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Full-Text Articles in Environmental Engineering

Evaluation Of The Natural Biodegradation Of Aircraft Deicing Fluid Components In Soils, Laura M. Johnson Dec 1997

Evaluation Of The Natural Biodegradation Of Aircraft Deicing Fluid Components In Soils, Laura M. Johnson

Theses and Dissertations

This research effort was conducted to analyze the biodegradation of propylene glycol (PG) and tolyltriazole in two different soil types; a sandy soil and a high clay soil. Both an automated respirometer and a high performance liquid chromatograph (H PLO) were used in the analysis. Two separate experiments were conducted. In the first experiment, one level of tolyltriazole was added to the soils to determine whether or not there was a difference in the biodegradation rates of tolyltriazole in the two soils. The respirometer results indicated that there was a significant difference between the respiration rates of the microorganisms in …


Optimal Pulsed Pumping For Remediation Of Aquifers When Sorption Is Rate-Limited, Lawrence J. Schmitt Dec 1997

Optimal Pulsed Pumping For Remediation Of Aquifers When Sorption Is Rate-Limited, Lawrence J. Schmitt

Theses and Dissertations

A variational optimization technique is developed to acquire an optimal schedule of pulsed pumping operations for use at existing pump-and-treat aquifer remediation sites. The optimization problem is stated as a minimization of a generic management objective functional, constrained by the contaminant transport equations in two-dimensional or three-dimensional flow models which account for rate-limited sorption. The two-dimensional case is fully developed and a first-order rate equation is used to describe the transport of sorbing contaminant. The first variation provides necessary optimality conditions that must be met by any optimal solution, in turn leading to a pulsed pumping schedule of operation. The …


Department Of Defense Hazardous Waste Site Remediation Issues In The Republic Of Korea, Edwin H. Oshiba Dec 1997

Department Of Defense Hazardous Waste Site Remediation Issues In The Republic Of Korea, Edwin H. Oshiba

Theses and Dissertations

The purpose of this research was to provide information to DoD decision makers regarding factors influencing hazardous waste site remediation policy for South Korea. This study addressed: International agreements and U.S. and South Korean laws and policies relevant to hazardous waste sites; objectives of DoD environmental policy makers; extent and effects of soil and groundwater contamination; cleanup precedents set in other foreign countries; availability of resources and technical capabilities to investigate and remediate hazardous waste sites in South Korea; and opportunities for cooperation between the U.S. and South Korean military with regard to hazardous waste site remediation. Data were collected …


Investigation Of Biodegradation Processes In Solid Waste Landfills, Philip A. Colborn Dec 1997

Investigation Of Biodegradation Processes In Solid Waste Landfills, Philip A. Colborn

Theses and Dissertations

Greater demands on landfill capacity, stricter regulations intended to minimize landfill environmental impacts, and the economic potential associated with landfill operations have shifted the emphasis of landfill disposal toward methods concerned with the long term performance and capacity of landfills. Two opposing philosophies have emerged in constructing and managing landfills: the dry tomb and the wet cell. The key to managing a landfill from the wet cell viewpoint is first understanding the biodegradation processes occurring within the landfill. This thesis attempts to determine the fundamental processes responsible for the degradation of solid waste by employing a system dynamics approach. A …


Mobilization Of Trace Elements In Aquifers By Biodegradation Of Hydrocarbon Contaminants, Scott L. Kearney Dec 1997

Mobilization Of Trace Elements In Aquifers By Biodegradation Of Hydrocarbon Contaminants, Scott L. Kearney

Theses and Dissertations

This study had two objectives: (1) to determine the extent of metal mobility within petroleum-contaminated aquifers, (2) to determine if biodegradation of petroleum hydrocarbons can explain metal mobility. The approach reviewed analytical results from 2305 groundwater sampling events, taken from 958 wells, located at 136 sites found at 53 Air Force installations. The study showed that high levels of metals are present at petroleum hydrocarbon sites where metals would not generally be expected. Of the metals with drinking water maximum contaminant levels (MCLs), mercury and silver were detected the least frequently. Barium and copper were detected at the sites, but …


An Examination Of Elements Necessary For Transfer Of An Environmental Remediation Technology From Full-Scale Demonstration To Implementation, Glenn C. Mandalas Dec 1997

An Examination Of Elements Necessary For Transfer Of An Environmental Remediation Technology From Full-Scale Demonstration To Implementation, Glenn C. Mandalas

Theses and Dissertations

The fact that an innovative environmental remediation technology has been proven feasible in a full scale evaluation does not assure that the technology will be implemented. A number of regulatory, economic, and institutional barriers may impede the transition of a remediation technology from full scale demonstration to implementation. This research explores these barriers, suggesting means to overcome them. Regulators, technology users, and other remediation decision makers apply the nine criteria specified in the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) to evaluate the applicability of an innovative remediation technology at uncontrolled hazardous waste sites. These criteria consider such things …


