Environmental Engineering Commons^™

Removal Of Trace Organic Compounds In Domestic Wastewater Using Recirculating Packed-Bed Media Filters, Brittani Nikole Perez

Masters Theses

Pharmaceuticals and personal care products (PPCPs) are commonly detected in the environment resulting from their survival from conventional wastewater treatment systems. More information is needed about the fate and transfer of these trace organic compounds in domestic wastewater and their associated risks so that efficient strategies for their removal can be developed for both large/small scale treatment systems. This study aimed to determine whether onsite wastewater treatment systems were capable of providing PPCP removal, in addition to quantifying different forms of removal (biodegradation/sorption). A column study was constructed to determine the removal efficiencies of 3 target PPCPs, endocrine disrupting compound …

Production And Harvest Of Microalgae In Wastewater Raceways With Resource Recycling, Alexander Colin Roberts

Master's Theses

Microalgae can be grown on municipal wastewater media to both treat the wastewater and produce feedstock for algae biofuel production. However the reliability of treatment must be demonstrated, as well as high areal algae productivity on recycled wastewater media and efficient sedimentation harvesting. This processes was studied at pilot scale in the present research.

A pilot facility was operated with nine CO₂-supplemented raceway ponds, each with a 33-m² surface area and a 0.3-m depth, continuously from March 6, 2013 through September 24, 2014. The ponds were operated as three sets of triplicates with two sets continuously fed …

Pathogen Removal In Natural Wastewater Treatment And Resource Recovery Systems: Solutions For Small Cities In An Urbanizing World, Matthew Eric Verbyla

USF Tampa Graduate Theses and Dissertations

Sanitation, renewable energy, and food security are among the most pressing global development needs of the century, especially for small cities with rapid population growth. Currently, 53% of the world’s population either lacks access to improved sanitation or discharges fecal waste to the environment without treatment. Furthermore, 80% of food consumed in developing regions is produced by 500 million small farms, and while many of them are still rain-fed, irrigated agriculture is increasing. The post-2015 Sustainable Development Goals, recently adopted by the United Nations, include targets to address the water-energy-food nexus. Wastewater reuse in agriculture can be an important solution …

Label-Free Surface-Enhanced Raman Spectroscopy-Linked Immunosensor Assay (Slisa) For Environmental Surveillance, Vinay Bhardwaj

FIU Electronic Theses and Dissertations

The contamination of the environment, accidental or intentional, in particular with chemical toxins such as industrial chemicals and chemical warfare agents has increased public fear. There is a critical requirement for the continuous detection of toxins present at very low levels in the environment. Indeed, some ultra-sensitive analytical techniques already exist, for example chromatography and mass spectroscopy, which are approved by the US Environmental Protection Agency for the detection of toxins. However, these techniques are limited to the detection of known toxins. Cellular expression of genomic and proteomic biomarkers in response to toxins allows monitoring of known as well as …

The Contribution Of Syntrophic Fatty-Acid Degrading Microbial Communities To Anaerobic Digester Function And Stability, Prince Peter Mathai

Dissertations (1934 -)

Anaerobic digestion (AD), the conversion of complex organic matter to methane, occurs through a series of reactions mediated by different guilds of microorganisms. AD process imbalances, such as organic overload or high organic loading rates (OLR), can result in the accumulation of volatile fatty acids (VFA) e.g., propionate, which must be degraded to maintain stable reactor function. VFAs are metabolized by syntrophic fatty-acid degrading bacteria (SFAB) in association with methanogenic archaea (collectively, syntrophic microbial communities, SMC). Despite their indispensable role in AD, little is known about the ecology of SFAB, especially under stressed conditions. To facilitate ecological studies, four quantitative …

Heterogeneous Oxidation Of Catechol, Elizabeth A. Pillar, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

Natural and anthropogenic emissions of aromatic hydrocarbons from biomass burning, agro-industrial settings, and fossil fuel combustion contribute precursors to secondary aerosol formation (SOA). How these compounds are processed under humid tropospheric conditions is the focus of current attention to understand their environmental fate. This work shows how catechol thin films, a model for oxygenated aromatic hydrocarbons present in biomass burning and combustion aerosols, undergo heterogeneous oxidation at the air–solid interface under variable relative humidity (RH = 0–90%). The maximum reactive uptake coefficient of O₃(g) by catechol γ_O3 = (7.49 ± 0.35) × 10^–6 occurs for …

