Engineering Commons^™

Partially Oxidative Torrefaction Of Woody Biomass Pellets: Burning Behaviour And Emission Analysis, Sajid Riaz, Yasir M. Al-Abdeli, Ibukun Oluwoye

Research outputs 2022 to 2026

Non-conventional torrefaction under partially oxidative conditions is an emerging cost-effective thermochemical pre-treatment method to improve the quality of biomass for energy applications. The literature lacks data on the combustion of biomass torrefied under oxygen-deficient atmosphere with actual reactor conditions (inevitable non-uniformities in the thermal environment). In this work, a dual mode fixed-bed biomass (torrefaction) reactor and combustor was operated on Australian biomass pellets, to torrefy the fuels at 275 °C for 30 min using partially oxidative atmosphere (O₂: 5 vol %, balance N₂) and then to combust them. Combustion behaviour with a particular focus on gaseous …

Catalytic And Non-Catalytic Methods For Hydrocarbon Upgrading, Valorization, And Pollutant Control, Michael Morgan Royko

Theses and Dissertations

This work investigates catalytic and non-catalytic oxidative chemical upgrading and pollutant remediation techniques to responsibly utilize hydrocarbon feedstocks with existing infrastructure as the transition to more renewable and cleaner feedstocks for energy generation are developed. These technologies include oxidative dehydrogenation of ethane, development of magnetically separable catalysts to reduce carbon monoxide emissions during biomass upgrading as well as the subsequent use of the upgraded biomass for partial coal replacement, and electrochemical treatment of a washcoat free wire mesh supported catalyst to reduce carbon monoxide emissions in combustion exhaust.

First, doping of secondary metals in M1/M2 catalysts for oxidative dehydrogenation of …

Torrefaction Of Mixed Solid Waste, Zhuo Xu

Dissertations, Master's Theses and Master's Reports

The world is witnessing unprecedented accumulation of solid wastes in the environment and landfills with well-documented ecological, environmental, health, and economic consequences. With population growth and rise in living standards, solid wastes generation will increase, making the issue more pressing. In addition, current practices of solid waste disposal are creating an immediate challenge and a long-term disaster-scale problem. The solid wastes comprises two main groups of materials: (i) fiber wastes (paper, food, wood, trimming, 61% of U.S. municipal solid waste) and (ii)uniquely challenging subset of plastic wastes (13%) that become a threat to global sustainability including dangers to marine and …

Bio-Oils From Vacuum Ablative Pyrolysis Of Torrefied Tobacco Residues, Nattawut Khuenkaeo, Blake Macqueen, Thossaporn Onsree, Sangu Daiya, Nakorn Tippayawong, Jochen A. Lauterbach

Faculty Publications

Fast pyrolysis, in combination with torrefaction pretreatment, was used to convert tobacco residues to value-added bio-fuels and chemicals. Tobacco plant residues were torrefied at 220, 260, and 300 °C, before being pyrolyzed at 450, 500, 550, and 600 °C in a rotating blade ablative reactor under vacuum conditions to test the effects on product yields. With torrefaction, tobacco residues thermally decomposed 20-25% w/w at low temperatures. Torrefaction and pyrolysis temperatures were found to markedly affect pyrolytic product yields of bio-chars and bio-oils, while having no effect on gas-phase products. Bio-oil yields exhibited a direct relation with pyrolysis temperature and an …

Bio-Oils From Vacuum Ablative Pyrolysis Of Torrefied Tobacco Residues, Nattawut Khuenkaeo, Blake Macqueen, Thossaporn Onsree, Sangu Daiya, Nakorn Tippayawong, Jochen A. Lauterbach

Faculty Publications

Fast pyrolysis, in combination with torrefaction pretreatment, was used to convert tobacco residues to value-added bio-fuels and chemicals. Tobacco plant residues were torrefied at 220, 260, and 300 °C, before being pyrolyzed at 450, 500, 550, and 600 °C in a rotating blade ablative reactor under vacuum conditions to test the effects on product yields. With torrefaction, tobacco residues thermally decomposed 20-25% w/w at low temperatures. Torrefaction and pyrolysis temperatures were found to markedly affect pyrolytic product yields of bio-chars and bio-oils, while having no effect on gas-phase products. Bio-oil yields exhibited a direct relation with pyrolysis temperature and an …

Chlorine Removal From U.S. Solid Waste Blends Through Torrefaction, Zhuo Xu, Josh W. Albrecht, Shreyas Kolapkar, Stas Zinchik, Ezra Bar Ziv

Michigan Tech Publications

The amount of solid waste generated annually is increasing around the world. Although the waste has a high calorific value, one major obstacle that may prevent it from becoming a feedstock for power applications is the existence of polyvinyl chloride (PVC), which causes corrosion and emission issues after combustion due to its high chlorine content. Torrefaction is known to release hydrochloric acid; thus, it has been applied in this study for the reduction of chlorine from potential waste feedstocks. Fiber-plastic (60-40%) waste blends, with different chlorine content levels, as well as PVC were used in the current study. Torrefaction was …

