Engineering Commons^™

Simulations Of Electrode Heterogeneity And Design For Lithium-Ion Batteries, Amir Sina Hamedi

Theses and Dissertations

This work develops three models for simulation of the high-current operation of Li-ion batteries. Simulation as a tool can provide understanding beyond what experiments can offer. Different types of electrodes such as graphite, silicon, and NMC are modeled to study cell performance and aging under aggressive operating conditions. The first part of this work focuses on the effect of electrode microscale lateral heterogeneity on the degradation of conventional Li-ion batteries, especially for fast-charge applications. The non-uniform pore distribution leads to the nonuniform current density and state of charge (SoC), which can finally result in non-uniform Li plating and aging. The …

Production Of Lithium Carbonate From Geothermal Brine By Selective Extraction Of Lithium Using A Novel Ion Sieve Method, Ujjwal Pokharel, Sandeep Kumar

College of Engineering & Technology (Batten) Posters

The project implements a novel approach to extract lithium from a geothermal brine with minimal water loss. Production of high-capacity lithium-ion (Li-ion) batteries for electric vehicles (EV) is believed to be the way to reduce dependence on fossil-fuel based vehicles. Currently, most of the lithium in the world comes from the mining of lithium or the evaporative/concentration of the brine. Mining is not environmentally friendly, and the evaporative process takes 12 months for the completion of the extraction process and results in a large amount of water loss which can lead to scarcity of water. The brines constitute 82% of …

Open-Circuit Voltage Models For Battery Management Systems: A Review, Prarthana Pillai, Sneha Sundaresan, Pradeep Kumar, Krishna R. Pattipati, Balakumar Balasingam

Mechanical, Automotive & Materials Engineering Publications

A battery management system (BMS) plays a crucial role to ensure the safety, efficiency, and reliability of a rechargeable Li-ion battery pack. State of charge (SOC) estimation is an important operation within a BMS. Estimated SOC is required in several BMS operations, such as remaining power and mileage estimation, battery capacity estimation, charge termination, and cell balancing. The open-circuit voltage (OCV) look-up-based SOC estimation approach is widely used in battery management systems. For OCV lookup, the OCV–SOC characteristic is empirically measured and parameterized a priori. The literature shows numerous OCV–SOC models and approaches to characterize them and use them in …

Modeling Hierarchical Porous Electrodes With Tailored Anisotropic Structure, Debanjan Sarker

All Theses

Modern electric vehicles and consumer electronics applications demand high specific energy from Li-ion batteries, which can be charged and discharged faster. In the search for high specific energy, researchers have tried to make thicker battery electrodes which contain a greater proportion of active material. While chemical and structural modification of electrodes can help to increase the electronic conductivity of active material, the microstructure of porous electrodes can be engineered to enhance ion transport for fast charge and discharge. Previous research has shown that macropores introduced by directional freeze tape casting can enhance the performance of thick porous electrodes. For instance, …

Understanding Microstructure Heterogeneity In Li-Ion Battery Electrodes Through Localized Measurement Of Ionic Transport, Baichuan Liu

Theses and Dissertations

Electrode microstructure influences ionic transport and electronic transport and is a key factor that affects lithium-ion battery performance. Non-uniform microstructure or heterogeneity in battery electrodes has long been observed and leads to non-uniform transport properties. This work provides a better understanding of in-plane heterogeneity at millimeter length scale and through-plane heterogeneity at micrometer length scale, through a combination of experiment and modeling. The first part of this work develops the aperture probe technique, which is an experimental method and associated model to locally estimate ionic transport, represented by MacMullin number, in the electrode. By generating contour maps of MacMullin number, …

Study And Improvement On Expansion Property Of Silicon Oxide, Wei-Chuan Qiao, Fang-Ru Li, Jin-Lin Xiao, Li-Juan Qu, Xiao Zhao, Meng Zhang, Chun-Lei Pang, Zi-Kun Li, Jian-Guo Ren, Xue-Qin He

Journal of Electrochemistry

The silicon-based anode materials have the potential to meet the ever-increasing demand for energy density in lithium-ion batteries market owing to their high theoretical specific capacity. Unfortunately, their commercialization was hindered by the continuous volume expansion. Herein, the expansion characteristics and corresponding mechanism of the silicon oxide and graphite-silicon oxide composites were investigated by in-situ displacement detection systematically. The results showed that the expansion property was improved by material process modifications. During the de/lithiation processes of graphite, the expansion ratio in 30% ~ 50% SOC changed little because of the small interlayer spacing variation of the intercalated graphite. …