Application Of 3d Printing Technology In Porous Anode Fabrication For Enhanced Power Output Of Microbial Fuel Cells, Bin Bian

Electronic Thesis and Dissertation Repository

Microbial fuel cells (MFCs) are widely researched for application in wastewater treatment. However, the current anodes used in MFCs often suffer from high fabrication cost and uncontrollable pore sizes. In this thesis, three-dimensional printing technique was utilized to fabricate anodes with different micro pore sizes for MFCs. Copper coating and carbonization were applied to the printed polymer anodes to increase the conductivity and specific surface area. Voltages of MFCs with various anodes were measured as well as other electrochemical tests such as linear sweep voltammetry and electrochemical impedance spectroscopy. 3D copper porous anode produced higher maximum voltages and power densities …

Ecoscience + Art Initiative: Designing A New Paradigm For College Education, Scholarship, And Service, Changwoo Ahn

The STEAM Journal

The paper presents a new initiative, EcoScience + Art, which blooms at George Mason University. The creator explains the background, history, and recent activities of the initiative, and also introduces an on-going special project called “The Rain Project”, a student participatory project to design, construct, and monitor a green infrastructure (i.e., floating wetland) for sustainable stormwater management on campus. The special project is geared to design and present a new paradigm to integrate college education, scholarship, and service. The relevance of the initiative and the special project to STEAM education is discussed.

Ultrasonic Enhanced Liquefaction And Saccharification Of Corn For Bio-Fuel Production, Samir Kumar Khanal, Melissa T. Montalbo, Johannes Van Leeuwen, Gowrishankar Srinivasan, David A. Grewell

Gowrishankar Srinivasan

Dry grind corn milling does not reach full efficiency of starch conversion to sugars and subsequently to ethanol because of limitations in the milling process. This paper examines the use of high-power ultrasonics to enhance the release of fermentable sugars from milled dry corn. In this work, 20 kHz ultrasonic energy was used to pretreat corn mash prior to enzymatic conversion of corn starch to glucose in a batch-mode. The ultrasonic amplitude was varied from 0, 191 to 320 µm _pp . The corn mash was sonicated for 0 (control), 20 and 40 seconds. Other experimental variables that were studied …

Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur

Electronic Thesis and Dissertation Repository

This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …

Investigations And Management Of Epizootic Plague At Ice House Reservoir, Eldorado National Forest, California, 1994 And 1995, Kenneth R. Townzen, Malcolm A. Thompson, Charles R. Smith

Charles Kay Smith

The occurrence of plague (Yersinia pestic) at Ice House Reservoir in 1994 and 1995 was characteristic of widespread epizootics in high use recreational areas of California. Staff of the Vector-Borne Disease Section investigated these epizootics and found dense populations of plague susceptible California ground squirrels (Spermophilus beecheyi) with high numbers of fleas, primarily Diamanus montanus, the most important plague vector. This combination indicated a high risk of plague exposure to campground users. A non-fatal human case of plague, contracted at Mountain Camp II, was reported after the initial epizootic investigation. The patient's exposure occurred prior to the reporting of the …

Photocatalytic Mineralization Of Phenol On Fluidized Titanium Oxide-Coated Silica Gel, Guillermo J. Rincon

University of New Orleans Theses and Dissertations

A bench-scale tubular reactor with recirculation was built in order to study the efficiency of the photocatalytic oxidation of phenol on fluidized titanium oxide-coated silica gel beads. A UV-C lamp placed along the central vertical axes of the reactor was used as source of photons. A bed of silica gel beads was fluidized by means of fluid recirculation and forced to follow upward helical flow around the lamp. Anatase was successfully synthetized on silica gel particles of average diameters 224, 357 and 461 µm, as confirmed by scanning electron micrographs, through a sol-gel technique using a titanium (iv)isopropoxide / hydrochloric …

Ultrasonic Enhanced Liquefaction And Saccharification Of Corn For Bio-Fuel Production, Samir Kumar Khanal, Melissa T. Montalbo, Johannes Van Leeuwen, Gowrishankar Srinivasan, David A. Grewell