Experimental Design And Testing In A Pilot-Scale Rotary Kiln For The Torrefaction Of Beech Wood Under System Restrictions, Jorge López-Ordovás, Ibai Funcia-Muguerza, Katie Chong, Javier Gil, Raúl Pérez-Vega, Tony Bridgwater

Bio-Char II: Production, Characterization and Applications

The torrefaction process increases the energy density of the torrefied feedstock through the loss of volatiles and moisture. The anhydrous weight loss (AWL) measures the loss of volatiles and it is easily correlated with the net calorific value (NCV) of the torrefied product.

This work has two different parts. The first part consists of the design of the experiments and the second includes the experiments with results. The system used in CENER, where the simulation and experiments were completed, is a rotary kiln with a maximum capacity of 500 kg/h and a range of operating temperatures between 220-310°C. The innovative …

Slow Pyrolysis Of Lignin Rich Residue From Lignocellulosic Biorefining Operations, Paola Giudicianni, Corinna Maria Grottola, Raffaele Ragucci

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

Europe is committed to have a bio-based economy in 2030. It follows that a huge contribution of biorefinery products on the European demand for chemicals, energy, materials and fibers is expected in the near future. To be environmentally and economically sustainable, biorefinery will need to be flexible, versatile, energy and cost efficient [1]. In a lignocellulose based biorefinery, the sugar platform that leads to bioethanol and added-value products through biochemical processes represents a challenging option. After ethanol distillation a lignin reach residue (LRR) is produced and used as energy source. However, it is currently underutilized with about 60% more lignin …

Paddle Mixer-Extrusion Reactor For Torrefaction And Pyrolysis, Stas Zinchik

Dissertations, Master's Theses and Master's Reports

This work is focused on the fundamental understanding and the development of paddle mixer reactors (or modified screw augers). This work will contribute to the effort of the thermal conversion of biomass and wastes. We developed and studied two paddle systems (i) 25-mm lab-scale (up to 1 kg/hr) and (ii) 101-mm pilot-scale (up to 100 kg/hr). Thermal behavior of the two systems was studied and it was estimated that the lab-scale system has a high heating rate of up to 530 °C/s. Residence times were thoroughly measured and were determined as a function of rotation frequency and volume fraction. We …

Properties Of Torrefied U.S. Waste Blends, Zhou Xu, Stas Zinchik, Shreyas Kolapkar, Ezra Bar Ziv, Ted Hansen, Dennis Conn, Armando G. Mcdonald

Michigan Tech Publications

Power generation facilities in the U.S. are looking for a potential renewable fuel that is sustainable, low-cost, complies with environmental regulation standards and is a drop-in fuel in the existing infrastructure. Although torrefied woody biomass, meets most of these requirements, its high cost, due to the use of woody biomass, prevented its commercialization. Industrial waste blends, which are also mostly renewable, are suitable feedstock for torrefaction, and can be an economically viable solution, thus may prolong the life of some of the existing coal power plants in the U.S. This paper focuses on the torrefaction dynamics of paper fiber-plastic waste …

Optimal Level Of Woody Biomass Co-Firing With Coal Power Plant Considering Advanced Feedstock Logistics System, Sangpil Ko, Pasi T. Lautala

Michigan Tech Publications

Co-firing from woody biomass feedstock is one of the alternatives toward increased use of renewable feedstock in existing coal power plants. However, the economic level of co-firing at a particular power plant depends on several site-specific factors. Torrefaction has been identified recently as a promising biomass pretreatment option to lead to reduction of the feedstock delivered cost, and thus facilitate an increase in the co-firing ratio. In this study, a mixed integer linear program (MILP) is developed to integrate supply chain of co-firing and torrefaction process and find the optimal level of biomass co-firing in terms of minimized transportation and …

A Quantitative Environmental Assessment Of Incorporating Torrefaction Into Farming Enterprises In Eastern South Dakota, Dinesh Fuyal

Electronic Theses and Dissertations

The use of renewable energy sources has been increasing in the recent years due to population growth and environmental concerns. Biomass is a promising energy source that can be used to produce biofuels or torrefied pellets. Torrefied biomass may be used in power plants, industrial and residential heating, feedstocks for gasification, air and water filtrating, and soil amendment. The interest of torrefied pellets as energy sources for various applications has been increased in the recent years due to the concerns about energy security and environmental issues. This study focuses on the economic and environmental assessment of agricultural feedstocks like corn …

Woody And Agricultural Biomass Diversity In Torrefaction: A Complete Study In Solid Conversion And Volatiles Formation On Tga-Gcms, María González Martínez, Capucine Dupont, Xuan Mi Meyer, Christophe Gourdon

Biochar: Production, Characterization and Applications

Nowadays, there is an increasing awareness on the importance of biomass waste as a renewable source of energy, materials and chemicals. In this context, the European project MOBILE FLIP aims at developing and demonstrating mobile conversion processes suitable with various underexploited agro- and forest based biomass resources in order to produce energy carriers, materials and chemicals. One of these processes is torrefaction, which consists in a mild thermal treatment, occurring typically between 200 and 300°C during a few tens of minutes in a default-oxygen atmosphere.

