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Full-Text Articles in Engineering

Multiscale Modeling Approach To Understand Active Sites In Non-Conventional Catalyst Layers For Fuel Cell Applications, Diana Constanza Orozco Gallo Dec 2017

Multiscale Modeling Approach To Understand Active Sites In Non-Conventional Catalyst Layers For Fuel Cell Applications, Diana Constanza Orozco Gallo

Doctoral Dissertations

Fuel cells development required stable, active and more abundant catalytic materials. Oxygen reduction reaction (ORR) is the key process to enhance better activity and reduce the fabrication costs. Pt-based has proven to be the best catalyst for ORR and greater efforts has been made in terms of reducing the Pt content in the electrodes, reduce electrode thickness and enhance better catalytic activities. To overcome many of the challenges present, the catalyst layer studies are the great importance in the fuel cell community. Understanding catalyst layer with new catalytic materials, and configurations requires the development of methodological approach to relate structure, …


Structural, Interfacial, And Electrochemical Properties Of Pr2nio4+Δ – Based Electrodes For Solid Oxide Fuel Cells, Emir Dogdibegovic Jan 2017

Structural, Interfacial, And Electrochemical Properties Of Pr2nio4+Δ – Based Electrodes For Solid Oxide Fuel Cells, Emir Dogdibegovic

Theses and Dissertations

Currently, the electrochemical performance and performance durability of solid oxide fuel cells (SOFCs) are limited by cathode materials. The high polarization resistance and phase instability of the cathode are two major challenges to hinder the commercialization of SOFC systems. Two families of oxides are presently known as potential cathode materials for SOFCs: (1) the perovskite family of oxides with a general formula of ABO3, and (2) the Ruddlesden-Popper (RP) family of oxides (e.g. nickelates) with a general formula of A2BO4. The electron-hole conduction in these materials occurs simultaneously with oxygen ion conduction based on …