Environmental Engineering Commons^™

Temporal And Spatial Variability Of Specific Energy Consumption For Atmospheric Water Generators, Anthony T. Brenes

Theses and Dissertations

Atmospheric Water Generators (AWG) produce potable water from the moisture in the air, providing a potentially viable water source in austere locations or emergency response scenarios. In this study, the operating constraints of three existing commercially available AWG devices are investigated, compared to historical weather data from across the continental United States. Utilizing linear regression modeling and weather station data for the years of 1985-2019, the monthly and spatial trends of energy demand to produce water from these devices are evaluated. Energy and water production efficiencies for the devices are highly dependent on environmental conditions with relative humidity and temperature …

Net Zero Water Air Force Installations, Kenneth R. Mcknight

Theses and Dissertations

The United States continues to face problems of a reduction in quality and quantity of groundwater sources because water extraction exceeds natural source recharge. The Air Force has recognized the importance of these groundwater sources but has put minimal effort into determining their contribution to the depletion of these sources. The purpose of this study is to determine this contribution by determining whether Air Force installations are net zero water. This is done using a geospatial information system to determine the volume of water recharging groundwater sources associated with an Air Force installation. This volume is then compared to the …

Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski

Theses and Dissertations

Atmospheric Water Generators (AWG) extract water from the air using one of three available technologies: refrigeration, sorption, and fog harvesting. A refrigeration device works like a dehumidifier and works best in conditions above 60% relative humidity. A sorption device utilizes a desiccant to extract the water vapor from the air and works in very low humidity levels. A fog harvesting device utilizes a mesh to capture the water vapor from the air and requires 100% relative humidity. In this research, I analyze two refrigeration-based devices and one sorption-based device and their efficacy in providing supplemental water supply. Due to climatological …

Persistence And Mitigation Of Pfas Within Concrete Stormwater Drainage Infrastructure, Jason R. Mcdonald

Theses and Dissertations

The persistence, fate, and transport of per- and poly-fluoroalkyl substances, which have been shown to have adverse effects on human health, have been previously studied in environmental media such as soils and groundwater. This study investigates concrete, a medium that is rarely studied but frequently present in instances where PFAS originating from AFFF releases and spills have occurred. Used heavily throughout aviation firefighting, AFFF poses environmental hazards due to the length of PFAS degradation and toxicological implications, thus its classification as a forever chemical. From the very limited reports to date, studies have suggested very slow release from concrete, potentially …

Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch

Theses and Dissertations

A secure water source is essential to the resiliency and readiness of military installations and contingency operation locations, especially those located in the dry climates the US military operates in today. There are multiple issues of concern when identifying water sources, such as security, cleanliness, accessibility, and sustainability. Water resources pose a potential vulnerability to mission readiness in a remote, agile environment, such as a forward operating base (FOB). Having a secure water resource helps facilitate mission readiness in the contingency environment, offering the opportunity to be more resilient and cost-effective. Current water treatment technologies present the possibility to perform …

Fluid Dynamics Modeling For Per- And Polyfluoroalkyl Substances Removal In Legacy Fire Suppression Systems, Jacob G. Spaulding

Theses and Dissertations

Legacy per- and polyfluoroalkyl substances (PFASs) exist in the form of aqueous film-forming foams within hangar fire suppression systems throughout the country, posing a threat to both surrounding environments as well as local populations. The United States (US) Department of Defense (DoD), in conjunction with the US Environmental Protection Agency (EPA), is investigating best practices to flush out existing contaminants prior to disposal and replacement with a less environmentally harmful replacement. While current procedures dictate a triple rinse of the entire system to yield contaminant levels acceptable to the DoD, the practice has never truly been tested. Designed as a …

Sustainability In Construction: Using Lean Management Principles To Reduce Waste, Matthew Waite

Theses and Dissertations

The construction industry is facing many challenges. There are growing consumer demands for sustainable building. The construction industry generates a significant portion of the waste going into landfills. The construction industry has failed to keep pace with productivity in the manufacturing industry. Through adoption of Lean management principles, the construction industry can become more sustainable while increasing productivity. The literature was evaluated for three concepts: Lean management principles interaction with sustainability, the current state of sustainability in the construction industry, and the current state of Lean management principles in the construction industry. Lean management philosophies interactions with sustainability has been …

Numerical And Experimental Investigation Of Aeration Self Mixing By Using Pulsating And Continuous Air Flow, Ahmed Ali Alkhafaji

Theses and Dissertations

Wastewater treatment is considered one of the most common forms of pollution control in the united states. Considered as an integral part of the wastewater treatment, the aeration process is the most energy-consuming process among all the processes that take place in any wastewater treatment plant. According to the United States Environmental Protection Agency (EPA), a wastewater treatment plant is expected to remove at least 85% of the suspended solids and dissolved organic compounds from the wastewater before discharging it to a river or a lake. The normal operation of the aeration process is by compressing air continuously to basin …

