Environmental Engineering Commons^™

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

Monitoring And Modeling The Hydrological Performance Of Extensive Green Roof Systems, Joseph Seidl

Theses and Dissertations

Urban stormwater runoff causes many problems for watersheds located within large metropolitan areas, including such detrimental effects as flooding, erosion, pollution, and the increased risk of combined sewerage overflows. Increased amounts of impervious areas resulting from urban sprawl have also been shown to escalate stormwater flows, which exacerbates water management issues in these metropolitan areas. Water resource engineers have progressively turned toward green infrastructure to solve stormwater problems, and green roof systems represent one type of this green infrastructure. As of current, however, green roof systems are largely underused in as an effective stormwater management tool.

The major factor limiting …

Evaluation Of First Order Error Induced By Conservative-Tracer Temperature Approximation For Mixing In Karstic Flow, Philippe Machetel, David A. Yuen

Sinkhole Conference 2015

Fluid dynamics in karst systems is complex due to the heterogeneity of hydraulic networks that combine the Porous Fractured Matrix (PFM) and the interconnected drains (CS). These complex dynamic systems often need to be treated as “black boxes” in which only input and output properties are known. In this work, we propose to assess the first-order error induced by considering the temperature as a conservative tracer for flows mixing in karst (fluvio-karst). The fluvio-karstic system is treated as an open thermodynamic system (OTS), which exchanges water and heat with its surrounding. We propose to use a cylindrical PFM drained by …

Building Codes To Minimize Cover Collapses In Sinkhole-Prone Areas, George Veni, Connie Campbell Brashear, Andrew Glasbrenner

Sinkhole Conference 2015

Cover- collapse sinkholes are forming with increasing frequency under buildings. Analyses of sinkhole distribution in Beacon Woods, Florida, preliminarily indicate their occurrence is an order of magnitude greater in urban versus undeveloped areas, suggesting the structures themselves are enhancing the collapse process. The most likely causes are induced recharge via at least one of two sources. First, runoff and drainage from roads, structures, and impoundments that is not adequately dispersed will promote sinkhole development. Second, leaking water, sewer, and septic systems beneath or adjacent to a structure will also promote collapse. The process of cover-collapse from induced recharge is well …

Karst Spring Cutoffs, Cave Tiers, And Sinking Stream Basins Correlated To Fluvial Base Level Decline In South-Central Indiana, Garre A. Conner

Sinkhole Conference 2015

The Mitchell Aquifer averages 80m in thickness and underdrains a karst region in the Crawford Upland and Mitchell Plateau region in south-central Indiana (110,000 km2). The Springville Escarpment is a transitional boundary between the upland and plateau. Cave stream linking between cave tiers in the aquifer and correlation of cave tier inception horizons to a base level decline surface is interpreted for the Kirby Watershed, encompassing the prekarst headland of Indian Creek (42km2). The watershed was severed from lower Indian Creek at Eller Col by limestone cavern drainage on the ridge between White River and East Fork. Correlation of recharge …

Tracer Studies Conducted Nearly Two Decades Apart Elucidate Groundwater Movement Through A Karst Aquifer In The Frederick Valley Of Maryland, Keith A. White, Michael K. Cobb, Thomas Aley, Ethan Weikel

Sinkhole Conference 2015

A pair of groundwater tracer studies at a single karst test site were completed 18 years apart. The results of these studies have provided evidence of both relatively rapid advective transport via conduits and an extreme capacity for dye storage and retardation. The tracer results, coupled with other subsurface investigation data, are used to develop a conceptual model for groundwater movement through this karst aquifer in the Frederick Valley of Maryland, as well as identify implications for remediation. Three fluorescent tracer dyes used in the initial study were detected in several background monitoring locations established for the second study conducted …

Integration And Delivery Of Interferometric Synthetic Aperture Radar [Insar] Data Into Stormwater Planning Within Karst Terranes, Brian Bruckno, Andrea Vaccari, Edward Hoppe, Scott Acton, Elizabeth Campbell

