Environmental Engineering Commons^™

Optimal Pulsed Pumping For Remediation Of Aquifers When Sorption Is Rate-Limited, Lawrence J. Schmitt

Theses and Dissertations

A variational optimization technique is developed to acquire an optimal schedule of pulsed pumping operations for use at existing pump-and-treat aquifer remediation sites. The optimization problem is stated as a minimization of a generic management objective functional, constrained by the contaminant transport equations in two-dimensional or three-dimensional flow models which account for rate-limited sorption. The two-dimensional case is fully developed and a first-order rate equation is used to describe the transport of sorbing contaminant. The first variation provides necessary optimality conditions that must be met by any optimal solution, in turn leading to a pulsed pumping schedule of operation. The …

Modeling Uptake And Translocation Of Lead (Pb) In Maize For The Purposes Of Phytoextraction, Mark A. Brennan

Theses and Dissertations

Phytoextraction is a remediation technology that uses plants to remove heavy metals from soil. This technology has the potential to decrease the costs of remediating contaminated sites by several orders of magnitude compared to traditional technologies. To effectively implement this technology requires an understanding of the plant processes that control uptake and translocation of metals from the soil. Currently these processes are poorly understood, and especially so for Pb. The purpose of this thesis was to gain insights concerning the plant mechanisms that control uptake and translocation of Pb and how these mechanisms interact to control levels of Pb accumulation …

A Modeling Study For The Implementation Of In Situ Cometabolic Bioremediation Of Trichloroethylene-Contaminated Groundwater, John A. Christ

Theses and Dissertations

The limitations of conventional groundwater remediation technologies have led to the development of innovative technologies which may achieve national hazardous waste site remediation goals. Before an innovative technology can be implemented in the field, remedial project managers, regulators and other stakeholders require adequate modeling tools to help assess the applicability of the technology at a particular site. This modeling study investigates how an innovative technology, in situ cometabolic bioremediation, might be implemented to remediate a TCE-contaminated site, under different site conditions. A steady-state model is developed which couples an analytical expression to simulate the effect of flow between multiple pumping …

Mobilization Of Trace Elements In Aquifers By Biodegradation Of Hydrocarbon Contaminants, Scott L. Kearney

Theses and Dissertations

This study had two objectives: (1) to determine the extent of metal mobility within petroleum-contaminated aquifers, (2) to determine if biodegradation of petroleum hydrocarbons can explain metal mobility. The approach reviewed analytical results from 2305 groundwater sampling events, taken from 958 wells, located at 136 sites found at 53 Air Force installations. The study showed that high levels of metals are present at petroleum hydrocarbon sites where metals would not generally be expected. Of the metals with drinking water maximum contaminant levels (MCLs), mercury and silver were detected the least frequently. Barium and copper were detected at the sites, but …

A Cercla-Based Decision Model To Support Remedy Selection For An Uncertain Volume Of Contaminants At A Doe Facility, Christine E. Kerschus

Theses and Dissertations

The Paducah Gaseous Diffusion Plant (PGDP) operated by the Department of Energy is challenged with selecting the appropriate remediation technology to cleanup contaminants at Waste Area Group (WAG) 6. This research utilizes value focused thinking and multi attribute preference theory concepts to produce a decision analysis model designed to aid the decision makers in their section process. The model is based on CERCLA's five primary balancing criteria, tailored specifically to WAG 6 and the contaminants of concern, utilizes expert opinion and the best available engineering, cost, and performance data, and accounts for uncertainty in contaminant volume. The model ranks 23 …

Evaluation Of The Natural Biodegradation Of Aircraft Deicing Fluid Components In Soils, Laura M. Johnson

Theses and Dissertations

This research effort was conducted to analyze the biodegradation of propylene glycol (PG) and tolyltriazole in two different soil types; a sandy soil and a high clay soil. Both an automated respirometer and a high performance liquid chromatograph (H PLO) were used in the analysis. Two separate experiments were conducted. In the first experiment, one level of tolyltriazole was added to the soils to determine whether or not there was a difference in the biodegradation rates of tolyltriazole in the two soils. The respirometer results indicated that there was a significant difference between the respiration rates of the microorganisms in …

