelt-Hunt, Lisa M. Durso, John E. Gilley, Xu Li, David B. Marx, Amy M. Schmidt, Daniel D. Snow

Department of Agricultural and Biological Systems Engineering: Faculty Publications

This study was conducted to measure the effects of swine slurry application method, time following slurry application, and runoff rate on selected water quality characteristics. Slurry from a commercial swine operation was broadcast or injected on field plots at a rate required to meet annual nitrogen requirements for corn. Rainfall simulation tests were conducted at five varying periods following slurry application. During each study period, three simulated rainfall events, separated by 24 h intervals, were applied for 30 min duration at an intensity of approximately 70 mm h^-1. Following the third rainfall simulation event, inflow was applied at …

Removal Of Cattle Manure Constituents In Runoff From No-Till Cropland As Affected By Setback Distance, John E. Gilley, Aaron J. Sindelar, Brian L. Woodbury

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Vegetative filter strips located at the bottom of a hillslope have been shown to substantially reduce nutrients and sediment in runoff. Cropland areas could serve a similar function. However, little scientifically derived information is available to help identify the setback distances required to effectively reduce the transport of contaminants in runoff. The objective of this study was to determine the effects of setback distance and runoff rate on the concentrations and mass transport rates of selected constituents following land application of beef cattle manure to a no-till cropland area. The study site had a residue cover of 8.84 Mg ha-1 …

Removal Of Cattle Manure Constituents In Runoff From No-Till Cropland As Affected By Setback Distance, John E. Gilley, Aaron J. Sindelar, Bryan L. Woodbury

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Vegetative filter strips located at the bottom of a hillslope have been shown to substantially reduce nutrients and sediment in runoff. Cropland areas could serve a similar function. However, little scientifically derived information is available to help identify the setback distances required to effectively reduce the transport of contaminants in runoff. The objective of this study was to determine the effects of setback distance and runoff rate on the concentrations and mass transport rates of selected constituents following land application of beef cattle manure to a no-till cropland area. The study site had a residue cover of 8.84 Mg ha …

Ion Exchange-Precipitation For Nutrient Recovery From Dilute Wastewater, A. T. Williams, Daniel Zitomer, Brooke K. Mayer

Civil and Environmental Engineering Faculty Research and Publications

Regulated phosphorus (P) and nitrogen (N) discharges and the cost of fertilizer provide economic drivers for nutrient removal and recovery from wastewater. This study used ion exchange (IX) in dilute (domestic) wastewater to concentrate nutrients with subsequent recovery by struvite precipitation. This is the first tertiary wastewater treatment study directly comparing P removal using a range of Fe, Cu, and Al-based media followed by clinoptilolite IX columns for N removal and precipitation using the combined regenerants. Phosphate removal prior to breakthrough was 0.5–2.0 g P L_media⁻¹, providing effluent concentrations −1 PO₄-P and −1 NH_{4 …}

Nutrient Recovery From Anaerobic Membrane Bioreactor Permeate Using Ion Exchange, Patrick Mullen

Master's Theses (2009 -)

Phosphorus is a common element in wastewater streams and traditional treatment processes are often designed remove it to achieve low effluent limits. Such processes often do not often consider the potential value of the nutrient. Currently, production of phosphate fertilizers has dramatically risen causing concern for the depletion of phosphate rock reserves, bringing about exploration into alternative sources of phosphorus for agricultural use. Combining the needs of phosphorus removal from wastewaters and securing alternate sources of the nutrient provide an opportunity for recovery. This project evaluated a nutrient recovery process through ion exchange with beneficial recovery as precipitated struvite using …

Diffuse Nutrient Pollution From Residential Catchments, Melissa Rachelle Butcher

USF Tampa Graduate Theses and Dissertations

Nonpoint source nutrient pollution is diffuse pollution lacking discrete origin and conveyance. This thesis synthesizes and critically reviews research on residential nitrogen and phosphorus loss to stormwater runoff and leaching. The evaluation pulls from research covering influential socio-demographic indicators, such as use of lawn maintenance services and homeowner fertilizer practices. The extent to which such social and economic factors may influence the prevalence and fate of diffuse nutrients in stormwater runoff from residential areas has not been adequately established. Understanding the source and influencing factors of diffuse nutrient pollution is important in order to effectively protect surface and groundwater resources. …

The Effects Of Bam As An Adsorptive Media On Phosphorus Removal In Stormwater, Sultan Salamah

Electronic Theses and Dissertations

To maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of this project is to find the BAM values for coefficients such as maximum adsorption capacity (QM: 4.35E-05) for the media through SRP isotherm equilibrium experiments using the Langmuir …

Development Of Treatment Train Techniques For The Evaluation Of Low Impact Development In Urban Regions, Mike Hardin

Electronic Theses and Dissertations

Stormwater runoff from urban areas is a major source of pollution to surface water bodies. The discharge of nutrients such as nitrogen and phosphorus is particularly damaging as it results in harmful algal blooms which can limit the beneficial use of a water body. Stormwater best management practices (BMPs) have been developed over the years to help address this issue. While BMPs have been investigated for years, their use has been somewhat limited due to the fact that much of the data collected is for specific applications, in specific regions, and it is unknown how these systems will perform in …

Nutrient Concentrations Of Runoff As Affected By The Diameter Of Unconsolidated Material From Feedlot Surfaces, John E. Gilley, Gregory Boone, David B. Marx

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Beef cattle feedlots contain unconsolidated material that accumulates on the feedlot surface during a feeding cycle. This study was conducted to measure the effects of varying diameters of unconsolidated surface material and varying flow rates on nutrient concentrations in runoff. Unconsolidated surface material with an average diameter of 4.76, 9.53, 19.1, or 47.5 mm and a composite sample with a 15.2 mm mean diameter were placed within 0.75 m wide × 4.0 m long plot areas. Flow was then introduced at the top of the plots in successive increments, and runoff samples for water quality analyses were obtained. Particle diameter …

Runoff Nutrient Transport As Affected By Land Application Method, Swine Growth Stage, And Runoff Rate, J. E. Gilley, Shannon L. Bartelt-Hunt, S. J. Lamb, X. Li, D. B. Marx, D. D. Snow, D. B. Parker, B. L. Woodbury

Department of Agricultural and Biological Systems Engineering: Faculty Publications

This study was conducted to measure the effects of slurry application method, swine growth stage, and flow rate on runoff nutrient transport. Swine slurry was obtained from production units containing grower pigs, finisher pigs, or sows and gilts. The swine slurry was applied using broadcast, disk, or injection methods at a rate required to meet annual nitrogen requirements for corn. Three 30 min simulated rainfall events, separated by 24 h intervals, were applied to the experimental plots at an intensity of 70 mm h^-1. Inflow was applied at the top of each plot in four successive increments after …

Integrated Assessment Of Anthropogenic, Climate, And Policy Induced Changes Of Phosphorus Export In The United States Laurentian Great Lakes Watersheds, Meredith Ballard Labeau

Dissertations, Master's Theses and Master's Reports - Open

Anthropogenic activities have increased phosphorus (P) loading in tributaries to the Laurentian Great Lakes resulting in eutrophication in small bays to most notably, Lake Erie. Changes to surface water quality from P loading have resulted in billions of dollars in damage and threaten the health of the world’s largest freshwater resource. To understand the factors affecting P delivery with projected increasing urban lands and biofuels expansion, two spatially explicit models were coupled. The coupled models predict that the majority of the basin will experience a significant increase in urban area P sources while the agriculture intensity and forest sources of …