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Articles 1 - 24 of 24
Full-Text Articles in Environmental Engineering
The Efficacy Of Wetland Treatment Systems Used To Treat Runoff Mixtures From Different Landscapes Across Kentucky, Emily Nottingham
The Efficacy Of Wetland Treatment Systems Used To Treat Runoff Mixtures From Different Landscapes Across Kentucky, Emily Nottingham
Theses and Dissertations--Biosystems and Agricultural Engineering
The overarching goal was to improve our understanding of the cumulative effect of increased use and occurrence of commonly detected contaminants of potential concern (CPCs) on nitrogen (N) transformation processes in wetlands. The central hypothesis was that those various mixtures of nutrients and CPCs entering treatment wetlands impact N removal pathways. The first study assessed the current state of the literature on the implications to N removal in wetlands in the presence of pesticides and antibiotics. 181 primary studies were identified. Removal efficiencies for nitrate varied widely across the studies, with CPCs impacting microbial communities. A knowledge gap remains in …
Nanopesticide Influence On Nitrogen Cycling In Soils, Jacob Richardson
Nanopesticide Influence On Nitrogen Cycling In Soils, Jacob Richardson
Theses and Dissertations--Biosystems and Agricultural Engineering
Nanotechnology has several applications in the agricultural industry, as the small size of nanoparticles and high reactivity enables targeted delivery of pesticides and fertilizers to the intended crop. Copper-based nanopesticides such as Kocide, are proposed as a more efficient method for targeted pest control. Despite the potential benefits of nanopesticides, little is known regarding the transport and implications of nanopesticides under long-term inundation conditions often found in downstream wetlands. Specifically, the impact of nanopesticides on microbial nitrogen processes in wetland environments remains unknown. Therefore, this thesis explores the impact of nanopesticides, specifically Kocide, on microbial nitrogen cycles in agricultural and …
Evidence Of Coal Conversion In The Majuba Underground Coal Gasification Pilot Plant, South Africa, L.S. Mokhahlane, N.J. Wagner, D. Vermeulen
Evidence Of Coal Conversion In The Majuba Underground Coal Gasification Pilot Plant, South Africa, L.S. Mokhahlane, N.J. Wagner, D. Vermeulen
Coal Combustion and Gasification Products Journal Archive
Underground coal gasification (UCG) is a coal conversion method that permits coal resources to be exploited in situ using high-temperature conversion reactions. An understanding of the chemical, mineralogical, and petrographic properties of the coal, and resultant unburned carbon, degasified coal, and ash (minerals) in the UCG gasification zone, is fundamental to determining conversion rates, gas composition, and environmental and groundwater risk assessments. This study aims to provide a mineralogical and petrographic characterization of UCG residues obtained from the Eskom Majuba UCG pilot plant site in South Africa. Samples were selected from a verification borehole (VH3) drilled at the site following …
Gadolinium Enrichment In Association With The Magnetic Fraction Of 1 Fly Ash: Real Or An Illusion?, James C. Hower, John G. Groppo, Dali Qian, Nicolas J. Briot, Tonya D. Morgan, Shelley D. Hopps, Elizabeth Cantando
Gadolinium Enrichment In Association With The Magnetic Fraction Of 1 Fly Ash: Real Or An Illusion?, James C. Hower, John G. Groppo, Dali Qian, Nicolas J. Briot, Tonya D. Morgan, Shelley D. Hopps, Elizabeth Cantando
Coal Combustion and Gasification Products Journal Archive
Gadolinium, and possibly praseodymium, are relatively enriched in the magnetic 24 fractions of Class F fly ashes from Central Appalachian coal sources. Although the enrichment is 25 evident in the inductively coupled plasma–atomic emission spectroscopy (ICP-AES) 26 determinations of the rare earth content, transmission electron microscopy–energy dispersive x-27 ray spectroscopy (TEM-EDS) examination of the fly ash fails to show the sites of the Gd or Pr. 28 This apparent lack of correlation could be due to the inability of the EDS to detect low 29 concentrations of the rare earth elements definitively; interferences in the analytics, leading to 30 false …
Low-Density And High-Strength Fracking Proppant Made By High Alumina Fly Ash, Shuqiang Ding, Jinder Jow
Low-Density And High-Strength Fracking Proppant Made By High Alumina Fly Ash, Shuqiang Ding, Jinder Jow
Coal Combustion and Gasification Products Journal Archive