Metabolic Inhibition Of A Toluene-Enriched Microbial Population Due To Lead (Pb2+): Verification Of A Free Metal Ion Toxicity Model, Patrick J. S. Marbas

Theses and Dissertations

A dissolved oxygen probe and an ion specific electrode were used to study the lead-induced metabolic inhibition in a toluene-enriched microbial population. Predicted toxicity values were compared to the actual toxicity responses using a free metal ion toxicity model (TM) which linked metabolic inhibition with lead activity. Experimentally derived values for the model parameters (lead activity and a lead distribution coefficient) were used in the TM. It was postulated that cellular metabolism is disrupted by the conformational changes to the cell's plasma membrane produced by lead ion adsorption. The predicted toxicity values were higher than the actual toxicity response. This …

Department Of Defense Hazardous Waste Site Remediation Issues In The Republic Of Korea, Edwin H. Oshiba

Theses and Dissertations

The purpose of this research was to provide information to DoD decision makers regarding factors influencing hazardous waste site remediation policy for South Korea. This study addressed: International agreements and U.S. and South Korean laws and policies relevant to hazardous waste sites; objectives of DoD environmental policy makers; extent and effects of soil and groundwater contamination; cleanup precedents set in other foreign countries; availability of resources and technical capabilities to investigate and remediate hazardous waste sites in South Korea; and opportunities for cooperation between the U.S. and South Korean military with regard to hazardous waste site remediation. Data were collected …

Investigation Of Biodegradation Processes In Solid Waste Landfills, Philip A. Colborn

Theses and Dissertations

Greater demands on landfill capacity, stricter regulations intended to minimize landfill environmental impacts, and the economic potential associated with landfill operations have shifted the emphasis of landfill disposal toward methods concerned with the long term performance and capacity of landfills. Two opposing philosophies have emerged in constructing and managing landfills: the dry tomb and the wet cell. The key to managing a landfill from the wet cell viewpoint is first understanding the biodegradation processes occurring within the landfill. This thesis attempts to determine the fundamental processes responsible for the degradation of solid waste by employing a system dynamics approach. A …

Biodegradation Of Deicing Agents In Various Soil Types, Annmarie Halterman-O'Malley

Theses and Dissertations

Airports have found that spent deicing fluids eventually reach the airfield's stormwater system and soil surrounding the airfield. Due to toxic effects of spent deicing fluids, containing and collecting the fluid for treatment can be a very costly activity for airports. One alternative to dispose of the used deicing fluid is to institute a land treatment system if it can be proven that the deicing fluid is readily biodegradable in a soil system. The primary concern of this research effort was to monitor the behavior of a simulated aircraft deicing fluid in various soil systems. An automated respirometer monitored the …

An Examination Of Elements Necessary For Transfer Of An Environmental Remediation Technology From Full-Scale Demonstration To Implementation, Glenn C. Mandalas

Theses and Dissertations

The fact that an innovative environmental remediation technology has been proven feasible in a full scale evaluation does not assure that the technology will be implemented. A number of regulatory, economic, and institutional barriers may impede the transition of a remediation technology from full scale demonstration to implementation. This research explores these barriers, suggesting means to overcome them. Regulators, technology users, and other remediation decision makers apply the nine criteria specified in the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) to evaluate the applicability of an innovative remediation technology at uncontrolled hazardous waste sites. These criteria consider such things …

A System Dynamics Model Of The Bioavailability Of Metals In Constructed Wetland Sediment, Timothy S. Wood