A System Dynamics Model Of The Bioavailability Of Metals In Constructed Wetland Sediment, Timothy S. Wood Dec 1997

A System Dynamics Model Of The Bioavailability Of Metals In Constructed Wetland Sediment, Timothy S. Wood

Theses and Dissertations

Constructed wetlands used for storm water treatment accumulate metals primarily in their sediment. This sediment has the potential to produce toxic effects in benthic organisms at some period in time. Bioavailability of metals in sediment is directly linked to pore water metal activity. The mechanisms that influence pore water metal activity are included in physical, chemical, and biological processes. A system dynamics model was developed to represent these processes and the major influences affecting pore water metal activity in a treatment wetland receiving storm water influent. The model structure and behavior was tested and validated using several system dynamics validation …


Modeling Uptake And Translocation Of Lead (Pb) In Maize For The Purposes Of Phytoextraction, Mark A. Brennan Dec 1997

Modeling Uptake And Translocation Of Lead (Pb) In Maize For The Purposes Of Phytoextraction, Mark A. Brennan

Theses and Dissertations

Phytoextraction is a remediation technology that uses plants to remove heavy metals from soil. This technology has the potential to decrease the costs of remediating contaminated sites by several orders of magnitude compared to traditional technologies. To effectively implement this technology requires an understanding of the plant processes that control uptake and translocation of metals from the soil. Currently these processes are poorly understood, and especially so for Pb. The purpose of this thesis was to gain insights concerning the plant mechanisms that control uptake and translocation of Pb and how these mechanisms interact to control levels of Pb accumulation …


A Modeling Study For The Implementation Of In Situ Cometabolic Bioremediation Of Trichloroethylene-Contaminated Groundwater., John A. Christ Dec 1997

A Modeling Study For The Implementation Of In Situ Cometabolic Bioremediation Of Trichloroethylene-Contaminated Groundwater., John A. Christ

Theses and Dissertations

The limitations of conventional groundwater remediation technologies have led to the development of innovative technologies which may achieve national hazardous waste site remediation goals. Before an innovative technology can be implemented in the field, remedial project managers, regulators and other stakeholders require adequate modeling tools to help assess the applicability of the technology at a particular site. This modeling study investigates how an innovative technology, in situ cometabolic bioremediation, might be implemented to remediate a TCE-contaminated site, under different site conditions. A steady-state model is developed which couples an analytical expression to simulate the effect of flow between multiple pumping …


Biodegradation Of Deicing Agents In Various Soil Types, Annmarie Halterman-O'Malley Dec 1997

Biodegradation Of Deicing Agents In Various Soil Types, Annmarie Halterman-O'Malley

Theses and Dissertations

Airports have found that spent deicing fluids eventually reach the airfield's stormwater system and soil surrounding the airfield. Due to toxic effects of spent deicing fluids, containing and collecting the fluid for treatment can be a very costly activity for airports. One alternative to dispose of the used deicing fluid is to institute a land treatment system if it can be proven that the deicing fluid is readily biodegradable in a soil system. The primary concern of this research effort was to monitor the behavior of a simulated aircraft deicing fluid in various soil systems. An automated respirometer monitored the …


A Cercla-Based Decision Model To Support Remedy Selection For An Uncertain Volume Of Contaminants At A Doe Facility, Christine E. Kerschus Dec 1997

A Cercla-Based Decision Model To Support Remedy Selection For An Uncertain Volume Of Contaminants At A Doe Facility, Christine E. Kerschus

Theses and Dissertations

The Paducah Gaseous Diffusion Plant (PGDP) operated by the Department of Energy is challenged with selecting the appropriate remediation technology to cleanup contaminants at Waste Area Group (WAG) 6. This research utilizes value focused thinking and multi attribute preference theory concepts to produce a decision analysis model designed to aid the decision makers in their section process. The model is based on CERCLA's five primary balancing criteria, tailored specifically to WAG 6 and the contaminants of concern, utilizes expert opinion and the best available engineering, cost, and performance data, and accounts for uncertainty in contaminant volume. The model ranks 23 …


Metabolic Inhibition Of A Toluene-Enriched Microbial Population Due To Lead (Pb2+): Verification Of A Free Metal Ion Toxicity Model, Patrick J. S. Marbas Dec 1997

Metabolic Inhibition Of A Toluene-Enriched Microbial Population Due To Lead (Pb2+): Verification Of A Free Metal Ion Toxicity Model, Patrick J. S. Marbas

Theses and Dissertations

A dissolved oxygen probe and an ion specific electrode were used to study the lead-induced metabolic inhibition in a toluene-enriched microbial population. Predicted toxicity values were compared to the actual toxicity responses using a free metal ion toxicity model (TM) which linked metabolic inhibition with lead activity. Experimentally derived values for the model parameters (lead activity and a lead distribution coefficient) were used in the TM. It was postulated that cellular metabolism is disrupted by the conformational changes to the cell's plasma membrane produced by lead ion adsorption. The predicted toxicity values were higher than the actual toxicity response. This …