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Graduate Theses and Dissertations

Asymmetric flow field-flow fractionation

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New Insights Into Disinfection Byproduct Formation And Control: Assessing Dissolved Organic Matter Diffusivity And Chemical Functionality, Ashley Pifer Aug 2012

New Insights Into Disinfection Byproduct Formation And Control: Assessing Dissolved Organic Matter Diffusivity And Chemical Functionality, Ashley Pifer

Graduate Theses and Dissertations

Methods were developed for application of asymmetric flow field-flow fractionation (AF4) and fluorescence parallel factor (PARAFAC) analysis to raw and treated samples from drinking water sources to improve characterizations of dissolved organic matter (DOM) and discover DOM properties correlated to disinfection byproduct (DBP) formation potential (FP). Raw water samples were collected from a reservoir, adjusted to pH 6, 7, and 8 and subjected to (1) jar tests using aluminum sulfate (alum) and (2) treatment with magnetic ion exchange (MIEX®) resin. Both treatments were followed by DBPFP tests at pH 7. AF4 was used to size DOM in raw …