Engineering Commons^™

Experimental Study For Improving Oil Recovery Using Organic Alkaline And Nano-Silica For An Egyptian Oil Field, Attia Attia, Mohamed Sadek Hamedi Al, Mayar Abdelrahman Hassan Eng.

Petroleum Engineering and Gas

The oil and gas industry continually seeks innovative methods to enhance hydrocarbon recovery due to the declining productivity of conventional techniques. Current recovery methods, such as water flooding and chemical flooding, often face limitations like high interfacial tension, unfavorable wettability, and reduced mobility of oil, especially under harsh reservoir conditions of high salinity. To address these challenges, this study explores the implementation of nanotechnology in enhanced oil recovery (EOR), focusing on the distinct and unique properties of nanoparticles. Nanoparticles, particularly SiO2, were chosen for their ability to significantly decrease interfacial tension, alter wettability, and improve oil mobility. SiO2 nanoparticles exhibit …

Radiation Assessment And Distribution In Changing Atmospheric Structures And Turbulence (Radcast), Steven B. Hernandez

Theses and Dissertations

The accessibility of materials and online information has made radiological dispersal devices (RDDs) a more probable threat than conventional nuclear weapons. This study analyzed five datasets from three test periods, using a correlation analysis between optical turbulence, aerosol concentration, and environmental parameters, and geometric mean diameter (GMD) calculations. The correlation analysis failed to yield meaningful insights, prompted a transition to the GMD analysis, which produced clearer results. Findings show GMD ranged from 38–41 nm, increasing at night and during neutral events as reduced vertical motion and boundary layer contraction correlated with optical turbulence. An alternative GMD dataset, calculated by the …

Optimization And Dft Study For Boosted Electooxidation Of Formic Acid At Niox Modified Pt Using Urea Derivatives As Blending Fuels, Aya Saada

Biochemical Engineering

This paper addresses the enhancement of formic acid electrooxidation (FAO) at Pt and Pt-NiOx nanoparticles based-catalysts assisted with urea derivatives as blending fuels. Blending formic acid with various ratios of urea derivatives showed noticeable enhancements of FAO as demonstrated by a favorable negative shift of its onset potential (Eonset) and increase of its peak current density concurrently with suppression of the amount of CO poisoning reaction intermediate. Among all the used derivatives, phenyl urea (PU) showed superior enhancing effect towards the direct FAO with a minimal CO formation together with a favorable negative shift of Eonset by 150 mV. The …

Plasmonic Nanopore Sensing For The Characterization Of Viruses And Biomolecules, Scott Renkes

Bioengineering Dissertations - Archive

The rapid advancement of nanomedicine has enabled increasingly precise nanotherapeutic platforms, including targeted nanoparticles, monoclonal antibodies, and viral gene delivery vectors. As these technologies mature, quality control and analytical characterization have emerged as critical bottlenecks, particularly in systems where functional outcomes depend on one-to-one molecular or particle–biological interactions. Conventional ensemble-averaged techniques obscure heterogeneity that is often central to therapeutic efficacy, safety, and manufacturability. A prominent example is adeno-associated virus (AAV)–based gene therapy, where production yields heterogeneous populations of empty, partially loaded, and fully loaded capsids. Genome fill percentage and integrity directly influence therapeutic efficacy and dosing accuracy, while limited understanding …

Gold Nanoparticle-Enhanced Molecularly Imprinted Polymer Electrode For Non-Enzymatic Lactate Sensing, Christopher Animashaun, Abdellatif Ait Lahcen, Gymama Slaughter

Center for Bioelectronics Publications

We are reporting the development of a high-performance, non-enzymatic electrochemical biosensor for selective lactate detection, integrating laser-induced graphene (LIG), gold nanoparticles (AuNPs), and a molecularly imprinted polymer (MIP) synthesized from poly(3,4-ethylenedioxythiophene) (PEDOT). The LIG electrode offers a highly porous, conductive scaffold, while electrodeposited AuNPs enhance catalytic activity and signal amplification. The PEDOT-based MIP layer, electropolymerized via cyclic voltammetry, imparts molecular specificity by creating lactate-specific binding sites. Cyclic voltammetry confirmed successful molecular imprinting and enhanced interfacial electron transfer. The resulting LIG/AuNPs/MIP biosensor demonstrated a wide linear detection range from 0.1 µM to 2500 µM, with a sensitivity of 22.42 µA/log(µM) and …

Viscoelastic Materials Evaluated For Blast-Resistant Designs, M. Sutter, C. Thomas, A. D. Douglas, F. Dogan, C. E. Johnson

Mining Engineering Faculty Research & Creative Works

Viscoelastic materials have extensive military applications due to their energy absorption capabilities, with the potential to reduce blast energy imposed on buildings, vehicles, and personnel. Based on current literature, limited information is available regarding the mitigation of blast energy related to these uses. The impact of thickness, nanoparticle addition, and layering variation was assessed in this study using commercially available viscoelastic materials in open-air blasts of Composition C4 to determine shock energy mitigation capabilities. Time-pressure waveforms were recorded to identify optimal changes in shock wave characteristics: reduced peak pressure, positive phase duration, and impulse, with increased rise times. Results were …

The Bacteriostatic, Regenerative, And Immunomodulatory Properties Of Extracellular Matrix Particles For Lung Injury, Keera P. Rhoads

Theses and Dissertations

Acute respiratory distress syndrome (ARDS) is a prevalent, life-threatening lung condition, affecting nearly 200,000 Americans annually, with a 40% international mortality rate. There is no cure for ARDS, and current pharmacological treatments have limited effectiveness. Symptoms can be mitigated with mechanical ventilation, though this often leads to ventilator-induced lung injuries (VILI) and puts critically ill patients at risk of infections, including ventilator-associated pneumonia (VAP). A promising therapeutic is the extracellular matrix (ECM), a complex network of structural proteins and bioactive molecules that has been shown to have anti-inflammatory properties and prevent fibrosis. We aim to utilize the regenerative and immunomodulatory …

Explorations Of Dna-Single-Walled Carbon Nanotube Interactions To Develop Multiplexed Molecularly Specific Biosensors For Inflammation, Amelia K. Ryan

Dissertations and Theses

Inflammatory cytokines such as interleukin-6 (IL-6) and interleukin-12 (IL-12) are central regulators of immune signaling and key biomarkers of disease, yet existing assays for their detection remain slow, invasive, and lack multiplexing ability. This dissertation advances the development of single-walled carbon nanotube (SWCNT) optical nanosensors capable of real-time, multiplexed, and molecularly specific cytokine detection through innovative use of single-stranded DNA (ssDNA) interfaces.

First, an IL-6-specific DNA aptamer was employed as both a dispersing agent and recognition probe for SWCNT fluorescence sensing. Sequence modifications, including anchor domains, truncations, and thermally induced refolding, were systematically tested to optimize sensitivity and selectivity. The …

Laser-Induced Graphene For Early Disease Detection: A Review, Sri Ramulu Torati, Gymama Slaughter

Center for Bioelectronics Publications

Electrochemical biosensors have been instrumental in early disease detection, facilitating effective monitoring and treatment. The emergence of graphene has significantly advanced sensor technology in various fields, including biomedicine, electronics, and energy. In this landscape, laser‐induced graphene (LIG) has emerged as a superior alternative to conventional graphene synthesis methods. Its straightforward fabrication process and compatibility with wearable devices boost its practicality and potential for real‐world applications. This review highlights the transformative potential of LIG in biosensing, showcasing its contributions to the development of next‐generation diagnostic tools for early disease detection. An overview of the LIG synthesis process and its applications in …

La2nio4+Δ-Based Solid Oxide Electrolysis Cell (Soecs) Electrodes Enhanced With Complex Perovskite Nanocatalyst Processed By Surfactant-Enabled Infiltration, Cole Samuel Klemstine

Graduate Theses, Dissertations, and Problem Reports (ETD)

As the world seeks to reduce its reliance on hydrocarbons, the demand for sustainable hydrogen production methods has become increasingly critical. Hydrogen is a versatile energy carrier that can be produced from various sources, including water, natural gas, and biomass. Replacing the burning of hydrocarbons with hydrogen could significantly reduce greenhouse gas emissions, contributing to global climate goals like those set by the US H2NEW program. The joint technologies of solid oxide fuel and electrolysis cells present the ability to both produce and process clean hydrogen to meet these goals. Development into solid oxide fuel cells has been met with …

