Open Access. Powered by Scholars. Published by Universities.®
- Institution
- Keyword
-
- Air-water interface (1)
- Anisole (1)
- Applied sciences (1)
- Atmospheric composition (1)
- BVOC (1)
-
- Benzene (1)
- Biogenic volatile organic compounds (1)
- Biomass burning (1)
- Brown cloud (1)
- Carboxylic Acids (1)
- Carotenoids (1)
- Catechols (1)
- Chloramine (1)
- Chlorophyll (1)
- Chlorophyll-a (1)
- Climate change (1)
- Climate change impacts (1)
- Combustion (1)
- Drones (1)
- Economy (1)
- Electron transfer (1)
- Emissions (1)
- Experiment (1)
- Fragmentation (1)
- Functionalization (1)
- GC-MS (1)
- Hydrology (1)
- Leaf area (1)
- Modeling (1)
- NDMA (1)
- Publication
- Publication Type
Articles 1 - 9 of 9
Full-Text Articles in Environmental Engineering
Unmanned Aerial Systems For Monitoring Trace Tropospheric Gases, Travis J. Schuyler, Marcelo I. Guzman
Unmanned Aerial Systems For Monitoring Trace Tropospheric Gases, Travis J. Schuyler, Marcelo I. Guzman
Chemistry Faculty Publications
The emission of greenhouse gases (GHGs) has changed the composition of the atmosphere during the Anthropocene. Accurately documenting the sources and magnitude of GHGs emission is an important undertaking for discriminating the contributions of different processes to radiative forcing. Currently there is no mobile platform that is able to quantify trace gases at altitudes(UASs) can be deployed on-site in minutes and can support the payloads necessary to quantify trace gases. Therefore, current efforts combine the use of UASs available on the civilian market with inexpensively designed analytical systems for monitoring atmospheric trace gases. In this context, this perspective introduces the …
Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham
Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham
Graduate Theses and Dissertations
The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …
Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman
Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman
Chemistry Faculty Publications
Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …
Nitrate Radicals And Biogenic Volatile Organic Compounds: Oxidation, Mechanisms And Organic Aerosol, Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Hermann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert Mclaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, Rahul A. Zaveri
Nitrate Radicals And Biogenic Volatile Organic Compounds: Oxidation, Mechanisms And Organic Aerosol, Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Hermann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert Mclaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, Rahul A. Zaveri
Chemistry Faculty Publications
Oxidation of biogenic volatile organic compounds (BVOC) by the nitrate radical (NO3) represents one of the important interactions between anthropogenic emissions related to combustion and natural emissions from the biosphere. This interaction has been recognized for more than 3 decades, during which time a large body of research has emerged from laboratory, field, and modeling studies. NO3-BVOC reactions influence air quality, climate and visibility through regional and global budgets for reactive nitrogen (particularly organic nitrates), ozone, and organic aerosol. Despite its long history of research and the significance of this topic in atmospheric chemistry, a number …
The Irreversible Momentum Of Clean Energy, Barack Obama
The Irreversible Momentum Of Clean Energy, Barack Obama
US Department of Energy Publications
The release of carbon dioxide (CO2) and other greenhouse gases (GHGs) due to human activity is increasing global average surface air temperatures, disrupting weather patterns, and acidifying the ocean. Left unchecked, the continued growth of GHG emissions could cause global average temperatures to increase by another 4°C or more by 2100 and by 1.5 to 2 times as much in many midcontinent and far northern locations. Although our understanding of the impacts of climate change is increasingly and disturbingly clear, there is still debate about the proper course for U.S. policy—a debate that is very much on display …
Sediment Mobilization From Streambank Failures: Model Development And Climate Impact Studies, Jody Juniper Stryker
Sediment Mobilization From Streambank Failures: Model Development And Climate Impact Studies, Jody Juniper Stryker
Graduate College Dissertations and Theses
This research incorporates streambank erosion and failure processes into a distributed watershed model and evaluates the impacts of climate change on the processes driving streambank sediment mobilization at a watershed scale. Excess sediment and nutrient loading are major water quality concerns for streams and receiving waters. Previous work has established that in addition to surface and road erosion, streambank erosion and failure are primary mechanisms that mobilize sediment and nutrients from the landscape. This mechanism and other hydrological processes driving sediment and nutrient transport are likely to be highly influenced by anticipated changes in climate, particularly extreme precipitation and flow …
Multiple Drivers Of Seasonal Change In Pri: Implications For Photosynthesis 2. Stand Level, Anatoly A. Gitelson, John A. Gamon, Alexei E. Solovchenko
Multiple Drivers Of Seasonal Change In Pri: Implications For Photosynthesis 2. Stand Level, Anatoly A. Gitelson, John A. Gamon, Alexei E. Solovchenko
Department of Biological Systems Engineering: Papers and Publications
The goal of this study was to explore the relationships between stand-level photochemical reflectance index (PRI) and canopy structure/ pigment pools, as well as light use efficiency (LUE) of photosynthetically active vegetation focusing on seasonal or ontogenetic time frames. PRI was originally designed as a means of assessing the xanthophyll cycle and LUE over short (e.g. diurnal) time frames, and few studies have explored the drivers of PRI over longer, seasonal time frames, particularly in crops having different photosynthetic pathways or canopy structures. Consequently, our purpose was to understand and quantify the drivers of PRI responses over seasonal time scales …
Spatiotemporal Distribution Of Eutrophication In Lake Tai As Affected By Wind, Wenhui Zhang, Qiujin Xu, Xixi Wang, Xiaozhen Hu, Cheng Wang, Yan Pang, Yanbin Hu, Yang Zhao, Xiao Zhao
Spatiotemporal Distribution Of Eutrophication In Lake Tai As Affected By Wind, Wenhui Zhang, Qiujin Xu, Xixi Wang, Xiaozhen Hu, Cheng Wang, Yan Pang, Yanbin Hu, Yang Zhao, Xiao Zhao
Civil & Environmental Engineering Faculty Publications
One common hypothesis is that wind can affect concentrations of nutrients (i.e., nitrogen and phosphorus) and chlorophyll-a (Chl-a) in shallow lakes. However, the tests of this hypothesis have yet to be conclusive in existing literature. The objective of this study was to use long-term data to examine how wind direction and wind speed affect the spatiotemporal variations of total nitrogen (TN), total phosphorus (TP) and Chl-a in Lake Tai, a typical shallow lake located in east China. The results indicated that the concentrations of nutrients and Chl-a tended to decrease from the northwest to the southeast of Lake Tai, with …
Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar
Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar
Civil & Environmental Engineering Faculty Publications
Previous studies of land degradation, topsoil erosion, and hydrologic alteration typically focus on these subjects individually, missing important interrelationships among these important aspects of the Earth's system. However, an understanding of water–soil–vegetation dynamic interactions is needed to develop practical and effective solutions to sustain the globe's eco-environment and grassland agriculture, which depends on grasses, legumes, and other fodder or soil-building crops. This special issue is intended to be a platform for a discussion of the relevant scientific findings based on experimental and/or modeling studies. Its 12 peer-reviewed articles present data, novel analysis/modeling approaches, and convincing results of water–soil–vegetation interactions under …