Gowrishankar Srinivasan

Dry grind corn milling does not reach full efficiency of starch conversion to sugars and subsequently to ethanol because of limitations in the milling process. This paper examines the use of high-power ultrasonics to enhance the release of fermentable sugars from milled dry corn. In this work, 20 kHz ultrasonic energy was used to pretreat corn mash prior to enzymatic conversion of corn starch to glucose in a batch-mode. The ultrasonic amplitude was varied from 0, 191 to 320 µm pp . The corn mash was sonicated for 0 (control), 20 and 40 seconds. Other experimental variables that were studied …

Biofilm-Related Materials As Total N-Nitrosamine (Tono) Precursors And Hydroxylamine-Based Interferences In Tono And N-Nitrosodimethylamine (Ndma) Measurements, David Allen Meints

Graduate Theses and Dissertations

In this study, a chemiluminescence-based total N-nitrosamine (TONO) assay was adapted to include a solid-phase extraction (SPE) step to assess the role of biologically derived materials as N-nitrosamine precursors. Methanol was determined to be a suitable solvent for the SPE-TONO assay, with N-nitrosodimethylamine (NDMA) losses estimated to be 30% by SPE alone and an additional 15% from concentration of the methanol extracts by N2-gas blowdown. Three biofilm-derived materials - poly-N-acetylglucosamine (PNAG), Pseudomonas aeruginosa, and tryptophan - were individually chloraminated and dose-response relationships were observed with the SPE-TONO assay, indicating biofilm are potential N-nitrosamine precursors. The role of hydroxylamine - a …

Applications Of Microbial Desalination And Photocatalytic Disinfection For The Removal Of Contaminants In Drinking Water, Kristen Shirlee-Ann Brastad

Theses and Dissertations

Trends in drinking water treatment in recent years have been moving toward the use of membrane separation in order to reduce contaminants in water. There are many forms of membrane separation technology such as ultrafiltration, nanofiltration, microfiltration, reverse osmosis, and extruded ion exchange membranes. These membranes have many different applications and may be used to remove many materials from water such as salts, viruses and bacteria, selectively remove cations or anions, or remove organics.

Microbial desalination cells (MDCs) are an emerging concept which use bioelectric potential produced from organics via microbial metabolism to accomplish desalination. MDCs consist of three compartments, …

A Soil Parameters Geodatabase For The Modeling Assessment Of Agricultural Conservation Practices Effects In The United States, Mauro Di Luzio, Martin L. Norfleet, Jeffrey G. Arnold, Jimmy R. Williams, James R. Kiniry

International Journal of Geospatial and Environmental Research

Soil parameters for hydrology modeling in cropland dominated areas, from the regional to local scale, are part of critical biophysical information whose deficiency may increase the uncertainty of simulated conservation effects and predicting potential. Despite this importance, soil physical and hydraulic parameters lack common, wide-coverage repositories combined to digital maps as required by various hydrology-based agricultural water quality models.

This paper describes the construction of a geoprocessing workflow and the resultant hydrology-structured soil hydraulic, physical, and chemical parameters geographic database for the entire United States, named US-SOILM-CEAP. This database is designed to store a-priori values for a suit of models, …

Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith

Theses and Dissertations--Biosystems and Agricultural Engineering

Biochars have been created and characterized from a variety livestock manure biomass including poultry, dairy, and swine. However, no research has been conducted on the physical and chemical makeup of biochar pyrolyzed from horse muck. Two horse muck derived biochars containing either straw (HS) or woodchip (HW) bedding were pyrolyzed at 700°C and characterized for their physical and chemical properties. Tests revealed both biochars had high alkalinity, moderate specific conductivity, and low surface area as compared to other biochars in the literature. HS contained more mineral structures than HW. Scanning electron microscopy presented differences in particle shape, size, and presence …

Peat And Coconut Fiber As Biofilters For Chromium Adsorption From Contaminated Wastewaters, Henryk Koloczek, Jaroslaw Chwastowski, Witold Zukowski

Witold Zukowski

Batch adsorption experiments were performed for the removal of chromium (III) and chromium (VI) ions from aqueous solutions using Canadian peat and coconut fiber. The Langmuir model was used to describe the adsorption isotherm. The maximum adsorption for peat reached 18.75 mg/g for Cr(III) and 8.02 mg/g for Cr(VI), whereas the value for fiber was slightly higher and reached 19.21 mg/g for Cr(III) and 9.54 mg/g for Cr(VI). Both chromium forms could be easily eluted from the materials. The adsorption of chromium forms to organic matter could be explained in terms of formation of donor-acceptor chemical covalent bound with hydroxyl …