Efficient Flatness Based Energy Management Strategy For Hybrid Supercapacitor/Lithium-Ion Battery Power System, Salam J. Yaqoob, Seydali Ferahtia, Adel Obed, Hegazy Rezk, Naseer Tawfeeq Alwan, Hossam Zawbaa, Salah Kamel

Articles

This article offers a flatness theory-based energy management strategy (FEMS) for a hybrid power system consisting of a supercapacitor (SC) and lithium-ion battery. The proposed FEMS intends to allocate the power reference for the DC/DC converters of both the battery and SC while attaining higher effciency and stable DC bus voltage. First, the entire system model is analyzed theoretically under the differential flatness approach to reduce the model order as a at system. Second, the proposed FEMS is validated under different load conditions using MATLAB/Simulink. Thus, this FEMS provides high-quality energy to the load and reduces the fluctuations in the …

Understanding The Relationships Between Ion Transport, Electrode Heterogeneity, And Li-Ion Cell Degradation Through Modeling And Experiment, Fezzeh Pouraghajansarhamami

Theses and Dissertations

Electrode microstructure directly affects ion and electron transport and, in turn, has a strong correlation to battery performance. Understanding the separate yet complementary effects of ionic and electronic transport in cell behavior is a challenge. This work provides through a combination of experiments and modeling a better understanding of the relationship between three aspects of the cell: ion transport within the electrode, electrode uniformity, and cell degradation. The first part of this work compares two experimental methods that determine ion transport in terms of tortuosity, a dimensionless geometric factor. The polarization-interrupt and blocking-electrolyte methods measure effective diffusivity and conductivity, respectively. …

Measurement Of Stresses And Their Effect On Transport In Thin Film Battery Electrodes, Subhajit Rakshit

Dissertations

At the moment, there is a significant push towards environmentally friendly energy production and gasoline-free transportation technologies. As a result, there is a renewed interest in energy storage devices such as lithium-ion batteries which will play a key role in providing energy storage capability for these applications. However, the current battery technology is reaching its limits and may not meet future energy storage demands. The increased demand and the limited lithium reserves in geographically remote areas of the earth will lead to higher cost of Li. The alternative battery technologies, such as sodium-ion batteries, are promising due to their low …

Modeling And Simulation Of A Utility-Scale Battery Energy Storage System, Oluwaseun M. Akeyo, Vandana Rallabandi, Nicholas Jewell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper presents the modeling and simulation study of a utility-scale MW level Li-ion based battery energy storage system (BESS). A runtime equivalent circuit model, including the terminal voltage variation as a function of the state of charge and current, connected to a bidirectional power conversion system (PCS), was developed based on measurements from an operational utility-scale battery demonstrator. The accelerated response of the battery unit was verified by pulse discharging it from maximum to minimum SOC and its application for grid resiliency was demonstrated through an example droop control frequency response. For the purpose of validating the equivalent BESS …

Power Utility Tests For Multi-Mw High Energy Batteries, Oluwaseun M. Akeyo, Huangjie Gong, Vandana Rallabandi, Nicholas Jewell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper reviews the procedures, layouts and metrics described in the new test manual issued by the Electric Power Research Institute (EPRI), in order to determine the performance and functionality of a utility scale battery energy storage system (BESS). In this approach, the large battery unit is connected to the dc-link of a bidirectional power conversion system (PCS), which may be interfaced with either the utility grid or a load bank for the purpose of estimating the BESS operation and performance characteristics, some of which includes; available charge/discharge energy at rated power, continuous charge/discharge duration, battery ramp rate, and ac …

Hybrid Battery-Capacitor System Based On Liti5O12 Anode And Ptpan Cathode, Xiu-Li Su, Xiao-Li Dong, Yao Liu, Yong-Gang Wang, Ai-Shui Yu

Journal of Electrochemistry

Owing to its high safe, high rate and long life characteristics, lithium titanate (Li₄Ti₅O₁₂) anode material has attracted extensive attention in recent years, and many efforts are being made to develop the Li₄Ti₅O₁₂ based high performance hybrid supercapacitors and Li-ion batteries. Herein, we prepared the organic cathode material polytriphenylamine (PTPAn) through chemical oxidation and polymerization of triphenylamine (TPAn), and investigated its charge storage mechanism and electrode kinetics withthe typical electrochemical methods in an organic electrolyte. It was demonstrated that the PTPAn exhibited the reversible capacity of 85 mA·g^{-1 …}

Simulation And Experiments To Understand The Manufacturing Process, Microstructure And Transport Properties Of Porous Electrodes, Mohammad Mehdi Forouzan

Theses and Dissertations

Battery technology is a great candidate for energy storage applications. The need for high-performance and cost-effective batteries has motivated researchers to put much effort into improving battery performance. In this work, we attempt to understand the elements that affect the microstructure and performance of two battery systems. The first part of this work focuses on the investigation of transport and structural properties of porous electrodes in an alkaline electrolyte. A DC polarization method was deployed for tortuosity measurements. An apparatus was designed to flow specified current through and measure the voltage drop over the porous electrodes. Using a modified Ohm's …

A Bayesian Network Approach To Battery Aging In Electric Vehicle Transportation And Grid Integration, Mehdi Jafari

Dissertations, Master's Theses and Master's Reports

Nowadays, batteries in electric vehicles (EVs) are facing a variety of tasks in their connection to the power grid in addition to the main task, driving. All of these tasks play a very significant role in the battery aging, but they are highly variable due to the change in the driver behavior, grid connection availability and weather conditions. The effect of these external factors in the battery degradation have been studied in literature by mostly deterministic and some stochastic approaches, but limited to specific cases.

In this dissertation, first, a large-scale deterministic approach is implemented to evaluate the effect of …

Capacity Fading Analyses Of Lini 0.5Co 0.2Mn 0.3O2And Lini 0.5Co 0.2Mn 0.3O2/Lifepo4 Cathode Materials For Lithium-Ion Battery, Yi Hu, Xiang-Zhu He, Zhong-De Deng, Ling-Yong Kong, Wei-Li Shang

Journal of Electrochemistry

The LiNi _0.5Co _0.2Mn _0.3O₂/LiFePO₄ (NMC532/LFP) composite cathode material for lithium-ion battery was prepared by wet ball-milling. The capacity fading behaviors of LiNi _0.5Co _0.2Mn _0.3O₂ (NMC532) and LiNi _0.5Co _0.2Mn _0.3O₂/LiFePO₄ (NMC532/LFP) were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM), charge/discharge and electrochemical impedance spectroscopy (EIS) tests. The results indicated that the capacity retention values of NMC532/LFP were 97.80% and 86.48%, respectively, after 50 cycles and 60℃ high temperature storage. The NMC532/LFP exhibited better cycle performance and high temperature storage performance. …

Comparison Of Lithium-Ion Anode Materials Using An Experimentally Verified Physics-Based Electrochemical Model, Rujian Fu, Xuan Joe Zhou, Hengbin Fan, Douglas Blaisdell, Ajay Jagadale, Xi Zhang, Rui Xiong

Electrical & Computer Engineering Publications

Researchers are in search of parameters inside Li-ion batteries that can be utilized to control their external behavior. Physics-based electrochemical model could bridge the gap between Li+ transportation and distribution inside battery and battery performance outside. In this paper, two commercially available Li-ion anode materials: graphite and Lithium titanate (Li4Ti5O12 or LTO) were selected and a physics-based electrochemical model was developed based on half-cell assembly and testing. It is found that LTO has a smaller diffusion coefficient (Ds) than graphite, which causes a larger overpotential, leading to a smaller capacity utilization and, correspondingly, a shorter duration of constant current charge …

Dft Study On The Li Mobility In Li-Ion-Based Solid-State Electrolytes, Shafiqul Islam

MSU Graduate Theses

I have investigated the diffusion mechanisms of Li-ion in amorphous lithium phosphite (LiPO₃) with addition of sulphur. By applying the nudge elastic band (NEB) method in crystal LiPO₃ and Li₃PO₄, I confirmed the easing of diffusion pathways for Li ion in LiPO₃ which is consistent with the previous theoretical finding[1]. From the diffusion study in 0.5 Li₂O- 0.5 P₂O₅ and 0.4 Li₂SO₄ – 0.6 (Li₂O-P₂O₅) melts above 3000K performed with ab-initio molecular dynamics (AIMD), produces identical outcome as …

Renewable Carbon From Lignin Biomass And Its Electrode And Catalyst Applications In Batteries, Supercapacitors, And Fuel Cells, Muslum Demir

Theses and Dissertations

Over the last century, almost all of the carbon materials developed for the energy industry are derived from fossil fuels. The growing global concerns about energy needs, fossil fuels consumption, and the related environmental issues have motived scientists to find new, green and sustainable energy resources such as the wind, solar and biomass energy. Essentially, biomass-derived materials can be utilized in energy storage and conversion devices such as Li-ion batteries, fuel cells, and supercapacitors. Among the biomass resources, lignin is a high volume byproduct from the pulp and paper industry and is currently burned to generate electricity and steam. The …

Modelling And Simulation Of Grid Connected Lithium-Ion Battery Using Homer, Shantu Ghose, Adel El-Shahat

Department of Electrical & Computer Engineering Faculty Research & Publications

In order to improve battery technology understanding the capacity fading method in batteries is very important. Battery models can be used to predict their behavior under various operating conditions. Here we proposed a simple dynamic model of lithium-ion battery with MATLAB/Simulink to observe the output characteristics of this energy storage device. Dynamic simulations are carried out, including the observation of the changes in battery terminal output voltage under different discharging/charging, temperature and cycling conditions. The simulation studies are presented for proving that the model is useful. At the end we will use this energy storage device to interconnect with HOMER. …

Printing 3d Lithium-Ion Microbattery Using Stereolithography, Qiming Chen

Open Access Theses

Microbatteries have been gained a lot of importance since the development of micro- and nanotechnologies. Integrating the microbattery system will enable a variety of applications, such as implantable biomedical devices and wireless sensor networks. In this paper, we demonstrated a new method to fabricate three dimensional lithium-ion microbattery using stereolithiography. A UV-curable gel polymer electrolyte resin is first synthesized and characterized. The electrolyte resin is then applied to build into 3D architecture by stereolithography. The gel electrolyte structure is designed into a zigzag shape in order to improve the contact area between electrode and electrolyte. Battery's active material, LiFePO4 (LFP) …

Research Progress Of Mn-Based Lithium-Rich Cathode Materials For Li-Ion Batteries, Luo-Zeng Zhou, Qun-Jie Xu, Wei-Ping Tang, Xue Jin, Xiao-Lei Yuan

Journal of Electrochemistry

With rapid development of new energy industry like electric vehicles and energy storage station, these fields highly demand the next generation of high performance Li-ion battery systems with stronger energy density, higher power density, and longer cycling life. Lithium-rich Mn-based cathode materials, xLi₂MnO₃·(1-x)LiMO₂(M=Mn, Co, Ni...), have become the hot topic and drawn attentions of scholars worldwide because of their high reversible capacity exceeding 240 mAh·g^-1, excellent electrochemical properties, and low cost, which makes them most promising cathode material candidates for next Li-ion battery system. The cathode material Li[Li_0.2Mn_0.54Ni …

Effects Of Neutron And Gamma Radiation On Lithium-Ion Batteries, Jie Qiu, Dandan He, Mingzhai Sun, Shimeng Li, Cun Wen, Jason Hattrick-Simpers, Yuan Zheng, Lei Cao

Jason R. Hattrick-Simpers

No abstract provided.

The Effect Of Microstructure On Transport Properties Of Porous Electrodes, Serena Wen Peterson

Theses and Dissertations

The goal of this work is to further understand the relationships between porous electrode microstructure and mass transport properties. This understanding allows us to predict and improve cell performance from fundamental principles. The investigated battery systems are the widely used rechargeable Li-ion battery and the non-rechargeable alkaline battery. This work includes three main contributions in the battery field listed below.

Direct Measurement of Effective Electronic Transport in Porous Li-ion Electrodes. An accurate assessment of the electronic conductivity of electrodes is necessary for understanding and optimizing battery performance. The bulk electronic conductivity of porous LiCoO2-based cathodes was measured as a …

Aqueous Solution-Evaporation Route Synthesis And Phase Structural Research Of The Li-Rich Cathode Li1.23Ni0.09Co0.12Mn0.56O2 By In-Situ Xrd, Chong-Heng Shen, Shou-Yu Shen, Zhou Lin, Xiao-Mei Zheng, Hang Su, Ling Huang, Jun-Tao Li, Shi-Gang Sun

Journal of Electrochemistry

The Li-rich Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ material was synthesized via aqueous solution-evaporation route. The structure and morphology of the material were characterized by means of XRD and SEM. The results indicated that the single particle of the product was polygonal with the size of 330 nm and the structure was layered solid solution with a certain amount of Li₂MnO₃. Electrochemical tests showed that the first discharge capacity of the Li-rich layered material was 250.8 mAh·g^-1 at 0.1C，the capacity retention was 86.5% after 40 cycles. Through in-situ XRD study a …

Effects Of Fluoroethylene Carbonate Additive On Low Temperature Performance Of Li-Ion Batteries, Feng-Ju Bian, Zhong-Ru Zhang, Yong Yang

Journal of Electrochemistry

The effects of fluoroethylene carbonate (FEC) on the low temperature performance of lithium ion phosphate full battery are evaluated by different techniques. By addition of 5 wt% FEC into a commercial electrolyte, effective solid electrolyte interface (SEI) film can be formed on the graphite electrodes, the discharge capacity retention at -40 ^oC was increased from 31.7% to 43.7%, and the discharge voltage plateau of the cell is raised. This is attributed to a reduced charge transfer resistance and a lowered polarization on the graphite electrode by electrochemical impedance spectroscopy (EIS) and reference electrode test.