Department of Earth and Atmospheric Sciences: Faculty Publications

As part of two USDOT-funded studies focused on the development of satellite-based Interferometric Synthetic Aperture Radar (InSAR) technology, the researchers integrated InSAR-derived point cloud data into the transportation design process to optimize the location of a stormwater management system in a karst terrane. After initial validation, the InSAR data (over 1.67 million data points comprising various “scatterers”) were brought into a GIS dataframe and georeferenced to locations of known sinkholes. This dataset was then used to evaluate karst hazard within a 40x40km data frame located in the Valley and Ridge Province of Virginia. The group identified systematic kinematic differences in …

Spatial Variability Of Subsurface Soil Conditions Causing Roadway Settlements, Ömer Bilgin, Kevin Arens, Mark Salveter, Alexander Dettloff

Civil and Environmental Engineering and Engineering Mechanics Faculty Publications

Settlement of problematic soils constituting the roadway subgrade may result in pavement distress and structural failure, requiring periodic pavement patching and resurfacing. Many of these problems occur as a result of the settlement of soft cohesive and organic soils. Due to the extent of roadway projects and the limited frequency of boring locations, spatial variability of subsurface soil conditions, and sometimes due to an inadequate extent of exploration, these problematic soils may not be identified suitably during subsurface explorations. An extensive subsurface exploration program was implemented for detailed characterization of subsurface conditions for a relatively short section of an existing …

Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur

Electronic Thesis and Dissertation Repository

This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …

Using A High Altitude Balloon Platform To Observe And Measure Seasonal Ozone Flux Over Agricultural Landscapes, Cody Sabo

2017 Academic High Altitude Conference

The concentration of greenhouse gasses (GHGs) in the atmosphere has continued to rise since the industrial era. This issue has had a multitude of negative impacts on all living things. Among the major GHGs are carbon dioxide, methane, nitrous oxide, and ozone. Ozone is of particular importance because it not only has the ability to trap heat in the atmosphere, but it also directly impacts organisms by causing harm to both plants and humans. The damage that ozone causes to plants is most closely linked to ozone uptake rather than ozone concentration. So, measuring ozone uptake is becoming critical for …

Feasibility Study: The Evaluation Of Polymer Coatings To Prevent Weathering Of Weak Rocks, Lauren Distler

Senior Honors Projects, 2010-2019

The weathering and erosion of weak rocks along roadways can cause dangerous and potentially fatal rockfalls.   Various slope stabilization methods exist, but each presents a set of challenges and trade-offs.   The focus of the project is to understand the feasibility of utilizing of a polymerbased slope stabilization technique. Rock samples were collected along US Route 33 in Virginia and West Virginia, and preliminary tests were conducted to evaluate the absorption of water (% mass) and durability. The study evaluates three polymer options in regard to the following criteria: adhesion to rock, layer thickness, semi-permeability, insolubility, and non-toxicity. The polymer selection …

On The Influence Of Ionic Strength On Radium And Strontium Sorption To Sandy Loam Soils, Brian A. Powell, Todd Miller, Daniel I. Kaplan

Journal of the South Carolina Academy of Science

Models which can estimate environmental transport of radioactive contaminants in natural and engineered systems are required to 1) deploy effective remediation strategies for contaminated sites, 2) design waste repositories for future waste streams, and 3) ensure protection of human and environmental health in all cases. These models require accurate transport parameters in order to correctly predict how these contaminants will move in the subsurface. This work aimed to determine more accurately the distribution coefficients for radium and strontium sorption to Savannah River Site (SRS) soils. Radium and strontium sorption to the soils was found to be highly dependent upon ionic …

A Soil Parameters Geodatabase For The Modeling Assessment Of Agricultural Conservation Practices Effects In The United States, Mauro Di Luzio, Martin L. Norfleet, Jeffrey G. Arnold, Jimmy R. Williams, James R. Kiniry

International Journal of Geospatial and Environmental Research

Soil parameters for hydrology modeling in cropland dominated areas, from the regional to local scale, are part of critical biophysical information whose deficiency may increase the uncertainty of simulated conservation effects and predicting potential. Despite this importance, soil physical and hydraulic parameters lack common, wide-coverage repositories combined to digital maps as required by various hydrology-based agricultural water quality models.

This paper describes the construction of a geoprocessing workflow and the resultant hydrology-structured soil hydraulic, physical, and chemical parameters geographic database for the entire United States, named US-SOILM-CEAP. This database is designed to store a-priori values for a suit of models, …

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …