Engineering Commons^™

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part I, Leonid A. Ivanov, Li Da Xu, Elena Bokova, Aleksandr D. Ishkov, Svetlana Muminova

Information Technology & Decision Sciences Faculty Publications

The article provides an abstract review of patents. The results of creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials, being implemented, allow achieving a significant effect in construction, housing and community services, and related sectors of the economy. For example, the invention (A method to produce graphene-containing suspensions by means of graphite exfoliation and a device to perform it) refers to chemical and construction industries and can be used in modification of plastic lubricant, epoxy resins and concretes. The technical task of the invention is to increase efficiency of graphite exfoliation, to …

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part Ii, Leonid A. Ivanov, Li Da Xu, Zhanna V. Pisarenko, Qiang Wang, Petr S. Prokopiev

Information Technology & Decision Sciences Faculty Publications

The article provides an abstract review of patents. The results of creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials, being implemented, allow achieving a significant effect in construction, housing and community services, and related sectors of the economy. For example, the invention «Method for liquidphase synthesis of nanostructured ceramic material in the CeO2–Sm2O3 system to create a solid oxide fuel cell» can contribute to the active development of alternative, hydrogen energy. Fuel cells have a wide range of applications – from batteries in portable electronic devices to large-scale power generation and autonomous …

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part Vi, Leonid A. Ivanov, Li D. Xu, Konstantin E. Razumeev, Zhanna V. Pisarenko, Aleksey V. Demenev

Information Technology & Decision Sciences Faculty Publications

Introduction. Advanced technologies impress people's imagination demonstrating the latest achievements (materials, methods, systems, technologies, devices etc.) that dramatically change the world. This, first of all, concerns nanotechnological inventions designed by scientists, engineers and specialists from different countries. Main part. The article provides an abstract overview of inventions of scientists, engineers and specialists from different countries: Russia, USA, China, Kazakhstan, Sweden. The results of the creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials allow, when introduced to industry, achieving a significant effect in construction, housing and communal services, and related sectors of the …

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part Iii, L. A. Ivanov, L. D. Xu, E. S. Bokova, A. V. Demenev, V. A. Ivanov

Information Technology & Decision Sciences Faculty Publications

Introduction. Advanced technologies impress people’s imagination demonstrating the latest achievements (materials, methods, systems, technologies, devices etc.) that dramatically change the world. This, first of all, concerns nanotechnological inventions designed by scientists, engineers and specialists from different countries.

Main part. The article provides an abstract review of patents. The results of creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials, being implemented, allow achieving a significant effect in construction, housing and community services, and related sectors of the economy. For example, the invention «Composite material with oriented carbon nanotubes» refers to the area of …

Enhancing Emulsion Liquid Membrane System (Elm) Stability And Performance For The Extraction Of Phenol From Wastewater Using Various Nanoparticles, Faris H. Al-Ani, Qusay F. Alsalhy, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Emulation liquid membrane (ELM) technology has recently garnered attention as an efficient alternative for separating pollutants, but it faces the problem of instability during the application, as well as emulsion breaking. With this in mind MgO, Al₂O₃, and three magnetic Fe₂O₃ nanoparticles (of different sizes) were utilized to fabricate a new Pickering ELM system (PELM). The extraction efficiency of phenol from aqueous solution by PELM was studied with different NPs types and with different phenol concentrations (1,000; 500; 100; and 50 ppm). It was found that the type of NPs and concentration of …

Cold Plasma Enhanced Active Sites On Supported Nip Nanoparticles For The Oxygen Evolution Reaction, Michael Ricci

Williams Honors College, Honors Research Projects

Identifying materials to efficiently facilitate the oxygen evolution reaction (OER) is key to advancing water electrolysis, an essential technology in the pathway towards a sustainable energy future. Here, we explore cold-plasma treatment as a facile method to enhance the activity of NiP nanoparticles supported on activated carbon. NiP nanoparticles were synthesized on an activated carbon support using a solid-state method and were then treated with argon, oxygen, and hydrogen plasmas for extended times. In all cases, plasma treatment reduced the number of active sites on the support. OER activity was evaluated by testing the materials in alkaline conditions. The activities …

