Environmental Engineering Commons^™

Bioremediation Of Chlorinated Ethenes: Ph Effects, Novel Dechlorinators And Decision-Making Tools, Yi Yang

Doctoral Dissertations

Chlorinated solvents have been widely used in different areas of modern society. Usage of these chlorinated solvents was not necessarily accompanied with proper handling and disposal of these hazardous compounds, which caused a variety of environmental problems and continues to affect human health. Remediation of chlorinated ethenes contaminated sites has high priority for state regulators and site owners. Among the available treatment technologies, bioremediation shows great promise as a cost-effective corrective strategy for a variety of environmental pollutants. Prerequisites are that the microbiology involved in contaminant degradation and geochemical factors, such as pH, are understood, so that bioremediation technologies can …

Potential Emissions And Exposures Of Toxic Organics From Storage Tanks For Chemical Additions In Hydraulic Fracturing: A Modeling Approach, Huan Chen

Doctoral Dissertations

Hydraulic fracturing has promoted the exploitation of natural gas in the United States (U.S.). However, the storing and emptying of chemical additives in hydraulic fracturing wells may pose adverse effects through inhalation exposures. Based on the information about hydraulic fracturing fluids, this study investigated: 1) water volumes used to mix chemical additives for making up the hydraulic fracturing fluids; 2) chemical species, concentrations and their degradability in the hydraulic fracturing fluids; 3) emissions of organics from chemical storage tanks; and 4) the occupational inhalation exposures by toxic and organic vapors.

Results shows for 80,047 wells fractured between 2008 and 2014 …

The Fate Of Haloacetonitriles In Drinking Waters, Yun Yu

Doctoral Dissertations

The fate of HANs in drinking waters from their precursors in natural waters to their degradation products in consumers’ tap were systematically investigated in this study. Combined amino acids were proved reactive with chlorine to form DCAN under typical drinking water conditions. However, the rate of DCAN formation from bound aspartyl residues was much slower compared to free aspartic acid. The key to DCAN formation from combined amino acids was a chlorine-induced peptide degradation process, which slowly degraded the peptide backbone to continuously produce reactive amine functional groups at the N-terminal end. Particularly, when an N-terminal aspartyl residue …

Integrated Urban Metabolism Analysis Tool (Iumat), Nariman Mostafavi

Doctoral Dissertations

A number of tools are available today for simulating different aspects of urban activity, but these efforts are fragmented and do not effectively reflect the interrelationships between very diverse groups of urban sectors and resource flows. There is a critical need for robust and reliable urban metabolism analysis tools that integrate socio-economic elements of urbanization and physicality of the built environment into evaluating sustainability in cities. This dissertation outlines the development of an Integrated Urban Metabolism Analysis Tool (IUMAT) that dynamically measures the environmental impacts of land cover, transportation, and consumption of energy, water and materials employing a holistic framework. …

Predictive Modeling Of Riverine Constituent Concentrations And Loads Using Historic And Imposed Hydrologic Conditions, Mark Hagemann

Doctoral Dissertations

This research was principally concerned with the task of quantifying dissolved and suspended constituents carried in river water when direct measurements are not available. This is a question of scientific and societal relevance, and one with a long history of study and a great deal of remaining difficulty. The traditional approach to estimating these quantities, linear regression models (LMs), suffers from poor flexibility and high subsequent bias in many applications. This research applied semiparametric generalized additive models (GAMs), a more flexible class of regression models, evaluated their performance in various locations and conditions, and applied them in a proactive modeling …

The Stability Of Ferrate(Vi) In Water And Its Impacts On Disinfection Byproduct Precursors, Yanjun Jiang

Doctoral Dissertations

Ferrate has been proposed as an alternative pre-oxidant in drinking water treatment for many years. Despite extensive studies that examined ferrate oxidation of specific contaminants, little research has been done on the impacts of ferrate in raw waters that include natural organic matter (NOM) and bromide, and that are also treated with coagulants and chlorine. The future of ferrate as a potable water treatment chemical depends on its ability to achieve adequate disinfection while minimizing the formation of disinfection byproducts (DBPs) under these realistic scenarios. In this work, laboratory-scale treatment studies were conducted to (1) clarify the stability of ferrate …

Proactive Assessment Of Climate Change And Contaminant Spill Impacts On Source Water Quality, Lillian C. Jeznach

Doctoral Dissertations

Managing the water quality of surface drinking water sources has become an increasingly difficult task for water suppliers due to increased watershed urbanization and climate change. Changes in source water quality may affect public perceptions, treatment effectiveness, and ultimately costs to treat water to drinking standards. Although there are increased threats to current and future drinking water quality, current approaches to managing these threats are typically reactionary. Prior detailed modeling efforts of hypothetical events that may impair raw water quality allow for an understanding of constituent fate and transport, including potential maximum concentrations and travel times to the drinking water …

Response Of Microbial Community Structure To Clay Flocculation Of Harmful Algal Blooms, Chunyi Chen

Doctoral Dissertations

Harmful algal blooms are cosmopolitan and can produce extremely dangerous toxins that can sicken or kill people and animals, and create dead zones in the water. The U.S. economic loss caused by algal blooms is $82 million every year. Clay-based flocculation techniques have been developed to mitigate algal blooms; however, the potential impacts on the microbial community are poorly understood. This dissertation includes multi-scale experiments (Jar, field, microcosms) to study the response of microbial community structure and function to clay flocculation of algal blooms.

Jar tests of removal of Microcystis aeruginosa by chitosan and two types of commercially available clays …

Investigation Of Effluent Nitrogen Derived From Conventional Activated Sludge (Cas) And Biological Nutrient Removal (Bnr) Systems And Its Impact On Algal Growth In Receiving Waters, Heonseop Eom

Doctoral Dissertations

The main objective of this research was to evaluate the effects of effluent nitrogen from conventional activated sludge (CAS) and biological nutrient removal (BNR) processes on eutrophication in receiving estuaries. To investigate differences in effluent nitrogen from CAS and BNR processes, lab-scale wastewater treatment systems having identical influent were operated under controlled conditions. This reactor study showed that the BNR system decreased nitrogen discharge by removing dissolved inorganic nitrogen (DIN) from wastewater but generated more effluent dissolved organic nitrogen (DON) than did the CAS system. The transition of treatment conditions from anoxic to oxic within the BNR process facilitated the …