Theses and Dissertations

Constructed wetlands used for storm water treatment accumulate metals primarily in their sediment. This sediment has the potential to produce toxic effects in benthic organisms at some period in time. Bioavailability of metals in sediment is directly linked to pore water metal activity. The mechanisms that influence pore water metal activity are included in physical, chemical, and biological processes. A system dynamics model was developed to represent these processes and the major influences affecting pore water metal activity in a treatment wetland receiving storm water influent. The model structure and behavior was tested and validated using several system dynamics validation …

Maine Guide To Energy Efficient Residential Construction : A Manual Of Accepted Practices, State Of Maine Energy Conservation Division

Maine Collection

Maine Guide to Energy Efficient Residential Construction : A Manual of Accepted Practices

State of Maine Energy Conservation Division, Department of Economic and Community Development, 59 State House Station, Augusta, Maine 04333-0059

Second Edition - November, 1997

Contents: Dedication / Acknowledgements / Introduction / Part 1. Summary of Maine's Residential Energy Standards / Part 2. Siting and Initial Design Considerations / Part 3. Important Considerations for the Design Phase / Part 4. Recommended Construction Practices / Appendixes

The Detoxification Of Petroleum Contaminated Coastal Plain Sandy Soil Using An Amended Vermicomposting Approach, John Charles Kraemer

Health Services Research Dissertations

This study explores the feasibility of utilizing an amended vermicomposting treatment approach for detoxifying petroleum hydrocarbon contaminated sandy soil. The bench-scale testing of gasoline and diesel contaminated soil using three test soil vessels and one control soil vessel was performed in a laboratory setting for a six week time period. The control soil received no treatment other than distilled water to maintain soil moisture. Treatment 1 consisted of direct application of liquid municipal biologic sludge on a weekly basis. Treatment 2 consisted of the addition of 30 Eisenia foetida earthworms and distilled water. Treatment 3 consisted of direct application of …

Greener And More Equitable: A Vision For Dams And Other Western Water Issues, Bruce C. Driver

Dams: Water and Power in the New West (Summer Conference, June 2-4)

10 pages.

Contains 1 page of references.

The Future Of Western Water Developments, John Keys

Dams: Water and Power in the New West (Summer Conference, June 2-4)

9 pages.

River Management In The Twenty-First Century: The Vision Thing, A. Dan Tarlock

Dams: Water and Power in the New West (Summer Conference, June 2-4)

12 pages.

Contains references.

Of Dams And Salmon In The Columbia/Snake Basin: Did You Ever Have To Make Up Your Mind?, Don B. Miller

Dams: Water and Power in the New West (Summer Conference, June 2-4)

106 pages (includes illustrations and maps).

Contains 4 pages of references.

Klamath Basin: Balancing Instream Flows With Irrigation And Power, Carl Ullman

Dams: Water and Power in the New West (Summer Conference, June 2-4)

15 pages (includes illustrations and maps).

Initiatives And Conflicts In Changing Federal Facility Operation, Lawrence J. Macdonnell

Dams: Water and Power in the New West (Summer Conference, June 2-4)

18 pages.

Contains references.

Glen Canyon Dam: Flood Flows And Adaptive Management In The Lower Colorado River Basin: Response, Joe Hunter

Dams: Water and Power in the New West (Summer Conference, June 2-4)

9 pages.

Contains references.

Environmental Benefits Of Reoperation, Relicensing, Decommissioning And Recapture, Richard Roos-Collins

Dams: Water and Power in the New West (Summer Conference, June 2-4)

35 pages.

Contains footnotes.

Glen Canyon Dam: Flood Flows And Adaptive Management In The Lower Colorado River Basin, Edmund D. Andrews

Dams: Water and Power in the New West (Summer Conference, June 2-4)

11 pages.

Contains 2 pages of references.

Integrating New Values With Old Uses In The Relicensing Of Kingsley Dam And Related Facilities (Making Part Of The Problem A Part Of The Solution), Margot Zallen

Dams: Water and Power in the New West (Summer Conference, June 2-4)

21 pages (includes illustrations and map).

