Engineering Commons^™

Mass Spectrometry Analysis Of Contaminants Of Emerging Concern: Nanoparticles, Algal Toxins, And Cyanotoxins In Natural Waters And Their Potential Health Impacts, Ariel R. Donovan

Doctoral Dissertations

“The analysis of contaminants of emerging concern is critical to protecting environmental health. In the presented dissertation, two groups of contaminants of emerging concern were assessed using mass spectrometry methods: nanoparticles and algal and cyanotoxins.

Analysis of metal oxide nanoparticles in environmental matrices has been a challenging issue, as most traditional methods require complicated sample preparation methods or that can alter or destroy the nanoparticles in the system. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) methods were used to detect metal oxide nanoparticles in surface waters and their removal through drinking water treatment simulations while retaining all information regarding …

Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino

Civil & Environmental Engineering Theses & Dissertations

The longitudinal dispersion coefficient is a parameter used to evaluate the effect of cross-sectional variations on substance mixing mechanisms in estuaries influenced by tide, wind and internal density variations. Considering a two dimensional approach, this study aims at evaluating a tidal area of the lower James River at approximately 19 miles upstream from the mouth at the Chesapeake Bay, in the City of Newport News, and applies an experimental procedure based on in-situ salinity concentrations to estimate the dispersion coefficient in the area where receives a discharge from the HRSD James River Wastewater Treatment Plant, and further characterizes Total Suspended …

Spatiotemporal Estuarine Water Quality Parameterization Using Remote Sensing And In-Situ Characteristics, Kwisun Park Yu

Civil & Environmental Engineering Theses & Dissertations

This dissertation develops a new paradigm in a water quality monitoring approach to parameterize spatiotemporal estuarine water quality with sustainable reliability, less cost and less time. A key underpinning of this paradigm of the spatiotemporal estuarine water quality parameterization is various water quality parameters' interrelationship with ambient water temperature as a common factor, their time dependent characteristics, and spatiotemporal characteristics of remote sensing. It has two core models to provide input data of water quality parameterization model in a system; the transfer function models of the physical system and an analytical temperature time series model. The objective of this dissertation …

Estuarine Influence On Tidally Driven Circulation In The South Atlantic Bight, Peter Bacopoulos

Electronic Theses and Dissertations

A high-resolution, finite element-based, shallow water equation model is developed to simulate the tides in the South Atlantic Bight. The model is constructed to include all of the estuarine features along the southeastern United States seaboard: coastal inlets, rivers and tidal creeks, sounds and lagoons, intertidal zones including salt marshes and mangrove swamps, and the Atlantic Intracoastal Waterway. The estuaries are represented in the finite element mesh using triangular elements with side lengths on the order of tens of meters. Also incorporated into the model is a spatially distributed bottom friction parameterization, based on the various landcover and benthic characteristics …

Wind-Induced Exchange In Semi-Enclosed Basins, Rosario Sanay

OES Theses and Dissertations

The wind-induced circulation over laterally varying bathymetry was investigated in homogeneous and in stratified systems using the three-dimensional Regional Ocean Model (ROMS). For homogeneous systems, the focus was to describe the influence of the earth's rotation on the lateral distribution of the flow with particular emphasis on the transverse circulation. Along-basin wind-stress with no rotation caused a circulation dominated by an axially symmetric transverse structure consisting of downwind flow over the shoals and upwind flow in the channel along the whole domain. Transverse circulation was important only at the head of the system where the water sank and reversed direction …