High-alumina fly ash is defined to have alumina (Al2O3) content of no less than 40%, according to the Chinese power industry standard DL/T 2297. Specification for resource utilization categorization of fly ash from coal-fired power plant (Standard No. DL/T 2297-2021), and is considered a valuable raw material to replace bauxite for making aluminum, refractory materials, and fracking proppants, etc. A low-density and high-strength proppant, conventionally made with bauxite, has been successfully made by high-alumina fly ash and commercially used in the market. This new high-alumina f ly-ash–derived proppant has some advantages compared with the bauxite-derived proppant: (1) lower raw material …
Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti
Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti
Theses and Dissertations--Biosystems and Agricultural Engineering
The need for assessment and management of aquatic vegetation in stream ecosystems is recognized given the importance in impacting water quality, hydrodynamics, and aquatic biota. However, existing approaches to monitor are laborious and its currently not feasible to track spatial and temporal differences at broad scales. The objective of this study was therefore to map and classify aquatic vegetation of a shallow stream with heterogenous mixtures of emergent and submerged aquatic vegetation. Data was collected in the Camden Creek watershed within the Inner Bluegrass Region of central Kentucky. The use of unmanned aerial vehicles (UAVs) was employed and both visible …
Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill
Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill
Theses and Dissertations--Biosystems and Agricultural Engineering
Seasonal hypoxia in the Gulf of Mexico and harmful algal blooms experienced in many inland freshwater bodies is partially driven due to excessive nitrogen loading seen from agricultural watersheds. Within the Mississippi/Atchafalaya River Basin, many areas are underlain with karst features, and efforts to reduce nitrogen contributions from these areas have had varying success, due to lacking a complete understanding of nutrient dynamics in karst agricultural systems. To improve the understanding of nitrogen cycling in these systems, 35 months of high resolution in situ water quality and atmospheric data were collected and fed into a two-hidden layer extreme learning machine …
Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff
Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff
Theses and Dissertations--Biosystems and Agricultural Engineering
In the Midwestern U.S. seasonal hypoxia experienced in the Gulf of Mexico and harmful algal blooms in inland freshwater ponds, lakes, and rivers are partly fueled by dissolved orthophosphate loadings from disturbed landscapes. Efforts to reduce dissolved reactive phosphate (DRP) loadings have had varying levels of success and have led to insufficient water quality improvements. Inefficiencies in conservation strategies can stem from poor understanding of phosphate source and flow pathway dynamics. This study focused on monitoring sources and flow pathways of dissolved reactive P in a karst agroecosystem with phosphatic limestone. We collected event water samples at the Camden Creek …
Impact Of Preferential Flow, Source Water Connectivity, And Agricultural Management Practices On Sediment And Particulate Phosphorus Dynamics In Midwestern Tile-Drained Landscapes, Saeid Nazari
Theses and Dissertations--Biosystems and Agricultural Engineering
Tile drainage is recognized as a significant transporter of sediment and particulate phosphorus (PP) in the Midwestern U.S., leading to proliferation of Harmful Algal Blooms (HABs). Numerous studies have focused on Dissolved Reactive Phosphorus (DRP) and Nitrogen (N) flux dynamics in tile-drained landscapes; however, the impact of preferential flow and agricultural management practices on fate and transport of sediment and PP has remained poorly understood. The overarching objective of this study was to improve understanding of sediment P delivery in tile-drained landscapes. This dissertation focuses on four studies. In the first study, forms and flow pathway dynamics of total phosphorus …
Soil Bulk Density Effects On Runoff Estimation, Colton Pugh
Soil Bulk Density Effects On Runoff Estimation, Colton Pugh
Theses and Dissertations--Biosystems and Agricultural Engineering
Urbanization has long been a major factor in the hydrology of surrounding areas. Engineers are commonly tasked with mitigating the extra runoff that urbanization brings with it. The NRCS Curve Number (CN) method is a commonly-used approach to predicting the amount of runoff that will be experienced from a given area. However, this method is known to be highly simplified in model of the processes involved. This study focused on determining the relationships between soil bulk density, simulated rainfall events, hydrologic soil group (HSG) and runoff estimation (specifically via the NRCS CN method). It was determined that soil bulk density …
Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell
Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell
Theses and Dissertations--Biosystems and Agricultural Engineering
In-stream fate of nutrients in karst agroecosystems remains poorly understood, despite the known impact of karst on water resources at local to global scales. In the Inner-Bluegrass region of central Kentucky, heterogeneity of karst maturity, flow pathways, and nutrient sources adds to the complexity of quantifying nutrient dynamics, thus requiring novel monitoring and modeling approaches. The significance of these streams is recognized given spring/surface water confluences have been identified as hotspots for biogeochemical transformations. In slow-moving streams high in dissolved inorganic nutrients (particularly dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP)), benthic and floating aquatic macrophytes are recognized to …
Mineralogy And Geochemistry Of Feed Coals And Combustion Residues From Tunçbilek And Seyitömer Coal-Fired Power Plants In Western Turkey, Ali Ihsan Karayigit, Ozlem Yigitler, Seda Iserli, Xavier Querol, Maria Mastalerz, Riza Gorkem Oskay, James C. Hower
Mineralogy And Geochemistry Of Feed Coals And Combustion Residues From Tunçbilek And Seyitömer Coal-Fired Power Plants In Western Turkey, Ali Ihsan Karayigit, Ozlem Yigitler, Seda Iserli, Xavier Querol, Maria Mastalerz, Riza Gorkem Oskay, James C. Hower
Coal Combustion and Gasification Products Journal Archive
This study focuses on the enrichment of elements in feed coal (FC) and combustion residues, namely, fly ash (FA) and bottom ash (BA) samples, picked up from the Tunçbilek and Seyitömer coal-fired power plants in western Turkey. The FCs in both plants have generally similar mineralogical compositions, although siderite and dolomite are more prominent in Tunçbilek and feldspar and pyrite are more abundant in Seyitömer. Minerals in the FA from both power plants are mainly quartz, hematite, magnetite, anhydrite, and mullite. Along with quartz, the Fe-oxides are dominant phases in the BA samples. Accessory minerals in the FCs, FAs, and …
Phaselous Vulgaris Growth Under The Influence Of Manufactured Coal Ash Aggregates, Sangchul Hwang, Imiraily Hernandez, Isomar Latorre, Sahid Rosado
Phaselous Vulgaris Growth Under The Influence Of Manufactured Coal Ash Aggregates, Sangchul Hwang, Imiraily Hernandez, Isomar Latorre, Sahid Rosado
Coal Combustion and Gasification Products Journal Archive
Manufactured coal ash aggregates (MAs) are a 2:1 (w/w) solidified composite of fly and bottom ash. The current study assessed the feasibility of beneficial utilization of MAs as a subsoil substitute for open-pit restoration to phyto-viable land. A series of indoor and outdoor experiments examined Phaselous vulgaris growth under the influence of MAs in the soil environment. With the MAs layer below the topsoil, P. vulgaris showed enhanced growth with respect to shoot height, leaf number, and leaf chlorophyll intensity. Similar growth enhancement was observed when the MAs were mixed with topsoil or applied as a micronutrient source over the …
Separation Of Unburned Carbon From Coal Conversion Ash: Development And Assessment Of A Dry Method, Charlotte J. Badenhorst, Nicola J. Wagner, Bruno R.V. Valentim, Karel S. Viljoen, Ana C. Santos, Alexandra Guedes
Separation Of Unburned Carbon From Coal Conversion Ash: Development And Assessment Of A Dry Method, Charlotte J. Badenhorst, Nicola J. Wagner, Bruno R.V. Valentim, Karel S. Viljoen, Ana C. Santos, Alexandra Guedes
Coal Combustion and Gasification Products Journal Archive
Unburned carbon found in coal conversion ash has the potential to be used in a variety of value-added applications. However, it is first necessary to separate the unburned carbon from the rest of the ash phases. This poses challenges due to the relatively low starting carbon-in-ash values (0.4 to 7.8 wt% reported for South African sources), and the high carbon grades (ideally ∼90 wt% carbon) and recoveries that need to be achieved. In this study a dry method for the separation of unburned carbon from coal ash was developed and assessed using fly, bottom, and gasification ash samples obtained from …
Use Of Ponded And Fresh Ashes From China For The Production Of Portland/Calcium Sulfoaluminate Clinkers, Tristana Y. Duvallet, Robert B. Jewell, Anne E. Oberlink, Thomas L. Robl, David Harris