Agenda: Dams: Water And Power In The New West, University Of Colorado Boulder. Natural Resources Law Center

Dams: Water and Power in the New West (Summer Conference, June 2-4)

Conference organizers and/or speakers included University of Colorado School of Law professors David H. Getches, Douglas S. Kenney, Kathryn M. Mutz, Elizabeth Ann (Betsy) Rieke, Charles F. Wilkinson and Lawrence J. MacDonnell.

The keynote address by Charles F. Wilkinson is titled Coming to Grips with Growth in the West: Traditional Communities, Free Rivers and the New Megalopoli, and it will be held on Monday, June 2, at 12:30 p.m. in the Lindsley Memorial Courtroom of the law school. Wilkinson is a noted law professor, writer and authority on Western issues.

The conference will begin by providing historical context for the …

Artificial Recharge In The Las Vegas Valley: An Operational History, Michael Johnson, Erin Cole, Kay Brothers, Las Vegas Valley Water District

Publications (WR)

Artificially recharging the Las Vegas Valley (Valley) ground-water system with treated Colorado River water is one water resource management option employed by the Las Vegas Valley Water District (District) to help meet future long-term and short-term peak water demands. The District began operation of an artificial ground-water recharge program in 1988 in order to bank water for future use and to slow declining water levels. Artificial recharge occurs in the winter months, typically from October to May, when there is excess capacity in the Southern Nevada Water System (SNWS), currently a 400 Million Gallon per Day (MGD) treatment and transmission …

The Study Of Permeability In Concrete, Jie Yuan

Theses

In this study, samples of regular, high performance, expansive and the polymer concrete and mortar were prepared for test of permeability and mechanical property. In the permeability measurement, water and an aqueous chemical solution were employed as the permeant.

The test results of the samples, ranging from 5.7 x 10-9 cm/sec to 1.0 x cm/sec for the permeability and 3800 psi to 10600 psi for compression strength, indicated that the polymer coated concrete has the lowest permeability among the concretes and high performance concrete has the highest compression strength . The finding leads to the possibility that a high strength …

Enhancing The Bioavailability Of Sorbed Pollutants From Sediments Using Ultrasound, Rachel Mathew

Theses

Many organic compounds, that enter aquatic systems have a strong tendency to sorb onto particulate matter which may be present in suspension or as sediment. Numerous studies have shown that the sediment in aquatic systems concentrate contaminants several orders of magnitude greater than the concentration in the aqueous phase. Particulate associated contaminants in sediments are not easily bioavailable. Hence the efficacy of any treatment technology would be strongly undermined if the contaminants are not made available for microbial utilization. Sediment associated contaminants can be made biologically available to various microorganisms under certain conditions.

In this study, desorption studies were conducted …

An Analytical Approach To Toxic Substance Replacement In Support Of Pollution Prevention, Ithan B. Zimmer

Theses

In support of pollution prevention and in accordance with Executive Order 12356 concerning pollution prevention, all federal agencies must comply with the Toxic Release Inventory (TRI) chemical release reduction and pollution prevention planning. The inventory lists hundreds of chemicals and choosing those to replace and finding actual replacement chemicals or procedures is not always clear. This study focuses on an analytical approach to this problem by understanding the application of two substances. The representative chemicals are two volatile organic compounds (VOC), ethyl ether and ethanol, used as solvents in ammunition manufacturing.

Thirteen military specifications provide the cases involving ether. Ethanol's …

Evaluation Of Environmental Characteristics Of Wtp Residuals For Disposal In Monofills, Ping Tian

Dissertations

Disposal of water treatment plant (WTP) have raised great concerns due to the stringent water quality standards and environmental regulations, and limited availability of land for ultimate disposal. The ultimate disposal of water treatment plant residuals by using monofill may be one of the most economical, and feasible options. Design and operation of such a monofill will be simple because of the uniformity of the characteristics of WTP residuals.

The objectives of this project were to determine the environmental characteristics of WTP residuals and to apply these characteristics for the design of monofills and development of the metal leaching model …