Please click on the file below for full content of the abstract.

Techno-Economic And Life Cycle Assessments Of Biofuel Production From Woody Biomass Through Torrefaction-Fast Pyrolysis And Catalytic Upgrading, Olumide Winjobi

Dissertations, Master's Theses and Master's Reports

Biofuel production through fast pyrolysis of biomass is a promising conversion route in the production of biofuels compatible with existing technology. The bio-oil produced from fast pyrolysis is a versatile feedstock that can be used as a heating oil or upgraded to a transportation hydrocarbon biofuel. Comparative study of a one-step, fast pyrolysis only pathway and a two-step torrefaction-fast pyrolysis pathway was carried out to evaluate the effect of torrefcation on (i) the minimum selling price of biofuel and (ii) the potential life cycle GHG emissions of the biofuel production pathway.

To produce bio-oil which can serve as a substitute …

Techno-Economic Feasibility Of Distributed Torrefaction Systems Using Corn Stover Feedstock, Evan Almberg

Electronic Theses and Dissertations

This study investigated the economic feasibility of distributed torrefaction biorefining systems using corn stover feedstock to generate value-­‐added products. Distributed torrefaction systems have the potential to operate on private agricultural enterprises as well as community-­‐scale processing facilities, similar in scale to local grain elevators. Distributed systems will thus, reduce the need for large capital investments for dedicated commercial biorefining facilities and decrease logistical concerns for harvesting and marketing the torrefied corn stover products. In this study, a techno-­‐economic model was developed to analyze the economics of harvesting techniques, logistics, processing requirements, and end product utilization. Results were determined using baseline …

Modeling Of Biomass Torrefaction And Pyrolysis And Its Applications, Jordan L. Klinger

Dissertations, Master's Theses and Master's Reports - Open

Utilizing biomass provides a possible near-term alternative solution for fossil energy dependence in both electricity generation and transportation. Though thermochemical conversion can produce solid/liquid fuels that are compatible in existing infrastructure, detailed scientific chemical and mechanistic understanding are still being developed. In contribution to these efforts, this work is focused on development of a semiempirical, lumped parameter, chemical kinetic model to describe the degradation of woody biomass.

The initial kinetic model was developed in the torrefaction region to describe the gas-phase evolution of products (water, organic acids, permanent gases, and furfural) through a three consecutive reaction model. In this model, …

Thermal Decomposition Dynamics And Severity Of Microalgae Residues In Torrefaction., Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Thermal Characterization Of Oil Palm Fiber And Eucalyptus In Torrefaction., Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Non-Oxidative And Oxidative Torrefaction Characterization And, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Product Yields And Characteristics Of Corncob Waste Under Various Torrefaction Atmospheres, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Biomass Torrefaction Characteristics In Inert And Oxidative Atmospheres At Various Superficial Velocities, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Thermogravimetric Analysis And Kinetics Of Co-Pyrolysis Of Raw/Torrefied, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Production Of Bio-Coal And Activated Carbon From Biomass, Diana C. Cruz

Electronic Thesis and Dissertation Repository

The slow pyrolysis of different biomasses (maple wood, birch bark, switch grass, coffee pulp and corn stalk) was studied with the aim to produce a solid pyrolysis product (bio-coal) with promising properties and potential for use in traditional fossil-coal applications. Batch pyrolysis experiments were conducted in a Mechanically Fluidized Reactor (MFR) at temperatures ranging from 143 to 665 ^oC, which includes the torrefaction temperature range (200-300 ^oC). The effects of temperature and holding time on bio-coal mass yields were determined. The bio-coals were characterized in detail and a highly-controlled study on bio-coal hygroscopicity is presented. Optimal conditions for …

An Experimental Analysis On Property And Structure Variations Of Agricultural, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Torrefaction And Low Temperature Carbonization Of Oil Palm Fiber And Eucalyptus, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Hydrothermal Carbonization Of Sugarcane Bagasse Via Wet Torrefaction, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Torrefied Biomasses In A Drop Tube Furnace To Evaluate Their Utility, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

An Evaluation On Improvement Of Pulverized Biomass Property For Solid Fuel, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Isothermal Torrefaction Kinetics Of Hemicellulose, Cellulose, Lignin And Xylan Using, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.

Thermal Pretreatment Of Wood (Lauan) Block By Torrefaction And Its Influence On, Wei-Hsin Chen

Wei-Hsin Chen

No abstract provided.