Use Of Ponded And Fresh Ashes From China For The Production Of Portland/Calcium Sulfoaluminate Clinkers, Tristana Y. Duvallet, Robert B. Jewell, Anne E. Oberlink, Thomas L. Robl, David Harris
Coal Combustion and Gasification Products Journal Archive
This article summarizes the use of two fly ashes in the synthesis of Portland/calcium sulfoaluminate (OPC/CSA or A/CSA) clinkers. They are from the Shentou second power plant located in the Shanxi Province and from the Zhungeer power plant located in Inner Mongolia, China. The Zhungeer ash was collected dry, and the Shentou ash is from a pond. Their chemical compositions differ highly, especially the SiO2 and Al2O3 contents. The high contents of silica and alumina make both ashes candidates as a partial or total substitute for bauxite, an expensive source of alumina, in the production of OPC/CSA clinkers. These particular …
Long-Term Effects Of Forestry Best Management Practices On Hydrology And Water Chemistry In Three Appalchian Headwater Catchments, Kameryn I. Wright
Long-Term Effects Of Forestry Best Management Practices On Hydrology And Water Chemistry In Three Appalchian Headwater Catchments, Kameryn I. Wright
Theses and Dissertations--Biosystems and Agricultural Engineering
In 1982, a study was initiated in the Field Branch watershed, in the University of Kentucky’s Robinson Forest, to evaluate forestry best management practice (BMP) effectiveness after intensive harvesting. The study utilized a paired watershed approach on three adjacent Field Branch subcatchments. One subcatchment was left as the control, one had BMPs implemented (including a 50-ft undisturbed buffer along the stream), and one was clear-cut to the stream’s banks without the use of BMPs (i.e. logger’s choice). Prior research has shown that logging can negatively impact watershed functions by altering stream hydrology, geomorphology, water quality, and instream habitat. Thus, the …
Development Of Regional And Hydraulic Geometry Curves For The Eastern Kentucky Coalfields, Ashlan Berry
Development Of Regional And Hydraulic Geometry Curves For The Eastern Kentucky Coalfields, Ashlan Berry
Theses and Dissertations--Biosystems and Agricultural Engineering
Regional curves and hydraulic geometry curves relate bankfull channel dimensions to drainage area and bankfull discharge, respectively. These curves are used in the natural channel design process to help identify bankfull and to estimate bankfull dimensions of the design channel. Nineteen streams were surveyed to determine their bankfull parameters (cross-sectional area, width, mean depth, discharge, slope, and Manning’s n), along with 27 streams previously surveyed in other studies. The data were used to create regional and hydraulic geometry curves for three hydrologic landscape regions (HLR 9, HLR 11, and HLR 16, individually) in the Eastern Kentucky Coalfields (EKC) as well …
Determining Soil Erosion With Varying Corn Stover Cover Factors, Nicole K. Koeninger
Determining Soil Erosion With Varying Corn Stover Cover Factors, Nicole K. Koeninger
Theses and Dissertations--Biosystems and Agricultural Engineering
Since the Dust Bowl, conservation agriculture has become a common practice globally. Because of the rising interest in the use of corn biomass as a feedstock for biofuel production, the effects of corn stover removal on soil erosion were explored. It was hypothesized that selective harvesting strategies would impact soil erosion differently across a variety of slopes. Soil erosion boxes were constructed, and a rainfall simulator with an intensity of 30 mm hr-1 for 46 min was used to create runoff from slopes of 1, 5, and 10% and three cover factor treatments (no removal and two simulated corn …
Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch
Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch
Theses and Dissertations--Biosystems and Agricultural Engineering
Surface mining is a commonly used method for extracting coal in the Appalachian Coalfields of the U.S. This mining practice produces excess spoil or overburden, which is often placed in adjacent valleys resulting in the creation of valley fills. These valley fills bury headwater streams, which in turn can negatively impact downstream ecosystems. In 2008, the University of Kentucky designed and constructed 1,020 m of ephemeral, intermittent and headwater streams on an existing valley fill (Guy Cove) as a proof-of-concept. The goal of the project was to evaluate whether or not a stream recreation could occur on mined lands, particularly …
Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith
Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith
Theses and Dissertations--Biosystems and Agricultural Engineering
