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Full-Text Articles in Environmental Engineering
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Theses and Dissertations
This work examined ultraviolet (UV) light emitting diodes (LED) and hydrogen peroxide in an advanced oxidation process in support of a USAF installation net zero water initiative. A UV LED reactor was used for degradation of soluble organic chemicals. There were linear relationships between input drive current, optical output power, and first order degradation rate constants. When drive current was varied, first order degradation rates depended on chemical identities and the drive current. When molar peroxide ratios were varied, kinetic profiles revealed peroxide-limited or radical-scavenged phenomena. Molar absorptivity helped explain the complexity of chemical removal profiles. Degradation kinetics were used …
The Effect Of Ph And Pulsed Ultraviolet Light Emitting Diode Duty Cycles On The First Order Rate Constant And Byproduct Profile Of The Advanced Oxidation Of Tartrazine, Brandon M. Stewart
The Effect Of Ph And Pulsed Ultraviolet Light Emitting Diode Duty Cycles On The First Order Rate Constant And Byproduct Profile Of The Advanced Oxidation Of Tartrazine, Brandon M. Stewart
Theses and Dissertations
Water treatment capability is required for military operations, production of drinking water, and industrial wastewater treatment. The Advanced Oxidation Process (AOP) is one of many viable steps for treating water; however, it is important to understand the byproducts of the treatment process to avoid creating other constituents more severe than the first. Tartrazine (TAR) was oxidized with pulsed Ultra- Violet (UV) Light Emitting Diodes (LEDs) in combination with hydrogen peroxide (H2O2) in an AOP at the laboratory scale. The relative concentration of TAR was reduced from 1 to between 1 – 0.75 over pH values between 6 and 9, and …