Aqueous Fabrication Of Pristine And Oxide Coated Znse Nanoparticles, Nicholas L. Van Zandt

Browse all Theses and Dissertations

Semiconducting nanoparticles have received significant attention due to their unique optoelectronic properties. Quantum dots (QDs), a class of spherical nanoparticles, possess a size-dependent bandgap and photoluminescence at visible wavelengths. QDs have many applications including biological labelling, solar cells, chemical impurity detection, and optical glasses. Doping QDs into optical glasses is highly desirable. High-quality QDs can be synthesized via liquid solution methods. However, solution-synthesized QDs often degrade over time and they cannot survive incorporation into a glass melt without protection. In this work, the aqueous synthesis of ZnSe QDs and coating with nanometer silica and alumina protective shells are investigated. The …

Detection Of 2,4,6-Trinitrotoluene Using A Colorimetric Gold Nanoparticle Air Cassette Filter, Andrea I. Ferrer Vega

Master of Science in Forensic Science Directed Research Projects

Trinitrotoluene (TNT) is an explosive commonly used during military and terrorist activities. Current methods to identify this compound require sampling, transport and analysis at a forensic lab using analytical instrumentation. However, on-site detection is needed to assist efforts to prevent detonation. Gold nanoparticles have been used as sensors throughout the years due to their versatility and surface enhanced Raman scattering properties in the presence of an analyte and low limits of detection. By taking advantage of the Meisenheimer complex that TNT forms in the presence of amines, it is possible to determine its presence at picogram levels. Subsequently, adhering amine …

A Review Of Enhancement Of Biohydrogen Productions By Chemical Addition Using A Supervised Machine Learning Method, Yiyang Liu, Jinze Liu, Hongzhen He, Shanru Yang, Yixiao Wang, Jin Hu, Huan Jin, Tianxiang Cui, Gang Yang, Yong Sun

Research outputs 2014 to 2021

In this work, the impact of chemical additions, especially nano‐particles (NPs), was quan-titatively analyzed using our constructed artificial neural networks (ANNs)‐response surface methodology (RSM) algorithm. Fe‐based and Ni‐based NPs and ions, including Mg2+, Cu2+, Na+, NH4+, and K+, behave differently towards the response of hydrogen yield (HY) and hydrogen evolution rate (HER). Manipulating the size and concentration of NPs was found to be effective in enhancing the HY for Fe‐based NPs and ions, but not for Ni‐based NPs and ions. An optimal range of particle size (86–120 nm) and Ni‐ion/NP concentration (81–120 mg L−1) existed for HER. Meanwhile, the manipulation …

Nanoscale Material Interaction With Multicellular 3d Cancer Culture, Emilie Darrigues

Theses and Dissertations

Pancreatic ductal adenocarcinoma (PDAC) is the most common form of pancreatic cancer, it is difficult to diagnose, often recurs, has high resistance to chemotherapies, and can be marked by advanced metastatic stages. There is an urgent need to fill the knowledge on nanoparticle penetration, diffusion, and cellular interaction in the context of adaptive PDAC tumor microenvironment to allow the development of new imaging and therapeutic supports. Traditionally, cancer-treating nanoparticles have been engineered and tested on 2D cell cultures, but several studies indicate that this in vitro model does not mimic tumor features closely enough. In contrast, 3D culture models offer …

The Varied Thermal Response Of Magnetic Iron-Oxide Nanoparticles During Induction Heating In Liquid And Solid-Liquid Phase Change Mediums, Joshua Tompkins

Graduate Theses and Dissertations

This study investigates the induction heating response of uncapped iron oxide nanoparticles sonically dispersed as a nanofluid and mechanically distributed in solid phase change materials. The nanoparticles examined have a mean diameter of 14.42 nm and are magnetically heated in an alternating magnetic field at an amplitude of 72.6 kA/m at frequencies of 217, 303, and 397 kHz. Nanoparticle characterization was undertaken through transition electron microscopy, x-ray diffraction, and dynamic light scattering when in suspension. Carrier fluids were characterized through viscosity, heat capacity, and density measurements which were used in the calorimetric calculation of the specific absorption rate (SAR) of …

Direct Solar Absorption Nanoparticle Doped Membranes For A Hybrid Membrane Distillation And Photovoltaic Cell, Alejandro Espejo Sanchez

Boise State University Theses and Dissertations

The growing demand for clean water supplies is driving the need for an innovative approach of water desalination. Developing a method for treating water with high salinities is possible with membrane distillation (MD). Additionally, MD is very attractive for pairing with solar energy due to the low temperature requirements. The integration of a membrane distillation system with a photovoltaic (PV) system will result in the co-production of electricity and clean water, thereby improving the economics of MD. Such a hybrid system will directly absorb thermal energy in the membrane for desalination while taking advantage of the spectrally selective nature of …

Data Analysis To Evaluate The Performance Of Breathing Masks Used For Filtering Nano-Level Particles At Manufacturing Sites, Gracia M. Dardano

Honors College Theses

The work performed in this research aims to evaluate the performance of commercially available breathing masks in filtering airborne nanoparticles at manufacturing sites. Nanoparticles are found virtually anywhere, from dust in a worksite to a simple sneeze. Therefore, they pose a substantial threat to human health as their velocity and volatility are high. This research analyzes if current efforts of breathing masks to hinder nanoparticles are effective, especially at manufacturing sites. Data has been collected in order to analyze the behavior of nanoparticles and to measure nanoparticle levels at manufacturing sites and its working environment. Data is statistical in nature …

Erosive Wear Properties Of Za-27 Alloy-Based Nanocomposites: Influence Of Type, Amount, And Size Of Nanoparticle Reinforcements, Aleksandar Vencl, Ilija Bobić, Biljana Bobić, Kristina Jakimovska, Petr Svoboda, Mara Kandeva

Friction

Metal matrix nanocomposites (MMnCs) comprise a metal matrix filled with nanosized reinforcements with physical and mechanical properties that are very different from those of the matrix. In ZA-27 alloy-based nanocomposites, the metal matrix provides ductility and toughness, while usually used ceramic reinforcements give high strength and hardness. Tested ZA-27 alloy-based nanocomposites, reinforced with different types (SiC and Al2O3), amounts (0.2 wt.%, 0.3 wt.%, and 0.5 wt.%) and sizes (25 nm, 50 nm, and 100 nm) of nanoparticles were produced through the compocasting process with mechanical alloying pre-processing (ball milling). It was previously shown that the presence of nanoparticles in ZA-27 …

Metal-Containing Nanomaterials As Lubricant Additives: State-Of-The-Art And Future Development, Igor E. Uflyand, Vladimir A. Zhinzhilo, Victoria E. Burlakova

Friction

This review focuses on the effect of metal-containing nanomaterials on tribological performance in oil lubrication. The basic data on nanolubricants based on nanoparticles of metals, metal oxides, metal sulfides, nanocomposities, and rare-earth compounds are generalized. The influence of nanoparticle size, morphology, surface functionalization, and concentration on friction and wear is analyzed. The lubrication mechanisms of nanolubricants are discussed. The problems and prospects for the development of metal-containing nanomaterials as lubricant additives are considered. The bibliography includes articles published during the last five years.

Point-Of-Care Devices For Therapeutic, Medical And Environmental Applications, Alisha Prasad

LSU Doctoral Dissertations

Point-of-care testing (POCT) or Point-of-use (POU) devices or technologies are defined as testing aids that are capable for onsite use or testing. The key advantages of POCT are low sample volume, quick onsite diagnosis, high accuracy, and cost-effectiveness. POCT has the potential and the benefits to facilitate better health care management by rapid routine diagnosis and monitoring. To reach this goal, several researchers as well as the healthcare industry over a few years have conducted cutting edge research to bring science to technology by developing smart diagnostic devices capable of performing as per patient profiles and make personalized health care …

Effect Of Nanofiller Coating And Loading On Facial Elastomer Physical Properties, Rahmi K. Aulia

Theses & Dissertations

Current materials used for facial prostheses are far from being desirable, and improved properties with “skin-like” feel are needed. This study evaluates property changes induced by sequential additions of uncoated and hydrophobic-coated nano-SiO₂ to polydimethylsiloxane (PDMS) and compares them with those measured for conventional submicron SiO₂-filled materials. Each filler type was sequentially added to vinyl-terminated PDMS at 0%, 0.5%, 5%, 10%, and 15% by weight. Tensile, tear, Durometer hardness, translucency and viscoelastic properties were evaluated, with hardness and translucency also evaluated following 3000 hours of outdoor weathering. Results demonstrated that 15% coated nano-SiO₂-filled PDMS materials …

Nanoceria Distribution And Effects Are Mouse-Strain Dependent, Robert A. Yokel, Michael T. Tseng, D. Allan Butterfield, Matthew L. Hancock, Eric A. Grulke, Jason M. Unrine, Arnold J. Stromberg, Alan K. Dozier, Uschi M. Graham

Pharmaceutical Sciences Faculty Publications

Prior studies showed nanoparticle clearance was different in C57BL/6 versus BALB/c mice, strains prone to Th1 and Th2 immune responses, respectively. Objective: Assess nanoceria (cerium oxide, CeO₂ nanoparticle) uptake time course and organ distribution, cellular and oxidative stress, and bioprocessing as a function of mouse strain. Methods: C57BL/6 and BALB/c female mice were i.p. injected with 10 mg/kg nanoceria or vehicle and terminated 0.5 to 24 h later. Organs were collected for cerium analysis; light and electron microscopy with elemental mapping; and protein carbonyl, IL-1β, and caspase-1 determination. Results: Peripheral organ cerium significantly increased, generally more …

Synthesis And Characterization Of Bimetallic Gold-Silver (Au-Ag) Nanocatalyst Via Seed Colloid Technique, Berahim Nurafaliana

Student Works (2020-2029)

In the present study, unique catalysts of monometallic gold (Au), silver (Ag) and bimetallic gold-silver (Au-Ag) nanoparticles (NPs) were prepared with different size or diameters by the citrate-thermal reduction and the seed colloidal techniques, respectively. The catalytic nanoparticles were characterized by various advanced analytical techniques such as Ultraviolet-visible spectroscopy (UV-vis), zeta potential, electron dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), High-angle annular dark-field (HAADF) scanning transmission-electron microscopy (STEM) imaging and the energy dispersive spectroscopy (EDS) elemental mapping. The catalytic performance of the nanoparticles were ascertained through the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in …

Enhanced Water Electrolysis: Effect Of Temperature On The Oxygen Evolution Reaction At Cobalt Oxide Nanoparticles Modified Glassy Carbon Electrodes, Aya Akl, Hany A. Elazab, Mohamed A. Sadek, Mohamed S. El-Deab

Chemical Engineering

Water splitting producing hydrogen and oxygen gases appears promising in view of the increasing need of renewable energy sources and storage strategies. Investigation of stable and highly efficient electrocatalysts for oxygen evolution reaction (OER) is targeted in this study at cobalt oxide nanoparticle modified glassy carbon (nano-CoOx/GC) electrodes. The effect of the preparation (Tp) and measuring temperature (Tm) on the electrocatalytic activity of nano-CoOx/GC towards the OER is investigated under various operating conditions. Linear sweep voltammetry (LSV), cyclic voltammetry (CV) as well as SEM and XRD techniques were used to probe the electrocatalytic and morphological characteristics of nano-CoOx prepared under …

Nanohybrid Membrane Synthesis With Phosphorene Nanoparticles: A Study Of The Addition, Stability And Toxicity, Joyner Eke, Philip Alexander Mills, Jacob Ryan Page, Garrison P. Wright, Olga V. Tsyusko, Isabel C. Escobar

Center of Membrane Sciences Faculty Publications

Phosphorene is a promising candidate as a membrane material additive because of its inherent photocatalytic properties and electrical conductance which can help reduce fouling and improve membrane properties. The main objective of this study was to characterize structural and morphologic changes arising from the addition of phosphorene to polymeric membranes. Here, phosphorene was physically incorporated into a blend of polysulfone (PSf) and sulfonated poly ether ether ketone (SPEEK) doping solution. Protein and dye rejection studies were carried out to determine the permeability and selectivity of the membranes. Since loss of material additives during filtration processes is a challenge, the stability …

Synthesis, Self-Assembly And High-Pressure Properties Of Nanoparticles And Hybrid Nanocomposites, Lingyao Meng

Nanoscience and Microsystems ETDs

Nanoparticles have gained significant scientific interests owing to their unique structural dimensions, size- and shape-tunable properties, and numerous fascinating applications, from opto-electronics, sensor devices, to energy, environmental, and medical fields. Furthermore, the synergistic integration of other materials, including organic polymers, with nanoparticles provides new opportunities and strategies to obtain nanocomposites with superior properties and functionalities. While there is already significant research on the synthesis and characterizations of nanoparticles and hybrid nanocomposites, some research questions, such as how to design and control the interfacial morphology in polymer/nanoparticle hybrid nanocomposites, how to synthesize metal- organic framework (MOF) nanoparticles in well-defined and uniform …

Enhanced Water Electrolysis: Effect Of Temperature On The Oxygen Evolution Reaction At Cobalt Oxide Nanoparticles Modified Glassy Carbon Electrodes, Aya Akl, Hany A. Elazab, Mohamed A. Sadek, Mohamed S. El-Deab

Chemical Engineering

Water splitting producing hydrogen and oxygen gases appears promising in view of the increasing need of renewable energy sources and storage strategies. Investigation of stable and highly efficient electrocatalysts for oxygen evolution reaction (OER) is targeted in this study at cobalt oxide nanoparticle modified glassy carbon (nano-CoOx/GC) electrodes. The effect of the preparation (Tp) and measuring temperature (Tm) on the electrocatalytic activity of nano-CoOx/GC towards the OER is investigated under various operating conditions. Linear sweep voltammetry (LSV), cyclic voltammetry (CV) as well as SEM and XRD techniques were used to probe the electrocatalytic and morphological characteristics of nano-CoOx prepared under …

Bijels Made By Solvent Transfer Induced Phase Separation: Formation Principles And Transport, Stephen Boakye-Ansah

Theses and Dissertations

Bijels are made of non-equilibrium particle-stabilized emulsions with a bicontinuous arrangement of the constituent fluid phases. They spontaneously form through arrested spinodal decomposition in mixtures of partially miscible liquids and neutrally wetting colloidal particles. Soon after their discovery over 10 years ago, Prof. Mike Cates, Lucasian Professor of Mathematics, predicted their future use as continuously operated cross-flow reactors for chemical reactions between immiscible reactants.

Towards this goal, work in this thesis focuses on designing bijels via Solvent Transfer Induced Phase Separation (STrIPS) for microfluidic transport applications. Structure-function relationships of STrIPS bijels stabilized by silane functionalized nanoparticles are developed. In-situ surfactant …

Hyaluronic Acid Coated Targeted Lipid Micellar Nanoparticle As A Delivery Vehicle For Lapatinib And Ketoconazole In Egfr Mutated Lung Cancer, Nadia Tasnim Ahmed

USF Tampa Graduate Theses and Dissertations

Background: According to the American Cancer Society, lung cancer was accountable for over 142,000 deaths in the USA in 2019. Common mutations related to lung cancer mainly occur in TP53, EGFR, and KRAS genes. Lapatinib is a small molecule tyrosine kinase inhibitor which acts reversibly on both epidermal growth factor receptor (EGFR) and human epidermal growth factor receptor 2 (HER2). Overexpression of EGFR leads to increased production and signaling of proteins that cause upregulation of cellular proliferation, cholesterol synthesis and resistance to apoptosis. Ketoconazole is an imidazole antifungal agent which works principally by inhibiting the enzyme cytochrome P450 14α-demethylase (CYP51A1) …

In Vivo Biosynthesis Of Inorganic Nanomaterials Using Eukaryotes - A Review, Ashiqur Rahman, Julia Lin, Francisco E. Jaramillo, Dennis A. Bazylinski, Clayton Jeffryes, Si Amar Dahoumane

Life Sciences Faculty Research

Bionanotechnology, the use of biological resources to produce novel, valuable nanomaterials, has witnessed tremendous developments over the past two decades. This eco-friendly and sustainable approach enables the synthesis of numerous, diverse types of useful nanomaterials for many medical, commercial, and scientific applications. Countless reviews describing the biosynthesis of nanomaterials have been published. However, to the best of our knowledge, no review has been exclusively focused on the in vivo biosynthesis of inorganic nanomaterials. Therefore, the present review is dedicated to filling this gap by describing the many different facets of the in vivo biosynthesis of nanoparticles (NPs) using living eukaryotic …

Cancer Biomarker Detection In Human Plasma By Integrating Surface Acoustic Wave And Metal-Enhanced Fluorescence, Yuqi Huang

USF Tampa Graduate Theses and Dissertations

This thesis includes data and discussion about the technique of metal-enhanced fluorescence (MEF) to lower the detection limit of carcinoembryonic antigen (CEA). The detection limit goes down to 100pg/mL level when using MEF substrate made by rapid thermally annealed silver film covered by silica, which has great promise in diagnosing certain types of cancer that uses CEA as detection biomarker, such as pancreatic cancer and colon cancer. To further address the issue of background noises from non-specifically bound proteins (NSB) in complex media, such as plasma, serum, urine and blood, MEF is integrated with surface acoustic wave (SAW) streaming in …

Water Purification Device And A Method Of Decontaminating A Water Supply, Dibakar Bhattacharyya, Li Xiao

Chemical and Materials Engineering Faculty Patents

A water purification device is provided in the form of a hydrogel matrix containing immobilized nanoparticles that are directly synthesized in-situ in the hydrogel matrix. The hydrogel matrix is temperature sensitive, such that swelling draws in pollutants that are captured by the nanoparticles, while deswelling releases purified water. A related method of decontaminating the water supply contaminated with a target pollutant is also disclosed.

Geometric Optimization Of Plasmonic Nanostructure Arrays On Mwir Hgcdte (Mct), Nagendrababu Vanamala, Kevin C. Santiago, Naresh C. Das, Samuel Keith Hargrove

Mechanical and Manufacturing Engineering Faculty Research

Mercury Cadmium Telluride (MCT) is a primary absorber material used in most infrared (IR) detection technologies. Our previous studies show that the optical absorbance profile of MCT in the mid-infrared region can be enhanced by 13% under ambient conditions via integrating periodic Indium Tin Oxide (ITO) nanostructures. Here, we focus on the geometrical parameterization and optimization of ITO nanostructure arrays. We simulate several types of geometries, their corresponding effective absorption profiles, E-field distribution, and optimal geometric parameters. This work may lead to improved light collection and absorption edge engineering, as MCT continues to be the material of choice in IR …

Investigation Of New Forward Osmosis Draw Agents And Prioritization Of Recent Developments Of Draw Agents Using Multi-Criteria Decision Analysis, Jodie Wei Yu

Master's Theses

Forward osmosis (FO) is an emerging technology for water treatment due to their ability to draw freshwater using an osmotic pressure gradient across a semi-permeable membrane. However, the lack of draw agents that could both produce reasonable flux and be separated from the draw solution at a low cost stand in the way of widespread implementation. This study had two objectives: evaluate the performance of three materials — peptone, carboxymethyl cellulose (CMC), and magnetite nanoparticles (Fe₃O₄ NPs) — as potential draw agents, and to use multi-criteria decision matrices to systematically prioritize known draw agents from literature for …