Biochars have been created and characterized from a variety livestock manure biomass including poultry, dairy, and swine. However, no research has been conducted on the physical and chemical makeup of biochar pyrolyzed from horse muck. Two horse muck derived biochars containing either straw (HS) or woodchip (HW) bedding were pyrolyzed at 700°C and characterized for their physical and chemical properties. Tests revealed both biochars had high alkalinity, moderate specific conductivity, and low surface area as compared to other biochars in the literature. HS contained more mineral structures than HW. Scanning electron microscopy presented differences in particle shape, size, and presence …
Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines
Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines
Theses and Dissertations--Biosystems and Agricultural Engineering
Human activity such as surface mining can have substantial impacts on the natural environment. Performing a Cumulative Hydrologic Impact Assessment (CHIA) of such impacts on surface water systems requires knowing the location and extent of these impacted streams. The Jurisdictional Determination (JD) of a stream’s protected status under the Clean Water Act (CWA) involves locating and classifying streams according to their flow regime: ephemeral, intermittent, or perennial. Due to their often remote locations and small size, taking a field inventory of headwater streams for surface mining permit applications or permit reviews is challenging. A means of estimating headwater stream location …
Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine
Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine
Theses and Dissertations--Biosystems and Agricultural Engineering
Impervious surfaces such as roads, sidewalks, and roofs increase the volume of runoff generated in a watershed. Traditional stormwater management techniques emphasize conveyance of runoff away from impervious surfaces in order to reduce flooding. Rain gardens are becoming popular as a different means to manage stormwater in such a way that runoff is captured and infiltrated onsite rather than conveyed offsite. A stormwater management system consisting of a rainwater harvest system, rain garden, and infiltration chamber was built at the Coca-Cola Refreshments USA, Inc. distribution center in Lexington, Kentucky during the fall of 2011. Precipitation, inflow, and water level were …
A Multi-Analytical Approach To Understand The Chemistry Of Fe-Minerals In Feed Coals And Ashes, Marcos L.S. Oliveira, Frans Waanders, Luis F.O. Silva, Andre Jasper, Carlos H. Sampaio, Dursman Mchabe, Rachel S. Hatch, James C. Hower
A Multi-Analytical Approach To Understand The Chemistry Of Fe-Minerals In Feed Coals And Ashes, Marcos L.S. Oliveira, Frans Waanders, Luis F.O. Silva, Andre Jasper, Carlos H. Sampaio, Dursman Mchabe, Rachel S. Hatch, James C. Hower
Coal Combustion and Gasification Products Journal Archive
Seven feed coals used in the Brazilian power generation industry were obtained and subsequently analysed together with fly ash and bottom ash from a major Brazilian power plant. The samples were investigated by means of room temperature FeMo¨ssbauer analyses, X-ray diffraction, Raman spectroscopy, scanning electron microscope and petrographic analysis. In addition, nanometer-sized crystalline phases in coals and ashes were characterised using an energy-dispersive X-ray spectrometer and a high-resolution transmission electron microscope. The major identified Fe-bearing minerals in the coals were found to be actinolite, ankerite, chalcopyrite, chlorite, goethite, illite, ilmenite, magnesioferrite, natrojarosite, pyrite, pyrrhotite, and siderite; whilst in the fly …
Variations In Fly Ash Composition With Sampling Location: Case Study From A Portuguese Power Plant, B. Valentim, A. Guedes, D. Flores, C.R. Ward, J.C. Hower
Variations In Fly Ash Composition With Sampling Location: Case Study From A Portuguese Power Plant, B. Valentim, A. Guedes, D. Flores, C.R. Ward, J.C. Hower
Coal Combustion and Gasification Products Journal Archive
Fly ash (FA) is a heterogeneous and complex material resulting from coal combustion in thermoelectric power plants (TPP). Therefore, different types of coals, worldwide, produce FAs with different compositions. However, the location of the FA sampling system, inside the TPP, is also important to the composition of the FA produced at each location. A case study of FA from a Portuguese TPP, using several coal and FA characterization techniques (particle size analysis, proximate and ultimate analyses, XRF, SEM/ESEM/EDS, Optical microscopy, XRD, inferred chemistry, and AAS), has shown that FA chemical classification, mineralogy and phase-mineral classification, and trace elements (Cr, Cu, …