Synthesis Of Lifepo4/C Cathode By Sol-Gel And Calcining Method With Chitosan Monomer, Jia Xu, Yan-Yan Wang, Rui Wang, Bo Wang, Yue Pan, Dian-Xue Cao, Gui-Ling Wang

Journal of Electrochemistry

The LiFePO₄/C cathode materials for Li-ion battery were synthesized by sol-gel and calcining method using chitosan monomer as a carbon source and a gelating agent. The structures and morphologies were characterized by X-ray diffraction spectroscopy (XRD) and scanning electron microscopy (SEM). The electrochemical performance was investigated by the galvanostatic charge–discharge test. When the molar ratios between chitosan monomer and LiFePO₄ were 1:1.2, the LiFePO₄/C cathode calcined at 600 ^oC showed the best performance. The particle sizes ranged 200 ～ 400 nm. The initial discharge capacity of 155 mAh.g-¹ was achieved at room temperature …

Synthesis And Electrochemical Properties Of High-Capacity Cathode Material 0.08lico0.75Al0.25O2-0.92linio2, Ru-Ying Wang, Tian Qiu, Chong Mao, Wen-Sheng Yang

Journal of Electrochemistry

CoAl-LDH or Co(OH)₂ coated spherical Ni(OH)₂ precursors were obtained via a co-precipitation method at a constant pH. The mixtures of the precursors and LiOH.H₂O were annealed at high temperature in O₂ atmosphere, and then the cathode materials of 0.08LiCo_0.75Al_0.25O₂-0.92LiNiO₂, 0.08LiCoO₂-0.92LiNiO₂ and LiNiO₂ were synthesized. Effects of the coating layer were also studied. The results showed that the 0.08LiCo_0.75Al_0.25O₂-0.92LiNiO₂ material possessed the best rate and cycle life performance. The discharging capacities at 0.1C, 0.5C and 3C were …

Electrochemical Performances Of Carbon-Coated Na2ti6o13 Nanotubes, Guo-Ran Li, Shuai Sun, Xue-Ping Gao

Journal of Electrochemistry

With rutile TiO2 and NaOH as starting materials, the Na2Ti6O13 nanotubes were prepared by a hydrothermal reaction. The carbon-coated Na2Ti6O13 nanotubes were obtained by treating the Na2Ti6O13 nanotubes for 4 h in glucose aqueous solutions containing 0.1 mol?L-1 NaOH. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microcopy (TEM). The results showed that the dimensions of carbon-coated Na2Ti6O13 nanotubes were 14 ~ 19 nm of outer diameter, 2 ~ 5 nm of inner diameter, and several hundreds nanometers of length with a carbon layer of about 2 nm being coated on outer …

Low-Temperature Performance Of Li-Ion Battery With Fluoroethylene Carbonate Electrolyte, Chun-Wei Yang, Feng Wu, Bo-Rong Wu, Yong-Huan Ren, Jing-Wen Yao

Journal of Electrochemistry

The low temperature performance of electrolytes containing FEC including FEC+EMC,EC and PC,as well as the compatibility of electrolytes with LiFePO4 anode and with MCMB cathode were investigated.The electrolyte exhibits a high value of ionic conductivity at low temperature.The stability of cathode was enhanced by the formation of SEI film at 1.6 V as a result of FEC reaction.The infrared spectra showed that FEC can suppress decomposition of other solvents during SEI formation,and lower the resistance of SEI on MCMB cathode.The electrochemistry test indicates that Li-ion batteries with FEC electrolyte display high capacity at low temperature and better rate performance.

V2o5-Wo3 Composite Films And Surface-Coated Licoo2 For Enhanced Li-Ion Intercalation Properties, Chuan Cai

LSU Master's Theses

We have investigated the enhanced Li-ion intercalation properties of two different materials, which are V2O5-WO3 composite and surface-coated LiCoO2. A simple and novel solution processing method is employed to prepare V2O5-WO3 composite films that demonstrate enhanced Li-ion intercalation properties for applications in Li-ion batteries or electrochromic displays. This solution processing method employs precursors that only contain the elements of V, W, O and H, which avoids impurity elements such as Na that has been commonly used in other solution methods (e.g. using precursors of sodium metavanadate and sodium tungstate solution). The V2O5-WO3 composite films show enhanced Li-ion intercalation properties compared …