Influence Of Glycopolymer Structure On Amphiphilic, Hybrid, Linear Branched Block Copolymer Properties For Use In Biomedical Applications, Kevin Green

Dissertations

The focus of this dissertation is evaluating and adding fundamental knowledge regarding the structure-property relations of glycopolymers used in the design of hybrid block copolymers (HBC) that are cable of self-assembling into delivery vehicles for biomedical applications. A shift to the utilization of natural materials in the design and fabrication of drug-delivery vehicles has garnered significant attention. Understanding the effects of linear glycopolymers content and composition on the resulting HBCs properties can provide valuable insight into how these materials may be tailored for use in targeted biological applications.

The first chapter introduces current literature on the need for improvement in …

Multifunctional Peptides To Improve Nucleic Acid Delivery For Ovarian Cancer Treatment, Kharimat Lora Alatise

All Dissertations

RNA interference (RNAi) therapies, such as small interfering RNA (siRNA), offer a high-precision approach to reducing the expression of disease-promoting genes with minimal off-target effects. For aggressive diseases like ovarian cancer, RNAi therapy can serve as a robust treatment modality if delivered successfully. Over 70% of ovarian cancer patients are diagnosed in stages three and four, where the disease becomes more difficult to treat. High relapse rates and drug resistance in these stages demonstrate the need for novel strategies to sensitize tumors to chemotherapy, making siRNA a promising avenue for targeting resistance-associated oncogenes.

However, the delivery of siRNA remains a …

Innovative Approaches For Improving Orc Performance: A Review Of Pure Fluids, Zeotropic Mixtures, And Nanoparticles, Ebenezer Kumi, Vasudevarao Veeredhi, Christopher Enweremad

Journal of Mechanical Engineering Science and Technology (JMEST)

Although the organic Rankine Cycle (ORC) is said to effectively capture low-grade heat, its commercialization has been limited because of working fluid constraints and inefficiencies resulting from operating at low temperatures. This study reviews the working fluids used in organic Rankine cycles and examines how nanoparticles could enhance the efficiency of the ORC, by enhancing the thermophysical properties of the working fluids. Results from this review showed that zeotropic mixtures of pure fluids, provide a viable approach to improving the thermophysical characteristics of organic working fluids and have the potential to achieve thermo-economic performance superior to that of individual pure …

A Novel Hybrid Enhanced Oil Recovery Technique To Enhance Oil Production From Oil-Wet Carbonate Reservoirs By Combining Electrical Heating With Nanofluid Flooding, Farida Amrouche, Martin J. Blunt, Stefan Iglauer, Farid Aiouache, Michael Short

Research outputs 2022 to 2026

Enhanced Oil Recovery provides a promising technique to maximise fossil fuel recovery from existing resources, and when used in conjunction with Carbon Capture and Storage/Utilisation provides a way to support a transition to alternative cleaner fuels. A hybrid Enhanced Oil Recovery method by a combination of electrical heating and nanofluid flooding was applied to oil-wet carbonate reservoirs and assessed in terms of the oil production, zeta potential, contact angle, pellet compaction, interfacial tension, and pH values. The hybrid technique consisted of a combination of direct current (up to 30 V) and iron oxide (Fe2O3) or magnesium oxide (MgO) nanofluids. Both …

Persistent Luminescent Nanoparticle-Loaded Filaments For Identification Of Fabrics In The Visible And Infrared, Brian Yust, Abdur Rahaman Sk, Antonios Kontsos, Brian George

College of Humanities and Sciences Faculty Papers

Persistent luminescent materials are those which can store an amount of energy locally and release it slowly in the form of light. In this work, persistent luminescent nanoparticles (PLNPs) were synthesized and incorporated into polypropylene (PP) filaments at various loading percentages. We investigated the optical properties of both the as-prepared PLNPs and the PLNP-loaded filaments, focusing on any changes resulting from the integration into the filaments. Specifically, visible and near-infrared spectroscopy were used to analyze the emission, excitation, and persistent luminescence of the PLNPs and PLNP-loaded filaments. The tensile properties of the extruded filaments were also investigated through breaking tenacity, …

Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, a batch absorption reactor was used to evaluate the nanofluid of a binary aqueous solution of monoethanolamine and 2-amino-2-methyl-1-propanol (MEA/AMP) with nanoparticles of aluminium oxide (Al₂O₃) as a solvent used to remove carbon dioxide (CO₂) from simulated flue gas. Furthermore, the application of the Taguchi experiment design method determined the optimal conditions for the absorption process. This research focuses on the CO₂ absorption process and the optimal conditions related to nanoparticle addition. The main effects of using nanofluid were investigated. The concentration of nanoparticles, nanoparticle size, and stirrer speeds were …

Synthesis, Characterization, And Antibacterial Activity Of Graphene Oxide/Zinc Hydroxide Nanocomposites, Jo Ann Sanchez, Luis A. Materon, Jason Parsons, Mataz Alcoutlabi

Mechanical Engineering Faculty Publications

Graphene and graphene oxide have shown good antibacterial activity against different bacterial species due to their unique physicochemical properties. Graphene oxide (GO) has been widely used to load metallic and metal oxide nanoparticles (NPs) to minimize their surface energy during processing and preparation, hence reducing their aggregation. In this work, GO was effectively synthesized and coated with different concentrations of zinc hydroxide Zn (OH)x using the precipitation method to prepare a GO/Zn (OH)x hybrid composite. The Zn (OH)x NPs and GO/Zn (OH)x nanocomposites were synthesized and characterized using various methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and …

Emulsion Liquid Membrane (Elm) Enhanced By Nanoparticles And Ionic Liquid For Extracting Vanadium Ions From Wastewater, Qusay Al-Obaidi, Nora Yehia Selem, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Emulsion liquid membrane (ELM) stands out as an extraction process that has drawn much attention due to its promising prospects in industrial wastewater treatment technology. Nevertheless, the pivotal challenge is to reach high membrane stability to overcome the obstacle of applying ELM at the industrial scale. In this study, ELM was boosted by using nanoparticles (superparamagnetic iron oxide (Fe₂O₃)) in the stripping phase (W1) and ionic liquid (1-methyl-3-octyl-imidazolium-hexafluorophosphate [OMIM][PF6) in the oil phase (O) for recovering/extracting vanadium from synthetic wastewater to near completion and at the same time enhancing emulsion stability to be appropriate for industrial …

Emergent Magnetism And Hyperthermia In Phase- And Size-Tunable Iron Oxide Nanostructures, K Mudiyanselage Tharindu Supun Bandara Attanayake

USF Tampa Graduate Theses and Dissertations

Iron oxide nanoparticles (IONPs) hold immense potential across diverse fields, from spintronics, magnetic hyperthermia to drug delivery, biodetection, and magnetic resonance imaging. Unlocking these applications hinges on our ability to tailor the magnetic properties of IONPs, and this dissertation presents novel and powerful approaches for enhancing magnetic and hyperthermic responses of multiphase iron oxide nanostructures. This is achieved by manipulating their phase volume fraction, size, and shape with a focus on the magnetic tunability of nanostructures via strategic control over structural and environmental parameters. The aforementioned has been achieved by the following three key approaches: (i) phase-tunability of iron oxide …

Targeted Drug Delivery: Investigating Protein Corona Behavior, Atharva Markale

Theses

Due to high specificity and less toxicity, nanoparticles have become promising for targeted drug delivery against cancer, although they face challenges when they enter the bloodstream, making their behavior unpredictable. The deposition of proteins on nanoparticles, the protein corona, changes their biosignature, affecting their circulation, drug release potency, targeting ability, and immunogenicity. The continuous exchange of protein layers on a nanoscale is complex to analyze.

Nanoparticle tracking analysis (NTA) is a method to characterize nanoparticles in blood plasma by combining principles of light scattering microscopy and Brownian motion. In this work, time-dependent experiments with plasma were conducted to analyze the …

Combustion-Induced Endothermic Process In Carbon Dots Synthesized On Magnetite Nanoparticle Substrate, Khalid Zouhri, Luke J. Snyder, Michael Mcfarland, Parker O. Laubie, K. A. Shiral Fernando, Christopher E. Bunker

Civil and Environmental Engineering Faculty Publications

Carbon dots are synthesized alone and in the presence of commercial magnetite nanoparticles using a simple hydrothermal reaction. The spectroscopic and structural characteristics of CDot and CDot–magnetite materials are presented and their behaviors under combustion conditions are studied. A careful examination of their combustion behaviors reveals interesting results for the CDot–magnetite material: it undergoes early catalytic combustion at ~200°C and a strong endothermic process that quenches combustion. By investigating the physical mixtures of pre-formed CDots and magnetite and the starting material ascorbic acid and magnetite, it is determined that the strong endothermic behavior requires intimate interactions between the carbon source …

Stimuli-Responsive Glycopolymeric Nanoparticles To Boost Tumor Immunogenicity Through Macrophage-Targeted Therapy, Oluwaseyi Shofolawe-Bakare

Electronic Theses and Dissertations

Tumor-associated macrophages (TAMs) play a substantial role in sculpting the tumor microenvironment (TME) into an immunosuppressive bastion that undermines immune surveillance and enables tumor progression. They therefore represent a promising therapeutic target to make the TME more conducive for anti-tumor immunity and greatly improve treatment outcomes in cancers that are highly resistant to conventional forms of therapy. Several medications have been developed to modulate the activities of TAMs, showing tremendous potential, but these medications lack specificity for TAMs making their use susceptible to adverse side effects that could outweigh prospective benefits. Sophisticated delivery vehicles that can preferentially deliver these medications …

Chiroptical Second-Harmonic Tyndall Scattering From Silicon Nanohelices, Ben J. Olohan, Emilija Petronijevic, Ufuk Kilic, Shawn Wimer, Matthew Hilfiker, Mathias Schubert, Christos Argyropoulos, Eva Schubert, Samuel R. Clowes, G. Dan Pantoş, David L. Andrews, Ventsislav K. Valev

Department of Electrical and Computer Engineering: Faculty Publications

Chirality is omnipresent in the living world. As biomimetic nanotechnology and self-assembly advance, they too need chirality. Accordingly, there is a pressing need to develop general methods to characterize chiral building blocks at the nanoscale in liquids such as water-the medium of life. Here, we demonstrate the chiroptical second-harmonic Tyndall scattering effect. The effect was observed in Si nanohelices, an example of a high-refractive-index dielectric nanomaterial. For three wavelengths of illumination, we observe a clear difference in the second-harmonic scattered light that depends on the chirality of the nanohelices and the handedness of circularly polarized light. Importantly, we provide a …

Crystalline Colloidal Arrays: Exploring Light-Matter Interactions, Haley W. Jones

All Dissertations

Understanding and manipulating quantum light-matter interactions, especially in the context of nanostructured environments, is highly critical for technological progress and inventive solutions in the fields of telecommunications, energy-efficient lighting, and cutting-edge quantum computing technologies. The fundamental interactions of photons with a surrounding environment directly impact the performance and efficiency of devices such as lasers, light-emitting diodes (LEDs), and quantum computing elements, which leverage the unique properties of confined structured environments. Since the late 1980s, the connection between a structured environment and the decay kinetics of an embedded fluorophore has been a highly debated and unresolved topic in the literature. More …

Effect Of Patient Specific Blood Biomarkers On Nanoparticle - Cell Interactions, Veronica Gabriela Contreras

Open Access Theses & Dissertations

Nanoparticles are currently known to be a promising material class for bio-applications in drug delivery and vaccine development. Using gold nanoparticles of varied sizes, in this case 45 and 100 nanometers as a model nanomaterial system, we investigated how patients' blood physiology and chemistry (such as solute, protein, lipid levels) affect the biological response to bionanomaterials. When nanoparticles are injected into the body, biomolecules in the blood adsorb to the nanoparticle's surface to form a biomolecular corona that is specific to the patient's unique blood composition. This biomolecular corona is important because it affects the in vivo fate and biodistribution …

Earth Abundant Catalyst For Evironmental Sustainability Applications, Javier Hernandez

Open Access Theses & Dissertations

The development of experimental methodologies for synthesizing a diverse range of metallic and metal oxide nanoparticles tailored for sustainable water treatment applications was investigated. These nanoparticles are prepared using environmentally friendly and scalable synthesis methods, underscoring their potential for large-scale production. Synthesized nanoparticles are harnessed for various processes, including catalysis and electrocatalysis, with a primary objective of degrading and removing organic pollutants from water. Key to this research is the encapsulation of nanoparticles within solid supports. Multiple methodologies are explored to engineer supports that ensure nanoparticle stabilization, monodispersion, and prevent unintended release into the environment. Two alternative approaches were evaluated …

Enhanced Carbohydrate-Based Plastic Performance By Incorporating Cerium-Based Metal-Organic Framework For Food Packaging Application, Shima Jafarzadeh, Mitra Golgoli, Maryam Azizi-Lalabadi, Javad Farahbakhsh, Mehrdad Forough, Navid Rabiee, Masoumeh Zargar

Research outputs 2022 to 2026

The development of biodegradable active packaging films with hydrophobic characteristics is vital for extending the shelf life of food and reducing the reliance on petroleum-based plastics. In this study, novel hydrophobic cerium-based metal-organic framework (Ce-MOF) nanoparticles were successfully synthesized. The Ce-MOF nanoparticles were then incorporated into the cassava starch matrix at varying concentrations (0.5 %, 1.5 %, 3 %, and 4 % w/w of total solid) to fabricate cassava-based active packaging films via the solution casting technique. The influence of Ce-MOF on the morphology, thermal attributes, and physicochemical properties of the cassava film was subsequently determined through further analyses. Biomedical …

Development Of Quantitative Structure Activity Relationships (Qsars) For Predicting The Aggregation Of Tio2 Nanoparticles Under Favorable Conditions, Jaewoong Lee

Department of Civil and Environmental Engineering: Faculty Publications

This study developed multi-linear regression (MLR) quantitative structure-activity relationships (QSARs) to predict n-TiO₂ aggregation in the presence of high concentrations of representative emerging organic contaminants (EOCs), which presented favorable conditions to interaction with n-TiO₂. The largest diameter change (Δ 517 nm at 0 h and Δ 1164 nm at 12 h) of n-TiO₂ was observed by estrone, while the smallest diameter change (Δ -114 nm at 0 h and – 4 nm at 12 h) was observed by lincomycin during experimental periods. In addition, the zeta potential changes of n-TiO₂ were …

Dynamics Of Nanocluster Aerosol In The Indoor Atmosphere During Gas Cooking, Satya S. Patra, Jinglin Jiang, Xiaosu Ding, Chunxu Huang, Emily K. Reidy, Vinay Kumar, Paige Price, Connor Keech, Gerhard Steiner, Philip Stevens, Nusrat Jung, Brandon E. Boor

Purdue University Libraries Open Access Publishing Fund

Nanocluster aerosol (NCA: particles in the size range of 1–3 nm) are a critically important, yet understudied, class of atmospheric aerosol particles. NCA efficiently deposit in the human respiratory system and can translocate to vital organs. Due to their high surface area-to-mass ratios, NCA are associated with a heightened propensity for bioactivity and toxicity. Despite the human health relevance of NCA, little is known regarding the prevalence of NCA in indoor environments where people spend the majority of their time. In this study, we quantify the formation and transformation of indoor atmospheric NCA down to 1 nm via high-resolution online …

Tribological Properties Of H-Bn, Ag And Mgo Nanostructures As Lubricant Additives In Vegetable Oils, Victoria Granja, Kollol Sarker Jogesh, Jaime Taha-Tijerina, C. Fred Higgs Iii

Informatics and Engineering Systems Faculty Publications

There exists an ever-growing need for sustainable engineering solutions to improve emission control and the energy efficiency of tribosystems. This study examines the tribological properties of two environmentally friendly vegetable fluids, soybean and sunflower oil, with the addition of three non-toxic nanostructures (h-BN, silver and MgO) at different concentrations. It was found that nanostructures added to vegetable oils at specific concentrations can exhibit good friction reduction and wear preventive properties. The addition of h-BN nanosheets in sunflower oil decreased the coefficient of friction and the wear damage, as measured by the wear scar diameter. Silver and magnesium oxide nanoparticles further …