Engineering Commons^™

Engineering Multifunctional Silicon Nanostructures From Biorenewable Cellulose Nanocrystals, Nancy Chen

All Dissertations

The imperative search for alternative materials to address the pressing demand for advance energy storage is underscored by the escalating environmental predicaments. Lithium-ion batteries (LIBs) with graphite anodes have become the benchmark in energy storage; however, they are approaching a saturation point in terms of energy density. Silicon emerges as a promising contender to supplant graphite, owing to its profuse availability, cost-effectiveness, and impressive specific capacity of 4200 mAh g^-1. By integrating silicon anodes, LIBs stand to undergo a radical transformation, markedly diminishing in weight and size, thus heralding a novel wave of compact, lightweight energy storage systems. …

Application Of Artificial Intelligence To Lithium-Ion Battery Research And Development, Zhen-Wei Zhu, Jing-Yi Qiu, Li Wang, Gao-Ping Cao, Xiang-Ming He, Jing Wang, Hao Zhang

Journal of Electrochemistry

Lithium-ion batteries (LIBs) have become one of the best solutions to the energy storage issue in modern society. However, the battery materials and device development are both complex, and involve multivariable problems. Traditional trial-and-error approach, which relies on researchers to conduct experiments, has encountered bottlenecks in the improvement of the battery performance. Artificial intelligence (AI) is the most potential technology to deal with this issue due to its powerful high-speed and capabilities of processing massive data. In particular, the capability of machine learning (ML) algorithms in assessing multidimensional data variables and discovering patterns in the sets are expected to assist …

Comparison Of Layered Nickel Cobalt Manganese Oxide Cathodes With Different Compositions And Morphologies In Lithium-Ion Batteries, Fanny Poon

Electronic Thesis and Dissertation Repository

The revolutionary rechargeable lithium-ion battery paves the way for environmentally-friendly applications such as electric vehicles. Nevertheless, further improvements are required to match or exceed the performance of conventional internal combustion engine vehicles, such as higher energy density, faster charging speed, longer lifetime, better safety and lower cost. Lithium layered nickel cobalt manganese oxides (NCM) are a popular choice of cathode material, but they still suffer from problems such as cation mixing, volume changes, microcracking, surface side reactions, high temperature performance issues and structural reconstruction. This thesis compares various NCM materials to figure out what guidelines should be followed to improve …

Carbon Footprint And Cost Minimization For Grid Systems Through Day-Ahead Order And Battery Size Optimization, Omid Pourkhalili

Doctoral Dissertations

We modeled the problem of peak hours day-ahead order for smart grid companies integrating renewable energy and power storage systems. This results in optimizing day-ahead order, battery storage size, and consequently lowering the use of fossil fuels and emissions. The utility-scale power storage can balance the difference between the day-ahead forecasts and real-time consumer demand through energy arbitrage and transmission deferral for peaking capacity. We define system parameters and their associated costs and run a suggested algorithm to minimize the grid operating cost by optimizing day-ahead order amount and battery storage capacity. The model is designed to prioritize and take …

Developing And Investigating A Fast And Controllable Prelithiation Method For Lithium-Ion Batteries, Huainan Qu

Theses and Dissertations

Prelithiation is to pre-load Li ions in a Li-ion electrode prior to a formation cycle. A chemical, roll-to-roll prelithiation method was developed in this thesis research. The method can be applied to different anode materials. The prelithiation compensated the initial loss of lithium during the formation cycles of a lithium-ion battery (LIB). Eventually, the initial coulombic efficiency (ICE) was significantly increased. In addition, the cyclability of a prelithiated battery was highly related to the quality of the solid electrolyte interface (SEI) on the anode surface. Electrochemical impedance spectroscopy (EIS) was a major technique to evaluate the difference of the SEI …

Alf3-Al2o3 Ald Thin-Film-Coated Li1.2mn0.54co0.13ni0.13o2 Particles For Lithium-Ion Batteries: Long-Term Protection, Han Yu, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Improving the performance of existing cathode materials of lithium-ion batteries (LIBs) through surface modification has been proven to be an effective way to improve the performance of LIBs. However, it is a challenge to use a traditional method to prepare an effective coating film, which meets the requirements of uniformity, continuity, electrochemical stability, and strong mechanical properties. In this study, an ultrathin AlF₃-Al₂O₃ film was coated on the surface of Li_1.2Mn_0.54Co_0.13Ni_0.13O₂ (LRNMC) particles by atomic layer deposition (ALD) in a fluidized bed reactor. A cathode electrolyte …

“Transport Batteryfication” Analysis Of Pre-Recycling Phases Of End-Of-Life Electric Vehicle Lithium-Ion Batteries From An Irish Perspective, Matt Mcguinness

Masters

Transport plays a key role in maintaining the economic prosperity of our society. However, transport has remained reliant on fossil fuels, a main contributor to climate change. New EU and Government policies aim to decarbonise the transport sector through batteryfication by shifting to electric vehicles. The lithium-ion battery will underpin this strategy.

Lithium-ion batteries have a limited lifespan for automotive applications, this will bring new and unprecedented challenges for end-of-life waste management. The recent growth of electric vehicles is expected to continue exponentially which raises important questions on how to process this new waste stream.

This study investigates the recycling …

Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang

Journal of Electrochemistry

Herein, the lithiated sulfonated graphene oxide (Li-SGO) was successfully prepared via three steps by sulfonation of graphene oxide with 3-merraptnpropylt rimethnxysilane, oxidation of thiol into sulfonate with hydrogen peroxide and lithiation of sulfonate with aqueous lithium hydroxide. The as-prepared Li-SGO was then introduced into the semi-interpenetrating networks of single ion conducting polymer electrolyte (Li-SGO-FPAS) and poly vinylidenefluoride-hexafluoro propylene (PVDF-HFP) binder by in-situ polymerization to fabricate the porous single ion conducting polymer electrolyte membrane (Li-SGO-po-FPAS) generated from the poor compatibility between aromatic Li-SGO-FPAS and aliphatic PVDF-HFP binder. The key properties such as morphology, porosity, solvent uptake, mechanical …

Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang

Journal of Electrochemistry

Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of …

Characterization And Upgrade Of Endocarp Biomass Derived Lignin To Value Added Products, Makua Vin-Nnajiofor

Theses and Dissertations--Biosystems and Agricultural Engineering

Lignin is an abundant biopolymer and a promising source of feedstock for high-value chemicals and energy materials, however, application methods of lignin into valuable products is yet to be fully explored. This study explores the valorization of lignin derived from lignin-rich endocarp biomass through the development of lignin-derived electrode materials. The chemical composition and cellular structure of the endocarps were characterized using HPLC and scanning electron microscopy (SEM) imaging. Mechanical properties of walnut and peach endocarps and preprocessing requirements were investigated using nanoindentation and specific energy consumption during grinding. Next, lignin was extracted from endocarps using deep eutectic solvent and …

Fundamentals Of Distribution Of Relaxation Times For Electrochemical Impedance Spectroscopy, Jia Wang, Qiu-An Huang, Wei-Heng Li, Juan Wang, Quan-Chao Zhuang, Jiu-Jun Zhang

Journal of Electrochemistry

Electrochemical impedance spectroscopy (EIS) is a powerful electrochemical characterization technology, which has been widely used in the field of electrochemical energy, such as lithium-ion batteries, supercapacitors, fuel cells, etc. Distribution of relaxation time (DRT) is an EIS deconvolution technique which does not depend on the prior knowledge of the targeted research object. Furthermore, DRT can serve to separate and analyze physical and chemical processes which are highly overlapped in their EIS data. In order to encourage the application and popularization of DRT deconvolution technology, several core questions are addressed in this paper: (1) DRT deconvolution principle, implementation steps and important …

A Review Of Electrochemical Energy Storage Researches In The Past 22 Years, Yu-Sheng Yang

Journal of Electrochemistry

In this paper, research activities from my groups in the field of electrochemical energy storage are reviewed for the past 22 years, which is divided into three sections. The first section describes the researches related to high specific energy and high specific power energy storage devices, including lithium sulfur batteriies (sulfur composite cathode material, lithium sulfur battery fabrication, lithium boron alloy as lithium sulfur battery anodes, and sulfur lithium-ion battery new system), supercapacitors (super activated carbon, capacitive carbon prepared from phenolic resin, carbon nanotube array parasitic pseudo-capacitive energy storage materials, necessary properties of capacitive carbons, nickel hydroxide xerogels pseudo-capacitive energy …

Weighted Online Estimation Of Soc Based On Adaptive Battery Model, Haohao Sun, Tinglong Pan, Dinghui Wu

Journal of System Simulation

Abstract: Aiming at the problem that the traditional lithium battery model has poor adaptive ability in SOC estimation and the local estimation accuracy of the single SOC estimation algorithm is low, online identification of model parameters with Multi-Innovation Stochastic Gradient algorithm and method of weighted online estimation of SOC was proposed. The results of lithium-ion battery model parameters online identification updated in real time, realizing lithium-ion battery model adaptive. Aiming at the estimation of SOC, a method of weighted online estimation method based on the PI (proportion and integral) regulator's OCV combined with Ah (an integral method) was proposed. Weights …

The Sounds Of Science - A Symphony For Many Instruments And Voices, Gerianne Alexander, Roland E. Allen, Anthony Atala, Warwick P. Bowen, Alan A. Coley, John B. Goodenough, Mikhail I. Katsnelson, Eugene V. Koonin, Mario Krenn, Lars S. Madsen, Martin Månsson, Nicolas P. Mauranyapin, Art I. Melvin, Ernst Rasel, Linda E. Reichl, Roman Yampolskiy, Philip B. Yasskin, Anton Zeilinger, Suzy Lidström

Faculty Scholarship

Sounds of Science is the first movement of a symphony for many (scientific) instruments and voices, united in celebration of the frontiers of science and intended for a general audience. John Goodenough, the maestro who transformed energy usage and technology through the invention of the lithium-ion battery, opens the programme, reflecting on the ultimate limits of battery technology. This applied theme continues through the subsequent pieces on energy-related topics - the sodium-ion battery and artificial fuels, by Martin Månsson - and the ultimate challenge for 3D printing, the eventual production of life, by Anthony Atala. A passage by Gerianne Alexander …

Lithium-Ion Battery And Beyond: Oxygen Vacancy Creation In Tungsten Trioxide And Surface Modification Of Lithium Metal, Rajesh Pathak

Electronic Theses and Dissertations

The graphite-based anode material has a low theoretical specific capacity of 371 mAh g-1. The transitional metal oxides (TMOs) are considered a better choice owing to their relatively higher specific capacity. Among TMOs, tungsten trioxide (WO3) is considered promising due to a higher specific capacity of 693 mAh g-1, low cost, mechanically stable, and eco-friendly. It has been a challenge to utilize the TMOs as anode materials as they suffer from poor electronic conductivity and large electrode volume expansion during discharge/charge cycles. In our first project, we demonstrate a unique self-recovery of capacity in reduced WO3 by the incorporation of …

Recent Progress In Vanadium-Based Electrode Materials, Meng-Lei Sun, Da-Qi Zhang, Jin-Kui Feng, Jiang-Feng Ni

Journal of Electrochemistry

It is an important solution to solve energy storage problems by developing inexpensive and safe lithium-ion and sodium-ion batteries with superior performance. Vanadium-based electrode materials are promising electrode materials because of diversified chemical valences, open structures and high theoretical capacities. In the past few years, vanadium-based electrode materials such as oxides, sulfides, and phosphates have achieved a considerable development in the battery field, It is, therefore, necessary to summarize their recent research progress. In this review, we particularly highlight the key challenges that are facing in the application of vanadium materials, such as low ion diffusion coefficient and poor structural …

Cvd Preparation And Application Of 3d Graphene In Electrochemical Energy Storage, Yong-Kang Xia, Ming-Yuan Gu, Hong-Guan Yang, Xin-Zhi Yu, Bing-An Lu

Journal of Electrochemistry

Three-dimensional (3D) graphene combinations with the excellent intrinsic properties of graphene and the 3D micro/nano porous structures provide a graphene foam with high specific surface area, excellent mechanical strength and fast electron and mass transports. The 3D graphene foam and its composite nanomaterials are widely used in the fields of nano-electronics, energy storage, chemical and biological sensing. The 3D graphene foam prepared by chemical vapor deposition (CVD) method is of high purity and crystallinity. In this review, a brief overview in the CVD preparations of 3D graphene and properties of CVD prepared 3D graphene based nanomaterials in electrochemical energy storage …

Optimal Operation Of Grid-Connected Microgrid Based On Abc Algorithm, Qiuli Cui

Journal of System Simulation

Abstract: An optimal scheduling model of grid-connected microgrid composed of wind power generators, photovoltaic cells, fuel cells and batteries is established. The economy and environmental protection elements are considered in this model. To maximize the role of peak shaving and valley filling in microgrid system, based on the time-of-use price mechanism, the heuristic rules combined with peak shaving and valley filling is used to design a grid-connected energy scheduling strategy. By monitoring the net load state and the price time interval, and adjusting the particular state of the micro source of power, the system optimal energy scheduling state is obtained. …

Approach For Lithium-Ion Battery Rul Prognostics Based On Cpso-Rvm, Chaolong Zhang, Yigang He, Lifen Yuan

Journal of System Simulation

Abstract: On account of the measured battery state of health (SOH) data are often subject to different levels of noise pollution, a battery remaining useful life (RUL) prognostics approach is presented based on wavelet denoising and CPSO-RVM in the paper. Wavelet denoising is performed twice with different thresholds in order to weaken the strong noise and remove the weak noise. Relevance vector machine (RVM) improved by chaos particle swarm optimization (CPSO) algorithm is utilized to estimate the trend of battery SOH variation trajectory and predict the battery RUL based on the denoised data. RUL prognostic experiments using battery data provided …

Soc Estimation With Extended Kalmanfilter Based On Fuzzy Control, Fang Lei, Chen Yong, Zhao Li, Kangsheng Yin, Zheng Yang

Journal of System Simulation

Abstract: Many factors affect battery’s state of charge (SOC), such as temperature, charge/discharge rate, cycle life and so on.Extended Kalman filter (EKF) iscommonly used to estimate battery’s SOC.The observation equation’s error affects the accuracy of battery’s SOC estimationusing traditional EKF.Considering the effects of temperature and charge/discharge rateon the observation equation’s error, an SOC estimation method using EKF based on fuzzy controlis presented.Mamdani type fuzzy controller is establishedwiththe proposed method, in which temperature and charge/discharge rateare selected as thecontroller’sinput, and the observation matrix’s correction coefficient isused as thecontroller’s output to improvethe filtering process in real time.The simulationresults show that …

Recycling Licoo2 With Methanesulfonic Acid For Regeneration Of Lithium-Ion Battery Electrode Materials., Bin Wang, Xin-Ye Lin, Yuanyuan Tang, Qiang Wang, Michael K.H. Leung, Xiao-Ying Lu

Faculty of Science & Technology (THEi)

With the massive consumption of lithium-ion batteries in portable consumer electronics and electric vehicles, proper disposal of spent batteries is of paramount importance for sustainable development. In this study, biodegradable organic methanesulfonic acid (MSA) is investigated for the first time to leach valuable metals from waste LiCoO2 powders for battery material regeneration. Under the optimal conditions, leaching efficiencies of lithium and cobalt are achieved at nearly ∼100% and ∼100%, respectively. Comparison experiment indicates that MSA can achieve better leaching performance than previously reported organic acids (e.g. citric acid, malonic acid, succinic acid, oxalic acid) under the same conditions. Besides, strong …

Lignin-Derived Carbon And Nanocomposite Materials For Energy Storage Applications, Wenqi Li

Theses and Dissertations--Biosystems and Agricultural Engineering

With a growing demand for electrical energy storage materials, lignin-derived carbon materials have received increasing attention in recent years. As a highly abundant renewable carbon source, lignin can be converted to a variety of advanced carbon materials with tailorable chemical, structural, mechanical and electrochemical properties through thermochemical conversion (e.g. pyrolysis). However, the non-uniformity in lignin structure, composition, inter-unit linkages and reactivity of diverse lignin sources greatly influence lignin fractionation from plant biomass, the pyrolysis chemistry, and property of the resulting carbon materials.

To introduce a better use of lignocellulosic biomass to biofuels and co-products, it is necessary to find novel …

Ac-Impedance Investigations Of Li-Ion Batteries With Wide Temperature Performance, Huainan Qu

Theses and Dissertations

Solid electrolyte interphase (SEI) of lithium-ion batteries in three electrode pouch cells was studied by using electrochemical impedance spectroscopy (EIS). Two kinds of electrolytes were used for the comparison purpose. Electrochemical impedance of individual electrodes and the full cell was measured in various state of aging, charge and temperature conditions. The equivalent circuit was identified through distribution of relaxation times (DRT), and then used to fit the impedance data. The results show that majority of the full cell impedance at -20℃ arises from anode SEI.

The Effects Of Atmospheric Heat Treatments On Tio2 Nanotube Anodes For Lithium-Ion Batteries, Andreas Savva

Boise State University Theses and Dissertations

The effects of various heat treatments on the physical and electrochemical properties of anatase TiO₂ nanotubes were studied in this work. Well-ordered TiO₂ nanotubes were grown via electrochemical anodization and annealed at 450°C to induce a phase transformation to anatase. The heat treatments were conducted under atmospheres of O₂, Ar, N₂, and water vapor (WV) to create different point defects. The oxygen-deficient atmospheres were used to generate oxygen vacancies in the TiO₂ nanotubes, while the water vapor treatment was used to create Ti vacancies by stabilizing them via the protonation of O sites. …

Synthesis And Electrochemical Properties Of Nickel-Rich Cathode Material Lini0.6Co0.2Mn0.2O2 With High Initial Coulombic Efficiency, Xiao-Yun Guan, Chao-Yu Hong, Jian-Ping Zhu, Wei-Li Wang, Yi-Xiao Li, Yong Yang

Journal of Electrochemistry

Nickel-rich cathode materials LiNi_0.6Co_0.2Mn_0.2O₂（NCM622）were synthesized by a co-precipitation-solid state sintering method at different temperatures. The structure, morphology and electrochemical performance of the as-prepared materials were investigated by X-ray powder diffraction (XRD) /Rietveld refinement, scanning electron microscope (SEM) and electrochemical experiments. It is found that NCM622 calcined at 800 ℃ showed the lowest degree of cation disorder (~1.97%) with a high initial Coulombic effiency of 92.2% and the capacity retention of 81.4% after 100 cycles.

Advanced Energy Storage Technologies And Their Applications (Aesa2017), Rui Xiong, Hailong Li, Xuan Joe Zhou

Electrical & Computer Engineering Publications

The depletion of fossil fuels, the increase of energy demands, and the concerns over climate change are the major driving forces for the development of renewable energy, such as solar, wind and wave energy. However, the intermittency of renewable energy has hindered its large-scale deployment, which, therefore, has necessitated the development of advanced energy storage technologies. The use of large-scale energy storage can effectively improve the efficiency of energy resource utilization, and increase the adoption of variable renewable resources, the energy access, and the end-use sector electrification (e.g., electrification of transport sector).

Advanced Energy Storage Technologies And Their Applications (Aesa2017), Rui Xiong, Hailong Li, Xuan Joe Zhou

Electrical & Computer Engineering Publications

This editorial summarizes the performance of the special issue entitled Advanced Energy Storage Technologies and Applications (AESA), which is published in MDPI’s Energies journal in 2017. The special issue includes a total of 22 papers from four countries. Lithium-ion battery, electric vehicle, and energy storage were the topics attracting the most attentions. New methods have been proposed with very sound results.

Research Progress In Cycle Stability Of Silicon Based Li-Ion Battery Anodes, Ze-Liang Guo, Hui Wu

Journal of Electrochemistry

Silicon(Si), with the highest specific capacity currently known, is a promising anode material for Li-ion battery. However, in the charging and discharging process, with Li atoms inserting into and breaking out of the Si crystal lattices, the Si anode undergoes enormous volume expansion and contraction, ending in pulverization. The fact that the specific capacity of bulk Si anodes drop quickly is a challenging problem. In this review, we summarize recent progresses in Si anode. We concern about the nanostructure of silicon, cooperation of silicon with other additives and macrostructure design of anodes. We discuss strengths and shortcomings of different methods, …

High-Throughput Mechanical Characterization Methods For Composite Electrodes And In-Situ Analysis Of Li-Ion Batteries, Luize Scalco De Vasconcelos

Open Access Theses

Electrodes in commercial rechargeable batteries are microscopically heterogeneous materials. The constituents often have large variation in their mechanical properties, making the characterization process a challenging task. In addition, the mechanical properties and mechanical behaviors of electrodes are closely coupled with the electrochemical processes of lithium insertion and extraction. There is an urgent need to develop an experimental platform to characterize the chemomechanical response of electrodes under the in-situ conditions of charge and discharge.

In the first part of this thesis, instrumented grid indentation is employed to determine the elastic modulus and hardness of the constituent phases of a composite cathode. …

Silicon Anode Materials For Next Generation Lithium-Ion Batteries, Qizheng Li

Electronic Thesis and Dissertation Repository

Lithium Ion Batteries (LIBs) are a promising green energy storage system with application toward portable electronic devices, electronic vehicles (EVs) and smart grid energy storage. High energy density is one of the most important advantages for LIB, however, improvements toward performance measures, such as energy density, power and rate capability, cycling life, safety and cost, need to meet the different requirements for various applications. It is well known that battery performance is highly dependent on the type of electrode material that is employed. Currently most LIBs are predominantly fabricated using graphite as an anode material. Therefore, finding a qualified candidate …