An Analysis Of Tinker Air Force Base Thermal Spray Hazardous Waste Stream From 2003-2019 And Its Potential Reclamation, Amy E. Silverbush

Theses and Dissertations

The disposal of hazardous waste threatens the environment and human health. However, certain hazardous wastes can be recycled or reclaimed to alleviate environmental and financial impacts associated with its disposal and resource demand reduction. A hazardous powder produced by the United States Air Force stems from aircraft maintenance and is composed of metals and ceramics, called thermal spray. This waste can be purchased by an industrial recycler if the waste is composed of valuable metals. Historic data from the depot-level maintenance base Tinker Air Force Base initiated an analysis of annual thermal spray hazardous waste disposal fees, which combined with …

Optimizing Hydrogen Sulfide Removal And Biogas Production Using The Water Wash Method, Brian Leightner

Theses and Dissertations

Biogas forms from decomposing organic material in agricultural digesters, landfills, and wastewater treatment plant digesters. Biogas is mostly composed of methane, and can be used as a carbon-based fuel. Microorganisms that consume organics in these waste streams also produce hydrogen sulfide (H2S) as part of the biogas, in varying trace amounts. H2S is corrosive to engines and pipes for machinery, a human health hazard when inhaled, and an aquatic hazard when dissolved in water. Water washing is an absorption process that dissolves hydrogen sulfide and other water soluble compounds in this process and carries it away from the gas, thereby …

Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt

Theses and Dissertations

This research investigated the efficacy of granular activated carbon (GAC) as a method to treat water impacted with aqueous film forming foam (AFFF) after a firefighting response. Bench-top experiments were conducted and compared to field scale adsorber performance removing mg/L concentrations of PFAS in water contaminated with Military Specification AFFF. Batch tests compared four adsorbents, and determined Calgon F600 GAC and Rembind Plus mixed carbon media had the greatest perfluorooctane sulfonate (PFOS) capacities. Additional batch isotherm experiments using AFFF and higher PFOS concentrations (mg/L) indicated larger amounts of GAC are required (>30mg/L) for effective removal. Full-scale testing simulated an …

Modelling Of Dreissenid Mussel Impacts On Lake Michigan, Chunqi Shen

Theses and Dissertations

Invasive dreissenid mussel appear to have profoundly altered Great Lakes food webs and nutrient cycles during the past several decades. Recent declines of phytoplankton were supposed to be highly related with the increase of mussel population. These phytoplankton declines were further found to be coincident with declines in the abundance of planktivorous fish. In addition, the resurgence of Cladophora in Great lakes was estimated to be associated with the high density colonization of mussels. More light is available at lake bottom due to the mussels’ graze effect. The mussels further promote Cladophora growth by fertilizing it with nutrient-rich excrement. And …

Influence Of Permeate From Domestic Reverse Osmosis Filters On Lead Corrosion And Leaching From Plastic Pipes, Jyotsna Shrestha

Theses and Dissertations

Reverse Osmosis filters are gaining popularity nowadays, in domestic water supply system, to meet the increasing demand of pure and improved drinking water. There are various types of domestic RO filters with varying sizes, capacities, and treatment stages available. However, there exist a few concerns regarding the RO treatment system. One of the major issues in the quality and distribution of drinking water is the corrosive water that the RO system produces. Therefore, this research herein tends to focus on the corrosive effect of the permeate water on lead metal, as lead is considered a serious problematic drinking water contaminant. …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …

A Simulation-Based Analysis Of Chemical And Radiological Hazard Zones Adapted To Physical Boundaries, Mickie J. Sundheim

Theses and Dissertations

In the United States, industrial and terrorist use of chemical, biological, radiological, and nuclear (CBRN) materials pose a risk to public safety. During the initial phase of typical CBRN incidents, emergency responders establish hazard zones based on standard distances from published guidelines and recommendations. This research investigates how standard hazard zones change in a real world environment that accounts for physical boundaries. Using a python simulation in ArcGIS®, new hazard zones were created by expanding standard hazard zones to follow nearby roads, railroads, and rivers. The new and standard zones were compared by calculating the population and area affected by …

Hydrodynamic Modeling Of The Green Bay Of Lake Michigan Using The Environmental Fluid Dynamics Code, Paula Estefania Cedillo

Theses and Dissertations

In this project we created a hydrodynamic model of the Lower Green Bay of Lake Michigan in Wisconsin, United States using the Visual Environmental Fluid Dynamics Code (EFDC). The model includes four tributary rivers to Lower Green Bay as well as the open boundary flow conditions at Chambers Island. This case study is used to: 1) compare the results obtained with a previous study of Lower Green Bay to validate the creation of the model 2) examine the hydrodynamics of the bay, and 3) create a framework for future studies at Lower Green Bay. The Geographic Information used to build …

Sustainable Decolorization Of Reactive And Acid Dye Wastewater Using Photo-Fenton Oxidation Both With And Without Biodegradation: Laboratory And Field Studies, Marissa R. Jablonski

Theses and Dissertations

Photo-Fenton oxidation is an advanced oxidation process (AOP) used to degrade low-concentration textile dye wastewater using expensive chemicals. The technique has shown promise in laboratory-scale projects, but has not been scaled up sustainably to function for industry. Aerobic biodegradation is a common biological treatment method used in large-scale textile industrial applications that generates large amounts of hazardous biological waste. This waste is often left open to the elements and subsequently leaches into natural waterways or onto land. This is the first study of its kind to combine the two to treat cottage-scale industry-grade textile wastewater with a dye concentration of …

The Occurrence, Fate, Environmental Impact, And Management Implications Of Pharmaceutical And Personal Care Products In Wastewater And The Environment, Benjamin Donald Blair

Theses and Dissertations

Pharmaceuticals and personal care products (PPCPs) are a critical part of modern life. However, there is growing evidence that the levels of PPCPs detected in wastewater effluent and in the environment have the potential to cause damage to aquatic organisms. These pollutants enter the aquatic environment primarily through human use, disposal in the drain or toilet, land application of biosolids, and veterinary sources. Numerous questions remain regarding the occurrence, fate, and impacts of PPCPs in wastewater, along with limited feasible management recommendations that would adequately mitigate the risk from these pollutants. This dissertation will present three advances in the field …

Sediment Microbial Fuel Cell As Sustainable Power Resource, Ananta Kothapalli

Theses and Dissertations

This research demonstrates that Ceratophyllum demersum a root less non vascular aquatic plant has negatively affected the power generation from a Sediment Microbial Fuel cell (SMFC). In SMFC the reduced organic matter in the sediment in water produces electrons, which reduces oxygen. Whereas in Plant SMFC continuous supply of organic matter to the anode is done by rhizodeposition (root exudates). Six SMFCs were run for more than 3 months to see the effect of plants, pH and temperature on power generation. Out of six only two SMFC showed stable data. The maximum power density 18 ± 1mW/m3 was generated from …

Optimization Of Nanoscale Zero-Valent Iron For The Remediation Of Groundwater Contaminants, Andrew W. E. Mcpherson

Theses and Dissertations

Nanoscale zero-valent iron (nZVI) is an emerging tool for the remediation of groundwater contaminants. The nanoparticles are capable of reductively destroying or immobilizing a wide range of contaminants. Their small size results in a high surface area to mass ratio, making them much more reactive compared to their more-coarse predecessors. Small particle size also allows nZVI particles to be injected directly into contaminated areas via a well, limiting the above-ground footprint and allowing access to contaminated areas that are beyond the reach of some conventional methods. nZVI technology has the potential to facilitate remediation in difficult situations, improve remediation outcomes, …

Development Of A Screening Model For Design And Costing Of An Innovative Tailored Granular Activated Carbon Technology To Treat Perchlorate-Contaminated Water, William C. Powell

Theses and Dissertations

Perchlorate contamination of drinking water is a problem that has recently gained national attention. The purpose of this research was to develop a tool to predict the cost and performance of tailored granular activated carbon (T-GAC), an innovative technology to treat perchlorate-contaminated water. The ability to predict cost and performance is essential to promote transfer and commercialization of innovative technologies. This study investigated how data obtained from small-scale laboratory tests could be applied to predict cost and performance of a full-scale T-GAC system to treat perchlorate-contaminated water. A technology model was developed using GAC design principles and using a multi-component …

The Effects Of Orthophosphate As A Copper Corrosion Control Inhibitor In High Alkalinity Drinking Water Systems, Stephen Grace

Theses and Dissertations

The purpose of this research was to investigate orthophosphate as a corrosion inhibitor for copper pipe in a high-alkalinity drinking water system. Specifically, this thesis sought to answer three research questions regarding the impact of orthophosphate treatment, the nature of the mechanism by which orthophosphate controls copper corrosion, and the value of equilibrium modeling in predicting orthophosphate’s effects. The research questions were answered through a comprehensive literature review and experimental methodology integrating laboratory jar tests, water sampling and analysis from a field investigation, qualitative solids analysis, and equilibrium model application. This study analyzed field data obtained over the course of …

Characterization Of Chlorinated Ethene Degradation In A Vertical Flow Constructed Wetland, James M. Waldron

Theses and Dissertations

Chlorinated solvents, including perchloroethene (PCE) and trichlorethene (TCE), are among the most common groundwater contaminants found in the United States. Once released into the environment, chlorinated solvents are extremely persistent and often require costly and lengthy remedial actions. The use of constructed wetlands has shown promise as an effective and less costly alternative for the treatment of chlorinated solvent contaminated groundwater. This study characterized and evaluated the concentration of chlorinated ethenes within a vertical flow constructed wetland, fed with PCE contaminated groundwater, at Wright-Patterson Air Force Base (WPAFB), Ohio. Chlorinated ethene concentrations were characterized within three distinct layers of the …

Using Value-Focused Thinking To Evaluate The Use Of Innovative Stormwater Management Technologies On Air Force Installations, Jeffrey T. Falcone

Theses and Dissertations

Stormwater runoff occurs naturally after every storm event; however, traditional development practices have created many impervious surfaces, such as buildings, parking lots, and streets that increase runoff volume and flow rate. Conventional stormwater management practices focus on collecting runoff into centralized channels and conveying it as quickly as possible to local bodies of water. This type of conveyance system decreases the opportunity for stormwater to naturally infiltrate back into the ground. It also prevents contaminants from being naturally filtered out of stormwater flows. As a result, centralized conveyance systems can cause flooding, erosion, and terrestrial and aquatic habitat degradation. Innovative …

Molecular Characterization Of Wetland Soil Bacterial Community In Constructed Mesocosms, Ethan C. Bishop

Theses and Dissertations

The use of wetlands to effectively remediate aquifers contaminated with chlorinated solvents is an emerging technique, which shows high promise. In order to better understand this process and test its legitimacy, a treatment wetland was constructed at Wright-Patterson AFB, Dayton, Ohio and, in a joint effort with Wright State University (WSU), has previously shown the effective removal of PCE. The purpose of this research was to characterize the soil bacterial community, pre-PCE injection, among three wetland plant species from the sedge family (Cyperaceae) within constructed wetland mesocosms and to identify any bacterial dominance. Carex comosa, Scirpus atrovirens, and Eleocharis erythropoda …

Evaluation Of Microbial Diversity In Wetland Through Polymerase Chain Reaction (Pcr) And Restriction Fragment Length Polymorphism (Rflp), Gregory K. Joseph

Theses and Dissertations

The diversity of microbial communities in wetlands has not been fully measured. These communities may offer tools to naturally remediate sites polluted with chlorinated compounds. Polmerase Chain Reaction (PCR) and Restriction Fragment Length Polymorphism (RFLP) are genomic techniques that are capable of rapidly characterizing bacteria communities and can provide valuable information about the diversity of microbial communities.

Investigation Of Copper Contamination And Corrosion Scale Mineralogy In Aging Drink Water Distributions Systems, Nadja F. Turek

Theses and Dissertations

Research has shown higher levels of copper appear in drinking water conveyed through relatively new copper piping systems; older piping systems typically deliver lower copper levels in their drinking water. This research contributes field data from a real drinking water distribution system, providing a better understanding of this phenomenon, as it relates to treatment considerations and compliance with the Lead and Copper Rule. Copper pipes and copper levels were sampled from drinking water taps of 16 buildings with pipes ranging in age from less than 1 to 48 years. Water samples from each building were collected before and following a …

Modeling Study To Quantify The Benefits Of Groundwater Contaminant Source Remediation, David E. Wagner

Theses and Dissertations

The purpose of this research was to quantify the benefits of groundwater contaminant source remediation by using a model to simulate how reduction of source mass was related to reduction of contaminant concentration at a receptor. This thesis sought to answer three research questions: (1) how are contaminant source mass reduction and reduction of mass flux leaving the source-zone related; (2) how can we quantify the effect of the important natural attenuation processes that act upon the dissolved contaminant as it travels from the source zone to downgradient receptors, and (3) under specified site conditions, what is the maximum contaminant …

Analysis Of Bacterial Population And Distribution In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Bioremediation, Milton J. Clausen Jr.

Theses and Dissertations

Chlorinated hydrocarbons and their degradation products are among of the most common organic groundwater contaminates in the United States. These compounds attack the central nervous system in animals and can affect the photosynthesis of plants. These compounds are also resistant to degradation in the environment and, because of this, pose a risk to any ecosystem in which they are present. This study identified the dominant microbial species in a constructed treatment wetland at Wright-Patterson AFB, Dayton, Ohio using 16S rRNA gene sequence analysis. Samples were taken from three different depths and during each of the four seasons. These samples were …