Environmental Engineering Commons^™

Modeling Regional Secondary Organic Aerosol Using The Master Chemical Mechanism, Jingyi Li, Meredith Cleveland, Luke D. Ziemba, Robert J. Griffin, Kelley Barsanti, James F. Pankow, Qi Ying

Civil and Environmental Engineering Faculty Publications and Presentations

A modified near-explicit Master Chemical Mechanism (MCM, version 3.2) with 5727 species and 16,930 reactions and an equilibrium partitioning module was incorporated into the Community Air Quality Model (CMAQ) to predict the regional concentrations of secondary organic aerosol (SOA) from volatile organic compounds (VOCs) in the eastern United States (US). In addition to the semi-volatile SOA from equilibrium partitioning, reactive surface uptake processes were used to simulate SOA formation due to isoprene epoxydiol, glyoxal and methylglyoxal. The CMAQ-MCM-SOA model was applied to simulate SOA formation during a two-week episode from August 28 to September 7, 2006. The southeastern US has …