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Full-Text Articles in Environmental Engineering
Solar And Visible Light Driven Photocatalysis For Sacrificial Hydrogen Generation And Water Detoxification With Chemically Modified Ti02, Pankaj Chowdhury
Solar And Visible Light Driven Photocatalysis For Sacrificial Hydrogen Generation And Water Detoxification With Chemically Modified Ti02, Pankaj Chowdhury
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Photocatalysis is a recognized approach where light energy is employed to excite the semiconductor material producing electron/hole pair which eventually involves in the detoxification of pollutants and/or water splitting producing hydrogen. Existing photocatalysts suffer from poor activity or no activity in visible light irradiation which restricts them from solar light utilization. This work is focused on two key applications of photocatalysis (i) sacrificial hydrogen generation, and (ii) phenol degradation in visible and/or solar light. Platinum was loaded on TiO2 photocatalyst by solar photo-deposition method. Eosin Y dye was used as a sensitizer for sensitization of platinum loaded TiO2 photocatalyst. The …
Sacrificial Hydrogen Generation From Formaldehyde With Pt/Tio2 Photocatalyst In Solar Radiation, Pankaj Chowdhury, Ghodsieh Malekshoar, Madhumita Ray, Jesse Zhu, Ajay Ray
Sacrificial Hydrogen Generation From Formaldehyde With Pt/Tio2 Photocatalyst In Solar Radiation, Pankaj Chowdhury, Ghodsieh Malekshoar, Madhumita Ray, Jesse Zhu, Ajay Ray
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In this work, solar TiO2 photocatalysis was used for sacrificial hydrogen generation from formaldehyde. Platinum was loaded onto a TiO2 photocatalyst by a solar photodeposition method to suppress the electron/hole recombination process. The photocatalyst inside the reactor was irradiated from the top with a solar simulator. Photocatalytic hydrogen generation from formaldehyde was influenced by the solution pH, platinum loading (wt %) on TiO2, catalyst concentration, light intensity, and initial formaldehyde concentration. A Langmuir-type model fitted well with the experimental data, and the values of surface reaction rate constant, k, and the adsorption equilibrium constant, K, are 2.3598 × 10–6 mol …