Environmental Engineering Commons^™

Investigation Of Bench-Scale Packed Bioreactor For Perchlorate Reduction In The Presence Of Co-Contaminants And High Salinity, Julia Ribeiro Rabello

UNLV Theses, Dissertations, Professional Papers, and Capstones

Perchlorate (ClO4-), commonly found as a salt, is naturally occurring in nature and is found in natural nitrate deposits (such as the Chilean nitrate). Perchlorate anion is considered an inhibitor of iodine by the thyroid gland, reducing the production of thyroid hormones. The latest action by the USEPA was to not determine a national drinking water standard for perchlorate. However, the states still have their own regulations on perchlorate concentration in drinking water. Contaminated sites with high concentrations of perchlorate (ppm levels) are associated with historic perchlorate manufacture and use, while those with low concentrations (ppb levels) are found in …

High Salinity, High Concentration Perchlorate Reduction In The Presence Of Hexavalent Chromium, Nitrate, And Chlorate, Nicole Martin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Perchlorate is a chemically stable anion which was used as an oxidizer in rocket propellant and explosives throughout the 1950’s and 1960’s. While natural sources of perchlorate exist, perchlorate in the environment is primarily a result of contamination from anthropogenic processes. Perchlorate contamination has now been identified in at least 45 states and is hazard to human health due to perchlorate’s ability to interfere with uptake of iodine in the thyroid gland. One of the most common and cost effective treatment methods for perchlorate remediation is biological reduction—utilizing bacteria to enzymatically reduce perchlorate into chloride and oxygen.

The purpose of …

Treatment Of Perchlorate And Multiple Oxyanions: Chemical And Biological Investigations, Mark Elkouz

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater contamination with oxyanions is an issue that must be addressed for environmental, ecological and societal reasons. Chemical and biological treatment methods of reduction are already known and practiced, but the simultaneous presence of multiple oxyanions can add complicating effects to treatment sequence and efficacy. This research was concerned with the investigation of the chemical reductive treatment of Cr(VI) using both calcium polysulfide (CaSx) and ferrous sulfate (FeSO4), and the biological reductive treatment of chlorate, Cr(VI), nitrate and perchlorate using multiple organic substrates. The chemical treatment phase consisted of initial jar tests, using CaSx and FeSO4, followed by a laboratory …

Evaluation Of Electron Donors For Perchlorate And Nitrate Biodegradation In Contaminated Groundwater Applications, Mayra Alejandra Sarria Cortes

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the United States, perchlorate contamination has been widely reported, including in Las Vegas, Nevada, where perchlorate has been detected at concentrations of 34.7 mg/kg in vadose zone soil and 0.18-3.7 g/L in groundwater. Once this groundwater reaches the Las Vegas Wash, there is potential for widespread contamination of drinking water sources throughout the Southwest, including in Nevada, Arizona, and California. This issue is becoming increasingly important because even at low perchlorate concentrations, sensitive populations such as infants and pregnant women can be potentially impacted due to perchlorate’s ability to hinder iodine uptake into the thyroid glands, which leads to …